Search Documents

By E. J. Sullivan

This study seeks to define the mechanism of oxyanion sorption onto surfactant-modified zeolites. Zeolites which have been treated with hexadecyltrimethylammonium bromide (HDTMA) surfactant to produce a hydrophobic surface are capable of sorbing both organic compounds as well as oxyanions such as chromate, selenate, and sulfate. Simple ion exchange and charge-balancing mechanisms do not fully explain this unusual phenomenon. The sorption of HDTMA surfactant appears to be partly ion exchange and partly sorption to non-ion-exchangeable sites. Sorption of chromate is a simple exchange mechanism with bromide, which co-adsorbs with HDTMA to form a surface precipitate. Information from this study will be used to design on-site and in situ treatment systems for contaminated water, such as filter beds and permeable barriers.

Jan 1, 1995

Mines in the Lake Macquarie region of New South Wales, Australia, are faced with the dilemma of having to introduce longwall mining techniques at a time when increasingly large areas of the surface are being used for urban development. Increasing pressures on safety, costs and productivity performance dictate that longwall mining is the method for the future. Construction of surface structures is controlled by a statutory body known as the Mine Subsidence Board (MSB). All surface structures have to be designed to MSB criteria. All mining plans involving secondary excavation also have to be submitted to the MSB for approval. The Board acts as risk assessor in evaluating acceptable levels of surface subsidence vs. the value of the coal resource. Surface repairs are paid for by a levy on all coal producers.

Jan 1, 1995

By C. E. Jordan

The Bureau of Mines has investigated the fundamentals of fatty acid/fuel oil conditioning for improved flotation selectivity. Both conditioning time and intensity can provide optimum flotation selectivity as well as good recovery. Traditional conditioning seeks to optimize conditioning parameters with subsequent recovery of the hydrophobic mineral. In the fatty acid/fuel oil system many silica gangue particles are also rendered hydrophobic by the flotation collector. Fundamental studies have shown that particle-particle collisions transfer the collector reagents selectively to the mineral surfaces with the highest affinity for the reagent. This mechanism deactivates the gangue particles while increasing the collector reagent loading on the selected mineral. The degree of this transformation is directly related to the number of particle-particle collisions which can be controlled through conditioning time or conditioning mixing intensity.

Jan 1, 1995

By J. V. Atwood

The U.S. Bureau of Mines has developed a novel Double Membrane Electrolytic Cell (DMEC) that exhibits unique features for recycling contaminated metals and metal alloys. The DMEC incorporates two anionic ion exchange membranes, separating anodic and cathodic regions of the cell. The ion exchange membranes prevent significant transport of unwanted cationic impurities to the catholyte from the impure anolyte while the anion/cation balance in cell compartments is maintained through the free movement of anions between compartments. The membrane barrier makes it possible to electro refine highly contaminated materials or to electrowin from solution while utilizing alternate anode reactions. Sinceanolyte and catholyte cross contamination has been eliminated, premium cathode products are produced. The DMEC has been tested at bench, pilot, and commercial scales. Configuration of the DMEC, cell operation, scale, up efforts, and significant design factors are discussed. Two separate recycling investigations utilizing DMEC technology are presented. The first investigation examines recovery of high purity cobalt and nickel from severely contaminated super aIloy scrap. The second involves? upgrading contaminated cobalt in the U.S. Government's National Defense Stockpile. Capital and operating costs for both potential applications are presented.

Jan 1, 1995

By John Heilig, Patrick Andrieux

"Near-field monitoring of blast induced seismic vibrations is a practical and useful way of assessing blast field behaviour for diagnosis and optimization purposes. It is also necessary in order to provide the information from which empirical vibration prediction equations, such as the one proposed by Holmberg (11 for example, can be derived. (Strictly speaking, the “near field” extends from the blasthole itself to about one charge length away from it; however, throughout this article, “near field”will.most often refer to the outer limit of this zone, from roughly 0.75 to 1.50 charge length away.) In order to obtain reliable data, proper field monitoring techniques are of paramount importance. Once the data are properly recorded, analysis can be done either in the time domain (describing vibration amplitude vs. time) or in the frequency domain (usually describing vibration amplitude vs. frequency)."

Jan 1, 1995

By Morris Wong

"An antimony-bearing gold ore was studied in a cyanide slurry containing 7 -20 ppm dissolved oxygen. 1 g/L NaCN at pH 9.5 and 48 hours retention time is required to extract 94 % of the gold from the 90 % minus 200 mesh ore by conventional cyanidation at a 7 ppm O2. As oxygen concentration was increased to 20 ppm, the conditions required to extract the same amount of gold were: 0.25 g/L NaCN, 16 hours retention time and 80% minus 200 mesh. Compared to conventional cyanidation, oxygen-enriched leaching was shown to reduce retention time by three times and cyanide consumption by four times. The kinetics of gold dissolution related to the dissolved oxygen concentration in slurry was expressed by following equation:XAu = 100 * (Kt + I0) / (1 + Kt + I0)where XAu is the percentage gold extraction; t is the retention time; K and Io are the slope and the intercept of the plot of XAu I (100 -XAu) vs. t respectively. The values of Kand Io depend upon the concentrations of cyanide and oxygen, the fineness of grind and the origin of ore sample etc.. A preliminary cost analysis was also performed to justify the use of oxygenating slurries.IntroductionGeneral:It was proposed almost 149 years ago (Elsner 1846) that oxygen is required for the dissolution of gold in cyanide solution. However, little attention were paid to oxygen application in the gold milling industry during the following one hundred years. Due to the constraints of gold price, reagent costs, refractory ores, and environmental issues in the past decade, the oxygen enhancement in the cyanidation process was introduced to the gold milling industry for increasing operation efficiency, reducing production costs, and meeting the requirement of environmental standard.The advantages of oxygen-enriched cyanidation have been reviewed by several investigators (Hague 1992, Jara et al 1992, Henderson 1989, Loroesch et al 1988, Elmore 1987, Cathro 1963). Common to all conclusions are the following advantages."

Jan 1, 1995

By R. Kanniganti

The primary problems of pillar design in seams subject to interaction are due not only to difficulties in predicting loading, but also to the often unsymmetrical nature of the stress fields. The effects of uneven stress fields on failure patterns within a pillar were studied wing a two dimensional finite element method. Lower seams, including ultra- close mining situations were evaluated considering conventional pillars. Pillar case study data for under mining were analyzed to determine if empirical trends in stable pillar sizing could be derived. Recommendations for multi-seam pillar design are made, based on anticipated loading conditions within a pressure bulb. Applications of the research results are demonstrated using case studies

Jan 1, 1995

By P. Tsang

To gain insight into the current status of pillar design practice in the underground coal mines of United States, a survey has been undertaken in the late 1993 and early 1994. A total of 552 room-and-pillar mines and 75 longwall mines have been surveyed to collect general, geological and mine plan information. The collected information are critically analyzed with special emphasis on the pillar design criteria adopted in these mines. A safety factor analysis has also been carried out for the pillars in room-and -pillar mines.

Jan 1, 1995

By Edgar Peek

Lixiviant regeneration is by definition a precondition for any hydrometallurgical process. In chloride hydrometallurgy either HCl or Cl2 has to be regenerated in order to establish an economically viable metallurgical process. One such regeneration process is widely used with steel pickling where HC1 is regenerated through the thermal decomposition of ferrous chloride in either spray roasters or fluid bed pyrohydrolyzers. This standard HC1 regeneration process deserves to be considered as a potential separation process, since thermodynamic calculations show that a fluid bed pyrohydrolyzer can function as a ferrous-nonferrous separator. Several nonferrous,metals such as zinc, lead and cadmium can be volatilized as a chloride under ferrous chloride pyrohydrolysis conditions. If such a nonferrous metal volatilization could be achieved in the case of slurry feeding of "contaminated" iron oxides, then this would increase the Fe/H2O ratio of the (process) feed and thus save on fuel per ton of iron, while yielding a marketable iron oxide product. Previous test work on synthetic materials revealed that the near-complete separation of zinc, lead and cadmium from iron oxide was possible in a pyrohydrolytic atmosphere, even if zinc was present as zinc ferrite (more than 99.5%). This investigation, which was carried out in a tube furnace at 1100 K has now been extended to treat synthetic zinc minerals and also franklinite ore. For the latter, it was found that 85% zinc volatilization could be achieved in 4 hours at 1300 K. It is postulated that complete zinc volatilization could not be attained due to the formation and/or presence of gahnite and hardystonite, which might be stable in HCl/H2O atmospheres at 1100 K. The effect of adding small amounts of calcium chloride to react with gahnite and hardystonite to give zinc chloride and both calcium aluminates and silicates is being discussed. Test work on slurry feeding of this complex ore in a recently constructed 4-inch diameter fluid bed pilot unit has been planned for the near future.

Jan 1, 1995

By S. Ajima

The Naoshima Smelter and Refinery is the most important copper operation of Mitsubishi Materials Corporation. There are a Mitsubishi Continuous smelter and a conventional type of copper tankhouse. The continuous smelter with 240,000 mtpy of anode production was commissioned in May 19914 replacing two existing smelters, i.e an original Mitsubishi Process line and a conventional reverberatory furnace line. In July 1992, the copper tankhouae was expanded for the purpose to close the gap of production capacity between the smelter and the tankhouse. The cathode production capacity was increased from 13,800 to 15,800 mtpm. By these plant modifications, the distribution of minor elements was significantly changed and the impurities load is getting on increase reflecting recent shortage of clean copper concentrates supply. The paper discusses the distribution of minor elements and the impurity control strategy at the smelter end the refinery.

Jan 1, 1995

By M. A. Giralico

Solvent Extraction (SX) technology has undergone significant refinements including outright process changes to achieve greater copper production rates with lower organic entrainment levels. LIGHTNIN has completed a detailed study aimed at improving on the conventional Holmes & Narver and Davy Power Gas type impeller designs1 by optimizing the mixing through the use of high efficiency pumper turbines instead of making system changes as others are doing. Since each individual installation requires a different design head and flow, LIGHTNIN has developed the R320 "family" of high efficiency, curved blade pumper turbines. These impellers are designed to maximize head and flow while reducing entrainment through lower power consumption, less shear generation and turbulence, elimination of air incorporation, production of the optimum droplet distribution, and lower tip speeds. These improvements also maintain the required mass transfer and copper recovery of the traditional impeller designs. The R320 impeller benefits have been quantified using Laser Doppler Velocimetry (LDV) and proven in multiple domestic and foreign installations at flow rates exceeding 15,000 GPM. Design comparisons of this improved impeller type versus traditional technology impellers in head, flow, power and entrainment are presented for review. In addition, the inherent benefits of axial flow, high efficiency impellers like the A3 1 0 and A6000 in auxiliary mix chambers will be discussed. The high flow, low shear characteristics of these patented impellers provide the necessary dispersion stability for mass transfer while speeding phase disengagement in the settlers due to low power and low shear input.

Jan 1, 1995

By Robert F. Holub

The U.S. Bureau of Mines (USBM) has tested a personal dosimeter for measuring radon decay products that is manufactured by Tom Scurry Associates. The tests were made to determine the accuracy of the dosimeter system for record keeping of radiation exposures to radon decay products encountered in mining. The radioactivity-detecting head is based on a design developed by the USBM, and the associated air pump was developed by the manufacturer. The dosimeter system was tested in the USBM radon chamber. The detecting head uses CaF:Dy thermoluminescent phosphors and is mounted on a self-regulating air pump. Batteries supply power sufficient for an 8-h shift. The dosimeter system is worn on the miner's belt. Dosimeter calibration tests were performed by the USBM. In addition, the pumps were tested and evaluated under continuous flow conditions. The results of these tests indicate that the Tom Scurry Associates Model DOSI600 dosimeter is suitable for general use in mines where record keeping for natural radiation exposure is required.

Jan 1, 1995

By Ghassan Skybey

Australian coal mines uses state of the art technology in coal rib reinforcement. This paper highlights the development over the past 15 years in coal rib support technology, along with the advantages and disadvantages of each system. It also outlines the current trend in using coal rib reinforcement in speeding up the dowels installation to improve the current low drivage rate. An innovative cuttable dowel is discussed which improves the drivage rate. This new dowel is self anchoring it uses no resin anchor it has a 5 tonnes (5.51 tons) anchor capacity and can be fully installed in approximately 10 seconds.

Jan 1, 1995

By Michael K. Rhodes

A 120 tonne per day BacTech bacterial oxidation plant treating refractory gold concentrates for Gold Mines of Australia's Youanmi project in Western Australia commenced operation September 1994. This was the first commercial application of the BacTech process. A pilot plant trial on concentrates produced from Youanmi ore was carried out at BacTech's laboratory in Perth. Results and measurements from this trial were used by Signet Engineering Pty Ltd to design the commercial plant. This paper cover the results obtained from the piloting, their implementation in the plant design and the initial commissioning of the full scale plant.

Jan 1, 1995

By N. V. Gorelikova

A new type of zirconium mineralization has been recognized in the Devonian volcanic rocks from an orogenic depression in the Central Kazakhstan. The most characteristic features of this deposit are the fine-grained nature of the zirconium mineralization, an unusual texture of the zirconium ores, and a close association of zirconium with phosphorus in the ores. Zircon grains form fine globular aggregates with the features of hexagonal crystal habit. In addition to crystalline zircon, the ores contain metacolloidal zircon, similar to hydrozircon. The morphological and textural features of the zirconium ores suggest that the deposition of ore deposits took place at a low temperature from colloidal solutions. It is believed that this deposit should be considered to be a new type of zirconium mineralization that is related to low-temperature hydrothermal processes.

Jan 1, 1995

By A. K. Bakshi

Mineral suspensions show Newtonian flow properties at lower solid concentration, but change into non-Newtonian regime as the solids content is increased. For Newtonian fluids viscosity is independent of shear rate, but for non-Newtonian fluids it varies with rate of shear. Therefore, measurement of viscosity at a shear rate, different from the process will be futile unless the slurry is Newtonian. This is especially true for hydrocyclone operation, where the rate of shear is different at different points within the hydrocyclone. In this case, it is very important to determine the flow type of the suspension before attempting to establish any correlation between viscosity and process efficiency. A new technique to distinguish such changes in flow type has been developed. This involved a co-axial cylinder type viscometer which measured apparent viscosity at a low shear rate, and a vibrating sphere type viscometer which measured the apparent viscosity at a high shear rate. Special precautions were taken to allow measurements of viscosity of rapidly settling mineral suspensions. Because the vibrating sphere viscometer operated at a much higher shear rate than the rotating viscometer, the two instruments together could determine the shear-rate dependency of the viscosity. Ground silica of 80% passing 65~m size in water was used to prepare slurries at concentrations ranging from 1O-70wt% solids. Viscosity of each slurry sample was measured simultaneously by both the viscometers and the results were compared with each other. With this technique, it was found that all the silica slurry samples were in the Newtonian flow regime.

Jan 1, 1995

By Edita Vircikova

The best demonstrated available technology (BOAT) for the removal of dissolved arsenic and some heavy metals as reported by USEPA (Contaminants and Remedial Options at Metal Sites, Draft Report, August 1993) (1) is still the chemical precipitation. Coprecipitation with the excess of iron is usually practised because of the availability of iron at low/no cost and also in order to meet the stringent regulatory discharge limits. The arsenic is usually removed with iron because of its common occurence in the mined orebodies and the excellent adsorptive property of the precipitated hydrous ferric oxide compounds. There has been controversy, however, over the long-term stability of the arsenic-bearing ferrihydrite which is produced.

Jan 1, 1995

By M. C. Williams

The solution of the dynamic population balance model (PBM) of a closed grinding network consisting of a mill, sump, and cyclone is problematic. The fact that the dynamic PBM model equation solution to the Inverse Problem for grinding systems is degenerate or underspecified is demonstrated. Two numerical solution approaches to the Inverse Problem are used. These are: 1) providing additional constraints on breakage selection functions or 2) performing the Arbiter-Bhrany (or other) normalization of the selection functions. Actual experimental anthracite batch grinding data is used to demonstrate the non-unique functionality of the batch dynamic mill selection and breakage functions for a real physical system. The Levenberg-Marquardt algorithm for systems of constrained non-linear equations is used to solve the batch dynamic PBM grinding equations to obtain the grinding selection and breakage rate functions. Different solutions to the same PBM transport equations are provided. The mill, sump and hydrocyclone were modeled as a CSTR operating at various retention times. Batch dynamic PBM data was used to provide the mill kinetic and breakage selection function data. Two different solutions were obtained depending on the numerical solution approach. The severity of the non-uniqueness problem for dynamic grinding is demonstrated. Each solution approach to a dynamic PBM with transport, while giving the same prediction for a single batch grinding time, gives different solutions or predictions for mill composition for other grinding times. This fact makes dynamic nodal analysis and control problematic. The fact that the constraint solution approach gives a solution may suggest that normalization for closed networks is not necessary. Differences in solutions to the PBM cannot be excused away by inaccuracies in the data used to model the grinding phenomenon.

Jan 1, 1995

Continuous improvement has become the watchword of the 1990s for most iron-ore-processing operations. In many instances, this improvement has been achieved through stepwise application of advanced control techniques to optimize operations. The benefits of this stepwise application have been great. However, they have fallen short of the full potential offered by the prospect of overall plant optimization. The successful integration of computers, instrumentation and control software throughout a plant promises to deliver an additional 3% to 5% of productivity in even the best-run plants (Herbst and Bascur, 1984). LKAB is Europe's largest iron-ore producer and a leading implementer of advanced control technology. In the late 1980s, LKAB introduced advanced control in its concentrator at Kiruna, Sweden to improve plant performance through higher productivity, greater efficiency and lower costs at each processing step.

Jan 1, 1995

By Mohsen Sanai, Paul Gefken

"SRI International has developed and patented* a castable dilute explosive tile @ET) that offersunique advantages over conventional high explosive. The primary advantages of DET are that itsdetonation pressure can be adjusted over a wick range and its impulse can be controlled independently by adjusting its thickness and configuration. Because DET has a much lower detonation velocity than conventional explosives, the pulse duration produced by DET is as much as 10 times longer than the pulse duration produced by conventional explosives for equal explosive weights. These features of DET present several advantages to the mining industry. For example, DET can be tailored so as to control fragment size and distribution to enhance extraction of desired elements from ore or breakup of specific regions."

Jan 1, 1995