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By Jukka S. Sulanto

Outokumpu has applied its well -known copper Fl ash Smelling Process also for smelting su1phide lead . concentrates. The lead in the Flash Smelting Furnace slag is recovered by reducing the oxygen potential of the slag in an electric furnace by injecting reductant into the slag bath. A series of tests have been carried out in a 1000 KVA electric furnace? adjacent to a pilot Flash Smelting Furnace. The furnace has been fed continuously with molten Flash Furnace Slag. The feed rate has varied from 0.5 to 3.1 MTPH (0.55 - 3..4 STPH) depending on the feed rate and the quality of concentrate to the Flash Smelting Furnace. The inlet slag contained 15 to 40% of lead and the cleaned slag 1. 5 to 3. 0%. The lead recovery from sol id raw material was tested in the same continuous process by feeding lead calcine into the furnace. Feed rate was 0.7 to 0.95 MTPH (0.8 - 1.05 STPH) and the calcine contained 33 to 34% of Pb. Several reduction agents and procedures were tested. The process proved to be suitable for continuous recovery of lead from solid oxide raw materials.

Jan 1, 1990

By L. M. Demers, D. C. Kuhn, N. El-Ayouby, C. F. Stanley

"Oxygenated metabolites of arachidonic acid (MJ are produced by the alveolar macrophage (AM) and have been shown to mediate inflammatory reactions. We therefore assessed the production of eicosanoids by AM harvested from the lungs of rats ex· posed to a bituminous coal dust for 2 wk in an inhalation chamber in order to determine if AA metabolism was altered in a manner that may promote an inflammatory response in the lung. Exposure to coal dust resulted in a 66% increase in the number of AM harvested, an increase in thromboxane A2 (TxA;i) and leukotriene 84 (LTB,j) production to 222% and 181% of control values, respectively, and a decrease in prostaglandin E2 (PGE:i) production to '62% of control values. In AM harvested from rats allowed to breath clean air for 2 wk following coal dust exposure, PGE2 production returned to control levels but TxA2 and LTB4 production remained elevated. The TxA2 synthesis inhibitor UK 38,485 reduced TxA2 production in dust-exposed AM both immediately and 2 wk following exposure. Thus, exposure of rats to coal dust significantly alters the metabolism of AA in AM, with potentially important aspects of AA metabolism remaining altered even after a 2-wk recovery period. Based on the established role of eicosanoids in inflammatory and fibrotic processes, these results suggest that the alteration of AM eicosanoid production as a result of the inhalation of coal mine dust may be an important factor in the pathophysiology of coal workers' pneumoconiosis.The authors are grateful to Joan Greenwood and Barbara Scheetz for their excellent technical assistance and to Brenda Pavone for the preparation of the manuscript. This research was supported by the U.S. Department of The Interior's Mineral Institute Program administered through the Generic Mineral Technology Center for Respirable Dust under grant 1135142.Request for reprints should be sent to Douglas C. Kuhn, Ph.D., Department of Pathology, The M.S. Hershey Medical Center, Hershey, PA 17033.INTRODUCTIONPulmonary alveolar macrophages (AM) are activated by foreign particles and microorganisms that enter the small airways (Kass et al., 1966; Herscowitz, 1985). This defensive reaction involves phagocytosis, lysosomal enzyme release, and the generation of reactive oxygen species by the AM (Snella, 1986; Rich et al., 1987). A number of agents, including phorbol esters, zymosan, adenosine diphosphate, organic hydroperoxides, and calcium ionophore, have been shown to activate the AM in vitro (Badger, 1986; Marshall and Lands, 1986; Snella, 1986). The AM response to these activators appears to be mediated in part by the oxygenated metabolites of arachidonic acid (AA) (Bertram et al., 1988; Demers et al., 1987; Mcleish et al., 1987).The AM may metabolize AA through cyclooxygenase- and lipoxygenase- catalyzed pathways to produce a variety of eicosanoids including prostaglandin (PG) E2, thromboxane (Tx) A2, leukotriene (LT) B4, LTC4, LTD4, and several hydroxyeicosatetraenoic acid derivatives (HETEs) (Willis, 1970; Camp et al., 1983; Poubelle et al., 1986). The production of these eicosanoids may enhance the. defensive ability of the challenged lung since they stimulate chemotactic cell recruitment to the site of invasion, enhance extravasation of circulating immune cells, and promote local vasodilatation. However, continued stimulation of the AM population, with the consequent production of proinflammatory eicosanoids, may ultimately enhance the disease process by contributing to chronic bronchoconstriction, fibrosis, and the persistent release of toxic oxygen species."

Jan 1, 1990

"Air Products approached LAC Minerals in 1987 to initiate trials with pure oxygen in the leach circuit at several LAC facilities in Canada. This paper gives an overview of oxygen use and covers specific operating data from the Doyon and Terrains Aurifères mills near Val D'Or in northwestern Quebec. LAC also uses oxygen at the Macassa mill in Kirkland Lake, Ontario.In addition to the LAC facilities, oxygen is currently in use for test purposes at the Holt McDermott mine in Kirkland Lake, Ontario and the Camflo mine near Val D'Or.There are two requirements for oxygen in the cyanide leach mill. Firstly, oxygen is required in the familiar gold dissolution reaction as follows:(1) 4 AU (s) + 8 NaCN (aq) + 02 (aq)+ 2H 20(aq) - 4NaAu(CN) 2(aq)+ 4Na OH(aq)Of the reagents on the left side of the equation, the availability of gold is fixed by the ore in question. Obviously, water is available in excess, 1eaving cyanide and oxygen as the limiting constituents in the process. Most mills operate with an excess of cyanide, which is fairly closely monitored. Dissolved oxygen levels, however, are not normally watched very closely and find their own level based on the temperature, the availability of compressed air and the ability of the ore to consume oxygen.Typical D.O. levels are in the 3-8 ppm range, however levels less than 1 ppm are not uncommon for refractory ores.With pure oxygen, dissolved oxygen levels as high as 30 ppm can be achieved. (Figure #1). This greatly accelerates the kinetics of the leach reaction and may also shift the reaction further towards completion thus increasing gold dissolution slightly."

Jan 1, 1990

By G. A. Kosick, G. S. Dobby

"This paper presents the principles and application of a recently developed control system for flotation columns and column circuits. The control system uses triple pressure sensors to directly sense zone densities and level, and to help in characterizing the operating behaviour of individual columns. A complete expert system development tool is incorporated within the system to provide the facility for full operator training, an on-line help facility, and a means for incorporating the column behavioural patterns into decision making rules. The system is configurable to any number of columns and can be run in either supervisory mode or direct control through Minnovex PIO software. Additional process signals can be interfaced with the system if desired. Operating experience with the control system on the Minnovex column flotation pilot plant is described.I: INTRODUCTIONColumn flotation cells have been more difficult to control and are more sensitive to circuit changes than conventional mechanical flotation cells. This susceptibility encouraged investigation into various types of control strategies ranging from inexpensive single pressure measurements for level control, to highly instrumented and expensive systems using a variety of control methods.Flotation operators, in many cases, do not understand the column control philosophy or have not been trained to deal with this new type of cell. Some operators have subsequently absolved themselves of the column operating responsibility. Some column cells, for example, have run for hours with slurry pouring over the top or no froth coming off at all.ColumnEX is a column flotation control system which was developed from the viewpoint of an operating shift foreman who wishes to:1. control the column or column circuit through a genuine understanding of what is happening inside the columns, and2. to share this knowledge with his flotation operators and be available to guide them through times of circuit upsets."

Jan 1, 1990

Ventilation 'is currently used in mines to sustain human life, prevent explosions, and provide a more healthful work place. Future automated-mining systems could use ventilation techniques quite. different from today's practices. The Bureau of Mines is anticipating various methodologies for ventilating the automated mining systems which are now beginning to emerge in the mining industry. This paper examines the special ventilation requirements for automated mining systems. Topics include requirements for automated systems, current studies with blowup ventilation tubing, and ventilation of two types of highwall -ripper type mining machines.

Jan 1, 1990

By Raj K. Rajamani, Ilesh M. Shah

Maintaining pH, a routine requirement in many industrial processes, is by no means trivial. The control is troublesome because of the inherent nonlinearity and frequently changing process dynamics. Many researchers in the past have investigated advanced on-line estimation and/or adaptive control techniques to overcome these difficulties. Most methods require the development of a complex mathematical model. The present work deals with the use of a simple and elegant method for pH control, based on the use of fuzzy logic. First, a standard fuzzy-logic controller is discussed, followed by a self-organizing controller. The latter algorithm generates a set of rules based on observation of the process. Thus it is a learning algorithm. The development and application of the algorithms to a laboratory acid-base neutralization experiment are presented. This elegant technique is powerful and deserves attention in mineral pro- cessing.

Jan 1, 1990

Fossil resin types occurring in the Hiawatha seam of the Wasatch Plateau coal field, Utah, have been separated according to color and their physical and chemical properties evaluated. These resin types were separated into four color fractions, yellow, amber, light brown, and dark brown. Each resin type has then been subjected to comprehensive spectroscopic examination and other physical methods of characterization. Included among the spectroscopic methods of characterization are FTIR and 13C NMR spectroscopy. Physical properties that have been measured include density, optical, and magnetic properties. These analyses reveal that the resins are distinct from other macerals, predominantly nonaromatic in nature with small amounts of oxygen functionalities and a low degree of unsaturation. The four resin types show distinct differences in certain physical and chemical properties such as density, hexane solubility, magnetic susceptibility, and aromaticity.

Jan 1, 1990

By D. Su

This paper presents the details and results of a preliminary investigation into the response of borehole pressure cells (BPCs) in soft coal. Two parallel approaches, laboratory calibration and nonlinear finite element simulation, were adopted for deter- mining the BPC K-factor, which was defined as the ratio of cell pressure change to the corresponding change in external pressure. Results from both the laboratory calibration and the nonlinear finite element simulation revealed a nonlinear response of cell internal fluid pressure to external loading. The K-fact& also is shown to increase with increasing setting pressure and decreasing medium modulus. -Depending on the setting pressure, the K-factor for coal having a Young's modulus of 1.6 x lo5 psi ranges from nearly 1.2 at 2,000 psi of external pressure to 1.485 at 8,400 psi of external pressure. The improved under- standing of BPC behavior leads to the more accurate calculation of BPC K-factor in coal which significantly improves the correlation between pillar pressures measured in underground coal mines and those predicted by nonlinear finite element simulations of these pillars.

Jan 1, 1990

Project cost control procedures and computer systems have enjoyed a successful and simple relationship over the past decade, thanks primarily to the proliferation of portable computers or PC's. Prior to the introduction of this technology, project control was largely a manual and somewhat onerous task of historical data compilations, with little time available for dynamic forecasting, staged planning, or pre-emptive cost control. Automated systems developed during this era were resident on "Heavy Iron" or mainframe computers and were expensive to maintain and operate. Use of these early systems was limited to large engineering, construction, and industrial concerns with the economies of scale and funding required for their successful application. Systems were either designed for critical path analysis or task scheduling, but rarely integrated with the other, much less cost control.

Jan 1, 1990

By Robert L. Akright

The Sumich (Victorine) gold mine is located in the Toiyabe Mountain Range on the east side of Victorine Canyon, a north-trending branch off Kingston Canyon in the northwest quarter of Section 27 and southwest quarter of Section 22, T16N, R43E, in the southern end of Lander County, Nevada (Fig. 1). HISTORY Discovered in 1862, the Victorine reached a peak of development between 1872 and 1887. The "Victorine" and "Morning Star" lode mining claims, located on the outcrop of a prominent auriferous quartz vein, were patented in 1869 and 1891, respectively. 1, respectively. Gold ore was mined underground in adits driven, on the level, directly into the side of the mountain. Ore brought to the surface was trammed about 457 m (1500 ft) south on a track constructed along the contour to ore bins. From this transfer point, the ore was moved by aerial tram to the bottom of the canyon then hauled by horse-drawn wagon to the mill located about 3.2 km (2 miles) east down Kingston Canyon. Exact details of the milling process used on the Victorine are lacking, but old reports mention water-driven stamp mills, amalgamation, chlorination, and cyanidation. Gold and silver mill products are reported to have been sent to England for final refining. High-grade gold values of 103 g/t (3 oz per ton) remaining in mine walls and on outcrops, attest to the lack of success in treating the Victorine ore in the early mills. The Victorine mine may have been worked sporadically after 1887 with little success. In 1934, control of the property was acquired by William P. Moloney, an attorney from Marion, OH, who also control- 1 led an interest in the successful Goldacres mine in Lander County, NV. This property was studied, sampled, and metallurgical tests were done in 1934, but no development resulted from this work.

Jan 1, 1990

By F. J. Susko

The U.S. Bureau of Mines is using Fourier-transform infrared (FT-IR) analysis to investigate the bonding mechanism which occurs during the dewatering of clay slurries. High molecular weight polymers are used as flocculating agents in these processes. This investigation presents the results of an FT-IR study of calcium-exchanged montmorillonite treated with polyacrylamide (PAM) and polyethylene oxide (PEO). Both thin film and attenuated total reflectance (ATR) spectroscopic techniques were employed to study this clay-polymer system~ Results suggest PAM is adsorbed to the clay via the nitrogen atom of the polymer. A water bridge is involved in the bonding between the clay and PE~. Evidence also suggests that PEO may be adsorbed directly onto the surface of the clay.

Jan 1, 1990

By Corbett G, Iwai N

The Japanese gold mining industry has a long and productive history and is presently undergoing a period of revitalisation encouraged by the Hishikari discovery. Deposits exhibiting the characteristics of epithermal mineralisation are very widely distributed throughout the island chain and an encouraging number of these are large, seven containing gold in excess of one million ounces. All the important deposits are quartz vein type and contain extremely high grade, or "bonanza". Zones.

Jan 1, 1990

By L. Lui, A. Cauchon, A. R. Laplante

"The gravity circuit at Les Mines Camchib Inc. consists of two pinched sluices to bleed a feed to one of two 76 cm (30"") Knelson concentrator. The Knelson concentrate is upgraded to smeltable grade with a smaller Knelson (18/30 cm) and a riffleless table. Their tails are column cyanided and washed prior to recycle to the grinding circuit. This paper details size-by-size circuit performance. The Knelsons recover around 90% of free gold (as determined by Mozley Laboratory Separator), even below 37 µm. The sluices are ineffective, with upgrading ratios around 2, but approaching unity in the fine sizes. Much of the effectiveness of the circuit lies in the high gold circulating loads in the grinding circuit, which partly atone for the poor sluice performance, and the ability of the Knelsons to recover free gold. Secondary upgrading recovers slightly above 99% of the primary concentrate gold, 90% of it in a 65% Au concentrate and the balance in a heavily loaded (10 to 20 oz/st) pregnant solution. INTRODUCTIONBackgroundThe operating performance of the mill of Les Mines Camchib Inc. has been described earlier (Laplante et al., 1989). The presence of significant chalcopyrite (1 % and up) makes flotation necessary prior to cyanidation, to limit cyanide consumption and minimize environmental impact. In 1982, the presence of very high gold circulating loads in the grinding circuit lead to the commissioning of a gravity circuit, schematically shown in Figure 1. Gravity recovery of gold has been found beneficial because it increases metallurgical recovery by 1-3% (Laplante et al, 1987), as only part of the flotation tail is cyanided, and economic recovery, because of the lower net smelter return of gold in the flotation concentrate (as compared with the gravity concentrate). The latter increase is estimated, with a net smelter return of 95%, at 1.5% when gold recovery by gravity is equal to 30%. In early 1988, a sampling program was initiated to characterize the behaviour of gold in the grinding/gravity circuit. This paper reports on the results of this study."

Jan 1, 1990

By G. J. Simandl, H. -L. Jacob, S. Paradis, G. Valiquette

"Nos travaux de terrain dans le Grenville, effectués dans le cadre d'un projet d'inventaire des gîtes de wollastonite, ont démontré qu'il existe un secteur exceptionnellement favorable à l’exploration pour la wollastonite. Ce secteur s'étend de la municipalité de Grenville jusqu'au pare du Mont-Tremblant (nord de St-Jovite). D'autres secteurs favorables a 'exploration pour la wollastonite ont été délimités dans les regions du Lac-Saint-Jean, de Shawinigan et de la Gatineau. Neuf categories litho-structurales de gites de wollastonite furent identifiées. L'importance d'un système ou vert pour la formation des gîtes de hautes teneurs fut établie. Un guide de prospection pour la wollastonite propre à la province tectonique de Grenville fut développé. Plusieurs des indices sont prometteurs et mériteraient des travaux de raise en valeur afin de determiner s'ils représentent une source de wollastonite exploitable à profit. Lac-Saint-Jean, Shawinigan and Gatineau areas. Deposits may be classified into nine categories depending on their relationship to intrusive rocks, discordant or concordant contacts with the host rocks, morphology, and major structural controls. Deposits consist mainly of wollastonite, calcite and clinopyroxene. They may contain one or several of the following minerals: feldspar, scapolite, quartz, titanite sulphides, zoisite, clinozoisite, garnet, idocrase and prehnite. Wollastonite content may reach over 70%. Some deposits are associated with graphite veins. Better understanding of the geology, combined with the proposed classification provides new exploration guide for wollastonite. Several deposits have grades of economic interest. Further work is needed to determine if any of these deposits can be exploited for profit."

Jan 1, 1990

By M. Jennings

In 1987, Echo Bay discovered a major silver/gold ore body at their McCoy property in Nevada, and quickly made a decision to build a 5000 tpd mill which was expanded during the design to 7500 tpd. Since the ore reserves consisted of cyanide leachable oxide as well as sulfide, the plant flow sheet involved an oxide leach, a gravity circuit, and lead sulfide and a pyrite sulfide recovery by flotation. The paper describes the process development, equipment selection, plant design and the startup of the oxide treatment.

Jan 1, 1990

By W. S. Fyfe

The future environment of our planet, with the concept of sustainable development, has moved to centre stage of all future plans for development. This global view is new. It presents great opportunities and challenges for the Earth Sciences. We have the tools to describe our environment on all scales - planetary to molecular levels. We must respond to this great demand by world society.

Jan 1, 1990

By Welby G. Courtney

This publication reviews recent U.S. Bureau of Mines studies of frictional ignition of a methane-air environment by coal mining bits cutting into sandstone and the effectiveness of remedial techniques to reduce the likelihood of frictional ignition. Frictional ignition with a mining bit always involves a worn bit having a wear flat on the tip of the bit. The worn bit forms hot spots on the surface of the sandstone because of frictional abrasion. The hot spots then can ignite the methane-air environment. A small wear flat forms a small hot spot, which does not give ignition, while a large wear flat forms a large hot spot, which gives ignition. The likelihood of frictional ignition can be somewhat reduced by using a mushroom-shaped tungsten-carbide bit tip on the mining bit and by increasing the bit clearance angle; it can be significantly reduced by using a water spray nozzle in back of each bit, which is carefully oriented to direct the water spray onto the sandstone surface directly behind the bit and thereby cool the hot spots formed by the worn bit. A bit replacement schedule must be used to avoid the formation of a dangerously worn bit.

Jan 1, 1990

By J. D. McKay

Flotation columns have been readily accepted for use in most sulfide flotation plants; however, recently columns are being used in many other areas. Recent improvements in design methodologies have overcome many operating problems and led to improvements in metallurgy. In addition, physical improvements in column design have simplified their operation while leading to better control. The Turbo-Air External Bubble Generator has provided a method for bubble size control and variation in air holdup and carrying capacity. These have enabled commercial operations to improve grades and recoveries by optimizing performance.

Jan 1, 1990

By Stewart Gillies A D, Just G. D

An internationally recognised and uniform method for classification, categorisation and designation of mineral and energy resources is not yet available. With the increasing need for reliable and comparable coal resource data it is necessary to standardise the traditional classification procedures by quantifying the three basic evaluation criteria of economic feasibility, geologic assurance and recovery. For well documented deposits, geostatistical methods can considerably improve classification quality. A review is undertaken of major classification with particular emphasis on those that incorporate limits on estimation error.A geostatistically based algorithm for classifying coal resources within the current Queensland and New South Wales codes has been developed.Application of the classification algorithm for resources from a number of seams exhibiting different structural characteristics is assessed. The method is found to give classification results that closely reflect the error associated with an estimate of resource quantities based on current sampling densities.lbis requires a careful geostatistical analysis with an emphasis on geological awareness. Resource category restrictions although albitrarily assigned should remain constant for all deposits being compared. This requires some engineering judgement with additional interpretation also required for isolated and peripheral block.

Jan 1, 1990

By L. Lichty, R Bhappu, R. Rowan, G. Ramadorai

Treatment of refractory gold ores containing arsenic have always presented a major problem in their processing to recover the contained precious metal values. The major difficulties are concerned with lower recoveries, production of hazardous fumes, effluents and residues. Because of'these arsenic related problems, many otherwise economically attractive precious metal deposits and dumps all over the world are not exploited. In recent years, treatment processee for refractory gold ores and concentrates have been explored and a few commercial operations employing roasting or pressure leaching have resulted. Roasting has limitations due to environmental constraints related to off gases. Pressure leaching involving high temperatures (180% to 200%) and pressures (400 psi) is accompanied by high capital and operating costs. An alternate route to roasting for treating pyrite and arsenopyrite ores and concentrates ia the "lime-oxygen hydromet" process carried out at a moderate temperature (100%) and pressure (100 psi). A simplified process for treating such arsenic containing ores and concentrates utilizing low temperature and pressure oxidation is presented. This low cost treatment with compressed air and lime renders arsenic as an inert component in the residue, meeting all the requirements of the EPA Toxicity Test. The precious metal values are then extracted from the autoclaved residue by standard cyanidation. This paper discusses this new development.

Jan 1, 1990