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Chalcopyrite concentrate was combusted in oxygen-nitrogen atmospheres, the composition of which ranged from 1-100 per cent oxygen. Factors studied included particle size, experimental temperature and oxygen concentration. The study was assisted by chemical and X-ray diffraction (XRD) analysis and temperature measurements of single particles. Size reduction occurring after melting was found to have a major effect on the overall reaction time. Thus time to attain ignition was largely determined by the original particle size, whereas combustion time was independent of this factor. For particles larger than 40 I'm in air the time to attain ignition predominated. The maximum temperatures measured for single particles were the result of pyrite present in the concentrate. Chalcopyrite did not attain thesame temperatures. Vaporization, either as CU(g) or CuO(g) lImited the temperature. Maximum temperatures measured for single particles of pyrite ranged from 1610°C in 14 per cent oxygen to 2360°C in 100 per cent oxygen (both at 700°C). Measured temperatures were compared with those calculated from a diffusion-based model.

Jan 1, 1983

By Hans von Michaelis

The renaissance in extractive metallurgical practices for gold and silver recovery is far from over. This is one conclusion of a three year investigation into innovations in Cold & Silver Recovery by Randol International Ltd. (1981, 1983). The six volume reference report reviews a host of new processes and innovative applications of older metallurgical practices. Some of these were summarized by von Michaelis (1982, 1982a). There are several reasons to expect this renaissance to continue. One reason is the nature of gold and silver deposits. The list of known occurrences of These metals is very extensive. There are literally tens of thousands of prospects but over 99% of these are too low grade, too small or too refractory for a viable operation employing conventional processing.

Jan 1, 1983

Ground and air vibrations induced by large surface blasts have been monitored. These field results, as well as a large number of published results, have been used to assess the performance of existing predictors and for the development of improved prediction methods. Field monitoring has been performed, with four seismographs giving complete wave records, at limestone quarries, coal strip mines and an open pit copper mine. Conventional analysis includes least square fitting of peak particle velocities and peak air overpressures with scaled distance formulations. Frequency content has been analyzed, and correlated with blast design (detonation sequence). Two new methods have been developed for predicting ground vibrations induced by blasting. The proposed analytical predictor accounts explicitly for inelastic attenuation and geometrical spreading, and calculates the peak particle velocity as a function of charge weight and distance. Statistical analysis of case studies confirms the consistent improvement over conventional scaled distance predictors. The second new predictor is a computer program simulating blasts, including blast geometry, charge distribution and detonation sequence, and simulating propagation of individual pulses to any point of interest, where effects are summed. A complete blast vibration results, allowing prediction of frequency content and duration as well as peak velocities.

Jan 1, 1983

By William H. Lewis

Energy Research Corp., under contract to the Bureau of Mines, has developed a new miners' caplamp battery. The new battery is based on nickel-cadmium technology and offers significant improvements in performance with reduced size and weight when compared to the conventional lead-acid battery presently in use. This report describes the design and fabrication of the nickel-cadmium battery, which utilizes a roll-bonded electrode structure. The final battery design has a 15-A-h capacity in a 2-112-lb package, which is over 2 lb lighter than the present lead-acid caplamp battery.

Jan 1, 1983

By Marc C. Betournay, John E. Udd

"In this study, the authors investigated the stabilities of slopes cut predominantly into Trenton limestone in a large quarry in the Montreal region. Analyses of the bench and pit walls indicated that small-scale toppling, ravelling, and wedge failures are the most likely modes of instabilities. Because most of the joints dip steeply, however, the conclusion was made that relatively high walls could probably be justified.The field investigations were supplemented with the determinations of the shearing strengths of artificial discontinuities that were cut into samples of the limestone. The properties of a fine-grained limestone were found to be influenced very much by the magnitudes of the loads that were applied, while the properties of a crystalline limestone were found to be much less, or not load-dependent.The study is one of a number that are being conducted in this area.IntroductionExtensive quarrying has been done in the sedimentary strata of the Montreal area for a very long time. By any standards, it can be said that the Island of Montreal is a major mining area. At present, approximately 20 quarries are being operated in, or near, the city of Montreal.In addition to the millions of tons of limestone that are removed each year, a large number of excavations for foundations are cut into the sedimentary rocks.To date, however, very little information has been published concerning the engineering properties of the local geological materials. No mention is made of this aspect in the references which are presently available.Because of this lack of information, the senior author has initiated a study in which the strength properties of most of the rock types, and of the natural discontinuities contained in these, would be investigated. To date, the results of one other investigation have been published and other work is in process. It is hoped that the end result will be a comprehensive knowledge of the important strength properties of all of the rocks in the entire region."

Jan 1, 1983

By Paul B. Valenti

The Nevada Moly Operation of Anaconda Minerals Co., (a molybdenum/copper ore body) was initiated in 1978, with a contract to Bechtel Civil and Minerals Inc. for construction of a mining and milling facility near Tonopah, NV. Ground was broken on the concentrator portion of the project in August 1979$ with a multi-phased startup of the mill beginning in June 1981. Processing design tonnage of 20 000 t/d (22,000 STPD) was reached in early 1982. Major pitfalls of rapid design and implementation of engineering, construction, and startup are considered. The operation of the concentrator including SAG milling, ball milling, bulk rougher flotation, copper/moly separation, moly regrinding and cleaning, thickening, and product loadout are discussed.

Jan 1, 1983

By M. B. Mooiman

Cyanidation of gold and silver ores by conventional mining and milling techniques has been practiced for over a century. During the past decade, heap leaching has emerged as a viable process for treating certain gold and silver ores. (1) The rapid development of heap leaching for gold and silver ores is largely a result of lower capital and operating costs and faster start-up time than that offered by conventional mining and milling. In general, these features make heap leaching an ideal approach for exploiting either small or large low-grade disseminated deposits of gold and silver considered to be uneconomic by conventional methods. The development of heap leaching technology has evolved from the operations initiated in the western United States. The basic components of a typical heap leaching operation are depicted in Figure 1. Run-of-mine or crushed ore (usually 1 to 5 ppm gold) is delivered to specifically prepared impervious pads. Alkaline cyanide solution is applied to the surface of the heap and allowed to percolate through the heap (typically 10-30 ft high). Pregnant leach solution which drains from the heap is collected and stored in tanks of sufficient size or in collection reservoirs. Gold and silver are recovered from the pregnant solution and the barren solution is recirculated back to the heaps after reagent make-up.

Jan 1, 1983

By G. Zhu

Bulk and differential laboratory flotation tests have been carried out using a synthetic mixture of chalcopyrite and molybdenum ore. In addition to boiling and roasting, six different depressants are tested so that the best conditions of separation can be identified. These reagents include sodium cyanide with and without zinc sulfate, potassium ferrocyanide, sodium hydrosulfide, arsenic Noke's reagent, and sodium sulfide. The data indicate that most of these reagents are effective chalcopyrite depressants. However, sodium hydrosul fide can be used preferably if economic, operational, and environmental factors are taken into consideration.

Jan 1, 1983

By W. C. Shanks

Seventeen deeps, which contain hot or cold brines and/or metalliferous sediments, have been discovered in the axial rift zone of the Red Sea. Metalliferous activity results from the unique geological setting of this incipient ocean basin: oceanic crust intruding in a central rift zone flanked by thick evaporite sequences. Brine pools tend to occur in structural depressions where- transform faults intersect the spreading axis. The most significant metalliferous occurrence is in the Atlantis II Deep, which contains approximately 227 Mt (dry weight) of metalliferous sediment which averages 1.04% Zn and 0.28% Cu. Higher potentially economic grades (3-6% Zn, 1% Cu, 50 glt Ag) occur in the Southwest Basin of the Atlantis II Deep, comprising total metal tonnages of 1.7 Mt Zn, 0.4 Mt Cu, and 5000 t Ag. The Pre-Pilot Mining Test conducted in 1979 raised 15 000 m3 of mud by a slurry process and demonstrated the feasibility of mining, concentration by froth flotation, and tailings disposal at sea. A Pilot Mining Test is scheduled for 1983-1984. The metalliferous discoveries in the Red Sea provide a model example of deep marine mineral exploration. Detailed mapping of bottom bathymetry and brine-interface reflectors using a high-resolution narrow-beam echo sounder has been the most effective exploration tool in the Red Sea. Followup coring has discovered additional metalliferous deposits in basins without present-day brines, and potential exists for additional discoveries. Geochemical exploration using heavy metals values in sediments (iron, manganese, zinc, copper, and mercury) and sulfur isotope values of sulfides are considered to be the most promising techniques for discovery of currently inactive deposits. Positive sulfur isotope values in the range I to 17 are an indication of hydrothermal sulfides in the Red Sea, and there is considerable contrast from back- ground bacteriogenic sulfides ( - 10 to - 45).

Jan 1, 1983

By Rolland L. Blake

The Bureau of Mines investigated the mineralogy, tonnage, and beneficiating characteristics of oxidized (nonmagnetic) taconite iron resources of the Western Mesabi Range as part of its program to insure adequate future domestic mineral supplies. Magnetic taconite currently provides about 95 pct of Mesabi production, but the large tonnages of oxidized taconite between the magnetic deposits will be needed to help meet future domestic demand for iron ore. Three bulk samples that represent large tonnages from the Western Mesabi Range were selected to determine their mineral composition and liberation by light optical microscopy and to test their beneficiating response. This report describes the mineralogy and liberation characteristics of the three samples of the Biwabik Iron-Formation for 26.5 mi (42.7 kID) from Keewatin to Grand Rapids, MN. (Details of response to beneficia-tion were reported previously.) The samples represent mostly material from the Lower Cherty Member of the Biwabik-Iron Formation, although one sample included some Upper Cherty Member. Minerals of all three samples were quartz (chert), hematite, goethite, and minor to trace amounts of magnetite, iron carbonate, and iron silicates. It was concluded that the oxidized taconites of the Western Mesabi Range represent a subeconomic indicated resource that can be selectively mined and beneficiated as a future large source of iron feed for steelmaking.

Jan 1, 1983

By M. B. Mooiman

It has recently been discovered that the pH at which gold can be extracted from cyanide solution with primary, secondary, and tertiary amines can be increased 2 to 5 pH units by the addition of modifiers. Under these circumstances gold can be extracted at pH values from 9 to 11, commensurate with the pH range found in cyanide leach liquors. The selectivity of the amines and amine/modifier combinations for AU (CN)[-2] over other metal -cyanide complexes is presented and discussed. In addition, potential applications for the solvent extraction of gold from cyanide solutions are discussed.

Jan 1, 1983

Provide a means for continuous measurement and display of respirable dust concentrations in a mine so that when high dust levels occur, timely, corrective measures can be taken. Approach Develop a personal dust monitor that (1) is small and light enough to be worn by a miner, (2) has the capability to continuously measure the respirable fraction of coal dust, (3) will display the respirable dust concentration in mg/m3, and (4) can store the average respirable dust concentration and sampling time of several sampling shifts for later play-back. How It Works The personal dust monitor (PDM-1) uses light scattering and convection air currents to sample the respirable fraction of coal dust. Convective air currents cause dust laden air to pass through an open-celled sampling chamber (light sensing chamber). A near infrared light emitting diode (LED) located in the PDM-1 emits pulses of light. The pulsed light passes through a focusing lens and glass window into the sampling chamber. The light is then reflected, scattered, and refracted by the airborne dust particles. Light scattered within the angles of 450 to 900 (the angles within which the intensity of the scattered light is most closely related to respirable-size dust particles) passes through another window and is focused on a light detector. The light detector signal is amplified and presented as analog output voltage for conventional recording. This signal is also converted to a digital signal which the microprocessor uses with its crystal clock to calculate the 10-second average dust concentration, the shift average concentration, the time-weighted average concentration, and the elapsed sampling time. The microprocessor also stores dust concentrations of the seven most recent sampling periods, controls the operation of the LED and detector, and operates the liquid crystal display (LCD).

Jan 1, 1983

By N. R. Dixon

This report summarizes all work performed under U.S. Bureau of Mines Contract No. J0395028, "Noise Control of Rubber-Tired Front-End Loaders Used in Surface Mining. " Two loaders, a Caterpillar 988 and an International H-400B, were chosen for this program, and the noise sources and acoustic paths that contribute to the operator's noise exposure were identified. Retrofit noise control treatments were designed and installed on these loaders, and noise reductions of more than 10 dBA at the operator position were achieved on both machines. The retrofit packages are low cost and have been field tested in two mines for more than two years. The results of the program were communicated to the mining industry through a series of noise control workshops and a field manual. The workshops were given in nine states across the U.S. and more than 440 manuals were distributed An audio/visual slide presentation was also developed which the program.

Jan 1, 1983

By Ruston R

When coal mining first commenced in Australia, the principle objective was low cost production with development directed toward recovery of 'easy' coal. Future expans- ion of these early mines into major under- ground operations was neither envisaged nor planned. As the demand for coal grew, these mines were expanded to increase output. however, the absence of initial ventilation planning brought about ad hoc systems wh;ch required continual repair and upgrading. These systems proved satisfactory in the short term because the majority of undergrouni coal mining operations were carried out at relatively shallow depths where gas emission rates were low. By comparison, coal is now being won at depths exceeding 500 metres with a corresponding increase in gas flow from the working seams and adjacent strata. The following paper addresses, firstly, the planning and institution of a ventilation system in a mine where previous inefficiencies were many, and secondly, the value of pre- planning a mine ventilation system in the early stages of mine development, and the need to continually review and upgrade the plan to account for unforeseen ^hanges.

Jan 1, 1983

By N. A. Gokcen

This Bureau of Mines report reviews and summarizes recent studies of the rates of chlorination of aluminous resources with CO and C12 mixtures with and without COC12. No reaction mechanism could be obtained from the existing results; however, diffusional barriers in the gas and solid layers probably control the chlorination rate in thermogravimetric experiments. Fluidized beds of particles smaller than 0.1 mm appeared to show very little solid layer diffusional barrier. For optimum chlorination the particle size should probably be less than 8 mm, the calcination temperature approximately 700° C, and the chlorination temperature from 650° to 750° C. Relatively rapid chlorination with COC12 in thermogravimetric experiments was attributed partly to the simultaneous supply of reductant and chlorinator by one gas to the sample reaction site. Comparable results for chlorination of fluidized beds with COC12 are not available. Equimolar mixtures of CO and C12 produced the optimum rate of reaction. Addition to the calcine of 10 to 20 wt-pct NaCl accelerated the rate of chlorination, and addition of SiC14 to the gas mixture decreased the rate of chlorination of SiO2 drastically, but at the expense of chlorination of significant fractions of Al2O3. Further research in various areas is suggested.

Jan 1, 1983

By Lyle D. Randen

With the environmental movement beginning in the late 1960's came a deluge of permit requirements for the mining industry. Coal mining has been one of, if not the most, severely impacted of the mineral industries as a result of the passage of the Federal Surface Mining Control and Reclamation Act of 1977. Numerous provisions of this Act and numerous regulations developed under authority of the Act are being challenged in differing levels of the judicial system across the United States. Such court cases have had varied success. Numerous other regulatory programs that are not quite as dramatic as the SMCRA have presented an unending regulatory problem for mining operators. My comments in this presentation relate primarily to the major Federal and State agencies and their legal responsibilities which we in the coal mining industry must address in order to receive authority to construct and operate surface coal mines in the State of Wyoming. A list of the Federal and State agencies one could deal with in an application is as follows: 1. Bureau of Land Management (BLM). BLM is responsible for deciding where and when to lease federally owned coal and for establishing terms and conditions for leases. BLM also has some control over surface reclamation on federal land, i.e. regrading to eliminate highwalls, covering of spoils, maximum extraction of coal to limit future disturbance, contemporaneous reclamation, etc. BLM is also responsible for designation of federal lands unsuitable for all or certain types of surface coal mining operations. 2. Geological Survey (USGS). USGS coal mining responsibilities apply only to Federal and Indian lands and concern compliance with production requirements including diligent development, minimum production levels, royalty payments and resource protection, and

Jan 1, 1983

By K. Papke

Nine western states contain significant barite deposits, but most deposits are in Nevada, which has been the principal western producer for more than three decades. Nevada produces about 85% of the total United States production, but about one-half of the barite consumed in the country is imported. Approximately 95% of the barite is used in drilling muds. Sharply decreased oil and gas drilling, starting in early 1982, severely depressed the domestic barite industry. Other problems for western barite include long distances to the areas of major drilling, high railroad-freight rates, and increased barite imports. Bedded deposits, formed by submarine exhalative processes, account for almost all western production, and reserves are large.

Jan 1, 1983

By Joseph M. Pugliese

The Bureau of Mines through its contract research program recently analyzed the mining and environmental requirements in the premining stage for copper mining in the northern highland of Wisconsin. The Critical-Path-Method (CPM) was used in this research. However, a step-by-step derivation of the CPM Diagram was beyond the scope of this effort. The Bureau of Mines objective now is to show, step by step, how the original hand-computed CPM Diagram was constructed. The streamlining (restructuring) of this diagram from the original effort is also summarized. The critical path time (longest time) through the original CPM Diagram was 25.12 yr, excluding public liaison effort. This diagram showed the involvement of the regulatory agency, mining applicant and public in the premining stage. Analysis of this diagram produced a streamlined version which reduced the critical path time by nearly 7 yr. The CPM construction methodology offered here may be applied to mine planning for any mining operation.

Jan 1, 1983

By Travis Q. Lyday

During 1981, Ecuador's gross domestic product (GDP) increased by a reported 4.8% in real terms, a slight improvement over that of 1980. In current prices, the CDP in 1981 was estimated at $13.7 billion.2 The inflation rate increased to 15.6% according to official figures, above that of 1980. Ecuador's production of petroleum increased 3% in 1981 compared with that of 1980. The consortium of Corporación Estat al Petrolera Ecuatoriana (CEPE), the state oil company, and Texaco, Inc., produced almost 98% of the total from their Putumayo Basin operations in Oriente, the eastern jungle region. In sharp contrast, output from the Santa Elena Peninsula Fields, where oil was first produced commercially in 1921, continued to decline, producing only 510,000 barrels, a decrease of almost 8% compared with that of 1980.

Jan 1, 1983

By N. B. Aughenbaugh

Subsidence due to abandoned coal mines has received copious attention recently. This is a result of many factors such as the enactment of new mining laws and the effect subsidence has on land use over the mines. Prediction of subsidence features and the time aspects over supercritical extraction (i.e., longwall and high extraction ratio pillaring) is relatively accurate. However, predicting when subsidence will occur and the surface features' size and shape above subcritical extraction of room and pillar mining is not yet possible. This paper will discuss the factors that influence the time aspects of subsidence in room and pillar mining.

Jan 1, 1983