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A laboratory size solvent extraction apparatus has been constructed, which incorp- orates three stages of countercurrent extraction, followed by two stages of counter- current stripping. The model uses a gravity flow system from one stage to another and air lift pumps to recirculate organic and aqueous phases. A novel pump/mixer system is used to transfer solutions from the mixer compartments to the settler compartments. The model has proven valuable in the teaching of solvent extraction principles.

Jan 1, 1999

By Mark Jolly

"Over the last ten years or so many man hours have been dedicated to developing methods for simulating shape casting processes. The majority of the methods developed have been devised by a combination of computer, mathematics and materials specialists often with limited knowledge of foundries and foundrymen. As a result of this it would appear that although there are many software packages for the foundryman to use there still exist fundamental misunderstandings as to their usefulness and suitability within the foundry.The paper aims to identify how well current software packages perform. The relationships between physical phenomena, practical defects and software capabilities are presented. Some discussion of the use of criteria functions is also presented. Finally issues arising from the postprocessing of results are discussed as the presentation of the results to the lay-person in simulation techniques is possibly one of the most important aspects in influencing the adoption of this type of software in the foundry community."

Jan 1, 1999

By R Milton, D Hake, H Sprague

The North Western Sewer tunnel extends over 11.5 km in the North Western suburbs of Melbourne.The $253 million tunnel project provides a critical link in the Melbourne Sewer Network. The existing sewers fail to service the increasing demands of the growing population of the North West regions of Melbourne. This project will protect the environment and improve the standards of service of the existing system. This paper concentrates on Section three of this project, consisting of the final 4 km of the Contract, three access shafts and a cut and cover section of tunnel.Transfield Tunnelling as Head Contractor constructed the tunnel for Melbourne Water Corporation, with Enetech Streamline, formally Streamline Australia, a trading arm of Melbourne Water acting as Superintendent.Excavation of Section three of this project commenced in September 1994 and project completion is scheduled for October 1998. The tunnel passes below the residential suburb of Essendon, through some of the most challenging ground conditions ever attempted to be tunnelled in Australia.

Jan 1, 1999

By Les Gutzwiller

Fan applications in the mining industry have changed during the last 70 years. In 1922, J.R. Robinson authored a technical volume entitled Practical Mine Ventilation. At that time, atmospheric control had only recently shifted from natural to mechanical. The large, mechanical draft fans that were used then were centrifugal. The fans ran at low speeds, about300 rpm. Most were steam-engine driven. In the late 1920s and early 1930s, mines became larger, increasing the pressure and volume requirements of the fan equipment. Axial fans were designed to run at much higher speeds (710 to 880 rpm) and were driven by electric motors. They were also smaller and less expensive to install than the cumbersome centrifugal units. However, changes in mining have resulted in progressively higher static-pressure requirements. So centrifugal fans are once again proving to be a good choice.

Jan 1, 1999

By Kazuaki Mita

There are various intermetallic compounds in the Zn-Fe system. We synthesized them at about 673K. A specimen was examined chemically and X-ray diffraction was applied to ensure the formation of intermetallic compounds. Material containing two phases was placed in a Knudsen type effusion cell and the mass spectrum studied to evaluate the vapor pressure of zinc. The thermodynamic properties of intermetallics was then evaluated through measured intensity.

Jan 1, 1999

By Becerra J. O

HYL developed a direct reduction process (DR) that does not require a reformer; it is called self-reforming process. Typically, direct reduction processes based on natural gas utilise a reformer unit to transform the natural gas into reducing agents (hydrogen and carbon monoxide). The reforming reactions are: CH4+H20-?3H2+CO CH4 + CO2 - 2H2 + 2CO These reforming units require a catalyst agent to promote the kinetics of the reforming reactions. The catalyst for these reactions is typically a metallic element such as nickel in a ceramic matrix; iron is also an excellent catalyst for the reforming reactions.

Jan 1, 1999

By KNona C. Liddell

Goethite is an important naturally occurring sorbent for divalent heavy metals and has often been used as a model compound in studies of adsorption on oxide mineral surfaces. Surface complexation modeling, surface spectroscopy, and electrochemical techniques have all been applied to goethite adsorption. Modeling studies have shown that usually several different sets of fitted parameters are equally successful in representing surface charging and adsorption data. Surface spectroscopic data are proving valuable in determining the nature of the surface sites, and refined models now incorporate structural information on interatomic distances and coordination numbers. Multisite surface complexation models can give very good fits to surface charging and adsorption data, but further improvements are needed to better represent surface reactions involving exchange of protons and divalent cations. Recent experimental and modeling studies on adsorption of divalent transition metals on goethite are described and the present status of the field is assessed.

Jan 1, 1999

By J. Drelich

An improved experimental procedure to measure contact angle has been consolidated with coal surface preparation involving polishing with abrasive paper, alumina powder, and a cloth, followed by ultrasonic and mechanical cleaning. Specifically, the captive-bubble measuring technique has been compared with the sessile-drop technique and the former has been recommended for the examination of the hydrophobic properties of coal surfaces. Results of the research program, which is currently under way, on the examination of the effect of the nature, amount, size and distribution of mineral inclusions in coal on its wettability are briefly reviewed.

Jan 1, 1999

By T. W. Gonzales

The BHP San Manuel Smelter operates an Outokumpu Oy flash furnace, conventional Peirce-Smith converters, anode casting facilities, and two double contact sulfuric acid plants. The flash furnace was commissioned in July 1988 and since then, the smelting capacity has been continuously increased to 30% above design. The converter operation was challenged to process larger amounts of matte with existing capacity. Utilization of industrial technological improvements and people technology transformed the Converter Department from a constraint to easily accommodate the new demonstrated flash furnace capacity. This technology also increased secondary consumption, converter campaign life, and reduced operating costs. This paper will describe the important Converter Department achievements in the past five years.

Jan 1, 1999

By L. M. English, Y. J. Wang

When plotted as head vs. volume, fan curves start high and decrease with increasing volume, while mine head curves start low and rise with increasing volume. Their intersection is the system operating point. However, as every ventilation instructor knows, the fact that head loss is a negative number (debit) and fan head is an energy addition (credit) is often a stumbling block to student or audience comprehension since the curves seem to reflect the opposite. It is possible to use the intuitively correct curves- pressure losses as negative values and energy additions as positive values - and still obtain the correct operating point. Adding the two curves produces a third curve that intersects the x-axis at the operating point, the point at which the fan energy input exactly matches air circulation energy loss. Using this technique also makes it easier to account for outside influences on the system, such as natural ventilating pressure. With the standard approach, it is quite easy to add or subtract such influences to the wrong curve. This approach can be extended to the graphical solution of any series/parallel ventilation network. The results are the same, and the approach is logically consistent and less confusing.

Jan 1, 1999

By J. M. Mutmansky, Y. J. Wang

The usual method employed to determine the direction of flow in a connecting airway in advance is to conduct a survey between the two existing nodes being connected by means of the new airway. It is then assumed that airflow will take place from the node with higher pressure to the node with lower pressure. The purpose of this paper is to examine this direction-of-flow problem -- using properties of the system characteristic curve for a two-terminal network -- and specify some conditions that ensure that flow will take from the higher-pressure node to the lower-pressure node. It is concluded that the only requirement is that all characteristic curves of fans in the network should be strictly decreasing. Five numerical examples illustrate some important properties of the direction-of-flow problem.

Jan 1, 1999

By G. Duncan

Distinct trends in grinding mill technology have emerged in recent years. In an effort to optimize overall mill performance for the needs of the End User, broad measures of logistical speed, process flexibility, operational risk, and overall costs now exert greater influence on the specification of grinding equipment. As a result, innovative alternatives to conventional grinding mill structures, supports, drives, feed, and discharge configurations are now being offered and selected with greater frequency. This paper investigates these trends in grinding mill technology, utilizing optimization and decision-theory techniques. In particular, the paper considers how specific advances in process design, product engineering, manufacturing techniques, and mining operations continue to relax technological constraints, enabling further mill innovation. In this context, a methodology is presented, illustrating how proper selection and specification of grinding mill components and configuration can target an optimization of the four End-User performance measures listed above..

Jan 1, 1999

By J. W. Matousek

Since the late 1800s, copper-nickel ores have been mined and smelted in the Sudbury area. The Canadian Copper Company, the Copper Cliff ancestor of Inco Limited, commenced operations with a blast furnace smelter in 1888. Coal-fired reverberatory furnaces were added in 1911 and multihearth roasters in 1914. The blast and reverberatory furnaces smelted, respectively, coppernickel ores and ore fines until 1930, when a milling process and plant began operating to concentrate and separate the minerals of these two metals. Two reasons for this delay were: (1) the availability of high grade ores suitable for direct smelting; and (2) the difficulties in making the copper-nickel separation. The Mond Nickel Company, however, practiced flotation at its Coniston Smelter site from 1914 to 1930. A bulk concentrate containing six per cent copper and five per cent nickel was recovered from ore of 1.6 per cent each of copper and nickel. Gravity (table) and magnetic concentrates were also produced. Inco Limited (then The International Nickel Company) began laboratory-scale flotation tests on its ores in 1918. This work led, ultimately (in 1930), to the construction of the 7500 tonne-per-day Copper Cliff Mill, designed to recover separate copper and nickel concentrates. Its capacity was expanded to 11000 tpd in 1936, to 18 000 in 1940, and to 27 000 in 1942. Since 1971 it has operated to process only the bulk flotation products from other mills to yield individual nickel and copper concentrates.

Jan 1, 1999

By T. E. Warner

In order to detect arsenic and antimony in zinc, various electrochemcial experiments were performed involving the electrochemical introduction of sodium atoms into molten zinc using a solid electrolyte. Under high rates, the formation of the intermetallic phase NaZn13 was assumed to form. Under more moderate injection rates of sodium, employing a symmetric "zinc/zinc cell", a qualitative relationship between the current generated during cyclic voltammeuy and the arsenic and antimony concentrations in molten zinc was observed.

Jan 1, 1999

[Scott Aberle Western Energy Co POB 99 Colstrip, MT 59323-0099 Randy Acre Joy Mining Machinery 2569 Silver Oak Ct. Grand Junction, CO 81505 Brian L. Acton Oxbow Carbon & Minerals Inc 1601 Forum P1-#P2 West Palm Beach, FL 33401 Laine W. Adair Genwal Resources Inc POB 1420 Huntington, UT 84528-1420 Kent Adamson Solvay Minerals POB 1167 Green River, WY 82935]

Jan 1, 1999

By J. P. Gu, C. Beckermann

"Melt convection and macrosegregation in casting of a large steel ingot is numerically simulated. The simulation is based on a previously developed model for multicomponent steel solidification with melt convection, and involves the solution of fully coupled conservation equations for the transport phenomena in the liquid, mush, and solid. Heat transfer in the mold and insulation materials, as well as the formation of a shrinkage cavity at the top are taken into account. The numerical results show the evolution of the temperature, melt velocity, and species concentration fields during solidification. The predicted variation of the macrosegregation of carbon and sulfur along the vertical centerline is compared with measurements from an industrial steel ingot that was sectioned and analyzed. Although generally good agreement is obtained, the neglect of sedimentation of free equiaxed grains prevents the prediction of the zone of negative macrosegregation observed in the lower part of the ingot. It is also shown that the inclusion of the shrinkage cavity at the top is important in obtaining good agreement between the predictions and measurements.IntroductionMacrosegregation in large steel ingots is one of the most well-known and now classical problems in the field of solidification and casting [1]. Commonly found macrosegregation patterns in steel ingots are a positively segregated zone at the top, negative segregation near the bottom in the equiaxed zone, inverse segregation near the ingot surface, V-segregates along the centerline, and A-segregates in the columnar zone [2, 3]. It is well established that the macroscopic transport of species leading to macrosegregation can occur by a variety of mechanisms, including thermally and solutally driven natural convection of the melt in the mushy zone, flow due to solidification contraction, and the sedimentation of free equiaxed crystals. Fredriksson and coworkers [ 4,5] provide recent overviews of the solidification transport phenomena and macrosegregation in ingot casting."

Jan 1, 1999

By P. T. Craddock, H. V. Paliwal, L. K. Gurjar

The Indian cultural heritage of mining, smelting and the use of minerals and metals dates back to ancient times. Although the exact date of the commencement of such activities in India is not certain, Indians are known to have been familiar with gold, silver, copper, tin and lead and to a lesser extent with iron at least since the Vedic period (Table 1).

Jan 1, 1999

By C G. Ryan, D R. Cooke

The Thames gold-silver deposits are part of the Hauraki goldfield, situated within the Miocene to Pliocene calc-alkaline Coromandel Volcanic Zone (CVZ). The Waitangi vein system is one of the mineralised ore shoots in the Thames district. The Thames gold deposits are characterised by shallow-level epithermal vein mineralisation with phyllic to advanced argillic alteration assemblages and abundant sulphide minerals including pyrite, arsenopyrite, chalcopyrite, galena and sphalerite. Gold occurs as electrum in association with sulphide minerals. Sulphur isotope analyses of mixed sphalerite-galena and sphalerite-galena-chalcopyrite samples yield a narrow range of δ34 SCDT values (-1.0 to 0.9 ë; n=5), whereas late spongy pyrite gives unusually light sulphur isotope values (-16.7 to -27.9 ë; n=4). Vein quartz from the mineralised zone at Waitangi yields δ18OSMOW values from 6.8 to 12.7 ë (n=23). Fluid inclusion studies indicate a homogenisation temperature range of 190¦ - 296¦C and salinity range of 0.2 - 3.0 wt per cent NaCl equivalent. Similar temperature and salinity ranges have been recorded for the other gold deposits in the Coromandel Peninsula. PIXE (Proton Induced X-ray Emission) analysis revealed that the Waitangi ore fluids have 1090 - 2700 ppm K (average 1600), 145 - 205 ppm Ca (average 180), 80 - 100 ppm Mn (average 90), and 80 - 200 ppm Fe (average 120) but no detectable Cu, Zn, Br, Rb, Sr, Pb and Bi (only one fluid inclusion contains 28 ppm Zn). The sulphur isotopic values of base metal sulphides from Waitangi suggest that the sulphur was derived from a magmatic source (either directly, or by leaching of igneous sulphides). The calculated oxygen isotopic composition of ore fluids is between -2.1 to 3.8 ë at 250¦C and -0.1 - 5.8 ë at 300¦C. Oxygen isotope analyses have revealed significant variations in δ18O values with elevation and gold grades. Zones of gold enrichment coincide with a zone of variable oxygen isotope values at the top of the vein system, where boiling and/or fluid mixing most likely occurred. Mixing of ore fluids with convective ground water is a likely mechanism for gold deposition in a shallow environment for the Waitangi vein system and there is also lack of fluid inclusion evidence (eg liquid-rich and vapour-rich inclusions in the same growth zone) for boiling of ore fluids. Oxygen isotope values varying with gold grades within the Waitangi conduits suggest that δ18O values may be useful in targeting bonanza grade gold mineralisation in epithermal vein systems.

Jan 1, 1999

By H Susanto, N Belluz, D Flint, A Edw

The Deep Ore Zone (DOZ) is a block cave mining operation exploiting a diluted reserve of 131 million tonnes grading 1.06 per cent copper and 0.81 g/t gold in the lower portion of the Ertsberg East Skarn System (EESS). The EESS is a calcium-magnesium silicate skarn containing in excess of 250 million tonnes of copper-gold ore, located in the Ertsberg Mining District on the crest of the Jawawijaya mountain range in the highlands of Irian Jaya, Indonesia. The EESS was discovered in 1968 where it cropped out at an elevation of 4050 metres above sea level. The Ertsberg Mining District is underlain by siliclastic carbonate and siltstone formations of Jurassic to Tertiary age. The sediments have been folded and are cut by major bedding subparallel and crosscutting structures. Intrusion of a series of igneous bodies post-dates folding and faulting. These I-type intrusions are the source for the copper-gold mineralisation found in the Ertsberg Mining District. The EESS is hosted by carbonates of the Tertiary Waripi and Faumai Formations that have been altered to calcium-magnesium silicate skarn and is situated on the southern limb of a northwest-trending syncline. The EESS is an essentially vertical tabular body with a vertical extent of at least 1200 metres and a lateral extent of up to 1000 metres. The width of the EESS averages 200 metres and locally is in excess of 300 metres. The northeast (hangingwall) contact of the EESS is a skarn reaction front in sudden contact with barren marbles. This contact coincides with a zone of localised faulting and brecciation. The EESS is bounded to the southwest (footwall) by the Ertsberg Diorite, a 3.25 Ma old intrusive. The DOZ block cave operation extends from 3040 metres above sea level to a maximum of 3388 metres above sea level, has a length of 860 metres and a maximum width of 350 metres. The DOZ is a high temperature skarn with a prograde forsterite/diopside mineralogy whose protolith is the dolomitic Tertiary Waripi Formation. The principal retrograde alteration minerals include tremolite, actinolite, serpentine, talc and chlorite. Grade is highest where bornite occurs in large dense complex intergrowths with magnetite and anhydrite. Grade has been locally enhanced in the DOZ by a late-stage pyrite-chalcopyrite hydrothermal alteration event with associated brecciation. Ertsberg Diorite along the footwall of the skarn is also included in the reserve where it is mineralised endoskarn or has been mineralised by porphyrytic or late stage hydrothermal alteration. Formation of the EESS was initiated by contact metamorphism during the intrusion of the Ertsberg Diorite with later metasomatic alteration during both prograde and retrograde phases. The bulk of sulphide mineralisation formed late in the retrograde phase. The EESS is open along strike to the northwest and down-dip with on-going exploration of these areas. Current exploration is targeting both endoskarn and porphyry style alteration and mineralisation of the Ertsberg Diorite.

Jan 1, 1999

By Kristen E. Coose

Concrete is a mixture of a fine aggregate (sand), a coarse aggregate (gravel), cement, and water. Cement itself is the most expensive of the ingredients but generally amounts to only about 10% of the concrete mixture. Cement raw materials include calcium, alumina, iron oxide, silica, and gypsum. They are heated and chemically changed into clinker "minerals," which are then ground and shipped as cement. Each of the four main clinker minerals-tricalcium silicate, dicalcium silicate, tricalcium aluminate, and tetracalcium aluminoferrite-impart specific strength and compositional properties to the final concrete product. During hydration of the cement, chemical changes produce new minerals that include calcium silicate hydrate gel (C-S-H, the main constituent of hydrated cement paste), calcium hydroxide, and calcium, sodium, potassium, and sulfate ions, among others. Two main reactions can occur that may be deleterious to concrete. Normal cement pore solutions, in a hydrated cement, contain sodium hydroxide and potassium hydroxide. If these alkali concentrations are too high, they can react with the siliceous aggregate (alkali-silica reaction, or ASR) to form an alkali-rich calcium silicate hydrate gel (C-N+K-S-H), which, upon prolonged contact with water, can expand to crack the concrete. The other deleterious reaction occurs when the mineral ettringite (Ca6A12(S04)3OH12. 26H20) forms after the concrete is hardened (delayed ettringite formation) and cracks the concrete. Many of the concrete bridges and structures built in New Mexico in the past 20 years are in need of replacement due to deterioration. Many others constructed very early on in the century are still sound. By collecting and analyzing samples of both old and new concrete and good and bad concrete, we compared their differences on both a microscopic and macroscopic scale. Samples taken from concrete sidewalks, parking lots, drainage canals, spillways, and a railroad-trestle foundation have construction dates that range from 1923 to 1997. They were analyzed by electron microprobe and by petrographic microscopy. Cracks, air voids, and aggregate alteration were primary locations for investigation and analysis. Using the electron microprobe, ettringite was found in voids of most of the samples, both in good and bad concrete. This leads us to believe that ettringite formation is not causing distress in the concrete. There was one exception in which ettringite was found lining a crack. In this instance, ettringite may have the ability to further the cracking and cause distress. No alkali-silica gel was identified with the microprobe. Using the petrographic microscope in cross-polarized light, a light-brown material was observed that lined some of the air voids and cracks; however, exact mineralogic identifications were not made. Although many instances of chalcedony and other deleterious quartz phases were found, no clear evidence of ASR-gel deterioration was present in our samples using these methods. However, positive identification of the ASR gel was made on an in-place concrete near one of our sample sites and in several sample cores using a newly developed chemical test for the soluble potassium ions associated with the gel. The chemical used in this test is sodium cobaltinitrite, Na3Co(NO2)6.

Jan 1, 1999