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A simple and rapid method for delennining gold and silver in carbon samples is described. The method involves dissolution of carbon ash in a strong oxidising medium of aqua regia and hydrofluoric acid. Gold and silver are determined in the resultant solution using atomic absorption speetrometry (AAS). The method is efficient and reproducible. Gold results are comparable to the standard fire assay results, with agreement of results within ± 5 per cent. The co-efficients of variation for gold and silver are 0.37 and 0.39 per cent respectively for six replicate analyses. The analysis of gold and silver in a batch of ten carbon samples can be completed in approximately four hours.

Jan 1, 1992

By Bruce J. Barker

"Environmental concerns have recently been growing over the disposal of reactive desulphurizing slag. Consequently, increased pressure has been placed on the foundry industry to reduce the reactivity of this slag.To address this problem, Cyanamid has developed a new product which significantly reduces the calcium carbide content of the desulphurizing slag. Testing equipment and procedures have also been developed to evaluate both the existing levels of carbide in the slag and the decreased levels which are achieved with this new material.The development and use of this engineered carbide desulphurizer has made possible significant environmental and efficiency improvements in the field of calcium carbide desulphurizing. Consequently, the lifespan of calcium carbide in ductile iron desulphurization has been increased, as have the benefits of its use in the foundry industry. IntroductionIn the production of ductile iron, calcium carbide has long been used for hot metal desulphurization external to the cupola. Its cost effectiveness, reliability and ease of use have traditionally made it the desulphurizer of choice for a great majority of ductile operations. Recently however, environmental concerns have been raised regarding the quantity of calcium carbide remaining in the slag after desulphurizing. Analysis has shown that as much as 25070 of the weight of the slag may contain active carbide. This has caused disposal concerns as calcium carbide when in contact with water, produces acetylene via the following reactionr:"

Jan 1, 1992

By J. Y. Hwang

Sands are utilized to make molds for metal castings in the foundry industry. Approximately a half ton of sand is disposed of for each ton of metal cast in this country. In Michigan, annual sand disposal amounts to about one million tons. A process has been developed in this study to reclaim sands from a steel foundry. Physical separations are utilized in conjunction with other operations (such as the removal of binder, metal, spruce, washes, etc.) to yield silica and chromite sands with desirable molding properties. Several different separation methods, including electrostatic, magnetic, and various gravitational approaches have been examined. Experimental results are presented. The applicabilities of these separation methods are discussed.

Jan 1, 1992

By John H. Walsh

"ForewordPart I of this paper, published in the March 1992 issue of the CIM Bulletin, surveyed the probable consequences of a limitation on the emissions of carbon dioxide to the atmosphere for the steel industry. What might be termed the conventional responses to this restriction open to the industry were also surveyed in that section. This section, Part II of the paper, explores a new option - the possibility for the joint production of iron and liquid fuels useful for transportation purposes. In this case, it is shown that it is important to minimize the production of carbon dioxide during the reduction stage to maximize the proportion of the reductant carbon embodied in the fuel. It is also advantageous to conserve hydrogen in the reduction step. In essence, the same carbon fulfills two purposes: it serves as a reductant and fuel for ironmaking and then as a constituent of a liquid fuel. If recovered plastics could be used in ironmaking, the same carbon could serve three useful purposes in turn. The conditions and limitations for the joint use of carbon in such 'cascading' processes are explored below. ABSTRACTIt is becoming increasingly probable that emissions of carbon dioxide from the fossil fuels will have to be reduced to deal with the threat of global warming. This issue is likely to be resolved one way or the other in the period 1995 to 2000 which does not leave much time to develop responsive options. In the intervening period, the policy of the Government of Canada is to stabilize emissions of greenhouse gases at their 1990 level by 2000, by encouraging greater efficiency in the use of energy. Should further reductions prove necessary, economic instruments would probably be employed but these would not be applied before a comprehensive international agreement is reached.There are three main themes in this paper: it is assumed that measures to control carbon dioxide emissions will in fact be necessary by the turn of the century; that there will be a rising need for liquid fuels to supply the world's steadily growing fleet of motor vehicles for many years to come, and that the future niche for Canada's industry in such a carbon-constrained world will be the operation of the energy-intensive industries with efficiency and environmental sensitivity.The steel industry, as a large user of both coal and energy in other forms, would be significantly affected by a need to reduce carbon dioxide emissions. This paper first examines what might be called the conventional responses open to the industry in such a situation and then explores a new possibility for making better use of carbon by the co-production of iron and liquid fuels."

Jan 1, 1992

By Peter K. Mathison

The U. S. Department of Interior, Bureau of Mines (Bureau) is developing a hydrologic monitoring system for in situ leaching operations. A working prototype of this system was installed and tested at the Cyprus Casa Grande copper mine. Requirements specific to in situ leaching operations were identified by researchers. The system has been a useful tool for researchers and for mine personnel. Observations of the hydrologic monitoring system, including details of the development process, the design of the system, and the software developed at the Bureau have resulted in new ideas for an enhanced design of the system.

Jan 1, 1992

Electricity will play a major part in providing energy services in the 21st century. Ecologically Sustainable Development (ESD), that is accommodating the needs of the present without compromising the needs of future generations, will provide a focus for optimising the use of electrical energy. Environmental externalities may redefine the cost structure of electricity. Strong corporate environmental management will ensure that current environmental objectives are met and that future ones, identified by the ESD process and environmental externalities accounting, can be developed and implemented by receptive business managers. This paper addresses the current environmental issues of electricity production. It outlines a management strategy for the SECV becoming a community leader in protecting the environment. ESD is discussed in terms of using non-renewable resources wisely, extending their availability and putting in place mechanisms which ensure their ultimate substitution by renewable resources and conservation. The paper explores options for dealing with costing environmental externalities, particularly in relation to greenhouse emissions.

Jan 1, 1992

By J. C. Mullen

Today, the coal mining industry is more knowledgeable on the potential negative economic consequences associated with improper management of hazardous substances and various types of solid waste. The practices evaluated during environ-mental audits are discussed and example situations are shared from previous audits of coal mines and analogous situations. The importance of assessing and understanding purchasing, warehousing, safety, maintenance, electrical, operations, and environmental management practices and procedures is highlighted as a key to a successful and practical program. A waste minimization approach is presented including strategies for screening product purchases, product substitutions, and testing and record keeping.

Jan 1, 1992

By B M. Guerin

In this paper, some of the constraints to applying bioremediation to the decontamination of polluted soils are introduced. Particularly, attention has been given to those associated with the geology of the polluted site. Areas which require further research have been addressed and indicate that geologists will play a key role, alongside microbial ecologists and engineers, in designing and implementing bioremediation strategies.

Jan 1, 1992

By Eoghan T. M Doyle

Oxide mixtures of nickel (NiO), cobalt (COO) and chromium (Cr203) were prepared with graphite in stoichiometric amounts and the powder mixtures were compacted to produce cylindrical pellets. The composition of chromium oxide in these mixtures were varied. Pressed pellets were reduced in a flowing stream of argon-4% hydrogen gas (500 ml/min). Both slow and rapid heating methods were adopted to raise the temperature of a pellet during reduction of oxides to form superalloy powder. The reduction temperature was varied between. 1523 and 1623K. The effect of heating rate and niobium oxide addition on the microstructure of the superalloy produced was studied by using ordinary light and scanning electron microscopes. New phases formed as a result of reduction were identified by X-ray powder diffraction technique. The mechanism of reduction of oxides together with the microstructure of NiCrCo alloy are discussed. The thermodynamics of formation of ternary alloy phase is elucidated on the basis of binary phase equilibria and Gibbs free energy of mixing data for the constituent alloy compositions.

Jan 1, 1992

By Fernando Concha, Arturo Barrientos

The flow in a hydrocyclone is divided into a boundary layer around the walls, an exterior inviscid flow and an air core in the center of the equipment. The boundary layer flow over the lateral walls is associated with the short circuit of particles to the underflow, while the boundary layer over the top of the hydrocyclone and the outer part of the vortex finder tube is related to the short circuit of particles to the overflow. Classification takes place in the exterior flow. The model can be validated with pilot or industrial data and simulates the performance of hydrocyclones in a wide range of design and operating variables.

Jan 1, 1992

By Serge V. Krasavin

The behavior of rocks subjected to dynamic loading conditions under explosion includes sufficient information about hydrodynamic variables such as pressure P, mass velocity U, internal energy E, specific volume V and density p as functions of time. Measurement of dynamic characteristics in compressed media with manganin wire sensors has become common in the past few years, but the experimental data for certain media, such as rock, do not provide an exhaustive description of rock's behavior in the near zone of an explosion, which is highly responsible for the transformation of energy of explosives.

Jan 1, 1992

By E. Yalçin, A. Ünal

In transitional mineralization, the sill of the underlying variogram is relatively easily estimated, but the estimation of the nugget effect may be more difficult. This study aims to determine for massive copper deposits just how sensitive the estimations of ore reserve, economic copper content, total net value, and ultimate pit limits are to the errors of estimation in the nugget effect of the spherical variogram model. A massive copper deposit which has a log-normal distribution and a spherical variogram was simulated on a rectangular grid using the turning bands method. By using the three dimensional random kriging method, the mean block grades were estimated at four different sampling densities. The ultimate pit-limits were determined by using the two-dimensional dynamic programming algorithm. To calculate the estimation errors, the values obtained by using the actual nugget effect and structured component values were deducted from the estimations obtained using the incorrect nugget effect and structured component values. For isotropic massive copper deposits, it was found that the ratio of the nugget effect to the structured component of the spherical variogram has no significant effect on either the block grades estimated by the kriging method or on the ultimate pit limits.

Jan 1, 1992

By Heikki Tuovinen

The total utilization of raw materials and energy is the most important criterion when planning. industrial processes. The main goal is clearly to use the raw materials and energy as effectively as possible in order to make the desired products directly in the primary process itself', or to recycle unused materials and energy either as such, or after cleaning back into the process. However, few industrial processes are so straightforward. Most processes generate by-streams of materials and energy, which cannot be recycled directly and it is namely these by-streams which tend to remain as wastes. These by-streams are slags, dusts, vaporized metals, liquids, slurries, sludges, gases etc. Most base metal processes produce all these by-products. Waste water and gas emission controls and regulations are tightening all the time, so new processes must be developed to keep pace with these requirements. These processes generate more solid wastes, which must be utilized or at least processed into a harmless form landfilling. Municipal and hazardous wastes also contain valuable materials and energy, which must be used to minimize landfilling. The development of processes for these purposes places even greater demands on research and development. The same principles and methods developed for mining, ore dressing and metal refining processes can also be adapted for research and development work on processes for waste minimization. However, the problems encountered are much more complicated and less familiar, demanding more versatile and accurate tools and equipment. This paper presents principles, examples and some references of R & D work on processes for waste minimization.

Jan 1, 1992

By Richard P. Roberts

This paper will discuss the methods for the cooling of aluminum melting furnace? dross .and their impact on the environment. Also discussed will be a case history of an AROS Dross Processor installation, which is designed to maximize the recovery of metal content of the dross in a manner which is not only environmentally cleaner, but which also prepares the output in such a way as to facilitate downstream processes. Handling of the discharged material will be discussed in regards to the recycling of the preserved metal content and deposition of the unusable-materials.

Jan 1, 1992

By E. Manev

Thin aqueous equilibrium film studies and surface tension measurements on a mixed surfactant system consisting of polyethylene oxide (a model frother) and potassium ethyl xanthate (a model collector) enable the interaction between the two surfactants at the air/solution interface to be elucidated. For the film containing the non-ionic frother, the interface was charged and addition of low concentrations of xanthate acted as a common electrolyte and reduced the thickness of the film inducing rupture. However, at high xanthate collector concentrations, the negative charge xanthate was found to interact with the non-ionic and caused a build-up of negative charge at the air/solution. Higher frother concentrations were necessary to produce non-rupturing thin films upon increasing the xanthate concentration.

Jan 1, 1992

By M. Zanotto

[ ] A period of heavy rains caused the river Adda to flood parts of the Valtellina, one of the Alpine valleys of Northern Italy. The exceptionally high waters put under considerable strain the whole system of embankments and levees controlling the river and protecting the adjacent towns and lands. In some places the water breached and washed away the embankments, submerging large tracts of cultivated land, buildings, roads and railway tracks. The town of Talamona, in the lower Valtellina, was hit particularly hard: in its proximity the river overrun and then washed away 300 m (1,000 ft) of embankment (see vicinity map, fig. 2), depositing large amounts of riverbed debris onto over 400 hectares (1,000 acres) of fertile land.

Jan 1, 1992

By G. W. Luxbacher

Acid rain legislation included in the Clean Air Act Amendments of 1990 caused a great deal of uncertainty regarding the price, source and production quantities of coal supplied to the eastern coal market. Powder River Basin and other western coals continue a rapidly accelerating migration eastward. South American coals move into the northern markets. States are proposing legislation to assist utilities in complying with the new regulations in hopes of maintaining their own coal industries. Some utilities question the long-term availability of eastern compliance coal. Major coal producers must make decisions now to assure their continuing presence in the market place. Several companies have adopted a strategy to acquire eastern compliance reserves, while others have invested in technology to compete as a low-cost producer. Legislation "Acid rain." This is a topic that was debated within the scientific, environmental and industrial communities for years. Those discussions resulted in a large outlay for the federal National Acid Precipitation Assessment Project (NAPAP), which was then ignored. Acid rain then became the subject of a "60 Minutes" broadcast that debunked the acid rain theory, supporting the NAPAP study conclusions. In the final outcome, however, acid rain was the driver for the Clean Air Act Amendments of 1990.

Jan 1, 1992

Lignite constitutes approximately 97 percent of the near-surface coal resources in Texas. The most significant bituminous resources are in the north-central and southern parts of the state. Coal reserves in Texas are estimated to be 13.7 billion tons, about three percent of U.S. coal reserves. The average thickness of coal seams mined in Texas is approximately eight feet. Texas gained primacy when its regulatory program was conditionally approved February 16, 1980; the program was fully approved June 18,1980. The state's Abandoned Mine Lands program was approved June 23,1980.

Jan 1, 1992

By Duran A, Eggers M. J

It is standard practice in geotechnical studies for mine design to drill a series of inclined oriented boreholes into the proposed pit walls. However, this investigation tool is often used without an adequate understanding of the inherent shortcomings in the method and the many potential sources of error. Of the more commonly used orientation methods in Australia the clay imprint technique is probably the most reliable. Contoured stereographic plots of oriented core data are frequently characterised by diverse pole distributions and low concentration maximums compared with line mapping data. Common sources of error producing these poor results are misinterpretation of orientation marks or imprints, inaccurate marking of the reference line, errors in the structural measurement of the defects, lack of continuity information and blind zones sub-parallel to the borehole direction which correction methods frequently do not fix. Line mapping is the preferred method of structural data collection due to the lower overall cost, availability of continuity information and higher accuracy. The projectability of field mapping data to final wall positions can be assessed with a good understanding of the regional geology and local structural patterns. Where field mapping is not possible due to a thick regolith cover, core orientation should be carried out by experienced personnel to minimise the many potential errors.A series of case studies are presented which compare oriented core with mapping and highlight the inherent problems with the technique.

Jan 1, 1992

Rehabilitation has been very effective in the short to medium term in providing a cost effective and reliable means of containing the side effects of land disturbance. However, there is still insufficient data to critically evaluate the sucess of rehabilitation in the long term. There is an urgent need to develop objective criteria to monitor the sucess of rehabilitation. The aim of rehabilitation in Australia has traditionally been to return disturbed land to natural vegetation compatible with the surrounding area. This objective has often been accepted instinctively without adequately addressing alternatives.

Jan 1, 1992