Search Documents

By M. P. Hoffman

The U.S. Bureau of Mines is developing a roof bolter with a computer-controlled drill head that will increase the safety of roof bolting in underground coal mines by allowing miners to be relocated to a safe area. To ensure secure anchorage, acceleration and strain data are broadcast from an instrumented drill steel to a data acquisition system. These data are analyzed, correlated, and transformed to pro-vide information about roof strata, then are sent to a supervisory computer executing National Institute of Standards and Technology's real-time control software. The supervisory computer sends setpoint commands to proportional-integral-derivative control loops to control drill thrust, position, revolutions per minute, and torque.

Jan 1, 1994

By S. J. Ristorcelli

Historically, geologic data has not been adequately considered in resource estimation. More recently, with the use of computers and sophisticated estimation algorithms and geostatistical justifications, geology has been downplayed further. Many reasons are given for not using geology including cost, time and irrelevance. None are valid. Boundaries defining mineral domains should be used in computer-generated resource estimates. Selected case histories show how the failure to honor geology has caused discrepancies in resource estimates of actual in-place resources. After-the-fact differences have included decreases in tonnage of up to 50% and increases up to 300%; partial to complete recategorization of material; and 50% decreases in grade. The costs of gathering and using geology are trivial compared to the potential consequences.

Jan 1, 1994

By N. A. Barcza

DC plasma-arc technology using a hollow graphite electrode (cathode) has been successfully implemented in the primary metallurgical industry in South Africa up to the 30 MW scale. Mintek has applied its expertise base, established over the past fifteen years, to testing the treatment of metallurgical wastes such as carbon- and stainless-steel plant dusts, lead- and zinc-containing slags, and residues from the base-metal industry. Favourable results have been achieved, and disposable products were produced. The evaluation of numerous wastes indicates that recovery of zinc as metal gives the best economic return from these sources. Direct recovery via a splash condenser or electrolytic zinc extraction from fume are the two preferred alternatives under review. In both instances dehalogenation is an important issue, but can be achieved by suitable treatment processes. The Enviroplas technology provides a flexible, commercially viable approach to the treatment of a wide variety of wastes. Mintek, together with its associate Pyromet CC, are installing a plasma- arc pilot-plant facility with both an ISP lead-splash condenser of about 5 t/d condensed zinc capacity and a combustion chamber to burn zinc vapour to zinc oxide. This will demonstrate the suitability of the Enviroplas technology for treating specific metallurgical wastes, so that customized industrial plants can be engineered based on large-scale testwork.

Jan 1, 1994

This report on the Venezuelan coal industry is the seventh in a series of studies on coal exporting countries requested by the House Appropriations Committee, The committee asked that the basic differences in mining costs for U.S, and foreign mines be identified, especially those costs incurred in complying with health, safety, and environmental regulations.1 Basic costs in extracting raw coal are analyzed in this report for surface operations, This report also provides a limited analysis of the relative market competitiveness of selected Venezuelan and U,S. steam coal mines in three electric utility markets: New England and the east coast of Florida in the United States, and western Europe. Although some Venezuelan coal has coking characteristics, all coal-producing regions of Venezuela sell coal in steam markets.

Jan 1, 1994

By I. Gaballah

The chalcopyrite ore's anodic and cathodic electrodissolution are studied using a Porous Pulsed Percolated Electrode (3PE) reactor. Stationary solid electrode experiments are also performed to explore the mechanism of electrochemical dissolution of chalcopyrite. Experiments with a low - grade natural ore have been carried out at 25 "C in solutions containing 1 M NaCl and 1 M HCl. Galvanostatic and potentiostatic conditions are employed. The influences of current and potential on selectivity of the chalcopyrite ore dissolution are assessed. Anodic oxidation of this ore leads to a preferential dissolution of iron bearing minerals, whereas cathodic reduction is more selective with respect to chalcopyrite. However, in both cases the electrochemical dissolution is incomplete and the current efficiency is low. Design of the actual reactor has to be modified to increase the bed conductivity and to allow continuous experimentations.

Jan 1, 1994

By Henry E. Hilliard

The production, use, and emission of vanadium in the United States has been traced for the year 1991. Consumption was 3,300 tons2, exports 1,285 tons, and imports 2,013 tons. About 98% of production was used in metallurgy; the remainder was consumed in chemicals, including catalysts. Total emissions to the environment in 1991 were estimated at about 3,100 tons, including emissions due to the combustion of coal and petroleum products. Emissions resulting from the production of ferrovanadium were 130 tons, and emissions from the production of steel about 6 tons. Dissipative losses, defined as losses that occurred during use or as a result of wear, were estimated to be no more than 3 tons. Disposal losses were estimated to be about 4,600 tons. Most of these losses were steel products that contained 0.1% or less vanadium and mayor may not have been recycled. When these products are recycled by the steel industry, vanadium ends up in the steelmaking slag and does not return to vanadium use cycle. Worldwide emissions due to anthropogenic and natural sources were briefly reviewed. It was concluded that industrial emissions were about three times greater than emissions from natural sources.

Jan 1, 1994

By H. Hahn, B. H. Kear, K. Kan, S. C. Danforth, G. Skandan, W. Chang

"A new chemical synthetic process for the production of non-agglomeratednano structured ceramic (n-ceramic) powders, starting from metalorganic precursors, is described. The process combines rapid thermal decomposition of a precursor/carrier gas stream in a hot tubular reactor with rapid condensation of the product particle species on a cold substrate. Critical to the success of this Chemical Vapor Condensation (CVC) process are (1) a low concentration of precursor compound in the carrier gas, (2) rapid expansion of the gas stream through an uniformly heated tubular reactor under a reduced inert gas pressure of 1-35 mbar, and (3) rapid quenching of the gas phase nucleated clusters or nanoparticles as they exit from the reactor tube. A wide variety of metal organic precursors is available commercially, all of which can be utilized in the CVC process to produce n-ceramic powders, including single phase, multiphase and multicomponent systems.The CVC process has been used to synthesize non-agglomerated n-SiCxNy and n-ZrOxCy powders, with controlled particle size in the range 2-20 nm. Heat treatment of the assynthesized n-powders in various high purity gas streams causes compositional and structural modifications, including particle purification and crystallization, as well as transformation to a whisker-like morphology. Thus, as-synthesized amorphous n-SiCxNy particles transform to (1) cubic n-SiC particles, when heated in flowing argon at temperatures> 1350 °C, (2) hexagonal n-Si3N4 whiskers, when heated in flowing NH3IH2 at 1400 °C, and (3) cubic nSiC whiskers, when heated in flowing H2 at 1400 °C.Non-agglomerated n-ceramic powders form uniformly dense powder compacts by cold pressing, which can be sintered to theoretical density at temperatures as low as 0.5 Tm' For example, full densification ofn-Zr02 powder compacts under free sintering conditions can be achieved at 1125 °C."

Jan 1, 1994

By B. Kolonja

This paper considers simulation of truck dispatching system designs using maximum expected production of the truck-shovel system as the measure of performance. Two methods are utilized, multiple comparisons with the best (MCB) and the combination of MCB and the variance reduction technique known as common random numbers (CRN). These two techniques are compared via simulation experiments. The results show that the combined procedure of MCB with CRN is the superior tool to reduce the total number of replications needed to ensure the specified probability of correct selection over the finite number of designing systems. In this case study, MCB with CRN reduces the variance by 29% and the number of required replications by 48%. Also, the MCB with CRN procedure narrowed the confidence interval by 18%.

Jan 1, 1994

By Milan Lj. Stamatovic

The hydrometallurgical recovery of zinc from recycled blast furnace dust from a steel plant (Smederevo Metallurgical Company, Yugoslavia) was investigated. The dust contained 22% Fe, 17% Zn and 0.2% Pb. X-Ray diffractometry showed that the main components were hematite and magnetite, in combination with zinc oxide. Individual particles were generally spherical and ranged in size from 10 to 150 microns; 63% were less than 33 microns in diameter. An effective hydrometallurgical approach proved to be by caustic leaching and electrowinning. Recovery of zinc in the form of zinc powder was over 90%; this material can be used for the cementation of impurities in the conventional hydrometallurgical process for zinc production.

Jan 1, 1994

By Edward P. Hagarty

The Hazardous and Solid Waste Amendments (HSWA) of 1984 added Subtitle I to the Resource Conservation and Recovery Act (RCRA), authorizing the Environmental Protection Agency (EPA) to develop and implement a new regulatory program for Underground Storage Tanks (USTs) containing petroleum and other regulated substances. Technical standards required for release detection, prevention, and correction as necessary to protect human health and the environment were promulgated as described in 53 Federal Register 37082 (September 23, 1988). Virginia State Regulations (VR 680- 13-02) and U.S. Army Regulations require that a Corrective Action Plan and a Site Clearance Report be prepared to explain the details of remediation of any contaminated media. Construction of new buildings is proposed in two different areas at Fort Myer in Arlington, Virginia, where USTs containing gasoline, diesel and heating oil were located. Tightness testing performed on these USTs in September 1991 indicated that some of the tanks were leaking. Many of the tanks were removed for permanent closure. Initial Abatement (excavation of contaminated soil) was &ed out immediately. A detailed Site Characterization Study which included Hydropunch", field screening using immunoassay, and pilot test - dual phase (water and soil gas) extraction was conducted. Environmental media were analyzed for volatiles, semi-volatiles and metals. A detailed risk analysis (RA) was performed to determine risk-based clean up levels for benzene, toluene, ethylbenzene, xylenes (BTEX); polycyclic aromatic hydrocarbons (PAHs); and methyl-tertiary butyl ether (MTBE). The RA also discussed the presence of lead in the soil. Before constructing any buildings in these contaminated areas, remediation must be conducted in accordance with the State, Federal and other applicable regulations. The remedial alternatives evaluated included Vapor Enhanced Groundwater Extraction, Soil Vacuum Extraction, Soil Washing, Soil Steaming, Active and Passive Ventilation SolidificationlStabilization, Vapor Barrier Construction, and Excavation with Off-site Disposal. This paper discusses: (a) delineation of soil contamination @) risk analysis (c) evaluation of remedial alternatives and selection of the most appropriate technology and (d) consideration of various regulatory issues.

Jan 1, 1994

By S. J. Jung

The stability of underground openings for deep mines is critical, since incorrect orientation or geometry of shaft, stope, and accessways often results in the failure of openings due to high stress concentrations. Current state-of-the-art procedures for the design of underground openings are largely based on rules of thumb, experience, and trial and error. Rules of thumb are invariably based on the past experience of the designer and may not remain optimal as the depth and complexity of mine workings increase. Often, as conditions change, and as the interaction between geology, in-situ stress conditions, and mine openings grows more complex, the cost of maintaining structural integrity becomes prohibitive. Existing design procedures for deep mines are rapidly becoming inadequate as mines are worked at greater depths. For example, in the Coeur d' Alene Mining District, several million dollars are spent for inspection, repair, and maintenance on a regular schedule, largely as a result of inadequate design. In these types of situations, it is of critical importance that a new design methodology be developed for the layout and design of underground openings.

Jan 1, 1994

By C. Cheung, U. Erb

"Over the past few years, nano-processing of magnetic materials has received considerable attention, because many magnetic and other application-specific properties have been shown to be enhanced in materials with ultrafine grain size. This paper reviews recent advances in the production of nano-processed soft magnetic materials such as pure nickel and cobalt as well as binary nickel-iron and ternary nickel-iron-chromium alloys by electrodeposition. Magnetic, electrical and mechanical properties of these materials are presented and discussed in terms of their microstructural defects.IntroductionIn recent years, nano-processing of materials to enhance their magnetic properties has received considerable attention [1-23]. Thin films, compositionally modulated thin films, granular films and bulk materials have been produced by many different techniques. These include gascondensation [1-6], ball-milling [7,8], chemical processing [9,10], metal-organo complex routes, solution reduction and co-precipitation [11], sol-gel methods [12], sputtering [12-14], rapid solidification [15], devitrification of amorphous alloys [16-19] and electrodeposition [12,20,21]. The potential application of nano-engineered materials with enhanced magnetic properties has been specifically discussed for soft magnets [18,19,22,23], hard permanent magnets [15] as well as for layered materials showing giant magnetoresistance effects [13,14] and nano-composites for magnetic refrigeration [11,12].The purpose of the present paper is to review recent advances in the development of nanocrystalline soft magnetic materials by electrodeposition methods. These materials could find applications in areas such as magnetic recording heads, high efficiency electric motors, transformer cores, etc."

Jan 1, 1994

By Don Novotny, Dana Spencer

In this workshop our intent is quite simple; that is that we will introduce a relatively new technology that may have applications in blasting applications. This technology is the laser initiation of explosives. This workshop course is not intended to suggest ways in which specific blasting problems can be resolved. That is the purview of experts within each of your fields.

Jan 1, 1994

By Hanley J

Coal winning in the Latrobe Valley exceeds 45 mtpa uses a small number of Bucket Wheel Excavators and high speed conveyor systems. While this equipment offers many advantages in the production cycle, incorrect use can lead to low productivity and risks to the safety of the operators and equipment. The mining equipment is of high capital value and easily damaged when used outside the correct operating range. In the extreme case, this can result in total machine collapse, having major implications for personnel safety as well as production and costs. With an active productivity improvement program in the Latrobe Valley in the last two years resulting in a 50 per cent reduction of personnel, many experienced operators have retired. Mine management are facing the urgent need to rapidly train new operators to maintain high productivity levels and reduce the risk of accidents to personnel and high capital cost plant. With the assistance of the Central Gippsland College of TAFE a Certificate Level course has been developed for open cut operators. The course covers all essential training needs for the Latrobe Valley mines. The training is developed from National Competency Standards, allowing transfer of skills, and is flexible to suit other enterprises. It has been written for self-paced learning with the total job understanding, and to have competency-based learning outcomes, training tasks and assessments built-in to modules. With the introduction of this new training program, management is convinced that the element of risk within the mine will be significantly reduced. For these reasons it is an ideal training model for other enterprises.

Jan 1, 1994

By T Christie, A Swain

Patterns of quartz veining in epithermal gold-silver deposits at Wharekirauponga, Neavesville and Ohui in the Hauraki Goldfield, have been analysed to determine the effects of different lithologies on vein distributions. At Wharekirauponga, quartz veins are hosted in rhyolite and minor andesite, with the andesite containing slightly higher gold grades. Local basement andesite, rhyolitic tuff and silicified black shale host gold-bearing quartz veins at Neavesville. At Ohui, quartz veins are hosted in rhyolite, rhyolitic tuff and andesite. Fractal analysis was used to quantitatively describe the distribution of veining. The fractal dimension (D) of veining in silicified tuff is 0.25, moderately silicified rhyolite has D = 0.23 - 0.26, clay-altered andesite has D = 0.3, strongly silicified rhyolite has D = 0.3 - 0.39, silicified andesite has D = 0.4, and silicified black shale has D = 0.43. The D values are related to the composition of the host rock, and appear to be controlled by its competency. Hydrothermal silicification results in increased competency and higher D values. Vein thickness frequency plots for different lithologies show that andesite at Ohui, and to a much lesser degree at Wharekirauponga, contains more thick veins than rhyolite and tuff. Gold grades show a strong to fair correlation with higher vein density in three drillholes at Wharekirauponga. The fractal dimension of veining is an important control on fluid flow and gold deposition within an active epithermal system. Vein systems with higher D have a greater density of veining which would have favoured increased fluid-rock interaction. Lower D vein systems have more clustered arrays. The increased fluid-rock interaction induced by a high D vein system, when combined with a reactive host rock, results in an environment which is highly favourable for gold deposition. This situation is seen in the andesite at Wharekirauponga.

Jan 1, 1994

The challenge of planning to minimize interaction effects in multi-seam mining is compounded by the difficulties inherent in extrapolating essential geological and spatial data between sampling points. To predict the effects of ultra-close mining on lower seam entry stability, simulated mine openings were studied using finite element analysis and body loaded photoelastic models. Both symmetrical and unsymmetrical loading was used to represent stress fields generated under multi-seam conditions. Results were correlated with field data to determine stress levels at which failure could be expected to occur. Stability predictions require precise definitions of geologic and spatial data, which could not be accurately defined by interpolation between sampling points. To overcome this problem an expanded roof stability model, SESAME2, was developed to incorporate reliability concepts based on Monte Carlo sampling. The model was demonstrated in terms of variations of innerburden thickness using a case study.

Jan 1, 1994

By Ralph Harris, Javier Jara

"Oxygen is essential in gold cyanidation. It is supplied to the leaching media by sparging oxygen or compressed air into the cyanidation tank. The rate of oxygen transfer is critical to achieve the desired oxygen concentration in solution.The performance of a novel device for gas sparging recently developed at McGill University is compared to the mass transfer characteristics of the two spargers most used in the gold industry: the four lance configuration and the inverted cone. The distribution of gas and the kinetics of oxygen desorption of the three types of spargers was studied in a 140 litre tank. The oxygen dissolution of the new device is three to five times faster than the other spargers. This could increase the leaching rate and/or decrease the cyanide and oxygen consumption.IntroductionIn hydrometallurgical processing, it is often necessary to bubble gas through a pulp to carry out the wanted reactions. The gas can act to agitate the pulp and it can also supply reactant. The rates of the reactions which require a reactant supplied by the gas are often dependent on the rates of mass transfer from the gas to the solution.A common example of this is gold cyanidation which requires oxygen for gold dissolution. Since the gold containing slurry is rich in other oxygen consuming substances (sulphide like pyrrhotite), it is important to provide enough oxygen to allow complete gold dissolution within the residence time of the cyanidation reactors. It has been demonstrated that the rate of gold dissolution is directly proportional to the dissolved oxygen concentration of the pulp which in turn is proportional to the oxygen partial pressure in the bubble 1 2 3. Improving the rate of mass transfer of oxygen increases the dissolved oxygen concentration of the slurry and therefore improves the rate of the reaction.The rate of mass transfer from a bubble to its surrounding solution increases with decreasing bubble size and increasing gas bubble residence time which in turn increases with decreasing bubble size. The generation and dispersion of small bubbles is thus critical to achieving high rates of mass transfer. Different configurations and devices used to inject gas have different effects on the bubble size and the residence time, influencing the overall rate of mass transfer. Therefore better mass transfer can be achieved by adopting a more efficient method.The methods tested in this report are the four lance configuration (wall spargers), the inverted cone and a new device, designated HCD. The wall spargers and the inverted cone are used widely in the industry today."

Jan 1, 1994

By John E. Litz

The Denver Process is a chemical/metallurgical process for treating radioactive or mixed wastes by extraction and concentration of the radioactive and/or hazardous component(s). The process was developed at bench scale, evaluated at pilot scale, and will be implemented at full scale to remediate a low-level radioactive sludge. Six unit operations comprise the process: feed handling, leaching, solvent extraction, electrodeposition, precipitation, and tailing preparation. Unit operation design may be modified to tailor the process for varying feed stock composition. Radioactive or mixed waste is reacted with aggressive reagents in an aqueous phase, solubilizing targeted components. These components are then selectively extracted and concentrated in subsequent steps. Waste solids and solution exit the process as non-hazardous non¬radioactive waste. Dehydration of aqueous waste by submerged combustion eliminates aqueous discharge.

Jan 1, 1994

By Debra A. Griffith

The U.S. Bureau of Mines currently is researching the relationship between the level of back strength and the probability of low-back injury. This report is a review of the literature and statistics on over-exertion injuries. Overexertion continues to be a significant source of injury in metal and nonmetal mining, accounting for approximately 24 pct of all injuries yearly. These injuries, particularly to the lower back, can be very expensive in human and monetary terms. An examination of the accident data on overexertion injuries is necessary to provide a background for research into prevention and/or amelioration of those in-juries. The job categories outlined in the Accident Data Analysis data base most affected are "Mechanic/Electrician" and "Mill/Plant Worker." The age group most affected is "30-39" years, and the experience group most affected is "0-.99" years. The most prevalent type of overexertion injury is "Strain/Sprain," and the trunk is the body part most often involved in an overexertion injury.

Jan 1, 1994

By Bharat B. Dhar, M D. Nabinllah, A J. Prakash

The study is an approach made in simulating air overpressures induced by surface blasting from those produced during gallery blasting in the laboratory, and experiments conducted on a portable window with a view to establish the sound pressure Level (SPL) for cracking of window glasspanes.

Jan 1, 1994