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By K. Adham

Both the dry and the wet fluorination systems require hydrogen fluoride (HF) for the process of uranium conversion to uranium hexafluoride (UF6). The dry methods depend on the electrolysis of HF to generate the fluorine (F2) required for the high temperature pyro-fluorination. The wet methods require aqueous HF in water solutions for the low temperature hydro-fluorination (Argonne, 2019). This paper uses the available HF safety guidelines and industry information to discuss the issues of transportation, storage and utilization. Health effects and environmental considerations are reviewed. Safe practices for handling the HF (both as anhydrous and as aqueous) are considered. Proper selection of different materials of construction are discussed, for both the anhydrous and the aqueous HF.

Jan 1, 2020

By C. Holmes, T. Holmes

Engineered-in material handling problems are responsible for significant unrealized value in mineral processing plants. At the root, is a lack of awareness and understanding of bulk material handling science and how important it is, especially in early design stages. Mineral processes add value to mined raw feedstock through physical and chemical transformations in unit operations, but only if the material can flow through them. Essentially, each unit operation receives a unique feedstock and produces a unique product to be collected, transported, and fed into the next unit operation. Such material-handling systems can only be expected to achieve design throughput if the system equipment is designed to the materials’ characteristics, over their full range of conditions. This requires quantification of flow properties to support the necessary customized equipment designs. Too often, assumptions or “library values” of a material’s properties are used as the basis for flow modelling and conceptual, and sometimes even detailed, design. This is especially true for hazardous materials like uranium ore, for which the additional precautions, costs, and time necessary for safe handling are often used to rationalize postponing or even bypassing testing. The surprises that often transpire in the wake of insufficient material handling consideration can have acute and costly effects. Fortunately, there is a better way.

Jan 1, 2020

By M. Vaillé, B. Bossé, N. Durupt, A. Michaut

Imouraren is a sedimentary uranium deposit (> 150,000 tU @ 800 ppm), located approximately 100 km North-Northwest of Agadez (Niger); its depth reaches 110 to 170 meters. For low-grades ores, heap leaching is commonly considered as the appropriate technology for metal recovery. More precisely, the ore is crushed (≤ 300 mm) and agglomerated before being stacked. In this case, sulfuric acid can be added during agglomeration and/or irrigation (for three months to a year) to improve uranium recovery. It is known that mineralogical, chemical and physical properties of the uranium ore impact recovery, yet many challenges remain to increase recovery using this process. For example, ore heterogeneity and spatial variability (e.g., variation in uranium, carbonate and/or clay contents) can affect heap leaching performances (i.e., metal recovery, acid consumption or neutralization, percolation rate). However, laboratory column tests using composite ore sample that do not consider ore heterogeneity are widely used to anticipate recovery. Consequently, a new approach that consists in using Imouraren drill core ore samples was recently investigated. This latter also enabled a better assessment of the main parameters that influence uranium recovery and proposed a new predictive model to optimize mining operations.

Jan 1, 2020

By A. D. Burns, K. M. Nikolaisen

Electrolytic reduction followed by the addition of sulfuric acid and the application of heat can be used to selectively crystallize uranous sulfate from solution. This approach, when coupled with downstream thermal decomposition, forms the basis of a process for primary uranium recovery and purification where much of the sulfuric acid value can be recovered and recycled. In this process, a purified uranium (VI) leach solution is first electrolytically reduced to uranium (IV) in a membrane electrolysis cell. Sulfuric acid is then added to the solution which, in conjunction with the input of heat, causes the crystallization of uranous sulfate tetrahydrate. The precipitate is then dried and thermally decomposed to U3O8, which releases a mixture of high-purity SO2, SO3, oxygen, and water vapour. This gas can be recovered as sulfuric acid in an existing acid plant, processed through a new wet sulfuric acid process, or absorbed directly into the upstream electrolyte as a substitute for fresh acid in the crystallization step. This process has been shown to be practical, efficient, and cost-effective on the laboratory scale, and could be practiced on the industrial scale using commercially available equipment. This paper focuses on the thermal decomposition process and options for acid recovery.

Jan 1, 2020

By B. Holaday, H. McLaughlin

Orano Canada Inc. (Orano) operates the McClean Lake mill, located in the Athabasca Basin region of northern Saskatchewan. It processes high concentration uranium ore, delivered in slurry form from the Cameco Corporation operated Cigar Lake mine. After the ore slurry is leached at the McClean Lake mill, the leach residue solids are washed in a process known as counter-current decantation (CCD). This process uses six thickeners to facilitate counter-current washing of solids with diluted acid, flocculation and settling, as well as pumping the washed leach residue to the tailings neutralization circuit (TN), and the uranium laden aqueous to the solvent extraction circuit (SX). Challenges in settling the slurry in CCD started in early 2017. This is largely due to the variation in fines content of the slurry (D80≤75μm), and clay content. There are several changes that have allowed the mill to adapt to the evolving challenges of settling leached Cigar Lake leach residue. Flocculant selection and mixing, temperature effects, bed level management philosophy, and centre-well feed density are key parameters that have been explored as part of adapting to changes in Cigar Lake ore quality.

Jan 1, 2020

By Lisa L. Van Loon, Neil R. Banerjee

Canada is a world leader in uranium exploration, but many deposits are located in remote regions making exploration targeting challenging. Novel approaches are needed to detect the presence of large-scale ore-forming systems and to vector toward mineralization. Boron is commonly used as a key pathfinder element associated with sandstone/unconformity-hosted and basement-hosted uranium deposits in the Athabasca Basin, but the genetic relationship remains uncertain. Alteration assemblages containing boron geochemical anomalies are commonly spatially-associated with – and possibly coeval with – uranium mineralization. Boron is commonly found in tourmaline minerals but in some portions of ore deposits the host mineral for the anomalous boron remains cryptic. Boron coordination chemistry within alteration haloes can better constrain boron host mineralogy, provide insight into the nature of the boron-uranium relationship, and thus has the potential to better constrain targets for exploration. Synchrotron-source X-ray absorption near-edge structure (XANES) spectroscopy is a direct, element-specific analysis that identifies boron coordinated in both trigonally- (BO3) and tetrahedrally-coordinated (BO4) forms. This makes XANES uniquely suited for identifying the geochemical hosts for boron that may be related to hydrothermal ore forming processes. XANES spectroscopy was conducted on whole-rock assay powders from uranium deposits across the Athabasca basin containing boron concentrations ranging from <10 ppm to >10,000 ppm. XANES directly identifies the relative amount of trigonally- (BO3) and tetrahedrally-coordinated (BO4) boron in these complex mineralogical mixtures. Our work suggests a link between boron and uranium that is likely related to the unique physiochemical characteristics of ore bearing fluids that may provide a unique vector to mineralization.

Jan 1, 2020

By Patty Simpson, Sarah Benson

In an effort to improve consistency across the nuclear industry, over the past 10 years the Canadian Standards Association has developed a series of standards related to environmental management at Class 1 nuclear facilities and uranium mines and mills. Canadian uranium mines have been required by the Canadian Nuclear Safety Commission to align their existing monitoring programs with these standards. Orano’s McClean Lake Operation’s monitoring program, which was originally presented in the Environmental Impact Statement in 1991, has evolved through regulatory change, new scientific understanding, additional projects, and experience into a comprehensive set of monitoring requirements for effluent, groundwater, air emissions, and the receiving environment. The exercise of aligning the existing practices with the standards provided an opportunity to review and rationalize the entire program. To document the process the original “Environmental Monitoring Program Design Document” was restructured and developed as both a repository for historical information and monitoring rationalization, and also to be a living document describing on-going studies and supplementary work that are outside of the regular environmental monitoring program and may justify future changes to the program.

Jan 1, 2020

By M. A. Perras, H. A. Kasani, G. Walton

The development of an underground repository for the storage of spent nuclear fuel relies on a multi-barrier system to isolate the used fuel from the environment – ultimately, the biosphere. These barriers include engineered copper and steal canisters, dense bentonite, and the natural rock as well. In order to reduce the potential flow pathway along the excavation induced damage zone, various slots perpendicular to the excavation axis have been proposed. These slots are called cut-off seals and generally are filled with bentonite as it has high swelling potential and very low permeability. Many different geometries have been proposed, but clear guidelines on the selection of the optimum geometry have yet to be developed. In order to assess the optimum geometry, three shapes have been selected for this numerical study, including a trapezoid, a triangle, and a thin rectangular slot. The cut-offs were modelled for a conceptual shaft constructed in the Queenston Formation from Ontario over a stress to strength ratio that has been found at many underground research laboratories. It was found that the excavation of a triangular and thin slot cut-off had the smallest increase in the damage as quantified based on the extensile volumetric strain within the plastic yield zone. Both shapes showed an increase in the damaged zone by 13 cm at a stress to strength ratio of 2.75. The trapezoidal cut-off damage zone increased by 20 cm at the same stress to strength ratio. Further study is required to better define the optimum cut-off shape for wider variety of conditions and other geological formations.

Jan 1, 2020

By CHRISTOPHER D. HEBERT, SCOTT W. HOFFMAN

All Rights Reserved. Printed in the United States of America. Information contained in this work has been obtained by SME, Inc. from sources believed to be reliable. However, neither SME nor its authors guarantee the accuracy or completeness of any information published herein, and neither SME nor its authors shall be responsible for any errors, omissions, or damages arising out of use of this information. This work is published with the understanding that SME and its authors are supplying information but are not attempting to render engineering or other professional services. No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, or otherwise, without the prior written permission of the publisher. Any statement or views presented here are those of individual authors and are not necessarily those of the SME. The mention of trade names for commercial products does not imply the approval or endorsement of SME.

Dec 1, 2019

By Kym Runge, Fengnian Shi

Este artículo resume los resultados de la investigación realizada en los últimos 10 años sobre conminución por pulsos de alto voltaje (HVP) en la industria minera. En el estudio se adopta un nuevo enfoque mediante el uso de bajos niveles de energía HVP para cambiar la procesabilidad de los minerales y lograr una reducción general en el consumo de energía, así como un mejor rendimiento metalúrgico. El artículo discute los vacíos de conocimiento y las incertidumbres que inhiben la adopción del HVP por parte de la industria minera y hace hincapié en la necesidad de realizar más investigaciones para lograr la siguiente generación de tecnología de conminución.

Nov 30, 2019

By CIM Mineral Resource, Mineral Reserve Committee

The CIM Estimation of Mineral Resources and Mineral Reserves Best Practice Guidelines (MRMR Best Practice Guidelines) were prepared by the Canadian Institute of Mining, Metallurgy and Petroleum's (CIM) Mineral Resources and Mineral Reserves Committee (CIM MRMR Committee) to update an earlier version that was accepted by CIM Council on November 23, 2003 (CIM, 2003). These 2019 MRMR Best Practice Guidelines supersede and replace the November 23, 2003 version of the MRMR Guidelines. These 2019 MRMR Guidelines are not intended to be prescriptive and are not intended to provide detailed and exhaustive instructions for preparation of Mineral Resource and/or Mineral Reserve (MRMR) estimates. Rather, they are intended as general guidance to assist professional geoscientists (or equivalent) and engineers (or equivalent) in preparing high quality estimates of MRMR that incorporate sound geoscientific, engineering, evaluation and design practices. They are based on well-established estimation and mine planning principles and are designed to provide general guidelines of best professional practices employed in the preparation of MRMR estimates. Although the 2019 MRMR Best Practice Guidelines are intended for use by Canadian-based mining/exploration practitioners, many of the concepts and practices presented herein are in general agreement with current industry practices in jurisdictions with membership in the Committee for Mineral Reserves International Reporting Standards (CRIRSCO). For this document, persons preparing MRMR estimates are called Practitioners. Preparation of MRMR estimates should be carried out by Practitioners who either hold the status of Professional Geoscientist (or equivalent) or Professional Engineer (or equivalent), or who prepare the estimates under the supervision of a Professional Geoscientist (or equivalent) or Professional Engineer (or equivalent). For the purposes of this document, all references to reporting describe such necessary reports and related documentation that are created as part of the normal-course work flow of preparing MRMR estimates for internal purposes. For clarity, all public disclosure of MRMR estimates made by, or on behalf of, an issuer and intended to be, or reasonably likely to be, made available to the public in a jurisdiction of Canada must comply with the requirements of National Instrument 43-101 Standards of Disclosure for Mineral Projects (NI 43-101), as amended from time to time. At least one Qualified Person (QP) must take responsibility for each part of the estimation process when publicly disclosing the results of MRMR estimates. The intended audience for these 2019 MRMR Best Practice Guidelines includes Practitioners at all levels of skill and experience, government agencies, academic institutions, and the public.

Nov 29, 2019

By CIMVAL

This Code for the Valuation of Mineral Properties (the “CIMVAL Code”) is the result of a review more than a decade after the release in 2003 of the “Standards and Guidelines for Valuation of Mineral Properties” (the "2003 Standards"). The purpose of the review is to update the 2003 Standards to reflect domestic valuation, international valuation, and regulatory developments. The CIMVAL Code was adopted by the Canadian Institute of Mining, Metallurgy & Petroleum (the "CIM") Council on November 29, 2019. The CIMVAL Code supersedes the 2003 Standards. The 2003 Standards were dated February 2003 and were adopted by the CIM Council on March 9, 2003 as the first comprehensive set of standards for Valuation of Mineral Properties in the Canadian mining industry. The 2003 Standards followed recommendations of the Mining Standards Task Force of the Toronto Stock Exchange and the Ontario Securities Commission, where in its Final Report (January 1999), the CIM was specifically asked to form a committee of valuation practitioners to review and advise on standards for the Valuation of Mineral Properties. The Special Committee on Valuation of Mineral Properties ("CIMVAL") was created on May 5, 1999 with the mandate to recommend standards and guidelines for Valuation of Mineral Properties to be used by the mining industry in general. The CIMVAL Code is limited to the Valuation of Mineral Properties (including any interests therein) and does not cover valuation of corporations or other entities that hold Mineral Properties as assets. The CIMVAL Code does not cover petroleum and related assets. CIMVAL recommends that the CIMVAL Code be followed for all Valuations of Mineral Properties, including those required by securities administrators and stock exchanges. However, when a Valuation is required under the applicable rules of securities administrators or stock exchanges, such rules prevail to the extent of any inconsistency.

Nov 29, 2019

By M. A. Reyes, L. Yan

Heat and humidity buildup within refuge alternatives (RAs) may expose occupants to physiological hazards such as heat stress. The Mine Safety and Health Administration (MSHA) regulations require RAs in underground coal mines to provide a life-sustaining environment for miners trapped underground when escape is impossible. RAs are required to sustain life for 96 h while maintaining an apparent temperature (AT) below 95 °F (35 °C). The National Institute for Occupational Safety and Health (NIOSH) tested a 10-person tent-type RA, a 23-person tent-type RA, and a 6-person metal-type RA in its underground coal mine facilities to investigate the thermal environment over a 96-h period. The test results showed that mine air and mine strata temperatures surrounding an RA occupied by simulated miners (SMs) increased over the 96-h test period. The test results suggest that RA manufacturers should consider this increase in temperatures when calculating and evaluating RA components during surface and laboratory tests. The findings can equip stakeholders with additional considerations for calculating the interior heat and humidity temperature profiles for occupied RAs not tested in situ

Nov 22, 2019

By Samuel Filgueiras Rodrigues, Sebastião Raimundo de Jesus Belém leitão Filho, Gedeon Silva Reis, Eden Santos Silva

Nesse trabalho estudou-se o retardo na cinética de amaciamento estático do aço inoxidável austenitico ASTM F-1586 (ISO 5832-9) usado na confecção de implantes ortopédicos, por meio de ensaios de torção a quente isotérmico em duplo passe. Inicialmente as amostras foram aquecidas por indução até a temperatura de 1250 oC e mantidas por 300 s para solubilização, em seguida resfriadas até a temperatura de deformação (Tdef), que variou de 1000 a 1200 oC, com passes de deformações de ε1 = ε2 = 0,30, taxa de deformação de 1,0 s-1 e tempo entre passes (tp) variando entre 0,1 – 1800 s, simulando um processo de forjamento a quente industrial de um dispositivo ortopédico. Os resultados da simulação física do processamento termomecânico indicaram que 60 % do amaciamento dá-se por recuperação estática (SRV), com moderado valor de energia de falha de empilhamento (γEFE ~ 69 mJ/m2) do aço e tempo de encubação pra iniciar a recristalização estática (SRX) maior que 10 s abaixo de 1100 oC com formação de patamares nas curvas de amaciamento Xs vs tp, indicando atraso na cinética de recristalização estática (SRX) resultante do efeito dos precipitados da fase Z (NbCrN) induzidos por deformação nos contornos dos grãos austeniticos.

Nov 18, 2019

By Patrícia Freitas Rodrigues, Talita Gama de Sousa, Paulo Inforçatti Netto, Danilo Abílio Correa Gonçalves, Rebeca Vieira de Oliveira, Eduardo Hoisler Sallet, Jorge Vicente Lopes da Silva, Naiara Vieira Le Sénéchal, Rodolfo da Silva Teixeira, Andersan dos Santos Paula

O processo de fusão seletiva a laser (FSL) é comumente utilizado na manufatura aditiva de materiais metálicos, sendo este um processo rápido no qual as peças são formadas camada por camada. Neste processo uma fonte de laser varre o leito de pó e seleciona as regiões a serem fundidas, através da alta intensidade de potência aplicada, de acordo com o projeto digital proposto, para obter peças com boa densidade. Embora a FSL apresente diversas vantagens, em relação aos processos de fabricação convencionais, esta ainda é de alto custo para indústria. A otimização de parâmetros de processamento desta tecnologia para as ligas com memória de forma vem sendo explorada. As ligas NiTi com memória de forma se destacam por apresentarem o efeito memória de forma e a superelasticidade, o que lhe confere várias aplicações práticas. Otimizar, no processo da FSL para essas ligas, o parâmetro densidade de energia do laser, é fundamental para obter as peças com boas propriedades mecânicas e baixa porosidade. Com isso, este trabalho tem como objetivo observar e criticar a influência dos parâmetros de processamento na microestrutura e porosidade dos corpos de prova de ligas de NiTi manufaturados via FSL.

Nov 15, 2019

By Shimeni Baptista Ribeiro Daer, Patrícia Freitas Rodrigues, Edir Neves Teixeira, Naiara Vieira Le Sénéchal, Andersan dos Santos Paula, Francisco Manuel Braz Fernandes

Este trabalho visou em compreender as características microestruturais de uma liga de NiTi rica em Ni deformada a quente por meio do processo de forjamento rotativo, que foram submetidas ao processo com temperaturas distintas de pré-aquecimento (800 e 950 ºC) sem e com tratamento térmico de recozimento prévio (950 ºC por 2 horas) para homogeneização do lingote. Por meio dos aspectos da evolução microestrutural verificados com auxílio das técnicas de Microscopia Óptica, Microscopia Eletrônica de Varredura e difração de Raios X pôde-se observar que a adoção do recozimento prévio para homogeneização e incremento da temperatura de pré-aquecimento as etapas de forjamento rotativo a quente, conduziu a resultados mais satisfatório ao processamento termomecânico a ser aplicado nesta liga, a fim de seguir para as etapas de deformação a frio.

Nov 14, 2019

By Wainer da Silveira e Silva, Marco Antonio Teixeira, Robisom Damasceno Calado, Carlos Alberto Chaves, Tone Takayama Filho

A preocupação com o adequado tratamento de resíduos industriais surgiu com o conceito de desenvolvimento sustentável criado pelo Clube de Roma e contribuiu para o uso racional dos recursos naturais ao longo dos últimos 50 anos. A preocupação com a produção responsável e uso judicioso de recursos naturais priorizou a reciclagem de materiais na agenda das empresas, tornando-se numa atividade de alta relevância, vital para a sustentabilidade econômica e ambiental. Este trabalho aborda os aspectos técnicos, econômicos e ambientais da reciclagem de resíduos contendo zinco através do estudo de caso de reciclagem de resíduos gerados no processo de fabricação de aço em Forno Elétrico, denominado pó de Aciaria Elétrica (PAE). A indústria ainda está em busca de tecnologias para redução da geração e reciclagem desse resíduo. A relevância do estudo está na utilização da Análise Hierárquica de Processo (AHP) para avaliação e seleção da melhor alternativa, entre várias, para tratamento e reciclagem do PAE. Como resultado, demonstrou-se a eficácia do uso da metodologia no empreendimento de reciclagem de resíduos contendo zinco implantado pela Votorantim, em Juiz de Fora, Minas Gerais.

Nov 12, 2019

By Miguel Ângelo Menezes, Carlos Alberto Alves Viana

O presente trabalho possibilita o entendimento e a análise dos processos de conformação a quente dos metais. Isto, pela validação experimental do modelo de Johnson-Cook, para descrever o comportamento dos materiais no regime plástico, para grandes deformações, às altas taxas de deformações e nas altas temperaturas. Um entendimento dos parâmetros do modelo, utilizando-se um método analítico numérico simples, rápido e confiável foi desenvolvido anteriormente pela linha de pesquisa em Conformação Plástica dos Metais na UNESP – Campus de Ilha Solteira, obtendo-se as constantes empíricas do modelo referido. É proposto nesse trabalho a validação experimental do método simplificado para determinação dos parâmetros empíricos do modelo de Johnson-Cook através de um ensaio de tração a quente, considerando as propriedades mecânicas dos materiais analisados experimentalmente e/ou de dados de materiais disponíveis na literatura. De maneira geral, os resultados experimentais foram satisfatórios para o aço AISI 1045 à temperatura de 500 ºC, ensaiado à taxa de deformação de 1000 s-1, quando comparados aos resultados teóricos previstos pelo modelo proposto por SCADUTO e MENEZES. Particularmente, foi possível evidenciar erros máximos de 1,33% para o parâmetro n, 13,15% para o parâmetro B, 295,00% para o parâmetro C e 4,14% para o parâmetro m.

Nov 11, 2019

By C. D. Ashley, X. P. Garzon-Villalba, R. M. Lopez, T. E. Bernard

Federal standards for refuge alternatives (RAs) mandate that they not exceed a Steadman apparent temperature (AT) of 95 °F (35 °C) at an assumedmetabolic rate of 325W, a limit that appears to be arbitrary. Occupants in an RA spend most of their time at rest (a metabolic rate less than 325 W), and thermal equilibrium can likely be maintained at an AT > 35 °C. The purpose of this study was to examine the upper limit of sustainable heat stress during 4- and 8-h exposures at rest. Five men underwent five 4-h trials (phase 1: AT range 39 to 49 °C, 90% rh) and five 8-h trials (phase 2: AT range 46 to 56 °C, 90% rh) in a semi-recumbent position. Descriptive statistics for gastrointestinal temperature (Tgi), heart rate (HR), systolic and diastolic blood pressure (SBP and DBP), sweat rate, fluid intake, urine color, urine specific gravity (USG), and changes in body mass are reported. Mean Tgi for all trials ranged from 36.9 to 37.3 °C, and mean HR for all trials ranged from 61 to 75 bpm. To determine the effects of increased heat exposure, differences in heat strain between 4- and 8-h trials were examined via repeated measures analysis of variance (ANOVA). As AT increased, there were no significant changes in ?Tgi and ?HR from 1 to 4 h in the 4-h and 8-h trials. During the 8-h trials, as AT increased, there was a difference in ?Tgi between 4 and 8 h. In conclusion, there was support for sustainable exposures resulting in no significant increase in physiological strain at an AT greater than 35 °C AT, with a sustainable limit (no increases in Tgi due to increases in AT) below 46 °C AT. Although the participants were not representative of coal miners, the results provide support for sustainable exposures greater than 35 °C AT at an average metabolic rate of 155 W.

Nov 8, 2019

By Felipe da Silva Siqueira, Aline Cristine Lemos Duarte, Weslley Luiz da Silva Assis, André Luiz Moraes Alves, Guilherme Dias da Fonseca, Paulo Rangel Rios, Daniel Gomes de Souza dos Santos

Com o aumento da complexidade dos materiais metálicos, duas ou mais fases produto podem nuclear simultaneamente durante uma transformação de fase. A nucleação de novos grãos pode ocorrer por saturação de sítios ou por taxa constante. Neste contexto, esse trabalho busca estudar a influência da transformação simultânea com nucleação por taxa constante de duas fases produto na cinética, na microestrutura e na distribuição do tamanho de grão em uma região tridimensional. A efeito de comparação, também foi realizado o estudo de reações em que uma fase nucleia por saturação de sítios e a outra fase, por taxa constante e ambas iniciam sua transformação no instante inicial, de forma simultânea. Os resultados obtidos computacionalmente foram comparados às equações analíticas, apresentando ótima concordância entre os modelos. Foi observado que parâmetros microestruturais como tamanho médio de grãos e morfologia das interfaces podem auxiliar o pesquisador a identificar o tipo de nucleação, seja por saturação de sítios, seja por taxa constante.

Nov 8, 2019