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By Nar S. Dalal, Xianglin Shi, Val Vallyathan

"INTRODOCTIONIn an earlier communication 1 from our laboratory it was reported that mechanical crushing of coal and quartz under normal air atmosphere generates of free radicals on the particle surfaces, and that these radicals decay with time, hence pointing to a higher toxicity of fresh dusts in relationship to pneumoconiosis and silicosis. More recently Fubini et al.2 have also reported the detection by electron spin resonance (ESR) of the formation of SiO. and Si-type of radicals from quartz particles crushed under atmospheric conditions. In agreement with earlier ESR studies on single crystals of quartz crushed under high vacuum ( -10-10 torr>3 and subsequent exposure to air,3 and to other gases,4 these radicals were identified2 as being formed by the homolytic cleavage of the Si-0-Si bonds and the reactions of the Si• and SiO- radical with atmosphere. Fubini et al.2 also suggested that these radicals might be involved in the mechanism of the fibrotic action by silica, either by transforming the particle surface into a selective oxidating agent or as an initiator of a sequence of reactions leading to fibrosis. Earlier Gabor and Anca5 bad reported that lipid ·peroxidation caused by free radicals on the silica surface might be involved in the red blood cell membrane damage. Thus far, however, no parallel cytotoxicity, fibrogenicity, and free radica1 studies on a given quartz dust sample have been reported, except for some earlier work from our laboratory.1·6·7 We now present more recent results obtained from parallel cytotoxicity, fibrogenicity, and free radica1 measurements on a freshly made quartz dust. The dust's free radica1 content was measured using ESR spectroscopy while its cytotoxicity potential was estimated via hemolysis. Hemolysis was employed as the toxicity test because it is a widely used method for estimating the potential of a dust for disrupting the cell membrane. 8 The fibrotic potential was followed by measuring the dust-induced lipid peroxidation, using linoleic acid as a model lipid. As discussed below, the results obtained suggest new clues to the mechanism of the quartzrelated cytotoxicity and fibrogenicity. MATERIALS AND METHODSReagentsCrystalline quartz particles with a size range of 0.2-2.5 mm were obtained from the Generic Respirable Dust Technology Center, Pennsylvania State University, University Park, Pennsylvania. These particles were crushed in air to obtain quartz dust samples with particle sizes smaller than 20 microns. We chose to work with a dust with mixed particle sizes, rather than a specific range, as an effort to simulate the mining atmosphere. An agate mortar-pestle arrangement was used for the crushing and grinding because of the close similarity of the structure of agate to that of quartz. Diethylenetriaminepentaacetic acid (DETAPAC) were purchased from Sigma. All other chemica1s were purchased from Fisher or Aldrich.Hemolysls ExperimentsHemolytic activity of silica was measured, following an established procedure,9 as the amount of hemoglobin released from a 2 % suspension of sheep erythrocytes after incubation with 10 mg of silica dust for one hour at 37 °C. The hemoglobin release was estimated via the absorbance at 540 nm using a Gioford spectrophotometer. The procedure was calibrated by substituting the silica dust by a phosphate buffer solution as a negative control (background) and O.S % Triton-X-100 as a positive control (100% hemolysis). The percentage of hemolysis was calculated as follows:"

Jan 1, 1990

By Thomas L. Vandergrift

The type and severity of coal mine entry failures are affected by the strength and stiffness properties of the roof, floor, end coal. Knowledge of the mine-wide trends of these properties Is valuable in developing effective ground control plans. Within the context of a larger effort to Improve entry stability In high horizontal stress fields, the U.S. Department of the Interior, Bureau of Mines, has evaluated three portable, on-site test devices to determine their suitability for identifying mine-wide physical property trends. The devices evaluated were the borehole shear tester, the Schmidt harmer, and the point load tester. Despite the lack of standardized data Interpretation procedures, each device provided useful on-site physical property data. The Schmidt homer was preferred for trend identification because of Its speed and simplicity. Schmidt hammer data were collected over a large area of an underground coal mine to compare calculated roof strength trends with a known geologic feature.

Jan 1, 1990

The concept of optical basicity is now being widely applied to rationalize and predict the chemical properties of slags. It employs signals from a probe ion to indicate the "state" or relative "freeness" of the oxygen ions in the slag, and hence provides a fundamental measure of slag basicity. Values of the bulk optical basicity of a slag can either be measured spectroscopically in samples of transparent solid glassy slag, or calculated very simply and accurately from the chemical composition of the slag. The way in which these values vary in different systems are illustrated as isoptical basicity lines on ternary diagrams, and the patterns obtained are discussed. The difficulties associated with assigning optical basicities to the oxides of transition elements are also reviewed briefly. It has been demonstrated that these bulk values can be used as the basis of a flux control model for steelmaking to achieve end-point chemistries much more reliably. Furthermore, several correlations have been established which allow the prediction of the slag-metal distribution of various solute elements. This approach has been used to predict the phosphorus distribution at the end of steelmaking, and also to custom design fluxes for the ladle and tundish to aid in the control of residual elements in the steel such as suphur, hydrogen and nitrogen.

Jan 1, 1990

A comprehensive analysis of rock structures in non-oriented (axially oriented) drillcore is now available (Laing, in press). The system embodies new concepts which better equip the geologist and engineer to deal from the outset with optimising the acquisition of structural information in drillcore, logging: interpreting, and graphically presenting the results. The few existing techniques for determining orientations of structures are augmented by a wide range of new techniques, and all are brought together into two solution types by considering the underlying Euclidean geometries. Analysis of these solution types in terms of what data are required to implement each solution and what assumptions need to be made, leads to strategies which facilitate intelligent design of different drilling programs for blind and outcropping situations. Drillcore is variably structurally fertile, depending on the number of different structures present. This concept fosters the selective logging only of the more fertile core. Drillholes are also variably fertile, depending on their orientational relationship to the structures in the host rocks. Structural parameters are either vectorial or non-vectorial. Vectorial structures parameters comprise normal structural orientations plus polar vectors like vergence, younging, shear sense and so on. They can be determined by one of two solution types: external solutions, which use an external reference structure to fix the drillcore and thus permit orientation of all structures within that core, and internal solutions, which use orientational data from a selected structure at three or more different drillhole orientation to determine the unique orientation of that structure, without reference to any external structure. Both solution types rely on constant orientations (orientational stability) of the selected structure, but the internal solution actually provides its own test of orientational stability. External solutions are the norm in outcropping situations and internal solutions are invaluable in blind situations. In blind situations sequential "internal then external" solutions can be used respectively to provide a reference structure and then use this for subsequent external solutions at individual points downhole. Blind prospects can now be drilled and interpreted as easily as outcropping prospects. Each solution type has its own optimum requirements. External solutions are ambiguous for certain orientational relationships between the drillhole and the reference structure (for example, a perpendicular relationship), hence drillholes in which external solutions are planned should be designed to avoid these orientations. Internal solutions are ambiguous for straight drill paths, and are most unambiguously resolved when the drill path attains maximum drillhole dimensionality, that is, it occupies a wide variety of orientations in 3D space; hence drillholes in which internal solutions are planned should be designed as combinations of non-parallel holes or as individual strongly curved holes. For both solution types an understanding of the kind of structural fertility required leads to intelligent design of drill paths, which is termed structural drill targeting. It is distinct from spatial drill targeting, which is the process which defines and (x,y,z) point-or volume-target. Effective design of drilling programs requires both structural and spatial targeting. The external and internal solutions for vectorial parameters are implemented via (1) visual (qualitative), (2) stereographic, or (3) core orienting frame procedures. Each of these has its own advantages. Stereographic procedures have been simplified via the erection of a drillcore reference frame in which three fundamental angles are defined, and the formulation of an all-inclusive set of stereographic recipes for determining orientations from the measurement of these angles. Non- vectorial structural parameters comprise an ad hoc array of useful measures which are simply described by numbers. Examples are angles between structures, and density of structures. Such parameters (some of which provide useful vectors toward ore bodies) are invaluable in drillcore because they can be measured and recorded rapidly, without determining the orientation of the core. In a summary, non-oriented drillcore can now be structurally mapped exactly as if it were outcrop. Interpretation of the significant volume of unique structural information which is beginning to flow from this system can be optimised by using, in addition to the conventional cross section and longditudinal section, three new modes of presentation. The natural cross section is that section in space normal to a principal structure of interest. It is a section in which it is advisable to drill to obtain certain structural information, and in which the results need to be presented. A newly defined unique cross sectional orientational symbol is recommended for dramatic improvement in the quality of information presented in cross sections. Stacked level maps are a powerful adjunct to cross sections.

Jan 1, 1990

By R. Clarkson

"The Yukon's numerous (185) placer gold mines are still a major social and economic force in this developing economy. Gold recovery at each of the various sluiceboxes is not optimized due to extremely difficult sampling logistics and a shortage of technical expertise and industrial research.At each of six operating placer mines, numerous sluicebox tailings samples were collected with hand held sample cutters and combined into large (2-7 cubic yards) duplicate samples. The entire sample volumes were screened and processed on a shaking table to determine gold losses. The existing and potential gold recoveries and recommended sluicebox design and operating parameters are presented.2 ACKNOWLEDGMENTSThe Project Manager gratefully acknowledges the following support for this placer research program:The funding received from the National Research Council's Industrial Research Program, the Canada/Yukon Economic Development Agreement and the Canada Center for Minerals and Energy Technology (CANMET): andThe technical advice provided by Tad Cienski (CANMET), Ron Johnson (KPMA), George Poling (University of B.C.) and Dan Walsh (University of Alaska).3 OBJECTIVESThe objectives of the Gold Recovery Project are to: evaluate gold losses with statistically based sampling programs; determine how to improve gold recovery; assist miners with the recommended technology and make this information available to the entire placer industry."

Jan 1, 1990

By Smith N. S, Rholl S. A, Otterness R. E

The Bureau of Mines is conducting research to develop blast designs for the control of fragmentation and rock displacement and the reduction of overall mining costs. This Bureau experiment, a program of 25 reduced-scale blasts conducted at the University of Missouri-Rolla's experimental quarry, determined the effects on fragmentation of changes in burden, spacing, explosive diameter, and stemming-explosive length. Combined with previous work at this experimental quarry examining air gap, delay, and decoupling effects, this experiment provided a data base of over 50 shots. The fragmented rock, 1000 to 3000 kg from each 3- to 4-hole blast in the 1 m bench of massive dolomite, was completely screened to assess fragmentation. The explosive used for all the tests was extra dynamite initiated by seismic caps fired from a sequential blasting machine with delays of 5.2- to 13-ms/m of burden. Empirical equations were developed which predicted the effect of shot design parameters on the fragmentation. These formulas predicted the average fragment size of each of the 25-shots to within 13 percent. For spacing to burden ratios of 1, 1.4 and 2, there were optimum burden to explosive diameter ratios (B/de) of 30, 26 and 20, respectively. Decreasing the B/d. ratio beyond these levels resulted in little or no reduction in the average size. For B/de ratios above these levels the average size increased but, at least a 15 percent reduction in the average size results when the shot design parameters are optimized.

Jan 1, 1990

By S G. Keyte

Gravity methods of recovering alluvial gold are not very efficient at particle sizes below about 0.l mm. Whereas such gold may not have been economic to recover in the past, the same may not be true today. Centrifugal concentrators, like the Knudsen and Knelson bowls, are showing promise after an inauspicious start, at least in New Zealand. The large proportion of heavy mineral in many auriferous beach sands and the natural hydrophobicity of fine gold should make flotation an attractive contender for its recovery. The conventional mechanical flotation cell is effective, but roughing, scavenging and cleaning are necessary to achieve both high recovery and low mass Yield. More problematic is the difficulty of maintaining coarse and dense sands in suspension. The air sparged hydrocyclone is effective at recovering fine gold from a fine Colarado River sand, but is not effective for the coarse and dense beach sands of New Zealand. The flotation column shows much promise for these sands, when recoveries of over 80 per cent and mass yields of less than one per cent can be achieved in a single pass. The froth separator of the USSR and flash flotation could also be worthy contenders. It is felt that flotation could be limited to naturally and artificially de-slimed concentrates.

Jan 1, 1990

By Y. C. Kim

This paper describes the implementation aspect of a blast hole kriging system which has been developed for the purpose of daily ore-waste control in an open pit mine. The primary goal of blast hole kriging is to improve the ore-waste delineation procedure. A complete computer program package called Blast Hole Kriging (BHK) System was developed for IBM/PC AT or XT computer, using Fortran language and supplemented by a few Assembly language routines for bit-map manipulation. The emphasis of this paper is on the implementation aspect of the developed system. For this reason, the requirements for practical implementation and the system design considerations are discussed in the paper, as well as the main features of the University of Arizona's BHK System.

Jan 1, 1990

Knowledge of initial ground pressures or in-situ stresses and mechanical properties and geological conditions is of great importance in drivage and maintenance of a mine roadway. Field measurements of the in-situ stresses and the geological and mechanical properties have been carried out. However, these methods are really impractical in using in underground mines. Alternatively, back analysis method using measured displacements during drivage of roadway can be used. The paper presents discussion on some problems in applying inverse formulation of back analysis to a roadway driven in an in- homogeneous rock mass. The back analysis is formulated by 2-0 finite element method. The inverse procedure is carried out using a microcomputer, but for the multi-rock layer, a larger computer or a main-frame computer is used due to an iterative procedure.

Jan 1, 1990

By R. Hendrickson

In the 1940's a top blown water-cooled oxygen lance was developed to inject oxygen into liquid iron. This process, the LD or BOF process technique, today is used in 65% of the world's steel production, and represents the largest oxygen market for temperature enhancement in steel and non-ferrous smelting applications. There are three major approaches to the use of oxygen in metallurgical processes: (1) general enrichment of the air supplied to burners or tuyeres, (2) under-flame enrichment or injection, and (3) the use of an auxiliary oxy-fuel burner as a heat source. With each of these techniques there are technical and economic trade-offs.

Jan 1, 1990

By Robert G. Benson, David M. Jones

The San Luis deposit of Costilla County, Colorado contains 11,021,000 tonnes (12,149,000 tons) of ore at 1.4 g/t (0.040 oz/st) gold in two mineable zones. Gold mineralization is associated with silicification and quartz-sericite-pyrite alteration localized in breccias along a low-angle "detachment" fault zone in Precambrian gneiss. Gangue minerals include chlorite, specularite, chalcopyrite, molybdenite, and fluorite. Mineralization is mid-Tertiary in age and may have an indirect genetic relation to the emplacement of felsic intrusions. Portions of the ore body are unconformably overlain by sedimentary rocks of the Tertiary Santa Fe Formation. The deposit formed during the early stages of extensional tectonism along the eastern edge of the present day Rio Grande rift.

Jan 1, 1990

By J. F. T. Agapito

Significant economic benefits can result when rock mechanics is applied within a practical framework and integrated within the other engineering functions of the mine organization. This requires management support and understanding of rock mechanics as a practical tool to help attain high standards of safety, productivity and resource recovery. For such an approach, a long-term geotechnical program is needed in most operations to build an adequate data base and to ensure that design and ground control issues are handled in a cost-effective manner. This paper presents a summary of four case studies where significant economic benefits were realized with the help of rock mechanics. Although cost savings were not computed, the economic benefits are obvious and clearly impacted the mine operations favorably.

Jan 1, 1990

Provide a means to (1) rapidly disconnect a multifunctioning signal channel from a multichannel data collection system, (2) protect electronic devices from damage while causing the minimum amount of data collection disruption, and (3) operate electronic devices under gassy mine conditions. Background Data collection system instrumentation and cables are often located in hazardous areas of underground coal mines. As a result, frequent damage to the instrumentation cables occurs from roof falls, heavy equipment, and the relocation of air, water, and power lines. A similar problem exists in surface areas where cables and instrumentation can be damaged by animals and by vehicle traffic. Without a circuit-breaking feature, the damaged cables could cause instrumentation to be ruined, cause power supply failure, and otherwise disrupt data collection in some situations the lack of a circuit-breaking feature might cause an ignition in a methane atmosphere.

Jan 1, 1990

By Jr. Raleigh

In a cooperative agreement between the U.S. Bureau of Mines and the U.S. Department of Energy, laboratory column-flotation tests were conducted to evaluate fluorosurfactants as selective fine coal flotation collectors. A Middle Kittaning seam coal responded to flotation with both anionic and nonionic fluorosurfactants. These fluorosurfactants were no more selective than MIBC alone. However, for increasing coal yields, nonionic fluorosurfactant systems did not increase total sulfur and ash contents as sharply as MIBC systems. Flotation selectivity also improved slightly when a combined anionic fluorosurfactant-MIBC system was used in acidic pulps (pH < 3.6). While the fluorosurfactants examined will not likely have direct application in current coal flotation practice, other fluorosurfactant systems could eventually prove beneficial for floating fine coals.

Jan 1, 1990

By Halvorsen N

For mining medium-hard materials on the surface, "Continuous Surface Miners" have been employed for some years. The latest generation surface miner extends the performance of this type of machine to the point where the same cost efficiencies can now be achieved in medium-hard materials as has been achieved in softer materials by machines such as the bucket wheel excavator. The paper explains briefly the technology of the Krupp Surface Miner (recently released to the market) and develops the costs of ownership and typical operating costs. Comparisons are made between a shoveLtruck system and Krupp Surface Miner (KSM) systems based on both truck and conveyor transport systems. Further benefits of mining with the KSM, such as environmental, selective mining and improved product reovery are discussed briefly. The equipment is now available to mine semi-hard materials (with compressive strengths up to 60MPa) on a continuous basis and reap the benefits which continuous systems can deliver. All new and existing open cut mines should review their costs with regard to this technology.

Jan 1, 1990

By Thomas M. Gurtowski

This paper presents a summary of allowable bearing pressures and skin friction values that have been used to design drilled pier foundations for support of high-rise structures in downtown Seattle, Washington. These design parameters are based upon a review of geotechnical reports and records of more than 20 building projects. The following pages present a description of the soils encountered at these sites including foundation bearings soils, and design bearing and friction values. The accumulated data is summarized in Table 1, and the locations of the buildings are shown in Figure 1. A detailed description of the construction of two belled drilled piers are presented illustrating typical methods and procedures used in downtown Seattle. The two cases are from the Washington State Convention and Trade Center (WSC&TC). SEATTLE AREA SOILS The Puget Sound area was subjected to several major glaciations during the Pleistocene Epoch. Glacial ice originated in the cordilleran and coastal mountains and the Vancouver Range of British Columbia. The maximum southward advance of ice reached the area about halfway between Olympia and Centralia. As a result of these glaciations, the Puget Lowland was filled to significant depths by glacial and non-glacial sediments during the Pleistocene.

Jan 1, 1990

By P. J. Gron

"The Samatosum Project is a base and precious metal deposit located in south central British Columbia. A dilute ore reserve of 766, 682 tonnes grading an average 1.1% copper, 3.0% zinc, 1.4% lead, 833 gram per tonne silver and 1.6 gram per tonne gold is available. The base metals occur as tetrahedrite, chalcopyrite, sphalerite and galena. Virtually all of the silver and gold are associated with the tetrahedrite.The mill is operated at a rate of 21 tonnes per hour. Sulphur dioxide is used as a zinc depressant in the grinding circuit. Production of a Cu/Pb/Ag concentrate is accomplished by conventional flotation. This concentrate is then separated into Cu-Ag and Pb concentrates through a reverse flotation circuit utilizing sulphur dioxide, starch and sulphuric acid as lead depressants.The tailings from the Cu/Pb/Ag circuit are treated with copper sulphate to activate the zinc. Production of a zinc concentrate is accomplished by conventional flotation. Dewatering of the concentrates to 6% moisture is done with a LAROX filter press.Tailings effluent is treated with lime and sodium sulphide to precipitate out the heavy metals. The resulting sludge is treated in OYNASAND sand filtration units to produce a quality effluent."

Jan 1, 1990

By John A. Herbst, William T. Pate, A. Edward Oblad

Dynamic optimization is a cost-effective means to increase production or improve product quality in a plant. Several model-based approaches to dynamic optimization of mineral processing operations have been developed and implemented in plants. This paper reviews the phenomenological models that are the basis for dynamic optimization and the alternative methods of mathematical optimization. These methods range from theoretically complex and costly to implement to intuitively comprehensible and readily implemented.

Jan 1, 1990

By J. A. Barrera-Godinez

Traditional batch flotation tests produce a limited number of data points from which to evaluate the kinetics of the process. In this research, continuous weighing of froth, from a modified circular flotation cell, using a computer/data acquisition system., has been coupled with chemical analyses from intermittent froth sampling. This combination has permitted the experimental data to be smoothed such that the flotation kinetic parameters could be determined with enhanced confidence. To demonstrate the procedure, a galena ore was floated to permit flotation kinetics to be investigated as a function of cell parameters. It was shown that the kinetic data of this lead flotation most closely correlated with the Huber-Panu three parameter model. In addition the results illustrated the effect of froth thickness, froth scraper rate and air flow rate on the cell performance, in terms of mass flow, grade and recovery.

Jan 1, 1990

By H. J. Sohn, S. G. Doo

A systematic study was carried out to investigate the reduction reaction mechanism of oxygen on pyrite surface using electrochemical techniques. The polarization curves showed two distinct regions, the Tafel region for superoxide formation and limiting current region for diffusion of dissolved oxygen to form hydrogen peroxide. These results were confirmed with a-c impedance measurements.

Jan 1, 1990