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By Thierry Bernard, J. M. Laboz

2000 HIGH-TECH SEMINAR Blasting Technology, Instrumentation and Explosives Applications

Jan 1, 2000

By D. Dimitriadis, T. Polglase, W. Phillips, R. Jenny, M. Botz

Cyanidation processes for the extraction of gold or silver frequently involve the processing of sulfur-containing solids which react with cyanide to form thiocyanate. The formation of thiocyanate is an undesired side-reaction, and in many cases thiocyanate formation results in a prohibitively high cyanide consumption. With the increasing number of gold and silver mining projects which involve the processing of sulfide ores or concentrates or which utilize a biological sulfur oxidation process, more attention has been focused on minimizing thiocyanate formation and in treating solutions to eliminate toxicity associated with thiocyanate. Though not yet commercially applied, there are several technologies available to recover cyanide from thiocyanate to both reduce tailings toxicity and allow the reuse of cyanide otherwise lost to thiocyanate formation. This paper presents an overview of technologies available for recovering cyanide from thiocyanate along with estimated operating costs for the technologies. Pilot testing data suggests that in some cases, cyanide can be recovered from thiocyanate for approximately the same cost as newly purchased cyanide.

Jan 1, 2000

By Adrien Antenen, Didier Villette

CITRON has developed a new process for the recycling of hydroxide sludge, household batteries, catalysts, automobile shredding residues, grinding sludge and other metal containing organic and inorganic waste. A pilot plant with a capacity of 1,000 tons per year has started operations in April 1998. In August 1999, an industrial plant became operational with an initial treatment capacity of 23,000 tons.

Jan 1, 2000

By Hiroshi Nakajima, Kotobu Nagai, Toshihiro Hanamura

"Low carbon ferritic steel bars with ultra-fine grain structure was developed through a warm rolling for the first time by the present authors. They show better low temperature toughness than conventionally hot-rolled plates. Hence, the brittle fracture surfaces in Charpy tests were examined in terms of the effective grain size of fracture, compared with those of conventional QT steels. The ductile-to-brittle transition temperatures were in good accordance with those for the QT steels if referred to the effective grain size of fracture: · However, the size was a few times that of the ferrite grain. This means the grain refining is not yet fully utilized from the viewpoint of low temperature toughness. The anisotropy of· the impact properties and the annealing effect of highly dislocated structure on the toughness are also discussed in the present paper.IntroductionFor structural materials, both high strength and good toughness are required. Well-known approaches for obtaining better toughness for steels are as follows:1) Grain refining2) Addition of Ni3) Thin plate effect by cracking parallel to the rolling direction prior to crack propagation4) Contribution of metastable austenite.Among them, only the grain refining can raise the strength and improve the toughness. And it is well known that the finer the ferrite grain size, the lower the ductile-to-brittle transition temperature. For example, in the case of 0.11 carbon steel, the transition temperature decreases linearly to in d 1/2 [1 ]. However, these have been told in the regime of coarse grain size that is larger than 10 µm in diameter. There ~as .been no study dealing with the low temperature toughness in the regime of ultra-fine grain size with a diameter in the order of 1 µm."

Jan 1, 2000

By Charlie Brumbaugh

Antarctica with its diverse conditions such as severe cold, high winds, rock and ice structure and limited explosives available posed many obstacles. This paper will give an overall view of the methods used to overcome these obstacles on a daily basis on the highest, driest, coldest continent on earth.

Jan 1, 2000

By T. R. Ellis

The author attempted to concurrently apply the US Uniform Standards of Professional Appraisal Practice and the Australian VALMIN Code to a complex mineral property appraisal assignment. This led the author into many severe difficulties. These difficulties included the high standards needed in the work of others, and information and statements needed from the client. The exercise also highlighted many positive features of both documents. Some conflicts were found between the two documents. Implications and thoughts regarding the development of a set of US minerals appraisal standards are discussed.

Jan 1, 2000

By B. Mishra

The major waste product of the alkaline extraction of alumina from bauxite [Bayer Process] is known as red-mud. Approximately, a ton of red-mud is produced for every two tons of bauxite that is mined. The red-mud produced from Jamaican bauxite is rich in hematite, alumina and titanium oxide. It has been shown that over 90 wt. pct. alumina can be recovered from red-mud by soda-ash sintering and caustic leaching. Hematite can be carbothermically reduced with a degree of metallization of over 94 pct. At this stage, the product could be charged through the tuyeres in an iron blast furnace or smelted to produce pig iron. The mineralogical characteristics of the reduced product are not amenable to magnetic separation for iron recovery. The problems associated with the use of reduced red-mud as an alternative to direct-reduced iron [DRI] has also been discussed. Special attention has been paid to lower the alkali content of the reduced material. If smelted, the concentration of titanium oxide in the slag will be significantly high justifying its recovery by an acid-leach process. This paper describes the successful efforts of iron and alumina recovery.

Jan 1, 2000

The acoustic signals emitted from a laboratory-scale ball mill were used for the estimation of the comminution of two complex sulphide ores, viz. Merensky and UG2 ores from the Bushveld Igneous Complex in South Africa. The digital acoustic signals were transformed to power spectral densities that could be related to particle size distributions (-75 µm to 4000 µm) in the mill by use of continuum regression. This approach is more general than principal component regression methods or Kalman filtering used previously and resulted in significantly more accurate calibration in the case of the Merensky ore, where approximately 93.4% of the variance in the particle size distributions could be explained. With fewer data available, the variance in the particle size distributions in the UG2ore could be explained less accurately (82.4%), but still satisfactorily. In addition, smaller particle sizes (less than 300 µm) could be modelled more accurately in the case of the UG2 ore.

Jan 1, 2000

By R. J. Pruett

The Georgia kaolin district is the world’s largest producer of kaolin. Georgia production tripled from 2.87 Mt (3.17 million st) in 1968 to8.35 Mt (9.2 million st) in 1998. Development of the Georgia kaolin industry can be traced to the identification of the mineral resource, the adoption of innovative process technologies and the creation of markets for kaolin. Georgia kaolin is an abundant and high-quality resource that shows a range of advantageous properties. Technical developments in wet processing, delamination and calcination allowed production of high-value products. The use of kaolin pigments in the paper industry provided a market that absorbed the rapid growth in kaolin production.

Jan 1, 2000

By Jun Sugiyama, Hiroyuki Sano, Toshiharu Fujisawa, Hideki Takeuchi, Chikabiuni Yamauchi

"The solid .state electrotransport (SSE) is one of the most promising methods for the elimination of gaseous impurities from chemically active metals, such as rare earth metals. . In the present work, the SSE process was applied for the oxygen removal from praseodymium. The SSE factors, such as effective valence, were measured under the various temperatures, electric field intensities and initial oxygen contents, and the effects of those conditions on the SSE process were discussed. Furthermore, the solubility of oxygen in .solid praseodyillium was also measured·, by using the SSE method and metal-oxide equilibrium method.IntroductionWhen a direct current is passed through a solid alloy, not only electrons but also solute atoms are transported as charge carriers toward the anode or cathode. This phenomenon is referred to as an electrotransport or electromigration. The solid state electrotransport (SSE) is the application technique, based on this principle, to the pUrification of the solid metallic materials.Rare earth metals are used for various functional materials, such as magnetic, optical or electronic materials, therefore their high purity metals are required [l ,2]. However, rare earth metals are chemically active and have a strong affinity with gaseous elements (e.g. oxygen, nitrogen, hydrogen and carbon). In many cases, eliminating operations of gaseous elements have not been always made commercially, because these impurity elements could not be eliminated by usual treatments applied to the purification of ·common metals. As an alternative method, authors have proposed the· application of the SSE process to the elimination of gaseous impurities from rare earth metals. Investigations have been carried out on the yttrium-oxygen and neodymium-oxygen systems and the results were already reported[3,4]."

Jan 1, 2000

By J. Moskowitz

Construction of the new JFK International Airport Light Rail System (LRS) began in 1998 with a pre-construction load test program. This $1.2 billion design-build project consists of approximately 13 kilometers of elevated twin rail. The elevated rail system is supported on nearly 500 piers requiring deep foundations. The presence of underlying compressible and liquefiable soils as well as space constraints precluded the use of large spread footings. In the 1980's the Port Authority undertook extensive testing to evaluate various piles and drilled shafts types. The LRS piling sub-contractor and the Geotechnical Engineer conducted additional tests for this project to identify the most cost effective deep foundation type. Candidate piles types included: Monotube®, Tapertube®, and closed ended pipe piles. The tapered pile types were found to be the most cost effective and the project utilized both the Monotube® and Tapertube® piles. This paper presents the results of the load test program and the issues related to pile driving induced vibrations and ground movement.

Jan 1, 2000

By Kensuke Sassa, Shigeo Asai, Norihisa Waki

"A new method for separating inclusions from a molten metal using a high magnetic field has been proposed. The principle of this method based on the magnetization force has been confirmed in experiments of separating intermetallic compounds imitating inclusions from molten Al-Si-Mn-Fe and Al-Si alloys. In order to measure a magnetic susceptibility, the Gouy's method has been so modified by using a super-conducting magnetic as to work in a high temperature up to 1473K. A theoretical expression for the magnetization force, which is indispensable to evaluate the magnetic susceptibility, has been derived. The magnetization forces acting on intermetallic compounds which were used in the magnetic separation were measured over the range of liquidous to solidous temperatures and the magnetic susceptibilities of the intermetallic compounds were obtained from measured magnetization forces by use of the theoretical expression.I. IntroductionRecent developments in the technology of super-conducting magnets have given rise to the circumstance that a high magnetic field over a relatively large space is readily available without liquid helium. Then, it has been found that a high magnetic field provides magnetic effects to nonmagnetic substances and various interesting phenomena have been reported in the broad science fields of physics, chemistry and biology1). ""A science related to a high magnetic field"" in which many fields are transversally viewed from the standpoint of a high magnetic field2 ) is going to be established. In particular, new phenomena and functions brought by the science related to a high magnetic field are also useful for Material Science and Engineering so that the creation of Materials Science and Engineering related to a high magnetic field"" has been conceived 3).Now, when a substance regardless of being magnetic or nonmagnetic is put in a magnetic field, it feels a magnetization force, which is familiar to such a force that a magnet attracts iron. The force is in proportion to the product of magnetic field strength, its gradient and susceptibility so that a precipitated substance can be separated from a molten metal based on the difference between susceptibilities of a substance and a melt. This is a basic principle of the magnetic separation. So far the application of the magnetic separation has been limited to the separation of ferromagnetic substances from a nonmagnetic medium. A high magnetic field, however, has enabled to separate nonmagnetic substances from a nonmagnetic medium.In this study, a new method to separate inclusions from a molten metal using a high magnetic field has been proposed. The principle of the method was verified by experimental works and the feasibility on the elimination of inclusions in steelmaking processes has been studied"

Jan 1, 2000

By D. A. Horne, V. R. Daiga

Certain steel mill wastes contain significant amounts of zinc oxide due to the use of galvanized scrap during the steel making process. Typically electric arc furnace (EAF), and basic oxygen process (BOP) flue dusts contain 20 to 30% zinc oxide and 40 to 50% iron oxides, along with smaller quantities of lead and cadmium. These materials can be recovered from the flue dusts by using a proven rotary hearth furnace (RHF) process. By-products of the recycling operation include a crude zinc oxide fume, which is captured in a baghouse filtering system, and sponge iron that may be recycled into the steel making operation. Crude zinc oxide properties plus the operating experience from two commercial RHF installations utilizing MR&E's DRyIron™ Process will be presented.

Jan 1, 2000

By A. Hammel

This paper summarizes indigenous mining methods used to collectmetal ores in pre-colonial southern Africa, south of 15°S. These methods, for the purposes of discussion, are divided into sections inorder of increasing organizational complexity, from scavenging,which only required basic equipment and a relatively minimal division of labour, to underground mines, which necessitated complex planning to overcome obstacles such as the need for illumination and ventilation. Examples concerning the pre-colonial exploitation of iron, copper, tin, and gold have been taken from the archaeological literature. This review paper provides an introduction to the technology that was available to and used by miners in the past, illuminates some of the factors limiting their operations, and supports the claim to the indigenous nature of this activity

Jan 1, 2000

By E. J. Peuraniemi

Oxidation of chalcopyrite concentrate and two low-iron copper mattes were studied using a laboratory scale laminar-flow furnace simulating the phenomena taking place in different zones of the reaction shaft of a flash smelting furnace. In the experiments, screened fractions were fed into the furnace and sampled after short reaction time intervals by quenching them into a water film. Experimental conditions included temperatures of 1100 and 1300°C with reaction gas oxygen contents from 21 to 75 vol.%. Samples were analysed chemically for Cu, Fe and S to define removal rate of sulphur. Optical and scanning electron microscopy with EDS-analyser were used to examine the samples. In this paper, oxidation kinetics as well as ignition of particles are discussed. Changes in particle morphology, size, and composition are viewed to closely define the proceeding of the oxidation, and, consequently, to compose a detailed model of dust formation and reaction mechanisms. Data obtained in the experiments broadens the knowledge of physical and chemical phenomena in flash reactions and serves as reference for computer simulations.

Jan 1, 2000

The purpose of this paper is to look at the costs of tailings disposal, and in particular the comparative costs of different disposal methods in different situations. Costs are often the hidden design parameter. We know that they are important but sometimes feel that it is not very respectable to talk about them in public. It is better from a public relations point of view for it to appear that the decision-making process is driven by environmental factors or best practice rather than looking for the cheapest option. But this presumes that the two are mutually exclusive and this need not be so. These issues are discussed later in the paper. It is also commonplace for the scale of the mining operation to change with time, typically involving increased throughput rates and total tonnage. New ideas in tailings disposal make their appearance. The regulatory attitude can change. Having made a decision about the disposal method at the time of original feasibility study and design it is easy to suppose that the mine is æstuck with itÆ. But that also need not necessarily be so. Careful costing of options may reveal that a switch in method could be cheaper in the long run. The designer will often tend to think in terms of initial earthworks and site development costs. Aspects of power consumption, labour, and periodic campaigns to move tailings pipelines and carry out embankment raises are either overlooked or not given the same emphasis. This can distort the evaluation process. It is productive to think in terms of dollars or cents per tonne as a basis of comparison, not just the total sums. Tailings disposal can cost from as little as 10 - 20 ó/t to over $1.00/t which is a big range. There may be good and unavoidable reasons for the high figure but there would need to be to justify being so far over the industry average. At the same time, mining and processing costs, at least for gold, are around $15 - 20/t. Viewed from this perspective tailings disposal will always be a relatively small component of the annual budget.

Jan 1, 2000

AustraliaÆs strong position as an aluminium producer and potential magnesium producer combined with rapid market growth in the automotive industry, proximity to Asia and other natural advantages points to considerable opportunity for downstream processing and manufacture with light metals in this country. Development of a vertically integrated light metals industry in Australia needs to be pursued with vigour, as does the continued development of global strategic alliances through the value adding chain.

Jan 1, 2000

By D Millette, F Gay

Surface tailings are finely ground waste materials produced in all mines after the mineral or metal has been removed from the metallurgical process. Current methods for disposal of tailings involve constructing dams, dumping into existing waterways, and depositing as backfill underground. Each method has its drawbacks in terms of cost, level of complexity, safety and environmental concerns. Backfilling is the process whereby waste material (generally metallurgical tailings, prepared aggregates or a combination) is placed from the surface back underground into open mine workings via conveyor belts, hydraulic or pneumatic pipes or gravity. In the backfill process common difficulties are expensive placement costs, equipment wear and the ability to meet early and long-term strength requirements. Traditional tailings transportation in pipes involves the use of water as the transport medium. Foam technology involves the introduction of micro-air bubbles that replace the water as the main transport medium. This air can be removed after placement if necessary, by the addition of a defoaming agent. This could produce an under-saturated stable cake. Foam technology has the potential to revolutionise surface tailings disposal and backfilling by providing a less expensive and environmentally safe alternative to those just described.

Jan 1, 2000

By A von Johannides, G J. van Hout, L F

In the past various systems have been used to plan the extraction of ore from block cave operations. These systems have varied from rather sophisticated models with empirical ægravity flowÆ rules applied to the very rudimentary models where only the recorded mined tonnageÆs have been accounted for against the available resource. The normal requirement of these models has been to only plan the movement of ground through the drawpoints. Little cognisance has been taken of the other parameters that affect the total mining operations. The intended purpose of the linear program planning system is to not only include the management, resource availability and geotechnical constraints, but to also include the mining rules. The paper will discuss the various constraints that have been considered, and attempt to illustrate where the system better serves the production system than previous ones. A brief technical discussion on the linear programming system is included.

Jan 1, 2000

By A Murphy, D Lauder, J Miranda

Minera Alumbrera Limited operates the Alumbrera concentrator, treating a nominal 80 000 tpd of porphyry gold/copper ore. It is located in Argentina, 1200 km north-west of Buenos Aires in Catamarca Province, at an elevation of 2550 m above sea level. Treatment facilities consist of crushing, SAG and primary ball mill grinding circuits, rougher flotation, ball mill regrinding, gravity recovery and cleaner flotation. It is one of only a small number of concentrators in the world, which uses Jameson Cells alone for cleaner circuit flotation. Plant design was started in June 1995, with commissioning commencing in July 1997. Following a successful ramping up to design tonnages and recoveries, a number of options were reviewed to improve gold and copper recoveries. This paper concentrates on a detailed size by size flotation recovery project, commenced in May 1999. Utilising optical microscopy, scanning electron microscopy and analysis of surface chemistry it has allowed losses by size fraction to be quantified and options for enhanced recoveries to be developed. Coupled with extensive circuit surveys it has also provided an insight into previously unknown properties of Jameson Cell operation. Among these are unique residence time and bubble formation reactions to reagent and pulp flow variations, which has permitted a number of novel changes to the operation to maximise capacity and recovery.

Jan 1, 2000