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By M. H. Moys

I had the good fortune to attend the above Conference which was held in Kanpur, India, on 11-15 December, 1995. The Conference was held in honour of Professor P.C. Kapur of the Indian Institute of Technology in Kanpur. Professor Kapur was one of the early students of legendary teacher and researcher of mineral beneficiation, Professor Doug Fuerstenau of the Department of Materials Science and Engineering at the University of California at Berkeley. I have attended my fair share of international conferences and this one certainly rated at the top of the list on several counts. With an open-hearted hospitality which one might almost take for granted once you have spent some time in India, the organizers of the Conference looked after every need of their guests, including breakfast and transport to and from the conference centre, wonderful traditional lunches and dinners and outstanding entertainment in the evenings. The papers were generally of a high standard, and debate flowed enthusiastically and freely. Several international guests delivered seminal papers in their fields as discussed below.

Jan 1, 1996

By P. H. Qi

Activated carbon loaded with gold from different halide solutions has been characterized by thermal analysis techniques. The mechanism of gold uptake by carbon varies from predominately adsorption for gold iodide to predominately reduction for gold chloride. TGA and DT A measurements confirm the existence of adsorbed gold-halide species within the micropore structure of carbon. These results suggest that the ration of reduced; adsorbed gold increases for gold halides in the order Au-I > Au-Br > Au-Cl. In the case of Au-I, TA results for the loaded carbon were compared with pure compounds of 12, AuI and AuI3.

Jan 1, 1996

By B. J. Arnold

Utility coal specifications usually contain a requirement for a maximum moisture content in order to prevent coal handling problems and to minimize evaporative losses in the boiler. As most coal cleaning processes are water-based, dewatering and sometimes thermal drying steps are required to meet moisture specifications. Screens are often used for dewatering, with centrifuges and filters used to further reduce moisture in many cases. Algorithms to predict the performance of commercial dewatering devices were developed for the Coal Cleaning Simulator running under Aspen Plus? during a project sponsored by the U.S. Department of Energy and the Electric Power Research Institute. These algorithms include calculations for size degradation in the devices and fines loss to effluents, where appropriate, and a calculation for moisture content of the product based on particle size and specific gravity distribution. This paper discusses the algorithm for coarse and fine coal centrifuges and gives comparisons between predicted moisture and solids loss and published moisture and solids loss values for various particle size ranges.

Jan 1, 1996

By J R. "Dick" Daniel

One of the more common tasks in blast management is the adjustment of: shot geometry, explosive energy, and shot timing parameters to achieve changes in blast outcomes and costs. Many of these shot parameters, once a delayed blast is initiated, are modified by the development of new free faces which change the original or static input values to dynamic values. These newly generated dynamic values are easily calculated and find use in fine tuning shot adjustments and in rationalizing blast outcomes in a systematic manner.

Jan 1, 1996

By K. Osseo-Asare

"The molecular structural and solution chemical characteristics that underlie the surface activity of solvent extraction reagents are highlighted, with particular emphasis on the tendency towards reverse micelle and microemulsion formation. The physicochemical factors that lead to microemulsion-enhanced solvent extraction with chelating extractants are elucidated. Membrane-based contactor systems are described which are uniquely suited for enhanced solvent extraction with microemulsions. The possibility of combining solvent extraction with microemulsion-mediated materials synthesis is discussed. IntroductionThe discovery of new selective extractants has resulted in major breakthroughs which have helped to establish solvent extraction as a versatile separation technology (1-3). A complementary strategy towards new process development is to seek new ways of using the available reagents. This paper explores this second approach. From a molecular structural standpoint, an extractant may be viewed in terms of two components: a polar functional group and a hydrocarbon radical. In the conventional view of solvent extraction, this molecular structure serves two main purposes: The polar functional group provides the binding sites for complexation of metal ions, while the organic group is needed to render the resulting metal-extractant complex organic-soluble. But are these the only properties of the organic and the polar groups that are relevant to the solvent extraction process?In this paper, attention is directed to the fact that solvent extraction reagents possess the molecular structures of amphiphiIes; that is, they are characterized by the presence of spatially separated hydrophilic and hydrophobic groups on the same molecule. A case is made for the view that this amphiphilicity offers interesting opportunities to develop new separation processes which collectively may be described as enhanced solvent extraction (4-6)."

Jan 1, 1996

By Maurice Bottiau

The recent evolution of the piling market clearly shows a growing demand for screw piles with soil displacement. The recently developed Omega Screw pile ful-fill these new expectations, combining the advantages of vibration-free systems and the behaviour of a displacement pile. The paper describes recent experience and new applications with this very promissing pile. Full-scale load tests were carried out in different countries as U.K. or Sweden. A very attractive and innovative piled embankment is also described, using geogrids in order to transfer the loads from the superstructure to non-reinforced Omega-piles.

Jan 1, 1996

By Stephen A. Rholl

Computer software has been developed which uses fast Fourier Transform (FFT) techniques to analyze the frequency spectrum associated with peaks in ground vibration time histories. The procedure consists of filtering the FFT of a time history into individual frequency components.

Jan 1, 1996

By Robert C. Pease

Siskon Gold has started gold production at the San Juan deposit in northern California. The mine is located about 27 km (17 miles) north of Nevada City, CA (Fig. 1). It is scheduled to be-come the largest underground gold mine in California. It is situated in the western foothills of the Sierra Nevada Mountains in the Mother Lode gold belt. The property consists of 8 km2 (2,000 acres) of patented land. It is situated in a topographically high area known as San Juan Ridge, which is 213 m (700 ft) above and between the Middle Yuba and South Yuba rivers. The elevation is between 790 and 914 m (2,600 and 3,000ft) above sea level. Annual precipitation averages 1,346mm (53 in.). Most of that falls between November and April.

Jan 1, 1996

To provide accurate navigation and control of continuous mining systems.

Jan 1, 1996

By Hye-Sung Kim, Dong-Wha Kum, Gyeungho Kim

"Mechanical alloying is an effective way to finely distribute inert dispersoids in AI-TM (TM is a transition metal element) systems. It is considered that high melting point aluminides are formed by precipitation from the supersaturated aluminum matrix. The analysis is based on the fact that much higher content of TM than the solubility limit can be dissolved in alpha aluminum during the high energy ball milling. Nonetheless, the role of undissolved TM particles affecting the formation of aluminides is not suitably considered. In this paper, authors present experimental observation on the formation of Ab3Ti particles from mechanically alloyed AI-Ti alloys in the hyper-peritectic region. This study showed that, in the mechanically alloyed AI-20wt%Ti specimen, intermediate phase of cubic Ab3Ti and tetragonal AIz4Tis formed at 300 - 400°C and 400 - 500°C, respectively, before the MA-state reaches to the global equilibrium at higher temperatures. The formation behavior of Lh- Ab3Ti is interpreted by interdiffusion of Al and Ti in solid state based on the fact that large amount of nano-sized Ti particles exist in the milled powder. Present analysis indicated undissolved Ti particles of nanosize should have played an important role initiating the formation of Ab3Ti phase during annealing.IntroductionInterest in the hyper-peritectic AI-Ti alloys is based on industrial demand for high-modulus and high-temperature aluminum alloys. Earlier works on hyper-peritectic AI-Ti alloys with 4 to 12wt%Ti show that these alloys are strong at ambient temperature and maintain high strength above 300°C when titanium-trialuminide (e.g., Ab3Ti) is finely distributed in the aluminum matrix [1,2]. High melting point and high stiffness with low density of AbTi make the AI-Ti alloys strong with greater thermal stability while keeping weight savings as much as possible. Titanium in aluminum shares other merits of transition metal additions because Ti solubility in Al is low (i.e., 1.l5wt%Ti at 665°C and virtually zero below 400°C), and fine dispersion of Ab3Ti particles is readily accomplished and resists grain coarsening effectively."

Jan 1, 1996

By Funsho K. Ojebuoboh

With several “green” applications on the horizon, bismuth has become an even more important minor metal in the smelting and refining of lead. Smelters with a complex sulphide feed invariably deal with bismuth. Its behavior during the smelting of lead in conventional sinter-blast furnace operation is discussed. Because it readily deports to the lead phase during the refining of lead, its separation from refined lead remained unsatisfactory in early lead production. When commercial requirements of bismuth in lead became more stringent early this century, the procedure where by calcium and magnesium is used todebismuthise lead was developed. The present conduct of this 1936 process, the Kroll-Betterton process, is discussed with emphasis on operational improvements.

Jan 1, 1996

Jan 1, 1996

By Animesh Jha, Catherine Davey

"Carbothermic reduction and nitridation reactions using synthetic kaolinite mineral were investigated for the formation of silicon based nitrogen ceramics. The temperature dependence of the reaction rate and its effect on phases formed are reported. The effect of the reactivity of carbon on the kinetics of formation of AIN and ShN4 is discussed. Using the standard Gibbs free energy values for the formation of nitrides and oxides of aluminium and silicon, a log po2 verses I/T diagram is constructed. The experimental data results are discussed and compared with the predicted phase equilibria. We also report the influence of sub-oxide gaseous species on the microstructure of the ceramic phases produced.IntroductionSynthetic kaolinite is a clay containing alumina, silica and water of crystallisation, and has a chemical formula 3(Al2O 3.2SiO2.2H2O). This mineral is relatively inexpensive and, is therefore an ideal candidate for use in the production of ceramic powder mixtures for example silicon nitride and aluminium nitride for composite material formation, When the mineral is heated, the water of crystallisation from the crystal lattice is lost via the 3(Al2O 3.2SiO2.2H2O) = 3(Al2O3.2SiO2) + 6H2O reaction. It has been shown [1·2j that on further heating to 1673K, the anhydrous kaolinite decomposes to a mixture of mulllte and silica, 3(Al2O3.2SiO2) = 3Al2O 3.2SiO2 + 4SiO2 which is consistent with the alumina-silica phase diagram, shown in figure 1.The binary alumina-silica phase diagram has a well-defined sub-eutectic immiscibility dome and this characteristic dernixing behaviour is reflected in the thermal decomposition of anhydrous kaolinite consequently the microstructural features resemble the spinodal decomposition process. It is well established that the spinodal decomposition process raises the nucleation frequency due to their low free energy barrier, (?G). The small magnitude of this barrier consequently promotes the evolution of a very fine microstructure. The process of spinodal decomposition is therefore expected to be influential during the reduction-nitridation of kaolinite minerals."

Jan 1, 1996

By J. C. Yingling, R. J. Sweigard, S. T. Mickleborough

The geostatistical technique of conditional simulation is applied to measure the uncertainty inherent in the factor-of-safety (FS) predictions for soil slopes in which there is an incomplete knowledge of the spatial distribution of soil properties. A case study that considers a natural clay slope in Canada is presented. The sequential-indicator simulation technique was used as a means of generating a series of spatial maps of the soil properties at the site. These maps approximate random draws from the conditional probability density function that characterizes existing uncertainty in the spatial distribution. FS determinations were made for each simulated map using the simplified-Janbu approach. In using this approach, computations are performed using a new computer program that can operate on irregular spatial profiles of soil properties specified on a discrete grid. A unique capability of this approach is the ability to generate the FS distribution conditional to the type, position and value of existing site-characterization measurements. This capability should reduce uncertainty in FS predictions.

Jan 1, 1996

By E. R. Torak

Custom Coals, International has installed and is presently testing a 225 kg/hr. (500 lb/hr.) micronized-magnetite, fine-coal cleaning circuit at PETC's Process Research Facility (PRF). The cost-shared project was awarded as part of the Coal Preparation Program's High Efficiency Preparation Subprogram. The project includes design, construction and testing of a fully-integrated, bench-scale circuit, complete with feed coal classification to remove the minus 30 micron slimes, dense-medium cycloning of the 300 by 30 micron feed coal using three different size micronized-magnetite mediums, and medium recovery circuits using drain and rinse screens and various stages and types of magnetic separators. This paper describes the project circuit and goals, including a description of the current project status and the sources of coal and magnetite which are being tested.

Jan 1, 1996

By Richard P. Curtin, John M. Goris, Lewis A. Martin

Cable bolt supports are being recognized as an effective ground control system in under-ground coal mines in North America, and their use has increased considerably during the past few years. The U.S. Bureau of Mines personnel are conducting both laboratory and field tests to evaluate the performance of these supports under a variety of conditions and to establish realistic design guidelines. This paper describes efforts to evaluate the capability of cable bolts to resist the high shear forces often present in longwall operations. Shear tests were conducted on pairs of 0.025 m3 (0.88 cu. ft) concrete blocks having joint surfaces ranging from rough to smooth. Tests were conducted on blocks both with and without reinforcement with 15.2 mm (0.6 in.) diameter steel cables. During each shear test, the loads and displacements along the normal and shear axes, as well as loads on the cable, were monitored. Cableloads were determined using strain gauges attached to the outside surfaces of the barrel-and-wedge anchors used for pretensioning the cables. Test results show that a cable bolt placed across a joint more than doubled shear resistance of shear blocks having both smooth and rough joints.

Jan 1, 1996

By M. D. Johnson

Mina Santa Rosa, in west central Panama, is the first large-scale gold mine in Panama and will soon be the largest single-mine gold producer in central America (Fig. 1). At full production, the mine will process 1.8 Mt/a (2 million stpy) of ore and produce more than 1.8 t/a (60,000 oz/year) of gold and 9.3 t/a(300,000 oz/year) of silver. Mina Santa Rosa is a subsidiary of Greenstone Resources of Toronto, Ontario. Freeport-McMoRan geologists first visited the area in 1985. Their rock chip sampling adjacent to old shafts and adits confirmed widespread gold and trace element geochemistry anomalies. Surface mineralization appeared to be localized in and adjacent to narrow veinlets. However, they recognized astructural setting similar to the Nevada Tertiary volcanic-hosted epithermal gold systems.

Jan 1, 1996

By G. A. Campbell

This paper considers the international market trends of the rare earths and how they are strongly influenced by the by-product/co-product nature of their mining and processing. The two main economic minerals for the rare earths are bastnasite and monazite. Monazite is primarily a by-product of mining ilmenite and rutile and is affected by changes in these markets as well as the presence of thorium. Bastnasite is a by-product of mining iron ore in China and a stand-alone product in the USA. The paper will use conceptional relationships and empirical data to delineate the various by-products/co-products relationships and how they determine observed international market behavior.

Jan 1, 1996

By G. A. Kordosky

The literature contains several references to the influence of copper solvent extraction reagents on crud formation, but, there is disagreement as to whether the reagent has an influence on crud generation. The results of three pilot plant campaigns, where crud generation was studied as a function of the copper solvent extraction reagent, are reported. These pilot plants were run at operating copper solvent extraction plants using the aqueous solutions being treated by the commercial copper solvent extraction plants. Two of the pilot plant studies showed that the copper solvent extraction reagent had a significant influence on the extent of crud formation while the other pilot plant study indicated the copper solvent extraction reagent had a lesser influence on crud generation.

Jan 1, 1996

By Xinghui Meng

The leaching behavior of platinum powder in .iodide solutions under oxygen pressure in an autoclave was investigated. Ammonium salts were added to the leaching solution at neutral pH as a key lixiviant for platinum. The effect of temperature, partial pressure of oxygen, concentration of iodide and of arttmonium salts on the dissolution rate of platinum was examined. Under experimental conditions, the leaching behavior of platinum powder exhibited a complex reaction mechanism. A precipitate was found during the leaching process and was identified to be platinum ammine iodide, Pt(NH3hI4. The dissolution rate was controlled by a series of chemical reactions, the equilibrium concentration of the platinum ammine iodide being responsible for the ultimate limit to the recovery.

Jan 1, 1996