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By Biao Q, Mizuta Y

Thermal constants such as thermal con- ductivity and thermal diffusivity of rock and coefficient of heat transfer of airway wall are the most important characteristic values which decide accuracy of prediction calcula- tion. However, quality of rock is not homoge- neous and water content in rock varies with location and so, a method for in-situ measure- ment of thermal constants must be taken in. The method developed by us is to measure in- situ rock temperatures at two different depths from airway wall. It is simple and we found its accuracy is good enough in the engineering Sense.

Jan 1, 1988

By R. Llerena, P. Dunstan, R. L. Amelunxen

A single four feet diameter cell, treating a Cu/Mo rougher concentrate, has been fully instrumented and linked to a Distributed Control System. This has enabled the writers to further understand the mechanics of operation of the cell, particularly that of the "TRANSITION ZONE". This is the volume between the feed port and the pulp-froth inter- face. The results have shown a need for the re-designing the control loops whereby the Transition Zone volume (or pulp level ) becomes the single most important control parameter to achieve the de- sired recovery. Air consumption, previously thought to have played this role, is now kept at precoalescence level s for maximum efficiency.

Jan 1, 1988

By Malcolm D. Flavel

Recent research into the mechanisms of crushing processes has led to the establishment of new criteria for the effective design and operation of comminution plants. This paper reviews this work and gives examples of the productivity gains and cost benefits that have been achieved in the practical application of these findings.

Jan 1, 1988

By G. Haesebroek

In L969 Metallurgie Hoboken-Overpelt started an industrial plant for the separation of iron and zinc from a concentrated CoCL2 solution. Iron and zinc are extracted in column contactors by a solvent containing 12 vol % of tertiary amines in xylene. The extracted metals are stripped from the pregnant organic phase by precipitation with a NaOH solution at pH LL. In this paper an overview is given of the industrial process. In order to overcome some drawbacks of this process (low flash point of the diluent, reagent consumption, batchwise stripping) an alternative solvent extraction process has been examined. In this alternative process, iron and zinc are extracted with an or¬ganic phase containing 50 vol % of TBP in Escaid 110. The pregnant solvent is stripped with water in conventional mixer settlers. Despite the ability of this process to overcome most of the inconveniences due to the use of tertiary amines, it suffers from the poor stability of TBP in concentrated chloride solutions, resulting in unavoidable and inacceptable precipitation phenomena in the stripping section.

Jan 1, 1988

By N. C. Gay

The quantitative evaluation of the performance of fill materials placed in gold mine stopes is achieved by (i) measurement of the in-situ load- displacement, or stress-strain, characteristics of the materials; (ii) an objective comparison between the observed fill performance and that predicted from suitable computer modelling techniques; and (iii) objectively comparing conditions in backfilled and conventional stopes. Considerable problems have been experienced with the development of sufficiently robust instrumentation which can be installed within filled pad- docks and give reliable information over a long period of time. However, at most mines where backfill performance is being monitored, it has been possible to correlate stress measurements within the filled paddocks with strain measurements adjacent to the paddocks. The resultant stress-strain curves agree relatively well with those determined in the laboratory. Measurements in the hangingwall strata of filled and unfilled stopes indicate that the placement of fill does reduce the amount of inelastic convergence due to bed separation. Moreover, in some stopes, the rate of convergence with respect to face advance does reduce to that of the theoretical elastic convergence. Quantification of changes in the conditions at the stope face due to placement of fill has proved difficult. Observations indicate that, provided the fill is placed close to the face (- 5 m), and adequate temporary face support is used, conditions in filled panels are superior. In addition, in filled panels the damage caused by a rockburst in the stope and, particularly, in gullies is generally much less than would be expected in an unfilled stope. To quantify these improvements, parameters such as stope height, face advance and the frequency of falls of ground are being monitored.

Jan 1, 1988

By S. B. Gaidhani, V. A. Mandlekar, R. L. Sonolikar

Column flotation technique is applied for the depression of the magnetic material by the application of an axial magnetic field from chalcopyrite ore. It is observed that an increase in the intensity of magnetic field from 0 to 316.8 oersteds decreased the magnetic content in the froth from 25 to 2 %. . This might be due to retention of magnetic material in the magnetizable zone and the diffusion of nonmagnetics through it. The effect of air velocity increased the magnetic content in the froth and total froth content also. At low gas velocity the tiny bubbles are formed whereas at high gas velocity these coalesce into big bubbles and slugs formed breaks the magnetizable zone. This study opens a new field called 'Magneto-flotation'.

Jan 1, 1988

By T. Fujita

The removal of phosphorus is essential 1n order to increase the recycling of steelmaking slags for their manganese, iron and lime contents. This study aims at establishing the phosphorus mineralogy and its distribution in steelmaking slags, the effect of slow cooling, and the methods of phosphorus removal. A series of steelmaking slag samples was prepared at different cooling rates, and the mineralogy, chemistry and grain size of the samples were investigated with SEM/EDS and x-ray diffraction. The test results using high gradient magnetic separation are discussed.

Jan 1, 1988

By D. C. White

The Vulture Mine near Wickenburg, Arizona was a major gold producer from 1863 to 1942, having yielded about 11,000 kg Au and 8,000 kg Ag. Gold occurs as coarse native metal and electrum in quartz veins and also finely disseminated within a quartz monzonite sill and its silicified wall rock. The sill is semi-conformable within a Proterozoic volcaniclastic-dominated sequence all dipping north about 35°. Early mining focused on the vein-hosted gold particularly in the immediate hanging wall and footwall of the sill. Later efforts included some open-pitting of the outcropping sill and adjacent altered and mineralized rock. Two sets of post-mineral faults have complicated the orebody geometry.

Jan 1, 1988

By T. G. Carter

"During the early part of the 1980s, four new surface coal mines commenced operation in the Province of British Columbia. Each represented a major investment in both persons and materials in order to protect this investment in one significant area-the fixed portion of the surface coal handling system-a substantial amount of work was undertaken to ensure that the system was well protected from an outbreak of fire. A great deal of effort in this field had already been made by those coal mines which had been in operation for a number of years and experience gained at these operations was utilized in determining the level and extent of fire protection for the new mines.This paper summarizes the major problems, and suggests some of the methods of solution, in providing an adequate degree of fire protection for surface coal handling systems. It will also discuss the potential for gas and dust explosions together with ways to minimize this potential.The Fixed Coal Handling SystemNote: The word ""fixed"" has been used in its present context to denote that part of the coal handling system where the coal is moved via fixed installations such as a conveyor. It differentiates from that part of the system where coal is moved by mobile equipment.The raw coal delivered to the truck dump will undergo two major processes on its way to the rail load out. The first will be at the coal preparation plant where coal of specified quality will be extracted from the raw feed to the plant. If this coal is of metallurgical quality, and sometimes if it is of thermal quality, it will pass through a thermal dryer where part of the moisture acquired during coal preparation will be removed, i.e. the second process. As the complexity of both the coal preparation plant and the thermal dryer is such as to warrant separate considerations they will not form part of this paper. Each of the processes, however, is generally, housed in its own building, thus, containment of any hazards is usually more attainable than those existing or caused in the rest of the system."

Jan 1, 1988

By Doris M. Hyde

The 350,000-barrel-per-day Bahamas Oil Refining Co remained closed throughout 1986. Financially troubled Charter Oil Co., joint owner of the refinery with Chevron Oil Bahamas Ltd., agreed in principle to have Chevron assume full ownership in return for canceling debts owed Chevron. Finalization of the agreement was pending at yearend. Burmah Oil Ltd. took more than a $30 million loss on the sale of its interest in South Riding Point Grand Bahama Transshipment Terminal to South Riding Point Terminal Holding Ltd.

Jan 1, 1988

By J. W. Smith, J. Van Dusen, A. Papachristodoulou

"As part of a study to evaluate factors affecting tankroom air quality, the mechanism of aerosol generation from bursting bubbles in electrowinning operations has been investigated. Typically 2 to 3 mg/m2.s are produced in zinc tankrooms. Analysis shows that the rate of production of film drops (geometric mean diameter - 2 urn] increases with decreasing bubble size, and that jet droplets (geometric mean diameter - 20 um) are not produced with gas bubble larger than - 4 mm. Both mechanisms of drop formation and current efficiency are affected by surface active agents, with an over-all reduction in emission of up to 60% to 70% being achievable. A source control system which does not adversely affect electrolyte properties is always preferred, and coalescence of all gas bubbles in to a continuous stream of gas at a single point on the electrolyte surface would eliminate aerosol emissions. This objective was the basis for design of a coalescence device which, in laboratory tests, reduced the emission rate by over 95%.The control device fit s over the electrodes in the electrowinning cell and is partially immersed in the electrolyte. A number of changes in the design which resulted in significant improvement in the performance of the device are reported.Field tests have shown that only about 75% of the aerosol below 10 um can be eliminated by coalescence. The remainder (up to 95% of the total) is controlled by coalescence of droplets, by impaction on the exposed collector surface and gravitational settling.The device does not interfere with operation of the tankroom, handles the effect of surges in power during harvesting, and is simple and inexpensive to maintain. IntroductionDuring the electrowinning of metals (such as zinc and copper) gases are evolved along the electrode surface forming small bubbles. The bubbles travel upwards and burst on the electrolyte free surface generating, in this way, small droplets. Because the electrolyte is often highly acidic or contains toxic materials, the whole process can result in the formation of an aerosol in the atmosphere above the electrowinning cells which poses a serious health hazard to workers in the area, and corrodes equipment."

Jan 1, 1988

By Diane M. Doyle-Coombs

In late July 1985, air samples from a sealed portion of the Quinland coal mine in West Virginia showed the presence of carbon monoxide (CO). Mine Safety and Health Administration (MSHA) personnel concluded that a fire was burning behind the seals. Since an imminent danger existed, the mine operator was given a closure order. The gases behind the seals were monitored and almost 2 million ff of carbon dioxide (C02) gas was pumped into the sealed area to stabilize the environment. Sixteen days after the closure order was issued, MSHA allowed the mine to return to production. Approximately 1 yr later, mine management submitted a seal breaching request to MSHA in order to drive a set of entries to further develop the mine. The Bureau of Mines established a sampling strategy and monitored gases from behind the sealed area during the breaching operation until the atmosphere was safe. This report is an account of the seal breaching conducted by the mine, MSHA, and the Bureau. The logistics of this event, the sampling strategy, and the equations applied could be used by the mining industry in future breachings or mine recovery operations. Time to reenter the area was calculated by using the methane (CH4) concentrations sampled at the discharge of the seals. Tracer gas was used to verify the ventilation flows through the area.

Jan 1, 1988

By Barry Welch, Kai Grjotheim

"The capital intensive nature of the present process for aluminium smelting, the low productivity per unit reactor, and pressure to reduce the electdcal energy demand have motivated the search for an alternative process. Optional routes include carbo-thennal reduction of alumina (using an alloy phase immediate), chlorination followed by electrolysis of aluminium chloride, and electrolytic decomposition of alumina using inert electrodes. Materials performance and reactor design constraints have been a major limitation for alternatives. However parallel research has led to considerable advances in the process efficiencies and scale of both the Bayer process and the Hall-Heroult cells.Future development of alternatives is dependent on breakthroughs in Materials Science such as the development of stable conducting anodes and stable wettable cathode materials. However if successful it is probable that some spin-offs will be retrofitted to existing cells. Therefore the basic Hall-Heroult technology will continue as the dominant process for at least the next half century.IntroductionThe present Bayer/Hall-Heroult process for production of aluminium is just over 100 years old. Frequently, during the century of its technological development questions have been raised as to whether it is the ideal route for metal production. The questioning was particularly intense in the period between the mid-1950s and the mid-1060s when the limitations of the Hall-Heroult electrolytic stage were evident. Then the cells were only 30 to 35 % efficient with respect to the utilisation of the hydro-electricity (requiring 16 18 kWh/kg, thus making it strongly dependent on cheap electrical energy), while the size of cells being installed were 80 to 130 kA. Hence the process was capital intensive, the productivity per reactor volume low, and the process was labour intensive (requiring about 15 man hours per tonne of aluminium). In addition, the use of pitches for Soderberg anodes and the fluoride electrolyte were creating problems through emission. At that time material science had paid little attention to the manufacture and use of carbonaceous materials or the development of alternatives that were corrosion resistant to cryolite or liquid aluminium. Hence cell lives were short - typically 600 to 1000 days - thus adding to operating costs. Thus the grass over the fence, as foreseen in 1960s vintage crystal balls appeared much greener for alternative processes."

Jan 1, 1988

By Guenter F. Lehmann

This report summarizes the results of the development and testing of a prototype monorail suspended bridge conveyor (MBC) system as a method of continuous haulage In underground mining applications. Included are the results of full scale, surface and underground testing of the complete MBC system. Conclusions drawn from these results, together with recommended modifications, supports the viability of the MBC system.

Jan 1, 1988

By N. S. Dalal, X. Shi, V. Vallyathan

"INTRODUCTIONThis paper summarizes our recent investigations of the potential role of silicon-oxygen based free radical species in the biochemical mechanism of the lung injury caused by the inhalation of freshly fractured silica. The impetus for this study came from the following observations. Inhalation of crystalline silica is associated with the development of acute and chronic silicosis. Chronic silicosis is characterized by the development of sharply marked concentric fibrotic nodules in the lung. This occurs over a period of several decades with the development of progressive respiratory impairment. In contrast, acute silicosis is manifested by the filling of the alveoli with an amorphous lipoproteinaceous exudate within a short period after exposure, and rapid development of respiratory disability often leading to fatality. Most studies on the pathogenesis of silicosis have focused on the elucidation of cellular mechanisms of cell injury and the development of chronic silicosis. Because pulmonary responses to crystalline silica are distinctly different for · the acute and chronic silicosis, we hypothesized that the acute response is associated with some unique properties of ·freshly formed silica particle surfaces, due to the formation of some reactive chemical species caused by the rupturing or the silicon-oxygen bonds. In occupations involving drilling, tunneling and sandblasting operations acute silicosis can be correlated with this unique surface reactivity of silica. The formation or reactive species was demonstrated, using electron spin resonance (ESR) spectroscopy (Dalal et al., 1986; Fuibini et al., 1987; Hochstrasser and Antononi, 1972). Grinding of quartz crystals under ultra high vacuum (10-10 torr) leads to the formation of Si- and SiO• radicals and these radicals are quenched by exposure to air and other gases (Hochstrasser and Antonini, 1972). ESR signals have also been reported from micronized quartz samples that were evacuated at 413 K (Bolls et al., 1983). In order to find a more direct relationship of such radicals to acute silicosis, we made ESR measurements on quartz dusts freshly ground in ambient air and found- that indeed grinding under ambient environment leads to the formation of the Si• and SiO• type of radicals which decay on storing the dusts in air or in biological buffers (Dalai et al., 1986; Vallyathan et al., 1988). The Si• and SiO radical formation on grinding has also been reported by Fubini et al. (1987). In addition, we recently found that •OH radicals are generated in aqueous suspensions of freshly ground quartz (Dalai et al., 1988; Shi et al., 1988; Vallyathan et al., 1988). We have subsequently carried out detailed cytotoxicity and biological assays on freshly made as well as aged quartz dusts. As summarized below, the results provide new insight into the biochemical mechanism of acute silicosis."

Jan 1, 1988

By A. McCracken

Probabilistic methods for assessing the reliability of engineering systems in mining are the way of the future. So agreed the delegates of a recent short course on the subject, entitled 'Reliability-based Approach in Mining engineering Design'. This was a very successful five-day technical course sponsored by The South African Institute of Mining and Metallurgy and held at Mintek from 7th to 11th March, 1988. The main lecturer for the course was Milton E. Har, Professor of Geotechnical Engineering at the School for Civil Engineering of Purdue University, Indiana, USA. Professor Har was ably assisted by Dr Dirk van Zyl, a former student. Science quiz Teams of pupils from 37 schools within a radius of 12 kilometres of the Council for Mineral Technology (Mintek) competed in a science quiz held by Mintek at its headquarters in Randburg on Tuesday, June 7th, 1988.

Jan 1, 1988

By M. K. Matthews

The use of backfill has important environmental control implications which, although frequently overlooked, can be both beneficial and problematical. Where backfill is widely used, the reduction in stope heat load and improved air utilization influence the overall mine ventilation and refrigeration requirements significantly. A programme of work examining in detail all the environmental consequences of backfilling is currently underway at the Environmental Engineering Laboratory of the Research Organization of the Chamber of Mines. This paper gives an overview of the work and presents some findings. In so doing, the environmental implications to be considered when backfilling are highlighted.

Jan 1, 1988

By G. L. Hundley

The Bureau of Mines has devised a procedure to recover chromium chemicals from concentrates derived from low-grade domestic chromites. These domestic chromites contain silicon and aluminum impurities at levels that are too high to permit processing by present industrial processes. The Bureau procedure consists of reacting chromite with molten NaOH under oxidizing conditions to form sodium chromate (Na2Cr04)' The reaction product is leached with methanol to recover the majority of the unreacted NaOH, then with water to extract the Na2Cr04 and the remainder of the NaOH. The Na2Cr04 product is recovered by evaporative crystallization from the aqueous solution. This report presents laboratory results of studies to determine the optimum leaching conditions for the reaction products of several domestic chromite concentrates. Results of solution purification and crystallization studies are also presented. The concentrates are from a variety of sources including the Stillwater Complex in Montana, Red Bluff Bay and the Kenai Peninsula in Alaska, and a Ni-Co laterite from southern Oregon. Sodium chromate crystals were produced that contained less than 0.01 pct NaOH.

Jan 1, 1988

By E. C. Baker

The capital investment and operating costs of two methane-control systems used during longwall mining operations are compared in this Bureau of Mines report. Costs are given for a surface gob hole drainage system and an underground cross-measure borehole drainage system to control methane gas in gobs in four coal mining areas--central Pennsylvania, northern West Virginia, southern Virginia, and northern Alabama. Present-worth analysis is used to determine the more cost-effective alternative in each location. The alternatives have equal lives and provide the same service based on a minimum rate of return of 15 pet. In central Pennsylvania and northern West Virginia, the gob hole system is more cost effective than the cross-measure system, by 10 and 18 pet, respectively. In southern Virginia and northern Alabama, the cross-measure system is more cost effective, by 29 and 38 pet., respecitively. Costs for other locations must be developed on a case-by-case basis.

Jan 1, 1988

By S. D. Thompson, L. Adler

This study reviews and analyzes the empirical methods available for designing the capacities of coal mine gathering belts. The analyses lead to recommendations concerning the application and implementation of each empirical method. Operations research techniques, mainly simulation models, are also briefly mentioned, and a few recommendations are made concerning their selection and application. The objective of the study is to provide a reliable basis for the practicing engineer to properly select, apply, and implement a capacity design method.

Jan 1, 1988