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By Joseph F. Shirley

Introduction Inorganic depressants are chemicals added to the froth flotation process to maintain or produce hydrophylic surfaces on one or more minerals so they will remain in the pulp rather than attach to the air bubbles. Whether a depressant will be effective in depressing a given mineral depends on how it is used and the environment in which it is used. Some depressants must be added and conditioned into the pulp before the collector is added. Other depressants can be added in the presence of previously added collectors and effectively depress the desired minerals. Often the concentration of depressant relative to the collector concentration is critical to making an economic separation. It should be noted that some depressants will only work when specific collectors have been used. Some reagents such as sulfuric acid and hydrogen peroxide essentially act as depressants by altering the previously added collectors so that they are no longer effective. Some depressants such as sodium ferrocyanide are only effective in a very limited pH range and an essentially collector free environment. Major Depressants CaO Milk of Lime is by far the most used depressant both in tonnage and dollar value. Although it is most commonly listed as a pH modifier, it is also an important depressant for pyrite in copper and copper molybdenite flotation plants. Although a simple pH adjustment will often depress pyrite, there are times when grinding with fresh milk of lime is required to obtain optimum depression. Lime is also a molybdenite and gold depressant. NaSH Sodium hydrosulfide is by far the most commonly used reagent to depress copper and iron sulfide minerals in by-product molybdenite flotation plants. NaSH also depresses gold, silver sulfides and silver chloride. ZnSO4 Zinc sulfate is commonly used to depress sphalerite in lead-zinc and copper-lead- zinc flotation plants. It has also been used to effectively depress talc in by-product molybdenite circuits at a pH of 6.5.

Jan 1, 1986

By S. C. Sethi

The WIPP (Waste Isolation Pilot Plant) Project near Carlsbad, New Mexico, is a research and development project sponsored by U.S. Department of Energy, designed to demonstrate the safe containment for disposal of radioactive waste. A mine (repository) is currently being developed 2150 feet below the surface, in a thick salt bed which will serve as the disposal medium. Provision of a proper ventilation system at the WIPP Project is a major priority of those responsible for its design, management, and operations. As an ongoing effort towards this goal, it was decided to simulate the mine's ventilation system using Dravo's MINEVENT computer program. Specifically, the work included the development of the following simulation models: 1. Simulation of the current ventilation system 2. Simulation of the designed ventilation system for the following modes: o Mine Construction mode/shift o Waste storage mode/shift o Fire or exhaust filtration mode These computer models are useful in solving complex ventilation problems likely to be encountered in an R&D project, like WIPP. They are particularly helpful for the development of contingency plans to incorporate during emergency situations, such as fires, fan stop- pages, radiation leaks, etc. Also, they can be utilized when considering expanding certain underground areas to ensure the availability of adequate ventilation.

Jan 1, 1986

By Andrew M. Leszcykowski

In 1984, personnel from the U.S. Bureau of Mines examined 41,550 acres of the North Fork Owyhee River Wilderness Study Area for mineral resources. This study area, in southwestern Idaho, is underlain by tuffs and basalt of Tertiary age. There are no known mines, claims, or prospects in or near the area. The northeast and southwest corners of the area are covered by oil and gas leases or lease applications, but no known exploration has been conducted. On Nickel Creek and Pleasant Valley Tables, in the southern part of the area, thin flows of vesicular, moss-covered basalt occur that are suitable for use as decorative building stone. The stone available for exploitation crops out over several square miles. However, more suitable material, outside the study area, is closer to potential markets.

Jan 1, 1986

By Richard D. Lang

Introduction Argyle is located in the Kimberley region in northwest Australia (Fig. 1). It is a significant diamond discovery by world standards and is the first major diamond find in Australia. The deposit consists of a pipe and associated alluvial deposits. Before the 1970s, diamonds were known to exist only sporadically in Australia. They have been found occasionally in association with gold deposits in Western Australia. There is a small deposit near Copeton in New South Wales. Some alluvial occurrences have also been found in Victoria, South Australia, and New South Wales. The first indicator minerals in the Kimberley region of Western Australia were discovered in January 1973. Production from the alluvial deposits at Argyle began in 1983. A $430-million construction program to develop a mine and treatment plant capable of producing 25 million carats per year was completed in December (1 carat = 0.2 grams). Ownership and management Participants in the project are known as the Argyle Diamond Mines Joint Venture. The group consists of CRA Ltd., 56.8%; Ashton Mining Ltd., 38.2%; and the Western Australian Diamond Trust (formerly Northern Mining Corp.), 5%. The project is managed by Argyle Diamond Mines Pty. Ltd., a wholly-owned subsidiary of CRA. Marketing is undertaken separately by the Western Australian Diamond Trust and by Argyle Diamond Sales Ltd. (for CRA and Ashton Mining groups). History Ownership of the Exploration Joint Venture has changed over the last 12 years as various parties changed their shareholdings. The original Kalumburu Joint Venture was formed in 1972 with five participants, each holding a 20% interest. By 1983, a number of ownership changes had occurred. The end result is that two original participants have sold out. CRA now holds a 56.8% share and the Ashton Mining Group holds 38.2%. CRA also assumed project management in January 1977. Table 1 demonstrates the long lead times involved in developing a project.

Jan 1, 1986

By W. W. Roepke, B. D. Hanson

A major problem facing the coal mining industry today is the need to meet more stringent dust standards due to quartz. When secondary suppress ion is not adequate, the time-consuming and costly cut-and-try method of modifying the mining machine is used in the hope that it will reduce dust generation. The Coal Cutting Technology Group, at the Bureau of Mines' Twin Cities Research Center, has developed an inter-active computer program for drum- type cutting systems to help identify, in advance, modifications that offer the best potential for reducing dust. The program, Relative Dustiness Indicator (REDI), evaluates machine dimensions, seam characteristics, and operator-controllable variables for dust generaton, energy, forces, and product ion.

Jan 1, 1986

In 1985 BMR assessed Australia's economic demonstrated resources of mineral sands as follows: rutile 8.0 Mt, ilmenite 41.4 Mt, zircon 11.5 Mt, and monazite 229 000 tonnes. These resources are located along the east coast of Australia, in the southwest corner of Western Australia, and in the Eneabba region, north of Perth, WA. However, over 40% of Australia's rutile and zircon resources, particularly those on the east coast, are presently not available for mining because of environmental considerations. As well, east coast ilmenite has been considered unsuitable for use by sulphate route pigment producers because of its relatively high chrome content. World demonstrated resources of rutile and zircon are estimated by BMR as 29 Mt and 38 Mt respectively. Demonstrated resources of ilmenite amount to about 1 billion tonnes. These occur predominantly in hard rock deposits in Norway, Canada, USSR and China, as well as alluvial deposits in Australia, South Africa and India. Quantitative data for world monazite resources is sparse. However, world production of rare earth oxides is now mainly from bastnaesite, a hard rock resource. Australia is presently the world's principal producer of rutile and zircon, and also provides a major share of the world's ilmenite. With the expected increase in Australia's rate of output of these commodities, combined with restrictions on mining along parts of the east coast, its position could diminish substantially over the next 25 years.

Jan 1, 1986

By B. K. Parekh, W. M. Goldberger

Silicon carbide (Sic), produced by heating rice hulls to elevated temperatures, contains a mixture of beta crystalline silicon carbide whiskers, particles, and unreacted carbon. The silicon carbide whiskers are 0.5 micron in diameter and 50 to 100 microns in length and have been found useful for reinforcing metal and other composite materials. The carbon can be removed by combustion, but this makes separation of the silicon carbide whiskers from particles difficult and a high grade whisker product cannot be made. However, a clean, high grade SiC whisker product can be obtained from the pre-burned converted rice hulls using physical separation processes that are based on differential wetting. Recovery of Sic whiskers from the pre-burned material was found to exceed 90%. A modification of the froth flotation process developed during this study is now being used commercially to separate silicon carbide whiskers and particles and to recover a high grade whisker product.

Jan 1, 1986

By H. L. O. Huyck

A microcomputer equipped with spreadsheet, data management, and FOR- TRAN programming software is used to update and quantify a model for ranking seventeen economically important metal commodities in terms of market potential (Huyck, 1982). Weighted factors are used for the ranking: (1) demand growth trends, (2) end-use substitution vulnerability, (3) recycling trends, (4) price trends, and (5) cumulative demand versus world reserves factor. Price trends are defined using (1) price-vs.-year slopes (with prices in 1967 constant dollars) and (2) standard deviations of slopes (to indicate price volatility). Substitution vulnerability is defined as the percent of end-use which is replace- able by other commodities, and a factor indicating the likelihood of such substitution. Factors are normalized and linearly combined to produce a ranking of the seventeen metals. Microcomputer software is essential for organizing data and calculating statistical parameters and linear combinations of factors.

Jan 1, 1986

Coal slurry pumping was introduced into the U.K. in 1973. Gateside packs were prepared in areas of containment using R.O.M. coal and a special fast setting cement. The packs restricted roadway convergence and moderated spontaneous combustion risks, but costs were high and alternptives were sought. A similar system using OPC and an accelerator had limited success. Much more successful was the Aquapack process which used dilute slurries of a special OPC based cement and an accelerator based on sodium carbonate and bentonite pumped simultaneously into la fabric packbag. The Tekpak system using HAC and a much modified calcium sulphate mixture superceded Aquapack on the grounds of improved cement pumping life lower alkalinity and lower costs. A further modification of this system gave a cement with a 24 hour pumping life thus obviating flushing out pipe ranges except at the week-ends, improved packbags also increased the efficiency of the process. The hazard of spontaneous combustion can be inhibited if air supply channels across the waste can be located and plugged. Using gas samples from pack pipes to locate the heating and injecting a special grout, formulated from bentonite, sodium silicate and thixotroping agents. into the waste on the intake road has proved a successful method of controlling heatings. Mine' roadway and face cavities are being safely and successfully filled with cementitious foams produced in a novel placer machine. The foams are based on fast setting cements with specialised foaming agents. Up to 13 cu. metres per hour of fast setting thixotropic foams can be produced and their use is now widespread throughout U.K. coal mines.

Jan 1, 1986

By Laxman S. Sundae

The Bureau of Mines designed, fabricated, and is using an in-seam tester (1ST) for in situ determination of coal cutting forces. This re-port describes the results of field tests conducted in the Pocahontas No. 3 and Upper Freeport seams to obtain peak and mean cutting forces during coal cutting with several bit geometries, including radial and point attack bits currently used on drum-type machines. Comparisons were also made between new and worn bits, and using data obtained from a Bureau-modified chisel bit. The test results show that longwall plough cutting (horizontal cuts) in bony coal bands (shale) requires >3 times the cutting force for the same cuts in a vertical direction. When no bony coal is present, the cutting forces required to make horizontal and vertical cuts are equal. Worn bits require 4 to 5 times more cutting and normal force than new or undamaged bits. Normal force increased drastically for the worn chisel bit. Peak force encountered in making independent cuts was found to be ~3 times higher than that required to make interactive cuts using a spacing-to-depth-of-cut ratio of 2. Both rake and clearance angles were found to have a significant effect on normal and cutting force.

Jan 1, 1986

By Kenneth P. Michalek, James E. Kelly, Jonathan A. Dantzig

"Many investigations have been reported regarding the simulation of continuous casting with emphasis on in-mold heat transfer. These analyses have been limited, however, because they require either estimation or measurement of the characteristic heat transfer between the ingot and the mold. In this paper, a self-consistent model 'is presented for calculating the heat transfer between a solidifying continuous casting and the mold, in the context of the continuous casting of steel. Using both thermal and stress analyses, the air gap formed during continuous casting is calculated and used to compute the heat transfer coefficients. Iteration between the thermal and stress analyses is used to determine a self-consistent solution. IntroductionThe continuous casting process for steel is illustrated schematically in Fig. 1. Molten steel is tapped into a tundish from which it flows at a controlled rate into the continuous casting mold. The initial shell of the casting forms in the mold by transfer of heat from the metal through the mold wall to the cooling water. The remainder of the casting is solidified by application of water sprays, and/or radiation cooling below the mold.Heat transfer in the mold portion of the process is important because it controls the formation of various defects which are deleterious to subsequent processing. Examples of defects formed in this region are surface irregularities, such as cold folding and oscillation marks, and more serious defects, such as longitudinal or transverse cracks. A more catastrophic problem which may occur is a breakout, in which the shell ruptures and molten steel is discharged in an uncontrolled way."

Jan 1, 1986

By Z. R. Llanos

The petroleum refining industry makes extensive use of catalysts for the conversion of crude oils into more usable products such as gasoline, fuel oil and gas, aromatics, and others. Catalysts used for hydraprocessing contain cobalt-molybdenum or nickel -molybdenum, although there are catalysts that also contain tungsten. During hydroprocessing, nickel and vanadium are deposited on the catalysts, eventually rendering them inactive. The refiners are then confronted with the problem of disposing the spent catalysts. In the past, landfilling was a common method of disposal and it is still practiced in some countries. Other refiners prefer to stockpile the spent catalysts at the refineries until the price of metals warrants their sale to metal reclaimers. This practice, however, poses environmental problems to the refineries for storage and disposal of spent catalysts. Other types of catalysts are amenable to regeneration. The purpose of this paper is to focus attention on the recovery of nickel, cobalt, molybdenum, vanadium, and alumina from spent hydroprocessing catalysts by Gulf Chemical and Metallurgical Corporation and to review the use of sodium hydroxide and sodium carbonate for pressure leaching of spent catalysts.

Jan 1, 1986

By Baafi EY, Chatterjee PK

The quality of mine planning decisions ultimately depends on reliable estimates of the characteristics of the orebody. The quant- ifiable factors such as grades or thickness can be estimated from field data gathered from outcrops or exploratory drillholes. Since outcrop data is necessarily limited to the periphery of a deposit, extensive drilling generally is required. This paper outlines a method for selecting the number and location of additional exploratory boreholes using an iterative procedure based on a mathematical optimization concept called fixed point theory. The method is illustrated through its application to an exploratory drilling program for a coal mine where optimized locations gave a lower estimate of regional and block variances than a manual Choice.

Jan 1, 1986

Both the miner and the Regional Water Board have legal obligations to ensure that all discharges of water from a mine site are free of harmful wastes, and that proper authorisation is obtained to abstract, divert, or discharge water. This requires long-term planning of water management for the whole of the mine site. Guidance is given in the paper on the issues which must be covered in water right applications.

Jan 1, 1986

By Steve Jones

Minor subsidence damage to the Burgettstown Junior-Senior High School building and grounds near Burgettstown, Washington County, Pennsylvania, prompted an investigation of the site in early 1985 by the Bureau of Abandoned Mine Reclamation of the Pennsylvania Department of Environmental Resources. The investigation determined that subsidence over an abandoned coal mine was occurring and that additional damaging subsidence would occur if reclamation measures were not taken. A Pittsburgh Coal Seam Mine which was abandoned in the 1920's underlies the school at a depth of sixty-five (65) feet. This sixty-five foot section is comprised of five (5) feet of unconsolidated overburden and sixty (60) feet of thinly bedded, highly fractured shale. Approximately five and one-half (5-1/2) feet of Pittsburgh Coal was extracted at the school site. A thin shale binder and one (1) to one and one-half (1-1/2) feet of roof coal were left in place. Within the Contractor's Underground Working Area (See Figure 1) approximately thirty (30) percent of the coal was extracted. It appears that the mine was just being developed in the vicinity of the school when it was abandoned for no known reason. Other nearby portions of the mine show extraction approaching sixty-five (65) percent.

Jan 1, 1986

By M. F. Dibble

The technology available for mining of underwater mineral resources such as placers and phosphorite, typically occurring with variable amounts of overburden, has remained largely unchanged for decades. The traditional bucket ladder dredge with maximum digging depth of 48 m and monthly capacities about 500,000 m3 still reins as the only heavy duty mining system capable of working the tough materials characteristic of heavy metal placers. Attempts at adapting the bucket wheel cutter-suction dredge to these severe conditions have not yet been successful except in moving small volumes from shallow depths. High capital cost (20-30 million U.S. dollars), high cost of overburden removable, and turbidity generation for the bucket ladder are often significant negative factors in mining operations where this system remains the only viable alternative. The Japanese continue to advance the technology of their submersible dredge pump system powered by specially adapted, direct drive electric motors. Present systems are designed primarily for working surficial deposits of aggregate to depths as great as 90 meters, the pump suspended by cable from a surface vessel with an eductor pipe leading from the pump to the vessel. Such a system may prove adaptable to a variety of surficial deposits including phosphorite, shell and heavy minerals in addition to aggregate. However promising for the exploitation of surficial deposits, little advantage can be expected for the deeper buried and more difficult deposits.

Jan 1, 1986

By L. C. Galloway, G. L. Tiley

"Mine hoist brakes must meet the following statutory performance criteria:- There should be two independent braking systems; at least one should act directly on the hoist drum.-If one brake fail s, the others should be able to retard and stop the hoist safely before the descending conveyance, carrying the rated load, reaches any obstruction.- When all brakes apply, decelerations should not be so violent that men travelling in the conveyance are injured.- The brakes shall not overheat and fade during an emergency stop.This paper discusses design principles and capacities of caliper and disc type brakes, when applied to double drum and friction hoists of equivalent capacity.IntroductionThis paper is about the brakes that are used on mine hoists; their functions, especially in emergencies, typical design, and how they are operated, controlled, tested, and adjusted.There are two basic types of mine hoists:1. Drum hoists, where the ropes are attached to, and coil on drums. The simplest system has only one drum. Most such hoists, however, have two drums, attached to a common shaft. Ropes are wound on each drum in opposite directions, so that when one conveyance is being raised, the other is lowered. The conveynaces may travel in vertical or inclined shafts. In the latter case, the hoist s are referred to as slope hoists.2. Friction hoist s, where the headropes are not attached to the wheel, but are in contact with it for an angle of lap of, typically, between 180 and 195 degree s. Forces are transmitted from the hoist wheel to the head ropes by friction.The lower ends of the conveyances are connected to balance ropes , approximately the same weight per foot as the headropes."

Jan 1, 1986

By P. Somasundaran

Electrochemical properties of silicate minerals govern their behavior in processes such as flocculation and enhanced oil recovery that can occur at elevated temperatures. Knowledge of these properties as a function of temperature can be helpful in developing an under- standing of the role of these interfacial properties at non-ambient temperatures. Zeta potential of Sodium Kaolinite and quartz has been determined as a function of pH and temperature in this work. Both systems exhibited markedly different behavior at higher temperatures and also exhibited significant hysteresis. Results are examined in terms of possible dissolution of the minerals and surface reactions at different temperatures.

Jan 1, 1986

By J. W. Merks

At mineral processing plants the accuracy and precision characteristics of assays in mill feed, tailings and concentrate largely determine the reliability of the metallurgical balance. The accuracy of measurements is ensured by selecting effective sampling methods and efficient sample preparation procedures, and by effecting each phase without introducing a systematic error while the precision of measurements is determined by the sampling regime. Sampling systems and components, sampling methods and regimes, and sample preparation procedures will be reviewed. Different techniques to determine variance components for sampling, preparation and analysis, and to detect systematic errors in assays at mineral processing plants, will be discussed.

Jan 1, 1986

By R. C. Rastogi, F. F. Aplan

The goal of this study is to evaluate the coal flotation process and the interaction of the chemical (reagent) and hydrodynamic (machine, operational) variables as they affect yield, flotation of various sized particles, and sulfur and ash rejection. Coal flotation is found to follow a first order process with the coal floating much faster than either pyrite or ash. This circumstance may be used to achieve gangue rejection during flotation. When floated with MZBC, cresol, or pine oil frothers, coal floats in the size sequence: 108 pm ( - 65 mesh), 589 x 808 pm (88 x 65 mesh), and 1.17 mm x: 589 pm (14 x 18 mesh). However with a substantial amount of fuel oil collector, all particles tend to float roughly in proportion to their content in the feed. An increasing aeration rate was found to be the most important variable in increasing the coal flotation rate. This increase in flotation rate, unfortunately, is also accompanied by an increase in the flotation rate of the pyrite. The rejection of pyrite during coal flotation is best accomplished at low aeration rates, low frother concentrations, and low impeller speeds.

Jan 1, 1986