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By G. H. Khoe

Although some hydrometallurgical process liquors contain significant amounts of ferrous and arsenate ions, no reliable thermochemical data for the aqueous complexes and the solubility of the ferrous arsenate precipitate are available. The complexation of iron(11) with arsenate has been investigated using the potentiomemc titration method. The results indicated that virtually no complexation of iron(@ with arsenate has been observed. This is in contrast to the significant complexing reported for iron(1n) with arsenate. The solubility product of the precipitate was calculated using the concentrations of appropriate arsenate species pertaining to the observed precipitation pH's. The fit of the observed precipitation points on the solubility curve of the computed stability diagram was used to assess the appropriateness of the equilibrium model.

Jan 1, 1991

By Manlapig E. V

ABSTRACT- I Results are given for a series of tests in which a 300 mm pilot-scale Jameson cell has been used in copper recleaner flotation, and for the flotation of a lead rougher feed. the results indicate that the production rate of solids, at the same superficial air velocity Jg, is higher than in conventional columns. Thus in the copper recleaner application, the pulling rate reached 14 gm/cm2/min compared with between two and three for an operating column, while in the lead cleaner application the comparable figures were 12 - 14 gm/cm2/min for the Jameson cell vs 8 - 9 gm/cm2/min for a test column. A froth crowder was used to increase the air superficial velocity Jg in the Jameson cell in the copper recleaner, while holding the collection mechanism and pulp feed rates constant. The recovery increased from 50 per cent to over 90 per cent, suggesting that recovery is controlled mainly by the froth conditions, rather than the particle-bubble interactions in the Downcomer.

Jan 1, 1991

By William Petruk

The capabilities of SEM/image analyzers for determining quantitative mineral data which have a bearing on extractive metallurgy have given applied mineralogy a new dimension. The capabilities include automatic mineral identification, unattended operation, search for rare minerals, and measurements of (1) mineral quantities, (2) grain and particle size distributions, (3) liberation characteristics of minerals in ground ores, and (4) mineral associations. Data on mineral quantities define the distributions of elements among minerals, provide background information on characteristics of the samples, and provide a data base for a mineral-materials balance. Size analysis data of the minerals in unbroken ores are used to predict the grind required to liberate minerals. Data on liberation analysis can be used in many ways. One application is to process the image analysis data for feed, concentrate and tails by a materials balancing technique to calculate the recovery of liberated and unliberated grains at each point in a circuit. The calculated recovery data define the behaviour of an ore in a concentrator, pilot plant or bench test, and indicate whether recovery improvements are possible and/or feasible for a particular ore.

Jan 1, 1991

By James D. O, DeLa&apos

Multicomponent materials are common in nearly all areas of materials science and technology, yet the use of phase diagrams to represent these complex systems is hampered by the requirement of three or more dimensions for explicit graphical representation. In the present work, the "solid-modeling" capabilities of a computer aided design (CAD) system have been applied to the representation of three-dimensional phase diagrams. Relevant phase diagrams for a hypothetical quaternary eutectic system were constructed and used to demonstrate the capabilities of the technique. These capabilities lead to relative ease of phase diagram construction and improved access to qualitative and quantitative information. Results of this work are contrasted and compared to previous efforts toward computer ,representation of phase diagrams. It is concluded that solid-modeling of three-dimensional phase diagrams can be used to advantage in both education and research.

Jan 1, 1991

By J. Markussen

The Falconbridge Matte Leach Plant was based on leaching Ni-Cu matte with strong hydrochloric acid in rubber lined equipment. It operated from 1968 to 1983 as a precursor to Nikkelverk's present C12 Leach. The process comprised two S.X. systems. NiC12.4H20 crystallization, crystal drying, NiC12.H20 pyrohydrolysis and HC1 gas recovery. The naphtha fired fluid bed pyrohydrolyzer produced granular NiO, subsequently reduced with H2 to granular nickel for sale. The development and operation of the pyrohydrolyzer are described

Jan 1, 1991

By T. Chong, R. Pesalj, B. Marchant, Z. Nikic

"The Mount Polley copper/gold project is located in central British Columbia and is currently being developed by Imperial Metals Corporation. Extensive laboratory and pilot plant testing was required to develop acceptable metallurgy for recovery of both sulphide and oxide copper-gold mineralization. Copper recovery is highly sensitive to oxide copper content of the feed whereas gold is primarily associated with the copper sulphide minerals. A conventional flowsheet where sulphide flotation is followed by sulphidization and oxide scavenging is described. The conventional flowsheet was used in a feasibility study which resulted in a favourable production decision at Mount Polley. Detailed engineering and permitting are in progress.More recently, laboratory and pilot testing of a new flotation reagent, S-6493*, an oxide specific collector, has indicated that improved copper recovery can be accomplished with reduced reagent consumption, including elimination of the sulphidization step, using S-6493 compared with the conventional flowsheet. The comparative metallurgical results using S-6493 and conventional sulphidization methods are presented, from both bench scale and pilot testing. Comparative economics of the conventional flowsheet and that using S-6493 are also presented. Advantages of S-6493 include reduced reagent costs, increased revenues from additional copper recovery, and overall reduction in capital and plant operating costs due to the simplified flowsheet. INTRODUCDONThe Mount Polley copper/gold property is located in Central British Columbia, 56 air kilometres northeast of Williams Lake. The first recorded exploration was in 1964. By 1989, a total of 238 diamond drill holes, totalling 27, 522 meters, was completed to detail reserves on the Mount Polley prospect. A number of drill core composites were submitted, containing a variety of oxide copper levels, for metallurgical flowsheet development. Six bulk samples were collected from surface trenches for additional bench scale testing and for pilot plant testing."

Jan 1, 1991

By Aureo D. V. Machado

An experimental study to obtain zirconia powders (ZrOz) from carboxylate zirconium solutions followed by hydrogen peroxide stripping and precipitation, has been carried out. Zirconium carboxylate was prepared by solvent extraction from a chloride aqueous phase using magnesium carboxylate as organic phase. The variables examined in the precipitation reaction were: Temperature: 25 - 90 ?C ? H202= concentration: 0.3 - 5% wt/wt - pH: 1 ? 9 Organic/Aqueous ratio (1/1) and reaction time (30 minutes) were maintained at constant levels. The optimum results (98% precipitation) were achieved at 25 °C, 5 % wt/wt H202=, and pH = 5. The precipitates were composed of large amorphous aggregates (<I00 micrometers). After calcination for 1 hour at 1000 OC, monoclinic ZrO2 with a large variation in particle size (1 -100 micrometers) was obtained.

Jan 1, 1991

By S. Banisi, J. Marois, A. R. Laplante

"This paper compares the behaviour of gold and ore in the grinding circuit of Hemlo Mines Ltd. Particular attention is given to grinding kinetics, classification behaviour, and liberation. For grinding kinetics, laboratory grinding of gold flakes and silica, 840 µm to 1200 µm in size (14/20 mesh), was also performed to provide a standard for comparison and to study in a controlled environment the mechanisms of breakage, folding , smearing and impacting.Grinding kinetics were characterized at laboratory scale with breakage and selection functions. The breakage function showed that 75% of gold disappearing from the 840 µm to 1200 µm class reported to the 600 µm to 840 µm; this figure is much higher than for silica (46%) or most other minerals, and implies that comparatively fewer fine fragments are produced from the breakage of gold flakes, on account of gold&apos;s malleability. The selection function of silica was four times that of gold. At plant scale, the ratio of the selection function of ore and gold increased from 6 for at 50 urn to JOO pm to 20 at 500 um to 1000µm.Observation of original flakes and their fragments with the scanning electron microscope showed that the main mechanism of ""grinding"" from the 840 µm to 1200 µm to the 600 µm to 840 µm class was folding rather than actual breakage. This was confirmed by a measure of individual flake weight. The postulated breakage cycle is that relatively globular flakes become increasingly serrated through grinding; they can then regain their original shape through folding and reflattening into cylindrical and spherical shapes, as the majority does; however, some fragments will at this point undergo actual breakage. Photograhic evidence is presented to support the proposed mechanisms.Smearing of gold unto silica was observed when silica was ground after a gold, and embedding of silica into gold flakes when gold was ground after a silica. Both mechanisms occur whenever gold and harder minerals are jointly ground, and result in ""unliberation"" of gold. It is postulated that smearing of gold onto other minerals plays an important role in explaining how gravity recovery can increase over-all gold metallurgy, especially when used ahead of flotation.Classification of gold in the primary hydro cyclones takes place at a much finer cut-size than ore, 20 µm vs 57 µm. This and the slower grinding kinetics result in high gold circulating loads in the primary loop, 6700%, and a gold content in the primary cyclone underflow (PCUF) is twenty-four times that of the ore. The gold size distribution for primary cyclone overflow is much finer than that of the ore, although they are essentially similar in the PCUF.Liberation, or more accurately ""gravity recoverability"", was assessed with a 7.5 cm (3 in.) Knelson concentrator. It varied between the thirties for the primary mill discharge and two cyclone overflows, to highs of 89% and 92% for the PCUF and secondary mill discharge."

Jan 1, 1991

The patterns of flow of reaction gases through the flash furnace at the Kalgoorlie Nickel Smelter were simulated in a 1:20 scale model using a flow of water. Particular features of the flow down the reaction shaft, through the settling chamber and into the uptake leading to the waste-heat boiler were examined. Inferences were made concerning the effects of the patterns of flow on the efficiency of the smelting reaction, on the entrainment of dust by the gas stream and on the erosion of the refractory lining of the furnace. In addition, the effects of geometrical modifications to the arrangement of the concentrate burners and to the profile of the settling chamber were explored by making these changes to the model and observing the resulting variations in the patterns of flow.

Jan 1, 1991

By V. Rajagopal

Corrosion and abrasion properties of a series of chromium-containing cast iron balls with Cr contents ranging from 0 to 29% was evaluated and compared with austenitic stainless steel and mild steel balls. Marked ball wear tests were performed on artificial ore samples consisting of 95% quartzite with either 5% pyrrhotite or 5% chalcopyrite under a nitrogen or oxygen atmosphere. The electrochemical mechanism was investigated by correlating the corrosive wear with the corrosion currents obtained from potentiodynamic polarization curves under abrasion. An offset in their electrochemical activities was observed somewhere between 16 and 26% Cr. In fact, 26 and 29% Cr cast irons showed an excellent corrosion resistance approaching that of austenitic stainless steel. Flotation recoveries were estimated on a 95% quartzite + 5% pyrrhotite sample ground with various cast iron ball materials under an oxygen or nitrogen atmosphere. Electrochemical results are found to be in good agreement with corrosive wear obtained from marked ball wear test and with flotation results.

Jan 1, 1991

By C. -S. Jiang

In most copper refineries, addition agents are added at predetermined rates with no further monitoring of their activity or concentration in the electrolyte. Increasingly stringent cathode quality requirements, and a desire for better process control in tankhouse operations, have recently directed a number of refineries to search for a better addition agent control strategy. Extensive development work has been carried out at the Noranda Technology Centre for the monitor in of glue and thiourea in copper refinery electrolyte using cyclic voltammetry (cv~. Data from both synthetrc and commercial electrolytes are presented, showing the ability of CV to produce reliable and easily identifiable fingerprints of addition agent concentrations in copper refinery electrolyte.

Jan 1, 1991

By M. L. Apel

A conceptual approach to the bioremediation of uranium mill tailings (UMT) is presented., This approach focuses on, biosorption to remediate the. effluent solution and bioleaching remediate the. solid fraction. Comparative biosorption studies were performed with synthetic single metal solutions using a commercially available biopolymer. The maximum rate of metal sorption by calcium alginate was found to be 5.43, 6,39, 6.48, and 9.74 mg dm-3 min-1 for U022*, Ba2+, Cd2+ and Zn2+, respectively. Activation energy (AEa) for barium uptake by calcium alginate beads was determined to be 11.5 kJ, indicating a diffusion controlled reaction mechanism. Thermodynamic values (AG+ AH+ and ASt) of the metal-alginate activated complex, as reported in the literature, were found to be in agreement with those calculated from this research. Results show that this biopolymer can be effectively applied in the removal of select metals prevalent in uranium mill tailing effluents and associated waste streams.

Jan 1, 1991

By M. F. Gleason, S. Burns, J. R. Arnold

In 1986, Gold Fields began negotiations with a large Nevada electrical power utility to supply power for its Chimney Creek mine in northern Nevada. After the long negotiations reached an impasse over various costs associated with the power line, a decision was made by Gold Fields to generate its own power. Self-generation is not uncommon overseas, but it is rare for any but very large or very small operations in the United States. Surprisingly, under certain conditions a mine can generate its own power profitably, and Gold Fields has found that the associated operating and maintenance problems are minimal. The following report details what factors went into this decision and how it works. Hopefully, it can serve as a guideline for those who may find themselves in a similar position. History In the spring of 1986, Davy McKee Corp. was contracted by Gold Fields Mining Corp. to provide design engineering and construction management for the chimney Creek Mine. Chimney Creek is located about 50 mi northeast of Winnemucca, NV in a remote part of Humboldt County. The nearest industry using utility power was the Pinson Mine, about 13 mi from the proposed plant site. The existing electric line was not capable of carrying another mine the size of Chimney Creek, which required 29 million kwh per year. There were three options available to Gold Fields for the power supply: 1 )Power could be supplied by the public utility from a coal-fired plant about 30 mi away by constructing a new line to the mine,

Jan 1, 1991

By Joni M. Barnes

A strain of Pseudomonas stutzeri isohted from selenium contaminated surface waters, was found to be effective . in reducing selenate (Se04 2) stoichiometrically to selenite (Se03 2 &apos;), which was further reduced to elementaJ selenium (Se0 ). These reactions were concurrent with the microbial oxidation of lactate. In order to assess quantitatively the amounts of seilenate and selenitein solution, improvements to existing analytical methods (ion exchange chromatography and inductively coupled plasma atomic emission spectrophotometry technique) .were made.

Jan 1, 1991

By John T. Cantwell

INTRODUCTION The process engineer usually is responsible for the design operating philosophy and/or day-to-day operations of a process. Since instrumentation is an integral part of the operation, it is essential that engineers understand the general capabilities of the different types of control equipment available. Many "noncontrol" engineers have become involved with instrumentation for machinery monitoring and control as well as other plant applications. The advent of the microprocessor has led to significant changes in control, both in systems configurations and man-machine interfaces. Today&apos;s concept is called simply "distributed control." What is distributed control? Distributed control is exactly what the name implies; the control system is divided into several functional segments and spread out to cover a process. The systems are distributed for physical, functional, and risk reasons. Before delving further into the specifics of distributed control, let&apos;s look at the evolution of control systems to see how we got here. Instruments initially were located near measurement and control points in the field. Operators physically had to go to the instrument to change setpoints or take measurements. As processes became more complex, it became evident that a central control area was required. This allowed an operator to monitor and control many variables. The operator&apos;s effectiveness was increased dramatically, which resulted in greater efficiency, better quality control, and lower personnel requirements. At the same time, plants became much larger, control applications became more complex, energy became expensive, and the industry became more competitive. All of these factors placed pressure on process and production engineers to get the most for the money. The result was a continuing push to put more instrumentation into a central control room to maximize efficiency and productivity and minimize manpower. This chapter deals in some detail with devices for measuring physical and chemical properties of coal; devices for measuring the weight and weight-rate of flow of coal; devices for the monitoring and control of conveyor systems, solids inventory, fluid flow, liquid level, density, and specific gravity. These instruments have a multitude of uses throughout a coal preparation plant. The discussions cover advancements in "on-line analysis," nuclear control devices, and distributed control using microprocessors, mainframes, and soft-

Jan 1, 1991

By R. E. Moore

The lining systems currently in use in BOF furnaces, certain steel ladles, and the slag line of electric are furnaces were developed during the late seventies through the mid-eighties using a trial and error method of combining aggregate, carbon sources, additives and binders. They are currently based on magnesia, graphite, metal additives and resin binders, the selections of each being tied to the anticipated intensity of the use conditions. The general functions of the respective constituents are well appreciated, however, there is still a great deal that is not known about how the socalled antioxidants protect the graphite nor how impurities from the graphite and the aggregate enter into the wear processes. In a simplified assessment of wear processes, it appears that if the deoxidized layer can be kept very thin, less than 810 mm in depth, and if the viscosity and quantity of the matrix glassy phases can be controlled to resist erosion of the deoxidized layer, lining life can be maximized for the various applications. This paper will discuss the characteristics of the starting materials systems currently being employed for applications requiring a deoxidation function to realize extended wear. It will not attempt to explain all the complex interrelationships between the respective constituents but will point to the potential for improvements through the use of improved constituents.

Jan 1, 1991

"Polycom, a new approach to ore processing based on pressure comminution, is obviously a very attractive alternative to conventional processing methods.Since a full-scale pilot plant was commissioned in 1986, more than 125 commercial installations, with capacities up to 1000 t/hr, have gone ahead.Already successfully used in processing cement clinker, limestone, coal, and other minerals, Polycom high pressure grinding results in:o Significantly reduced capital costs, because smaller units can be used m new installations;o Capacity increases of up to 100% in existing facilities; and o Operating economies that include energy savings of 20% or more, and reduced wear parts consumption.1. IntroductionAutogenous or semi-autogenous mills in conjunction with rod or ball mills are used with preference for ore processing. Most ball mills are of closed-circuit design and operate with mechanical classifiers (spiral or rake classifiers) or hydrocyclones. In other words, the ores undergo wet primary grinding, since slurries are required for the downstream separation stages anyway. This paper presents a new grinding system based on high pressure comminution of ores. This grinding process allows:- Energy savings of up to 20 % or more- Capacity increases of up to 100 % and more- Reduction of wear costs- Smaller units for new installation and thus- Reduced investment costsThese advantages are highly interesting for both new installations and conversion projects, particulary in cases where an increasing hardeness of the ore, i.e. rising Bond Work Index, reduces the output of the plants or where the metal assay of the ore decreases and the capacity of the existing systems has to be increased. POLYCOM high-pressure grinding rolls have established themselves with great success already for grinding cement clinker, granulated blast furnace slag, limestone, cement raw materials, coal and other materials.Meanwhile more than 250 high pressure grinding rolls have been installed worldwide. Capacities up to 1.000 t/h with roller diameter up to 2.8 m and drive units up to 2.400 kW are installed."

Jan 1, 1991

By Jay Hilary Kelley

A ventilation system is described using dual aircourses: one zone occupied by working personnel, the other at the active working face. The two zones are separated by a partition or Shroud. The occupied zone to the rear of the face zone is ventilated adequately but with considerably less air because little gas, dust, or fumes are present. The face excavating zone is sealed and maintained at slightly more negative pressure preventing dust and gas generating from within to escape. Explosive mixtures within the face zone is rendered non-explosive by the introduction of inert gas therein. Each zone is vented separately to the outside of the mine. Because less total quantity of air is required for human breathing, etc, the total ventilation system can be drastically reduced in tan capacity, development entries, and air shafts, -- a great savings in costs.

Jan 1, 1991

By P. Massacci

The modelling of phenomena by nonlinear dynamic Systems Theory representations require the specification and identification of suitable models of the phenomenon and the availability of good optimization algorithms to determine the optimal controls. Stochastic disturbances and difficulties of monitoring the process lead invariably, otherwise, to suboptimal performance. It will be shown that an algorithm can be formulated which will simultaneously identify and optimize such a system. The properties of the algorithm will be derived and its convergence to an optimal control proved. Some results of actual applications will be presented and it will be shown how this approach generalizes easily to optimal control of the actual processing system. These results generalize those of optimal learning and input conditioning.

Jan 1, 1991

By Wu Y, Qu Q

The Central Coal Mining Research Institute has developed the MAE acoustic emission monitoring system, the BD4-1 portable acoustic emission monitor and the MRB rock burst monitoring system. In the MAE system there is an IBM-PLAT, a receiver and 16 channels and the investigating range is 100 m. The main functions are detecting acoustic events from the working faces, periodically making statistics, prints, displays and storing of the results, and performing the off-line process such as drawing the curves of acoustic activity. The BD4-1 instrument has four channels, it works for more than 24 hours continuously, and keeps the data for more than 30 days after power tum-off. The BD4-1 is suited to the monitoring for a long or a short time as a fixed point where the system is invalid, especially to the monitoring of the acoustic activity promoted by the blasting. There is an IBM-PC/AT, a receiver and 16 channels spread 10 km in the system MRB. The system could on-line collect microseismic events throughout the whole mine, calculate the source location and the energy, and off-line draw the seismic activity draft of time-based or distribution in space. In practice, the forecasting is successful by using the acoustic emission and microseismic monitoring system and the portable instrument.

Jan 1, 1991