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By A. R. Udupa

The reduction roasting behavior of chalcopyrite has been investigated using various combinations of a desulfurizing agent, i.e., CaO or Na2CO3, and a reductant, i.e., CO, H2 or C. Using these, combinations the sulfur is removed from the mineral as CaS or Na2S rather than SO2 as is the case with conventional copper smelting and converting. The laboratory reduction ex¬periments were conducted using thermogravimetric analysis (TGA) and boat tests of mixed combinations of fine particulate reactants subjected to a continuous gas stream. The degrees of metallization were determined by both weight loss and chemical analysis methods and the products examined using optical and scanning electron microscopy and electron probe microanalysis. The percent reduction after one hour at 900°C ranged from 60% to 94%. From these data It was possible to provide postulations as to the controlling reduction mechanisms.

Jan 1, 1983

By R. C. Beard

"Heap leaching, currently being applied in the treatment of low-grade ores in the south western United States, is shown to have potential for use in north western Ontario. The history and operation of the process are described, and cost comparisons are given.IntroductionHeap leaching is a simple, low-cost method of recovering gold from low-grade ore. Although it is not currently being used in Canada on a production scale, it is being used extensively, and successfully, in the southwestern United States as well as elsewhere in the world. Especially suited for large deposits of very low -grade ore, it also appears to be practical for use on small, high-grade deposits because it avoids the high capital costs of mills. Eveleth (1980) and others suggest that the capital and operating costs required for heap leaching are approximately 20% and 40% respectively of conventional milling methods.Northwestern Ontario is noted for its large number of undeveloped, small, high-grade gold deposits. Although there are a number o f larger and higher-grade deposits in the area as well, it is the relatively small undeveloped deposits which would benefit most from heap leaching, if it could be demonstrated to be a viable extraction method.To assess the significance of these small deposits, the Ontario Ministry of Natural Resources recently commissioned a consultants' study of the gold reserves in certain parts of northwestern Ontario. This report, titled ""Feasibility of Small-Scale Gold Mining in Northwestern Ontario"", by J.N. Neilson and R.C.E. Bray (1981, OGS Open File Report 5332), documents 106 known gold deposits having sufficient information to calculate gold reserves. A total of over 7.8 million tons having a weighted average grade of 0.19 oz of gold per ton were compiled in the proven, probable and possible categories, with an additional 8.2 million tons in the speculative category. Many of these deposits could be mined by open-pit methods."

Jan 1, 1983

By R. Blickensderfer

An impact wear testing machine was devised by the Bureau of Mines that simulates the repeated impact conditions encountered in large milling and grinding operations where breakage and spalling are problems. The apparatus provides data on materials that may help in the design of alloys with improved resistance to deformation, spalling, and breakage. The test blocks are 2 in thick by 6 in by 8 in. Impacts are produced by dropping 3-in-diam balls weighing 4 lb from a height of 10 ft. Tests were run until breakage occurred or to a total of 100,000 impacts. Four types of failures of the test block were observed: (1) cold flow of the bulk material by plastic deformation, (2) flaking of the surface in the impact region, (3) spalling of the block to form a crater in the region of impact, and (4) breakage of the test block into two or more major pieces. The effects of composition, heat treatment, microstructure, and hardness on types of failure are discussed.

Jan 1, 1983

By T. R. Yu, D. B. Counter

"Kidd Creek Mines primarily employs sublevel blasthole stoping for underground mining operations. During pillar recovery in No.1 Mine and panel mining in No.2 Mine, the free standing fill exposures may reach a height of 100 m or more. Consequently, a competent consolidated rockfill has been required to fill the mined openings.Since 1976, a total of more than fifty stopes and pillars have been filled with over four million tonnes of backfill. Fill exposures, up to heights of 100 m, have stood up well after blasting adjacent to the backfill.The fill material consists of a graded aggregate, Portland cement and ground slag. Sand has been occasionally mixed in the fill material to serve as avoid filler. The aggregate is prepared in a fill crushing plant, transported underground through raises, and hauled to the filling stopes by conveyors in No. 1 Mine and by trucks in No.2 Mine.Two mixing methods are currently in use. No. I Mine utilizes the free fall of gravity; the fill materials are sprayed with cement slurry as the aggregate departs from the conveyor into a mixing culvert. The other is the use of a rotary mixer on a batch basis in No. 2 Mine.This paper describes the fill systems, filling operation s, and the backfill quality control practice, together with various testing results related to improving fill quality as well as reducing fill costs.IntroductionThe Kidd Creek minesite, located 27 km north o f the city centre of Timmins, Ontario, produces 4.5 million tonnes of copper, zinc, lead, and silver ores annually from its No. 1 and No.2 underground mining operations. Both mines employ a sublevel blasthole stoping method."

Jan 1, 1983

During the period 1979 thru 1982. Multi Mineral Corporation conducted a mining research program at the United StAtes Department of the Interior's Bureau vi Mines Oil Shale Mining Environmental Research Facility in the Central Piceance Creek Basin, Rio Blanco County, Colorado. The program consisted of mining, environmental and geotechnical research data and. the results are described in this report.

Jan 1, 1983

By G D. Price

Scheelite mineralisation east of the main divide in' the Southern Alps of New Zealand was originally identified by Royden Thompson who is now a geologist with the NZ Geological Survey. This mineralisation was brought to the attention of CRA in 1978. Reconnaissance surveys were carried out in 1979 to delineate the extent of the mineralisation. This was undertaken using ultraviolet light examination of the sediments within the major drainages in the Southern Alps. This defined tentative zones of prospective mineralisation. As a result of this, preliminary reconnaissance, exploration licences were applied for -those areas in which indications of scheelite mineralisation were strongest. A total of 1737 km2 of ground was applied for within four exploration licences. These covered the main Southern Alps mountain chain between the Haast/Wanaka highway and the Mt Cook National Park.

Jan 1, 1983

By M. Hashimoto

The equilibrium distribution ratios of sulfur between molten copper and CaO-fluxes containing caF2 and caC12 were determined in the range of 1300° to 1400° C under carbon monoxide. The rate of approach to equilibrium is rapid and increases with increasing CaCll concentration. In CaO-CaFl-CaCl2 fluxes, the distribution ratio varies in a complex way with temperature and CaFl concentration. The results are compared with those obtained with the binary fluxes of CaO with BaFZ and MgFl ?

Jan 1, 1983

By J. C. Yannopoulos

The quest for a continuous copper smelting and converting process, which has been going on for a long time, has not as yet reached its objective. The most recent efforts for the development of a continuous copper?making process started about two decades ago. Among the contending proposed processes, four have been piloted and three of them are currently in operation: the WORCRA process., the NORANDA process, the MITSUBISHI process, the OUTOKUMPU process. The WORCRA process, after some long pilot plant tests, failed to develop as an industrial process: The NORANDA process, as currently operating, is a smelting process and not a continuous copper?making reactor as initially conceived. The MITSUBISHI, although the only continuous process, has not been widely accepted. The OUTOKUMPU process can be applied only to a low iron concentrate feed and co?produces blister and high in copper slag. The thermodynamics of these "continuous" systems and the practical problems of their industrial application are reviewed and discussed. The achievement of efficient and inexpensive environmental control should' be the primary objective of any new process development. A review of the environmental problems of the copper industry indicates that the quest for a continuous smelting and converting furnace should be intensified.

Jan 1, 1983

By R. D. Brittain

In order to analyze and control the transport of harmful trace-element impurities in various smelting processes, it is necessary to have fundamental information about the chemical thermodynamic properties of the pertinent condensed and vapor phases. This paper describes recent thermodynamic studies of the gaseous arsenic sulfides and of the activity of arsenic in a copper-iron sulfide matte phase. These studies were carried out by high temperature mass spectrometry and by effusion vaporization techniques, which permitted clear identification of the molecular species involved, a decided advantage in such complex systems. The nature of the results obtained and comparisons with previous interpretations will be described.

Jan 1, 1983

By L. E. Mannion

Sodium carbonate (soda ash) is one of two principal commercial alkalis. Its principal competitor is sodium hydroxide. The use of sodium carbonate is recorded in ancient Egypt, where naturally occurring brines and solid salts provided impure soda for early glassmaking. Until the 19th century, soda ash (as well as potash) was recovered mainly by leaching wood or other plant ashes. In 18th-century Europe, for example, leaching seaweed ash with hot water produced a brown laundry lye. One of the better grades of this material was a Spanish product, barilla, which analyzed 24 to 30% Na2CO3 (Hou, 1942). The modern chemical industry was born in 1691 with the LeBlanc process for making sodium carbonate from salt, sulfuric acid, and lime. English industry used this process extensively in the 17th and 18th centuries. The next major advance was in 1863, when Ernst Solvay devised the ammonia-soda, or Solvay process. The first of many Solvay plants was built in 1874. These supplanted the LeBlanc method and dominated worldwide soda ash production until 1974, when mined sodium carbonate became predominant. Although considerably less important until recently, natural sodium carbonate deposits historically have supported small soda ash operations throughout the world. Shortages during World War II stimulated production of "natural" soda ash from such deposits, particularly at Searles Lake, CA and Lake Magadi, Kenya. More spectacularly, increased production from the vast trona deposits in Wyoming has virtually supplanted the Solvay process in the US. Principal producers of natural soda ash as well as the character of the source deposits are listed in Table 1. [ ]

Jan 1, 1983

By Bobby J. Timmons

Luck; blind, beginner's, fisherman's, or whatever type, plays an important role in romance, racing, football, gambling, and mineral exploration. However, for each of these; education, training, technique, and experience are necessary for a long, continuous, successful relationship. Success, no matter how obtained, is easier to defend than almost success, regardless of the education or the degree of refinement of the seeker. Similarly, investment dollars are more readily available to a successful, uneducated and unscientific practitioner than to his beginning or unlucky professional counterpart.

Jan 1, 1983

By R. R. Potter

"IntroductionAlthough iron formations were recognized in western New Brunswick about 1820, commercial production was not achieved until 1848. The Jacksonville deposits near Wood stock were developed first, and ore was treated at a blast furnace constructed 5 km to the southeast on the Saint John River. Several charcoal burners were also constructed. Pig iron was produced sporadically until 1884, when operations were finally suspended. There was little further interest in the area until 1953, when Stratmat Ltd. initiated an ambitious exploration program. At the same time, the company carried out research on an electric-reduction process to produce metallic iron and ferromanganese. The technical feasibility of this process (Udy process) was confirmed, however the high energy costs were prohibitive and work ceased in 1957. Some metallurgical research was carried out by Mandate Refining Ltd. about 1970 and more recently by the New Brunswick Research and Productivity Council.The Years Prior to 1848New Brunswick became a separate province in 1784, shortly after the influx of a large number of Loyalists from the United States. Man y of these people sett led along the Saint John River, including the area of excellent farmland near the present town of Woodstock.There were indication s that some of these earl y settlers recognized iron formations in the vicinity of Woodstock about 1820, however the nature of the deposits was not known until 836 when Dr. C.T. Jackson, a geologist commissioned by the Stat e of Maine, investigated the mineral potential of the area. Jackson (1836) described the ""ore"" as compact red hematite yielding 44 per cent pure metallic iron, and suggested that sizable tonnages may be present. It was about this time that an extensive limonite deposit was found in north-central Maine, near Mt. Katahdin. Other iron deposits were found in the Nictaux area of Nova Scotia, and a few years later at Londonderry."

Jan 1, 1983

By M. Grun, A. C. Marlowe, I. Littleford

SYNOPSIS A Wirth tunnel borer owned by Anglo American Corporation completed a 1150m long tunnel some years ago and was subsequently extensively modified by Technical Development Services. In 1982 this borer provided new and particularly interesting information In the field of hard rock boring. The abrasive quartzltes traversed proved to be a challenge to the cutter manufacturer and the project team. This paper examines the problems faced, the solutions found and the lessons learnt.

Jan 1, 1983

By S. N. Sinha

The distribution coefficients of lead and silver between copper and matte phases have been measured at two different temperatures. Experiments covered the ranges of 0.009-1.8, 0.07-0.13, and 0-11 wt pct lead, silver, and iron in matte, respectively. The distribution coefficients of lead have been measured at 1405 and 1505 K and correlated with lead and iron concentrations in metallic copper and matte. The values of the distribution coef¬ficient of lead between copper and iron-free matte, at infinite dilution of lead, have been determined to be 3.60 and 4,06 at 1505 and 1405 K, respectively. The distribution coefficient of silver between copper and iron-free matte is independent of silver concentrations and has been measured to be 2.13 and 2.21 at 1400 and 1500 K, respectively. For an iron-bearing matte, the distribution coefficient of silver has been correlated with iron concentration in the matte at both 1400 and 1500 K. From the measured values of distribution coefficients, the Raoultian activity coefficients of PbS and AgS0.5 in copper-saturated matte have been calculated. At infinite dilution, the following equations correlating the Raoultian activity coeffici¬ents of PbS and AgS0.5 with matte- composition and temperature have been obtained: log Y° PbS =1.515 + 1080/T 0.14 NFes lbS Fog YAgS = -0.074 - 425/T + 0.09 NFes. - 0.5

Jan 1, 1983

By Louis Schaffer

The objectives of the research were to determine whether a model health and safety program could be defined in terms which would enable its application to mines of all types, and, if such a model program could be defined to determine through evaluations in two mining companies whether it would achieve measurable improvements. This volume describes the model, how it was applied in the field, and how it was evaluated. Anecdotal data to illustrate common kinds of safety problems and their solutions are included. The literature and field research that preceded the model definition is discussed in Vol. 2, which covers the period of September, 1980 to September, 1981.

Jan 1, 1983

By Moorrees C, Everson P

A detailed examination of carbonic acid leaching of crude iron-containing magnesia derived from Savage River magnesite shows that the rate and extent of magnesium and iron dissolution are affected by the slake time, leaching temperature, carbon dioxide pressure, pulp density and rate of agitation. In order to produce high-purity magnesia from the leachate by precipitation and calcination, the optimum leaching conditions, which are those that yield maximum magnesium and minimum iron dissolution, have to be a compromise in terms of the above parameters. For example, iron dissolution can be limited by leaching at an elevated temperature (-45°C), but because the maximum concentration of magnesium biearbonate decreases rapidly with an increase in temperature, it is necessary to use a low pulp density (-2 per cent solids) in order to achieve an acceptable degree of magnesium dissolution.Evidence is obtained that iron dissolution involves the formation of a soluble ferric bicarbonate complex that decomposes at elevated temperatures. The extent of iron dissolution is much higher than might be expected and it is probably because the original magnesite contains siderite in solid solution with the magnesite; on calcination, the hematite whieh is formed is in a very finely divided condition and hence more reactive.

Jan 1, 1983

By E. H. Cho

INTRODUCTION Activated charcoal has been used for several centuries in many capacities including the recovery, isolation and purification of various materials (1). The first use of charcoal in a gold metallurgical system was in the extraction of gold after chlorination (2, 3,4). The gold was dissolved in a chlorine system and subsequently filtered through charcoal. The application of charcoal with cyanide extraction was patented by Johnston (5) in 1894 and adopted commercially in Australia in 1897. The process consisted of dissolving the gold and silver in a potassium cyanide solution and passing it through a series of charcoal filters. The charcoal was subsequently smelted to recover the gold and silver. The interest in the use of charcoal diminished in the first part of the twentieth century as the practice of the use of zinc as a precipitating agent increased. However, in 1916, the Yuanmi Mine in Australia replaced their zinc precipitation plant with a charcoal adsorption plant. In 1926, Scott and Gross (7) of the U. S. Bureau of Mines con- ducted extensive research on the adsorption of gold and silver from cyanide leach solutions. Among their findings was the result that the most important factor in improving the adsorptive power of charcoal was heat treatment with oxidation by air or steam. The work of Zadra (8) in 1952 stimulated renewed interest in the use of activated charcoal in gold and silver recovery with the development of a method of recovery of the gold and silver from the charcoal other than its destruction by burning. The process involved simultaneous desorption

Jan 1, 1983

The design of mine ventilation systems for the BHP Steel Division Collieries is based on the acquisition of ventilation survey data for the establishment of a realistic computer net- work model. The branches which form the net- work for the computer models are calculated from a range of resistance factors incorporat- ing both a frictional and shock loss component. Since shock losses can account for up to 30 per cent of the total energy losses in mine airways the use of friction factors alone without accounting for shock losses will result in the choosing of an insufficiently performing fan. Published tables of friction factors have in- variably been taken from metalliferous or single entry studies and consequently are not reliable for Australia's mining conditions where multiple entries with regularly spaced cut-throughs are the normal practice. Typical resistance factors for roadways of rectangular cross-section 5.5 m x 2.0 m, with coal sides, have been found to vary from 0.11 Ns2/m8/km where no timber supports are used, to 0.98 Ns2/m8/km where double centre legging together with wooden chocks is used. In addition to the range of resistance factors due to varying support methods, the nature of use for a roadway is very significant because of the condition of repair and upkeep maintained.

Jan 1, 1983

By Louis Schaffer

The objectives of the research were to determine whether a model health and safety program could be defined in terms which would enable its application to mines of all types, and, if such a model program could be defined, to determine through evaluations in two mining companies whether it would achieve measurable improvements. Volume 1 describes the model, how it was applied in the field and how it was evaluated. This, Volume 2, describes the literature and field research that preceded the model definition.

Jan 1, 1983

By James E. Aplin

Previous studies have shown that fracturing of roof strata precedes ultimate failure, and that the fracture development causes an accompanying increase in the apparent resistivity of the strata. Using this principal, a microprocessor controlled resistivity roof fall warning system (RRFWS) was developed that automatically sequences through and records up to 32 electrodes that may serve as either voltage or current electrodes. This capability permits increased coverage with a minimal number of required electrodes. The data is stored in a nonvolatile memory and on an optional printout, making the system nonsusceptible to loss of mine-power. To further save battery power, the system's electronics shut down between readings, except for a carbon molybdenum steel real-time clock. At a preprogramed interval, the RRFWS reactivates and repeats the sequence. If the absolute change or the rate of change of resistivity exceeds a predetermined limit the system is capable of sounding an alarm. In addition to the monitor, a stainless steel mod led split-set electrode was also developed that permits long-term corrosion-free contact.

Jan 1, 1983