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By Andre L. De Vegt

For the past eight years Paques has been engaged in the development and installation of treatment systems based on biotechnological processes to remove sulfur compounds from water, air and gaseous streams. Metal and sulfate can be removed from mine waters using two biological steps: 1. Sulfate reducing bacteria convert sulfate to hydrogen sulfide (HzS). The HzS reacts with the dissolved metals to form insoluble metal sulfide precipitates. 2. Sulfide oxidizing bacteria convert excess H2S to elemental sulfur. Paques has designed and installed a groundwater treatment system for the Budelco zinc refinery in the Netherlands to remove metals and sulfate as described above. The system has been operating since May 1992 treating a flow of 5000 m3/d. A test program, utilizing a large scale pilot plant, will commence in November 1995 at a copper mine in the U.S.A. to remediate groundwater contaminated with sulfate and heavy metals. Biological reactor performance and selective metal recovery will be studied. Sulfur dioxide (S00 can be removed from fluegas using a combination of scrubber technology and the two biological steps. The end product is elemental sulfur. A commercial size biological desulfurization plant has been in operation since July 1994 treating 50,000 Nm3/h of fluegas. Sulfide can be removed from mining waters or anaerobic wetlands using a THIOPAQ® Sulfide Oxidizing reactor.

Jan 1, 1996

By Thomas P. Battle

Ilmenite (iron titanate) is the source of over 90% of all the titanium produced in the world today. At some point during production of titanium dioxide or titanium metal the iron impurity must be removed. Too often it becomes a waste instead of a product. DuPont and MINPRO have developed a solid-state process which separates the iron and titanium components of ilmenite into different high-purity powders, which can be separated using conventional mineral processing techniques. The main reactor in this process is a unique high-temperature ball mill, where the iron segregates from the ilmenite lattice with the assistance of catalytic quantities of He\. The results of lab, pilot plant, theoretical, and scale-up studies are presented and discussed.

Jan 1, 1996

By Peter K. Eriksson

Nanofiltration is very efficient in separating heavy metals from water solutions, even if they contain strong acids. Desalination System, Inc., has many years of experience in this area, and this paper deals with three different such cases. The first case deals with concentrating the heavy metals in the pregnant leach solution from a copper dump leaching site with a surplus water problem. The increased copper concentration in the pregnant leach solution increases the capacity of the following copper extraction stage. The nanofIltration permeate is polished with a biomass adsorption column to remove the small amounts of remaining heavy metals, before being discharged. This method eliminates sludge handling and disposal, which are quite costly with the alternative precipitation process. In the second case, a complicated precipitation method was used to remove heavy metals from the waste stream of a specialty metals manufacturer. Nanofiltration was installed to increase the metals concentration four times, which greatly simplified the precipitation process. The chemical consumption and sludge production decreased by more than 80 percent, and the labor cost decreased by 66 percent. In the third case, nanofiltration was used to purify waste sulfuric acid solutions containing heavy metals, to meet the specifications for technical grade acid. Sulfuric acid concentrations above 30 weight percent were successfully purified in a multiple pass membrane system.

Jan 1, 1996

By J. H. Kelley

In this paper, we show that the methane emission and the dust generation in under-ground mining currently and in the future pose operational, health and safety conditions which adversely Impact face productivity and worker satisfaction. One solution is the use of a dual-aircourse system of ventilation. In this concept, one aircourse captures and exhausts to the surface the dust generated and the methane emitted in coal/mineral fragmentation while a second aircourse provides workers with cleaner air for breathing and comfort. Various dual-aircourse configurations adapted to the Variable Wall Miner are analyzed and compared with conventional mining in gassy seams, indicating a marked reduction in the required air quantity and the number of aircourses.

Jan 1, 1996

By Versiane A. Leão

The adsorption of oleic acid and amine, by Expanded Hydrophobized Vermiculite (EHV) was studied. In appropriate conditions EHV is a good adsorbent for these flotation re-agents and the best results are obtained at situations where the chemicals are at non-dissociated form. The adsorbent shows good chemical stability and may been used in many adsorption-desorption cycles.

Jan 1, 1996

By H Bibby

Initial analysis of Long Offset Time Domain Electromagnetic (LOTEM) data has traditionally been made in terms of early and late time apparent resistivities. By using more than one grounded bipole as a source, a tensor analysis technique analogous to the method used to analyse DC resistivity multiple-source bipole-dipole surveying may be formulated. We define the æinstantaneous apparent resistivity tensorÆ as the tensor that relates the total electric field vectors at each instant to the steady state (DC) uniform half space current density vectors due to each source. Instantaneous apparent resistivity tensors calculated for a 3D resistivity model suggest that profiles of LOTEM measurements across simple 3D structures can be used to create an image that reproduces the main features of the subsurface resistivity. Where measurements are distributed over an area, maps of the tensor invariants or the tensor ellipses at different times can be made into a sequence of images which provide a way of ætime slicingÆ down through the target structure.

Jan 1, 1996

By F. H. A. Abdalla

A process is described for the recovery of valuable nonferrous metals from steelmaking dust by suiphatizing roasting using ammonium sulphate. Maximum recoveries of soluble metal sulphates achieved at optimum conditions were> 99.0 %. Selective metal separation of the soluble sulphates in the leached liquors were performed either by controlling the roasting temperature or by adjustment the pH values of the leached liquor ranging from 3.6-6.2. Either pure zinc oxide orland tin oxide could be obtained at optimum conditions, and the products were evaluated chemically and by X-ray analyses. The residues rich in iron oxide can be removed and recycled. The mechanism of sulphatizing roasting process was considered. A general flow-sheet for the overall process of treatment the steel making dust to recover its valuable nonferrous metals was suggested, which ca be applied for other nonferrous bearing materials.

Jan 1, 1996

By John R. Holliday, William Marcum

Apogee Coal Company, DBA Arch of West Virginia, faced the challenge of drilling and blasting over one million cubic yards of high temperature overburden at its Ruffner surface operation near Logan, West Virginia. The overburden was removed above the Upper Five Block seam that was previously deep mined, abandoned, and later engulfed by fire. Borehole temperatures were measured above 700” F.

Jan 1, 1996

By Thomas Oberndorfer

INTRODUCTION Since several years the author is engaged in research activities in the field of mining method modelling (Oberndorfer, 1993 and 1994). The initial goal was to improve and assist the selection of the most appropriate mining method. However during investigations it became obvious that the most beneficial application of computer support is the fast calculation of numerical assessment rather than the consideration of all, i.e. also qualitative, criterions necessary for final decision. Numerical results serve - together with qualitative considerations based on the experience of the mining engineer - as a basis for decision. The emphasis is on "fast" calculation, as only this property makes it possible to calculate and compare many distinct variations. As long as no procedure exists, which optimizes all involved parameters, calculating many variations is of great important, because it is the only way to increase the chance to pick a alternative "close to optimum", but also to learn about the sensitivity the result will react on changes of input parameters, which are rarely known exactly. Generally speaking many trials give a better basis for final decision. It is no secrete that the most important obstacle towards quick calculations of a series of alternatives is not the processing time of the computer, but the time required for setting the input data in way that the computer can start processing, which is usually inter- active man work on the screen. Furthermore usually several distinct programs are required to cover the whole range of involved problems, with corresponding problems in automatic data transfer. The research work's goal was to overcome these problems. The approach developed was to describe a mining method more in a theoretical way (i.e. to give the computer some degree of "consciousness" on mining methods), which then can be applied under any specific conditions. E.g. a cut-and-fill operation will be "generally" the same in narrow or thick deposit areas, but the resulting keyfigures, e.g. total tonnage, productivity, dilution and loss, or finally costs per ton, will differ significantly. The approach (MMM = mining method modelling) presented reflects a deduction from the general case to a specific one (rather than the other way round). The developed model is general enough to be applicable to any mining method, and also to any degree of precision the mining method should be described, contrary to programs designed for specific mining method layouts which can be adjusted in a more or less wide range. PROGRAM DEVELOPMENT The principle correctness and feasibility of the approach was proved by a prototype program. However this program was more on a research level and far away from application for "real world" problems. The reason for this was, that it was regarded wasted time to re-invent certain tools, e.g. geometry intersection, deposit modelling or visualization. Hence it was tried to attract several software producers to invest in finalizing the model. Unfortunately this endeavor was not successful. Despite this defeat - and after some months of resignation - a final start on the project was decided. he reason for this decision was not at last the research activity in respect of low-cost underground mining methods for bulk- material as a substitute of typical quarry operations due to environmental restriction. This research work - which is in particular important for Austrian mining activities in beautiful and touristically used landscape - requires a lot of calculations in the way described. Both are still in state of progress, but - regarding mining method modelling - preliminary results can be presented. A complete re-programming of the program was required. Most obvious are the changes of programming language and operating system environment. Instead of Pascal under DOS C++ under MS-WindowsNT is now used. Several problems could be solved by this, in particular memory management, device drivers for input/output, and user friendlyness by up-to-date windows technology. However also more basic structures were changed. The idea was to utilize as many existing commercially available programs as possible to minimize programming efforts. WindowsNT helps already a lot by MFC technology, but also due to its multi-task facilities. This feature allows to run simultaneously several pro-

Jan 1, 1996

By A. B. Desai

The construction of 1144 nos. of piles, each 1.5 m diameter, bored-cast-in-situ type and varying in depths from 6.5 to 23m, has been completed as foundation for 26 piers of 548 m long aqueduct across Orsang river to carry 1128 m3 water of Narmada Main Canal of the Sardar Sarovar Project in Gujarat. These piles are socketed 1.5 m into foundation grade rockmass. The portal system of 44 nos. of piles and pile cap at the top for each pier is analyzed considering the portal fixed at bottom of piles. The borings for pile shaft were done deploying reverse mud circulation rigs and also by conventional chiseling and bailing operations. Besides vertical loading tests and lateral loading test on piles, dynamic tests such as low strain integrity testing on 290 piles and high strain pile testing on 17 piles were also conducted. The results indicated that (a) the settlement/ displacement are much less than the prescribed limits (b) good quality of concrete (c) piles are firmly socketed and (d) piles have adequate structural capacity to withstand the design load.

Jan 1, 1996

By H. Cetin

The availability of coal resources of selected 7.5-minute quadrangles of southwest Indiana was examined in this study. Resources were defined as original coal in place, remaining after mining, and currently available considering land-use and technological restrictions. The amount of coal mined from each study area varies depending on the mining practices of the companies operating within the area. Of the three quadrangle investigations, the available resources range from 50 percent to 79 percent of the original resources. Most of the coal resources under deep-minable category were not available because of technologic restrictions, such as insufficient coal thickness.

Jan 1, 1996

By Tatsuro Ariyama, Michitaka Sato, Atsushi Sakai, Sumiyuki Kishimoto, Ryota Murai

"In order to achieve high pulverized coal injection operation in a blast furnace, optimization of the injection lance arrangement was carried out using an experimental furnace and mathematical models. To increase the injection rate of pulverized coal, it is required to raise the combustion efficiency of pulverized coal. It became clear that multi-point injection and the lance arrangement to avoid interference among the coal streams injected were so effective in increasing combustion efficiency. With these findings, the eccentric double lance arrangement has been newly developed.At NKK, Fukuyama No.4 Blast Furnace, after the improvement of the lance arrangement, the maximum injection rate reached up to 230 kg/thm and an average monthly record of 218 kg/thm was successfully achieved.IntroductionFrom the viewpoints of reducing the production cost of pig iron and prolonging coke oven life, high pulverized coal injection over 200 kglthm is actively pursued by ironmaking industries[1-2].Coal particles injected into the blast furnace are consumed by combustion in the raceway and also in-furnace reaction like solution-loss reaction (C + CO2 = 2CO). The amount of coal consumed by the latter process is determined by the carbon balance in the blast furnace and there is a limit. Therefore, to increase the injection rate, it is desirable to improve the combustion efficiency in the raceway. For these purposes, the optimization of the lance arrangement was examined by a hot model and mathematical models."

Jan 1, 1996

By Redhead Robert J.

"In 1991, the Canadian Council of Ministers for the Environment (CCME) charged its Waste Management Task Group with developing a nationally coordinated strategy to measure, monitor, and achieve the objective of decreasing the generation of waste (solid and hazardous) by50% from 1988 levels by the year 2000.With the encouragement of the CCME, which viewed hazardous waste as largely an industry problem, a committee, the “Industry Action Group”, representing eleven industry trade associations with a strong interest and involvement in hazardous waste was recruited.The Municipality of Markham, Ontario was also recruited (Appendix 1)."

Jan 1, 1996

By J. R. Allan

Loki Gold Corporation of Vancouver, B.C. is developing the Brewery Creek Mine, an open pit heap leach gold mine, 55 km East of Dawson City in Yukon, Canada. Mineable reserves are 17.1 million tonnes of ore grading 1.45 grams/tonne, containing 24.8 tonnes (797 000 oz) of gold. Ore processing will employ a cyanide heap leach using run of mine ore. Permitting this mine has drawn significant attention because the heap leach technology, while proven in other jurisdictions, has not been used in Yukon. Engineering design of the heap leach was similar to that for heaps in more temperate climates, with the added issues of permafrost and cold weather operations. Solution balance with seasonal placement of ore and year -round leaching requires very large pond capacity for spring thaw conditions.

Jan 1, 1996

By C. L. Jiang

The role of iron ions (Fe2+ and Fe3+) in the flotation of both ore-and coal-pyrite with ethyl xanthate was comparatively investigated. The complete/partial depression of ore-and coal-pyrite in neutral to weakly alkaline solution is due to the formation of ferric dihydroxy ethyl xanthate between xanthate and the oxidation products of pyrite, ferric and ferrous ions. With xanthate as collector, coal-pyrite was found to be nonfloatable above pH6. In the presence of iron ions and between pH6-9.5, the flotation of ore-pyrite was significantly depressed. Ferrous ions have a stronger effect on pyrite flotation than ferric ions in neutral to weakly alkaline solutions.

Jan 1, 1996

By P. Davies

The Hillside Smelter presently under construction at Richards Bay, Republic of South Africa, will be, on completion, the fifth largest aluminium smelter in the world. The site selected for this plant is underlain by sandy soils of variable density to depths of 30m or greater. In order to firmly establish pile founding depths required for alternative pile types in the variable subsurface conditions prevailing across the site, a pre-construction test piling programme was conducted incorporating piles instrumented with resistance strain gauges. The results allowed analysis of the relative contributions of end-bearing and shaft friction to the overall bearing capacity of each pile type and permitted comparison with the predictions of conventional static bearing capacity analyses. Conformance with acceptance criteria in respect of allowable pile head movements for single piles was also examined.

Jan 1, 1996

This paper sets out to discuss how alluvials - particularly mineral sands, tin and gold have adjusted to meet the problems of lower grade and more difficult physical political and economic conditions. The mineral sands industry seems to have adapted satisfactorily but less so with tin and gold.

Jan 1, 1996

By E. Forssberg

Studies have been carried out with the High Pressure Roller Mill, HPRM, to produce calcium carbonate minus 10 micron. This paper presents the optimization of the specific grinding force of the HPRM system for a maximum energy utilization when limestone is ground. In addition, experimental tests of producing carbonate minerals using the HPRM as a pre-crusher are described in this paper.

Jan 1, 1996

By J. A. Innes

"""The oxygen, next uniting with the carbon, sent up an ever-increasing stream of sparks and a voluminous white flame. Then followed a succession of mild explosions, throwing molten slags and splashes of metal high up into the air, the apparatus becoming a veritable volcano in a state of active eruption.""IntroductionHenry Bessemer F.R.S(An autobiography, 1905)Thank you Mr Chairman for the opportunity to speak: at this, the opening session of your International Symposium on the subject of ""Injection in Pyrometallurgy"". Judging from the list of papers to be presented over the next three days, the Symposium promises to provide a most valuable addition to our existing knowledge base in what is now an extremely active area of R&D investigations. Whilst we have obviously come a long way since Sir Henry Bessemer's pioneering experiments of the mid-19th century, there is still much for us to learn.Most importantly, the Symposium offers a further opportunity to acknowledge the many significant technical contributions made in this field by the Organising Committee's special guest, Professor Howard Worner - one of this country's most respected research leaders.When first approached to give this talk I had two areas of concern. Firstly, I was not entirely clear just what injection metallurgy was meant to cover. How should the overall scope of this particular subject be defined?My second concern related to Howard Worner himself - a man for whom I have the highest personal regard and who, in fact, played a most influential role in respect of shaping my own career. Having already spoken about Howard's achievements on earlier occasions, I wondered what I could sensibly add.Notwithstanding these personal reservations, I am delighted to be here with you this morning. If my thoughts on the meaning and scope of injection metallurgy appear to be slightly off-course, and if Howard should perhaps recognise some repetition in my remarks, then I hope I can be forgiven."

Jan 1, 1996

By K. Rambha Devi

The paper is an attempt to co-relate the findings of pile capacity using a number of formula suggested by various authors with the actual field load test results. Five locations consisting of wholly sandy or clayey soils were selected for this purpose. The clayey soils are on a hilly area having clays of medium to stiff consistency upto a depth of 20 m The sandy soils are near the bank of a river having angle of internal friction 'Ø' value ranging from 30 to 35 Degree. The details of the soil properties are given in Table-1 Bored cast-in-situ piles of 30 cm diameter and a length varies from 6.5 m to 13 m were designed and cast for load test to be carried out. The load applied was twice the design load. The load vs settlement curves were obtained. The theoritical values obtained by formula suggested by various authors were superimposed on the curves. From the careful study of these curves it is seen that De Ruiter and Berigen values are close to the actual results for clayey soil. For sandy soil it is found that both the BIS method and Meyerhof method found to give conservative resuslts. A multiplication factor is suggested to theoritical values for obtaining satisfactory results.

Jan 1, 1996