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By C. A. Young

Cyanide is a fast-acting, highly toxic substance but, at the same time, is deemed essential for sustaining life as well as our standard of living. In this manuscript, the facts about cyanide are presented beginning with a brief history and definition and ending with a discussion on cyanide alternatives. Other topics include speciation, physical characteristics, toxicity, manufacturing, cyanogenics, cyanide cycle, separation, destruction, and markets including those outside the mining industry. Emphasis, of course, is placed on gold production by leaching and how it is influenced by ore type, mineral characteristics and economics as well as its advantages and disadvantages.

Jan 1, 2001

By Gerhard Meyer

A new instrument for the determination of iron., zinc, calcium, and other metals independently directly in the fumes emitted from steelmaking processes is described. Based on the well- accepted method of X-ray fluorescence, the instrument can detect numerous metals simultaneously in the fume as well as report their concentration on a mass per unit time basis real time to a control room computer. The instrument mounts on the wall of the fume duct and can., via a small opening, directly view the hot exhaust plum inside the duct. The concentration of metal in the fume over time has been shown to change dramatically depending on process variables. Variables such as oxygen flow rate, lance height and nozzle configuration., slag condition., and episodic scrap addition can affect the presence of metal particles and fume in the exhaust. An analysis response time of 6 seconds enables better control of the steelmaking process thereby conserving primary resources and reducing environmental impact.

Jan 1, 2001

By A. W. Czarnowsky

More than ever before, mining projects are besieged from growing regulatory, political, public, and special interest group pressure. Administrative and legal appeals to permits and environmental documents can delay project start-up and add tremendous cost to mineral development. Some mining projects have been canceled given undue external constraints. Successful managers must learn to cope with these constraints. This paper will discuss controversy and present a number of environmental management tips to minimize the potentials for delay and to lessen the impacts from government and anti-mining pressures.

Jan 1, 2001

By Gennadiy M. Poletayev, Mikhail D. Starostenkov, Alexandra S. Starostenkova

"The process of the combustion synthesis was modeled by computer simulation using the molecular dynamics method. The set of the critical parameters regulating the velocity of the reaction was found from these computer experiments. It was established that the character of structure-energetical transformations at the combustion synthesis in the systems Ni-Al and TiAl depended on the type of boundaries used for the phases delimitation in the bimetal thin films.IntroductionProducing new materials and products, based on the combustion synthesis (CS), is the objective of scientific investigations as one of the most perspective one for industrial applications. But there are several problems connected with theory and experiment. It allows us to forecast the properties of materials. First of all, the main problems are stipulated by structure-energetical transformations taking place at high velocities of the reaction and at high temperatures. It prevents the analyzing of the transformation mechanisms in materials, taking place at microscopic, atomic levels in details.It is evident, that computer simulation allows to decide some problems and to approach to more exact theoretical presentation of structure-energetical reactions taking place at CS. It is known, that the most typical systems, where CS is observed, are bimetals Ni-Al and Ti-Al. The investigation of interphase boundary stability in the systems of Ni-Al and Ni-Fe was made by the method of molecular dynamics in [1]. The bimetal thin film was presented by the packing of atoms in the plane (111) of FCC lattice. It was found that the discrepancy in the sizes of atoms A and B of bimetal was compensated by the formation of 60° top dislocations, set against interphase boundary in the absence of point defects and free volume. The density of top dislocations was proportional to the factor of size discrepancy of atomic components of the bimetal. Diffusional reconstruction of the interphase boundary and areas, situated near it, was observed only at definite concentration of point defects - vacancies, inculcated in the structure of the bimetal at the definite temperature. The atoms of the bimetal component of less size penetrated in the area of the second component with higher velocity. The clusters of intermetallic germs began to form. It led to the growth of the system temperature and acceleration of the process of the diffusional reconstruction of thin film. The following transformations were found: top dislocations splitted into single ones, which climbed from interphase boundary into the zone of more plastic component; the formation of sub grain structures took place."

Jan 1, 2001

By H. Saint-Raymond, F. Gruy, P. Gardin, M. Cournil

"The control of inclusion elimination is getting more and more important to obtain clean steel. This paper presents a methodology under development for predicting cluster growth and elimination in ladle - RH system. The first key point is to express the collision efficiency, which is very specific for alumina cluster due to the non-wetting fluid. Second, a description of the two-phase flow in the system is necessary. In our calculations with Fluent CFD package and Lagrangian approach for bubbles, bubble growth is implemented, which improves the predictions. Using global reactor decomposition makes possible the prediction of the time evolution of cluster distribution. Important effect of fractal dimension is demonstrated.IntroductionElaboration of new steel grades requires not only to have a high purity in terms of C, O and N content but also to eliminate particles such as alumina or slag droplets. Flow optimisation making easier inclusion elimination is then a key figure to satisfy cleanliness requirements. Mathematical models of flow and inclusion behaviour are widely used for this purpose (1, 2). But having a predictive tool is still a challenge, because the number of phases is important in steelmaking industry: liquid steel, slag layer, bubbles and inclusions (with a large range of composition and rheology). The paper presents the methodology which is developed at IRSID to predict oxygen content evolution during RH degassing.The main mechanisms which have to be considered are :-inclusion growth by turbulent aggregation of elementary inclusions (keeping in mind that liquid steel is a non-wetting medium for inclusions); the difficulty is to express collision efficiency for alumina particles,-inclusion removal by flotation; the difficulty for alumina clusters stems from the complex morphology of particle; fortunately, the use of fractal concept makes it possible to cope with this problem.The paper describes the general modelling of inclusion removal taking into account the previous mechanisms. Hydrodynamic parameters are obtained by means of Fluent CFD package and a specific coding is developed for cluster growth."

Jan 1, 2001

By Graham Holmes, John Starkey

"The Kinross Kubaka Project is a gold mine located in the Russian Far East. The grinding circuit, comprised of a 6.1 m diameter x 2.74 m long SAG mill and a 4.1 m diameter x 5.5 m long secondary ball mill in closed circuit with cyclones, was built using SAG Power Index and Bond Ball Mill Work Index testing to determine the grinding energy requirements. Extremely cold climatic conditions and the need to keep heated space and capital costs to a minimum, dictated a grinding circuit with no in-circuit crusher and no conveyors external to the mill. High energy requirements for both the SAG mill and the ball mill were correctly predicted and have allowed grinding production tonnage forecasts to be met. Design test data and production results are given.INTRODUCTIONIn 1995 Davy International Canada, now Kvaerner Metals E & C, was commissioned as the Engineer and Project Manager for the Omolon Gold Mining Company, to design and construct a gold extraction plant for the Kubaka gold deposit, located in the Russian Far East. This deposit had been studied extensively in Russia during the exploration phase and a Feasibility Study was completed in 1993 by Kilborn who visited the site twice during that year to inspect facilities and to take metallurgical test samples. More samples were taken in 1995 to check ore hardness variability, as part of the final design program by Davy.The client’s objective in designing the Kubaka grinding circuit was to achieve design tonnage at all times, even when milling the hardest ore zones in the deposit. Since the samples taken in 1993 were taken as composite samples, it was necessary to take additional samples in 1995 to determine the extent of the variability. Six samples were sent to Canada for SAG Power Index (SPI) testing. Five of these were combined as a composite open pit sample, while the sixth sample was taken from the site adits as a composite sample to represent undergound ore. These two composite samples were tested to determine the MacPherson Autogenous Work Index for comparison with the SPI values."

Jan 1, 2001

By Peter J. Nicholson

Since the reintroduction of soil mixing to the United States over 10 years ago, the work installed by soil mixing technology has grown dramatically. From an annual turnover of less than ten million dollars per year the volume of soil mixing put in place has grown to an estimated $40 million per year in the year 2000. The majority of work done to date has involved walls, either for excavation support, permanent retaining structures or hydraulic cut-off walls. The other major use for soil mixing has been for mass stabilization of soils whether for isolation of contaminants or for retaining structures. This paper will discuss the uses of and costs of typical soil mix structures. BACKGROUND Soil mixing is defined as the in-situ combining of reagents, typically cement, with native soils, the purpose being to modify or improve the ground. This history of soil mixing covers only the use of cement slurry, aggregated with soil in-situ by mechanical mixing methods only. Soil mixing by use of high-pressure hydraulic means, also known as Jet Grouting, will not be discussed. In addition this will not cover ex-situ (above ground) mixing, or mixing dry reagents with soil. Only mixing applications for building, civil and heavy construction applications will be discussed, with only passing reference made to uses of soil mixing for environmental remediation work.

Jan 1, 2001

By M. Cross, K. Pericleous, A. Mouchmov

"Copper - nickel - sulphide alloys are typically cooled and solidified in 4, 8 and 16 tonne ingots. These ingots exhibit a variation of grain size distribution and macro segregation of the prime alloy components throughout. The former is assumed to be primarily due to the dominant relation between grain growth rate and the cooling profile, whilst the latter is heavily influenced by buoyancy driven residual convection. The objective of this research program is to examine the extent to which it is possible to develop a 'broad brush' computational model of this ingot cooling process, that can predict some 'integral' measure of the grain size (e.g. average diameter) and the macro-segregation as a function of operating conditions.A computational modeling software framework, PHYSICA+ is used to simulate the complex process of ingot casting, which involves coupling between different physical phenomena. The entire model involves:(i) a 'broad brush' grain growth model that could be used in the prediction of micro/macro-structure of alloy ingot cooling processes,(ii) a heat transfer and solidification model which takes into account a second phase transformation of P NhS2 to heazlewoodite, and (iii) NS fluid flow simulation which provides a good basis for further micro/macro segregation modeling.At this stage some results of the 3D convection driven thermal cooling and solidification profiles will be shown, together with the 'integral' model for the grain size prediction."

Jan 1, 2001

By C. D. Seybert, J. W. Evans

"The elimination of convection is essential in experimental investigations of diffusive transport (of heat and matter) during solidification. This paper describes an investigation of an approach whereby a magnetic field gradient is applied to a electrically non-conducting diamagnetic liquid. A magnetic body force then arises which is dependent on the volume susceptibility of the liquid and thereby on the density. With the field gradient aligned vertically and of correct magnitude, the variation of gravitational body forces due to density variations (arising from temperature variations, for example) can be counterbalanced by a variation in magnetic body force.Preparatory to a study of convection control in diamagnetic liquids, PN measurements have been made of the convection occurring during the solidification of water. A peculiar flow arises because of the density maximum at 4°C. Modeling of the flow the steady-state solidification of water in an extremely high field magnet at the NHMFL indicates that flow can be significantly reduced, but it is suggested that, due to field gradient variations within the cell, flow cannot be completely halted. INTRODUCTIONNatural convection is inherently a part of terrestrial solidification. Density-based convection during solidification, due to gradients of temperature and/or concentration, has a significant effect on a material's properties. The design of products with specific material characteristics has required the development of many processes to control convection (such as in the growth of semiconductor crystals, and electromagnetic stirring in steel casting). The expansion of fundamental knowledge about the process of solidification requires collecting data in the absence of density-based convection, while most of science's solidification data (and thus the equations that science has fitted to those data) have been obtained under the influence of gravity. Only relatively recently, through clever experimental design (e.g., drop towers, high altitude parabolic flights, and space laboratories), have investigators been able to study solidification in an environment with ""micro-gravity""."

Jan 1, 2001

By Jefferson Caponero

The tire is an expressive component of Municipal Solid Waste, manly when its occupied volume is considered. Its treatment by pyrolysis stands for a list of advantages, such as: landfill releasing and a production of a high quality fuel. The exploitation of new natural resources is becoming more difficult each day, basically due to the environmental damages caused by this type of activity. This work presents a study on the thermal behaviour of Brazilian tires using thermogravimetric analysis and differential thermal analysis, in order to optimise the pyrolysis process of tires. Samples of I to 2 mm were investigated at atmospheres of nitrogen, argon, oxygen and mixtures of these gases at temperatures up to 1273K, under heating rates between 1 to 50 Klmin . The results showed that the behaviour of each sample is related to both the atmosphere composition and the heating rate.

Jan 1, 2001

By Cheryl S. Lim

New technologies such as direct reduction and smelting reduction processes are increasingly being used in iron-making and steel-making in addition to conventional blast furnace technology. Critical parameters for control of these processes include the degree of metallization, degree of pre-reduction, and carbon and silica levels. On-line monitoring of these parameters is difficult because measurements often need to be made on hot ores (at or higher than -1000'C) in circumstances where representative sample streams are not readily accessible. A nuclear analyser has been developed which provides continuous, non¬intrusive, real-time measurements of iron, oxygen, carbon and silicon levels in hot ores undergoing reduction. The analyser has been tested in a plant using a direct smelting process on pre-reduced feed to the smelting vessel-, accuracies of 1% relative, 0.5 w'.96 (25% relative) and 1.0 wt.% (9% relative) were obtained for the degree of pre-reduction, carbon and silica respectively. The underlying method, capabilities and potential applications of the analyser will be discussed.

Jan 1, 2001

By T. W. Peglas, J. Doherty, R. A. Day

The South East Transit Project is a $520 million project in Brisbane, Australia which includes the construction of a 32 km Busway to access the south-eastern suburbs. Close to the centre of Brisbane, tunneling techniques have been used to minimise surface disruption. This paper describes some of the features of the longest driven tunnel on the project, the Vulture Street Tunnel. The Busway is a two lane expressway for buses which requires a 10.2 m finished width and a 12.6 m excavated span of driven tunnel. The Vulture Street Tunnel carries the Busway at minimal cover beneath the operating Vulture Street Railway Station, beneath a three storey office building and beneath the roadway to the Mater Hill Busway station. Halfway along the route, a Y-junction has been constructed to enable future connection with a light rail route. Key features in the design and construction of the Vulture Street Tunnel include: Use of canopy tubes to drive a 12 m wide tunnel beneath operating railway tracks with less than two metres of cover in highly weathered rock. Underpinning the office building in the route of the tunnel construction from within the building carpark. Construction of a 24 m span Y-junction with 7 metres cover of weathered and faulted rock. Use of predictive analysis as an adjunct to traditional back analysis to estimate the tunnel settlements from pressuremeter test results. This paper describes the design methodology with particular reference to settlement prediction, as well as construction innovations used to complete the tunnel. This paper will be of interest to all designers who have to create large spans in minimal cover in weak rock in urban areas and who have to predict the settlement

Jan 1, 2001

By Q Johnston

Since its inception in 1990, improved metallurgical processing technologies, coupled with mine planning enhancements and improved geological knowledge, have sequentially enabled better efficiencies and economies of scale at the Macraes Gold Project. Over a period of 11 years, processing enhancements have been achieved by: +        increasing mill throughput, from one million tonnes per year, to current throughput of 3.9 million tonnes per year; +        improving recovery rates, from 70 % to approx 84 %; and +        performance enhancement through innovation, eg the use of kerosene to combat ClL pregrobbing. Future processing improvements have been identified in optimising the ore feed and processing flowsheet. The introduction of the autoclave has transformed the process flow form a traditional 'mill headgrade and tonnes milled' operation, to a 'sulphur/gold ratio and sulphur tonnes oxidised' operation.

Jan 1, 2001

By S Bhandari

This paper is a step in the direction of developing a computer model of the near source dispersal of suspended particulate matter (SPM) in planetary boundary layer (PBL). Since Surface Mine blasting is done during daytime, study of daytime dispersion in convective boundary layer (CBL) is relevant to the mining engineers. The scope of this paper covers dispersal after the blast in any type of PBL ie stable, convective and neutral but only under weak wind condition. Mathematical analysis of the dispersion of vertical dust column has been carried out during weak wind conditions in a tropical meteorological environment. It is noted that dust concentration reaches its maximum value some distance away from the point of blast, immediately after the blast (t*=1) and thereafter rapidly decreases. After a short interval from the time of blast at t*=11 the dust concentration shows linear decrease in concentration with distance. Dust concentration also rapidly drops during the interval t*=1 to t*=11, thereafter, rate of drop is nearly the same at any distance from the point of blast.

Jan 1, 2001

The risks faced by organisations are part of a risk continuum. They can be evaluated in terms of hazard, uncertainty and opportunity as well as by the degree of influence they have on conformance, operating performance and strategic objectives. This paper discusses the application of risk management techniques for mitigating blasting hazards, reducing blasting output variability, and implementing blast improvement opportunities. Effective risk management practices can identify and evaluate risks across all levels of the continuum and can deliver realistic assessments of the likelihood and impact of risks on the companyÆs safety and business objectives. This paper does not attempt to present technical details about blasting, rather it aims to provide enough blasting context and examples so that the practical benefits of applying the risk management process to blasting can be fully appreciated. The topics discussed include: explosive management plan; statistical process control; quality blasting, rock-on-ground; Blast Management; Mine to Mill optimisation; and blasting information systems. The concept of a blasting risk management system employing a continuous improvement loop is also introduced. On reflection the insights presented should be extremely useful for observing and understanding which risk face has management focus at a mine site or for a blast site.

Jan 1, 2001

By Paul C. Schmall, John F. Donohoe, Arthur B. Corwin, Derek Maishman

Ground freezing was utilized to provide complete stability of the excavation face and complete groundwater cut-off for the jacking of the three tunnel boxes for the Interstate 90 / Interstate 93 approach to the Fort Point Channel crossing. Through a wide range of geological conditions and large buried obstructions, the freezing provided complete stability of the face so that a 11.5 m (38 ft) high free standing vertical face could be mined without the need for any additional face support. Obstructions were incorporated into the massive frozen ground matrix, and held in place so that they could be excavated with a minimum of disturbance. The freezing provided an absolute groundwater cut-off, and permitted the work to be done without disturbance to the active rail system immediately above. With the use of instrumentation such as borehole thermocouples, the effectiveness of the freezing was guaranteed and the jacking proceeded with complete confidence and assurance of the ground conditions ahead.

Jan 1, 2001

By M. M. Rajkovich

Just prior to the close of the century, the Federal Mine Safety and Health Review Commission issued its long-awaited decision in Berwind Natural Resources, et al v. Secretary of Labor, to usher in the new millennium. The case arose as a result of a mine explosion in Eastern Kentucky resulting in MSHA’s issuance of 225 citations, not only to the contractor, but to four affiliated entities of Berwind Corporation. While an Administrative Law Judge dismissed those citations as to three of the Berwind entities, both MSHA and the remaining Berwind entity appealed the case to the Commission. Although the Commission effectively left intact the Administrative Law Judge’s decision, it announced a new theory of liability that would apparently be applied in the future, namely the Unitary Operator Theory. This presentation will provide an in-depth look into the Berwind decision and explore the means under which MSHA might impose liability for contractor violations upon other entities in the future.

Jan 1, 2001

By W. G. Davenport

This chapter extends our mathematical description of flash smelting to -nitrogen in the flash furnace blast. As in chapters 4 and 5, the discussion is limited to auto thermal smelting (no hydrocarbon combustion). Hydrocarbon combustion is introduced in Chapter 9. Outokumpu flash furnace blast is a mixture of air and industrial oxygen. Most of its N2 originates in the air portion of the blast. A small portion originates as an impurity in the industrial oxygen. The nitrogen entering a flash furnace must always be heated from its input temperature, 298 K in this chapter, to its off gas temperature, -1500 K. Energy must be supplied for this purpose. With auto thermal smelting, the energy is-provided by oxidizing extra Fe-and S.

Jan 1, 2001

By C MacRae, N Wilson

CSIRO Minerals has recently developed an electron microprobe (EMP) based imaging (or mapping) method for characterising ilmenite concentrates. The method requires an electron microprobe analyser to collect elemental X-ray maps which are then processed via an in-house developed software module (CHIMAGE). The type of information readily available from EMP mapping includes; primary phase identification, modal analysis of phases, chemical analysis of individual phases, textural information (eg the alteration stages in the formation of leucoxene or pseudorutile from primary ilmenite and the development of macro-porosity), and the identification of coatings or pore-fill material. All of these parameters will impact on the choice of future downstream processing options considered for any particular ilmenite concentrate. The method has been demonstrated to be a sensitive analytical tool for assessing the distribution of aluminosilicate minor impurities in ilmenite feedstocks from the West Coast of Australia and also for characterising the complex chrome-spinel gangue phases common in East Coast ilmenite concentrates from the Murray Basin.

Jan 1, 2001

By Paula Pereira

The better the capability of accurately predicting the results of any process the less laborious and costly is the optimization or improvement of that process. Rock blasting is a process that one intends to optimize for productivity and cost. Cast or throw blasting is a particular type of rock blasting which is widely used in surface coal mines, where draglines are used to remove the overburden from the top of the coal seam, in preparation for coal mining. Usually, the more rock that is thrown by the blast to the spoil side of the cut or pit, so that the dragline does not have to handle it, the more cost-effective is the cast blasting operation. As such, from an operating cost standpoint, it is crucial to better understand and predict the performance of cast blasting. The Distinct Motion Code or DMC is a Discrete Element Model which has been under development since 1987 and has been used to predict rock motion in several types of mining operations, particularly in surface coal and gold operations.

Jan 1, 2001