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Mineral formations, accumulated during technogenic activities greatly influence an economic and ecological situation in the Kola North. On the one hand, the dumps from extraction of mineral resources, tailing ponds of beneficating plants, ash dumps, wastes of metallurgical and mechanical engineering productions destroy the regionÆs environment and require taking certain measures and costs to bury or protect from weathering, oxidation, etc. On the other hand, technogenic mineral formations contain a lot of valuable scarce components. The amount of solid wastes increases annually, causing damage to ecology and economy. Researches conducted in recent years showed a possibility and economic expediency of comprehensive processing of wastes from different enterprises in Murmansk region and their use for production of new competitive commodity output, possessing high consumer properties. Thus, involving mineral wastes from Khibiny apatite deposits into hydrometallurgical industrial processing provides the basis for setting up a large beneficating-metallurgical complex. In this case ores and wastes from other deposits on the Kola Peninsula, containing titanium, rare, rare-earth and other valuable elements, may be involved into processing. Establishing such a complex will allow to organise a deep processing of natural resources, utilise some production wastes, improve ecological security and supply production with competitive output. Expanding the complex implies not only involving new mineral raw material into processing, but mainly deepening raw material processing, maximum utilisation of local natural resources and obtaining a wider variety of prime products.

Jan 1, 2002

By George Mylonakis

The curvatures and subsequent bending imposed to piles by the surrounding soil during the passage of strong seismic waves is studied. This type of bending develops even in the absence of a superstructure and is referred to as "kinematic bending", to distinguish it from bending imposed to piles by loads generated from the inertia of the superstructure ("inertial bending"). Although kinematic loading may be severe in the presence of sharp stiffness discontinuities in the profile and may lead to damage, it has received little attention by engineers. The scope of the paper is twofold: (i) to discuss some fundamental aspects of seismic pile bending, and (ii) to review some existing design methods. To this end, a dimensionless bending strain parameter (instead of the more commonly used bending moment), and a strain transmissibility function relating pile bending strain and corresponding soil shear strain are introduced. Numerical examples are also presented.

Jan 1, 2002

By C. A. Young, J. D. Miller

The surface chemistry of the calcite/oleate flotation system was examined by in-situ FT-NIR/IRS. Spectra of combination and overtone bands of aliphatic stretching vibrations revealed gauche/trans conformational changes that occurred solely as a function of temperature. The conformational changes were attributed to the simple "melting" behavior associated with phase transitions. It was concluded that chemisorbed oleate at calcite surfaces is gel-like at temperatures below 22oC, resembles a coagel between 22oC and 31oC, and becomes micelle-like at temperatures above 31oC. By comparison, chemisorbed oleate at fluorite surfaces also undergoes these phase transitions but is additionally dependent on adsorption density. The conformational changes were observed at high chemisorption densities (> 2.0x10-10 mol/cm2) and attributed to molecular forces, primarily van der Waal's interactive forces, among neighboring chemisorbed oleate molecules. Similar analysis of in-situ FT-NIR/IRS spectra of surface-precipitated calcium dioleate at calcite surfaces did not exhibit this behavior thereby confirming that surface-precipitated calcium dioleate remains in an all-trans conformation. The results help explain why surface polymerization is not observed at calcite surfaces but is observed at fluorite surfaces.

Jan 1, 2002

By Anthony D. Hammond

Geographic Information Systems (GIS) are powerful analytical and data display tools for mining industry management, capable of linking spatial features with tabular data and integrating communications across departmental boundaries. This GIS application concentrates in four technical areas of underground mining: ownership and mineral claims; exploration management; production; and mine safety. GIS provides land and exploration managers with the ability to consolidate and archive claim data and to georeference property maps defined in local coordinates into world coordinate systems. It facilitates optimal siting and querying of service installations and refuge chambers relative to production centers. GIS's proximity analysis identifies areas of potential safety concern and points to and maps the shortest routes to emergency exits, facilitating the prompt evacuation of mine personnel.

Jan 1, 2002

By J. Kulas, J. Weaver, K. Hagley

An assessment of potential groundwater movement beneath the tailing impoundment at the Red Dog Mine was performed, and has indicated a unique aquifer situation within sub-permafrost groundwater at the site. The aquifer was shown to be isolated from both vertical recharge and a real discharge, and is characterized as a virtually no-flow system. The permafrost resulted in a deep aquifer with high tidal efficiency, meaning that variable surface loads are easily transmitted to the fluid. The tidal efficiency has been characterized through analysis of water level fluctuations that respond to earth tides, barometric pressure loads, and loading from the pond.

Jan 1, 2002

By Juha Järvi

Outokumpu Zinc Oy has two separate roasting lines with fluidized bed furnaces and waste heat boilers for calcine collection and heat recovery. During the last 30 years, zinc production in Kokkola plant has increased continuously and at the same time the raw materials have changed. Therefore, the waste heat boiler has been under continuous research and development. The waste heat boiler plays a significant role in the process and consequently the reliability and efficiency of the device is important for the effectiveness of the entire process. Many changes have been made to the boiler in the last decades. New radiation tube screens, tube bundles, and baffle-plate constructions have been added to the boiler and also rapping systems for the dust have been developed. The latest improvement to the boilers was a baffle wall, located in the middle of the radiation section roof in the first boiler, and baffle plates in the lower part of the convection section in the second boiler. The new boiler design and optimization were carried out using physical water and air-dust modeling as well as computational fluid dynamics. The modeling work agrees well with experiences in practice. The latest developments have increased the operating hours per year and the effectiveness of the waste heat boiler.

Jan 1, 2002

Numerical modelling was used to examine priming of bulk commercial explosives. Data for the HOM equation of state were calculated using a representative chemical composition, while Forest Fire model data were calculated, using a Pop plot which was estimated on the basis of existing sensitivity data, albeit for cap sensitive, small diameter explosives. The length and diameter of the primer, the location of the detonator in the primer and the shape of the primer form a set of parameters which are investigated. The effect of confinement and borehole diameter are also demonstrated, as reflections of shock waves create regions of high pressure in the explosive. The results are presented in terms of pressure and decomposition histories in the explosive and are interpreted in an engineering fashion to form rational suggestions for optimization of the priming process in the field.

Jan 1, 2002

By Zhijing Zhang

Long-term thermal stability of ionic liquids is essential for reliable performance of ionic liquids in any engineering applications. TGA studies were carried out on a series of ionic liquids with different cations and anions such as 1-butyl-3-methylimidazolium chloride ([C4mim]Cl), 1-hexyl-3-methylimidazolium chloride ([C6mim]Cl), 1-hexyl-3¬methylimidazolium tetrafluoborate ([C6mim]BF4), 1-hexyl-3-methylimidazolium hexafluorophosphate ([C6mim]PF6), 1-octyl-3-methylimidazolium hexafluorophosphate ([Csmim]PF6), and 1-butyl-3-methylimidazolium bis(trifluromethanesulflonyl)imide ([C4mim][Tf2N]). The short-term thermal stability of ionic liquids was evaluated by measuring the onset temperature of decomposition of ionic liquids, and the long-term thermal stability of ionic liquids was also evaluated by weight loss of ionic liquids over a long period of time at various temperatures. The experimental results showed that the long-term thermal stability of ionic liquids decreased with increasing temperature and was significantly lower than the onset temperature of decomposition of ionic liquids.

Jan 1, 2002

By J. Eldridge, A. J. Carter, D. N. Leavell

Minpro International has developed an innovative, flexible¬shaft impact crusher that produces glass aggregate from mixed¬color, post-consumer glass. The crusher operates with low power and generates a subangular aggregate, with minimal fines. Output is screened to yield sized aggregate, which can be used directly as surfacing material in Owens Corning's shingle process. Metal, plastic and paper waste is preferentially removed by the Minpro system. Duval County and the City of Jacksonville collect more than 12,000 tons of glass bottle waste per year. It is anticipated that a successful end-use application by Owens Corning, will allow increased collection and cost-effective glass recycling in north Florida.

Jan 1, 2002

By Karl A. Gschneidner

The magnetocaloric effect has been known for 120 years and has been utilized for cooling about 70 years. But in the last four years significant advances have been made to show that magnetic refrigeration is a viable and competitive cooling technology. Most of the work has focused on reciprocating devices, but rotary apparati are being developed. To date the magnetocaloric properties have been characterized for more than 200 materials. The magnetocaloric effect behaviors have been classified into three types of behaviors. The most common one is found in magnetic materials which exhibit a second order magnetic phase transition. Magnetic materials which exhibit a first order magnetic phase transition account for the second group of materials. Materials which exhibit multi-magnetic phase transitions make up the third group. The best candidate materials for magnetic cooling over the range from -4 to -1 350 K are also presented.

Jan 1, 2002

By B, J Bianchini, N Voermann, C Crowe

Operational and economic imperatives in the metallurgical industry have led to numerous advancements in furnace design. Modern furnaces provide high production rates, high percentage online time, long campaign life between rebuilds and safe operating conditions. Current trends for maximising plant efficiency include increasing the throughput of existing process vessels (often by a factor of two or more) and the use of newer, highly intense processes. In both instances, the process intensity results in the generation of higher heat fluxes to the crucible walls. High-intensity furnace operation with the objectives mentioned above has become possible with the following furnace design features: Strong sidewall cooling systems, using copper coolers, to accommodate the high heat fluxes encountered while protecting the crucible refractories; Robust, spring-loaded furnace horizontal and vertical binding systems which maintain tight brick joints through-out all stages of operation; and Well-designed, intensely cooled tapholes for metal, matte and slag. The integration of these features along with properly selected refractories, appropriate instrumentation systems and efficient water-cooling systems is also highly critical. These design features have been successfully implemented in electric smelting furnaces, flash smelting and converting furnaces (Outokumpu and INCO types) and lance injection furnaces (Mitsubishi, Ausmelt and Isasmelt types). This paper will discuss design aspects and operating results for several installations.

Jan 1, 2002

By M. M. Rajkovich, L. Adams, J. J. Zaluski, S. Gardner

In 1998, a group called Kentuckians for the Commonwealth filed an Administrative Petition with the Kentucky Natural Resources and Environmental Protection Cabinet to designate 8,903± hm2 (22,000± acres) on Black Mountain, which contains the state's highest point, as unsuitable for mining. A fast track legislative process was triggered that could have "taken" 91 Mt (100 million st) of coal reserves or, in the alternative, imposed severe restrictions on mining. Even with all parties represented by reasonable individuals, this process can be extremely cumbersome and expensive. The legal and technical preparation for this unusual hearing process as well as issues and strategies of the negotiated resolution are reviewed

Jan 1, 2002

By Michel Bustamante

The occasional substandard performances of continuous flight auger in particular soil conditions have prompted the drilling rig manufacturer to improve the standard CFA in order to reduce its negative effects. A real improvement of interest was the launching of the double rotary CFA system. The promising features of the latter have incited the authors to implement an extensive experimental research on pile constructed using this type of technique but in the specific context of cohesive soils. Short-term static load tests were carried out on a total of 9 test piles of various installation techniques in order to compare the respective performances. The promising features of the double rotary CFA have incited the LCPC & Durmeyer Company to implement an extensive experimental research on this type of pile technique but in the specific context of cohesive soils and more particularly in clayey marls. After load tests completion the research has been completed by an excavation of the double rotary CFA piles. All the collected data concerning the implemented program are reported.

Jan 1, 2002

By K. A. Lapakko, D. A. Antonson

Fourteen samples of pyrite-bearing Archean greenstone rock (d < 6.35 mm, 0.04% < St < 1.22%) were characterized (particle size, chemistry, mineralogy) and subjected to laboratory dissolution testing. The only sulfide and carbonate minerals identified were pyrite and siderite, respectively. Quartz, chlorite and sericite typically comprised 90 to 98 percent of the mineral content. For the first 60 weeks, seven samples with sulfur contents less than or equal to 0.16% produced drainage pH values exceeding 6.0. Over this period, six of the seven samples with sulfur contents greater than or equal to 0.20% produced drainage pH below 6.0, with minimum values ranging from 3.2 to 4.7. The seventh sample (0.72% S) had a siderite content of 18%. Small amounts of magnesium and, to a lesser degree, calcium carbonates present in the siderite apparently dissolved to neutralize acid and maintain drainage pH above 6.0. Sulfate release rates generally increased as sulfur content increased, and the rates of pyrite oxidation estimated for individual samples were roughly half to five times that reported in the literature for the abiotic oxidation of pyrite by oxygen. Observed neutralization potentials ranged from 0.2 to 2.0 g CaCO3/g rock.

Jan 1, 2002

By S. M. Pickering

Banks frequently manage large privately owned mineral land trust accounts for estate heirs. The bank has a fiduciary obligation to follow the “Prudent Man Rule”, which requires that trust properties be managed at least as well as a prudent and knowledgeable owner could. However, banks may not have internal staff proficient at mineral property values, lease contracts, royalties, mining practices, etc. This is an opportunity for experienced geologic consultants and certified minerals appraisers to provide needed help. Items valuable to Trust managers may include: 1. Marketing privately owned mineral trust lands to mining or oil & gas firms, assuring competitive offering prices and terms; 2. Negotiating favorable new mineral lease and purchase-option contracts; 3. Monitoring progress of mining, royalty payments, land reclamation, and environmental clean-up work; 4. Balancing future mining income with later industrial, commercial or housing development, timber harvest, etc.; 5. Assuring that Depletion Allowance tax advantage is taken for actual mine royalty payments, but not for annual non-mining lease (rental) income; 6. Appraising in-ground mineral value for bank audits, estate tax valuations, and equitable property division between heirs; and 7. Serving as expert witness, representing the legal interests of the bank, trusts, and the mineral heirs in litigation. Banks do welcome reliable advice which assists them in achieving the “Prudent Man Rule” and improving mineral income to their land Trust accounts.

Jan 1, 2002

About 90 per cent of the pre-mining BIF-hosted iron ore resource of the Hamersley Province of Western Australia is of the Phanerozoic supergene martite-goethite type. The remaining ten per cent formed as supergene deposits at ~2000 ¦ 200 Ma, and were later modified by burial to form the Proterozoic martite-microplaty hematite ores. The supergene-metamorphic segment of this general unified model has been challenged by three recently published hypogene-based genetic models for the hematite ores, all requiring meteoric oxidation to produce the ore. The most recent and detailed, by Taylor et al (2001), is based on data from the small Southern Batter and North deposits of the Mount Tom Price mine. The authors proposed that during Stage 1 æoverpressured bicarbonate-saturated basin brines from the dolomite aquifer of the Wittenoom FormationÆ at 150 - 250¦C, dissolved free silica from BIF to produce a stratigraphically thinned, magnetite-carbonate-silicate-apatite rock. In Stage 2, meteoric oxidation of siderite to secondary microplaty hematite + ankerite, and magnetite to martite, at unspecified elevated temperatures and pressures, was followed by carbonate leaching (Stage 3). Finally, during Stage 4, weathering with removal of apatite, produced the typical low-phosphorus, porous martite-microplaty hematite ores of the Tom Price-Whaleback type. However, evidence of both microplaty hematite and martite reduced to magnetite, and of infill silica, apatite, and ferroan chlorite, with late-stage pyrite, in the pore space of martite-microplaty hematite ore, shows that the hydrothermal activity at Mount Tom Price is a post-ore event. Neither pyrite nor ferroan chlorite could resist the oxidation required to form hematite ore. Recrystallisation of microplaty hematite in these infilled zones to a typically coarser form than present in most of the normal ores, is a further supporting factor. A more credible, post-ore alternative to the hypogene genetic model is suggested here. Re-exposure to leaching by ground water of the metamorphosed ore deposits in the Phanerozoic resulted in the partial removal of remnant goethite. Localised modifications in the porous BIF/ore contact zones were driven by exothermic oxygen/pyrite/carbon reactions in the footwall Mt McRae Shale. Cool descending oxygenated meteoric water in the permeable ore horizons, acted as one limb of a thermal convective cell. In the other limb, heated reducing solutions rose through the permeable contact zones, to produce the observed localised modifications of BIF and ore. Expelled silica from the carbonatised BIF invaded adjacent porous ore to form erratic silicified ore zones, and to produce the local quartz vein systems found in the associated overlying BIF.

Jan 1, 2002

By Denis Huber

The technical assessment of the final works on the "Stéphany Palace" project at Menton in France&apos;s Alpes-Maritimes region shows the importance of daily project monitoring based on the observation method recommended by the European standard Eurocode 7 which applies to Foundations and Geotechnical Engineering. Excavation operations to a depth of 10 m near the France-Italy railway track and adjacent buildings required precise observation of land deformations, regular piezometric monitoring as well as special design arrangements. Temporary active tie-rods were thus placed in phases in order to control deformations in the retaining structures resulting from excavation operations. The Menton region, terminating the Alpine arc of mountains, naturally required the consideration of seismic forces in phase in the lower floors of the building, directly linked to the buried walls. These calculations were carried out in accordance with the PS69/92 rules, calling for an increase in dynamic thrust under the effect of gravity field rotation.

Jan 1, 2002

The Pongkor Gold Mine employs 678 staff. The mine is owned by the Indonesian state company PT Antam Tbk and is located 100 kilometres south west of Jakarta, in Java, Indonesia. Mine and infrastructure development started in 1992 following intensive geological exploration over 15 years. First gold production was in June 1994. The mine comprises three main orebodies: Ciguha, which is nearly mined out, dips at 75¦ from surface to 150 m. Kubang Cicau, dipping at 80¦ from surface to 230 m, and averages 3.5 metres thick at a grade of 10 g/t Au and 128 g/t Ag; and Ciurug, dipping at 60¦ from surface to 300 m and averages eight metres thick at a grade of 14 g/t Au and 172 g/t Ag. Present global ore reserves are 4.6 million tons at a grade of 12.3 g/t Au and 133.6 g/t Ag. Exploration is continuing for new veins. Initial mining was by manual cut and hydraulic fill at Ciguha, followed by Kubang Cicau. In 1996, it was proposed to convert Ciurug to a mechanised cut and fill operation. Two single boom jumbos and three load-haul-dumps (LHDs) were purchased with the assistance of a gold loan from NM Rothschild and Sons. Implementation of this upgrade was delayed by both a national economic crisis and an invasion of the concession by illegal miners. It was not until May 1999 that raise bore vent rises and access drift infrastructure commenced. Major underground development started in 2000 and is continuing. Production cut and waste fill stoping started in July 2001. The change from manual to mechanised methods has required a total change in work practices and attitudes. However, the process has resulted in a production increase from 600 tpd to 1200 tpd. A three-month compliance test (a condition of the financing loan) was successfully completed, from July to September 2001, with an average production of 700 tpd at Ciurug and 500 tpd from Kubang Cicau.

Jan 1, 2002

By B. Simser

At Brunswick Mine, an increase in the number of seismically-related falls of ground and in particular rockbursts occurred during 1999. This was due to the ever-increasing stress levels in the remaining ore reserves, mining in difficult highly stressed areas and in particular troublesome geological features. In conjunction with the Noranda Technology Centre, development of rockburst support systems started at the Brunswick Mine in 1996 and efforts were accelerated in 1999. A support package consisting of #6 gauge chain link mesh, #0 gauge heavy mesh straps, and a 1 m by 1 m pattern of modified conebolts was developed. The conebolts were modified to enable mixing of the resin anchoring. Two major rockbursts occurred during an intense seismic episode at the Brunswick Mine from October 13th to 17th , 2000.The area was evacuated approximately four hours before the first burst hit, and remained closed during the seismic ?flurry??. The first damaging activity occurred around midnight on Friday the 13th, and a second damaging episode occurred on the 17th that included a local Richter Magnitude 2.7 event. The second rockburst had dimensions of approximately 5 m by 5 m by 20 m or 2150 tonnes of massive sulphide material (density 4300 kg/m3). The first failure area was more extensive, caving approximately six metres of an intersection back with the lateral extent not safely measurable. This paper briefly describes the mining conditions that led to the bursting, the seismic response of the region, the mechanisms thought to have caused the bursts, and a yielding support system which had been partially installed before the burst.

Jan 1, 2002

By K. N. Han, N. S. Kim, H. Yoon, J. S. Sohn

The leaching behavior of silver and silver oxides in ammonical solutions has been studied. The current study is concerned with an effective recovery of silver from secondary sources such as spent silver batteries. Silver associated with these batteries appears in various forms including metallic silver, argentous oxide, Ag2O and argentic oxide, AgO. The leaching behavior of metallic silver in ammoniacal solution has been studied using an electrochemical mehtod. Oxidants used in this study include hyperchlorite, hydrogen peroxide, bromine and iodine. Results on cyclic polarization and Tafel plots on the silver anode in ammoniacal solutions are presented and the results are discussed. The dissolution rate of metallic silver in ammoniacal solutions is also compared with those of silver oxides.

Jan 1, 2002