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By Moyle F. J

This paper describes an apparatus which was developed to study solid-vapour equilibria and presents results which were obtained during a study of the FeCI3-AlCI3-CI2 system. Analysis of the results showsthat fractional desublimation might offer a means of achieving a useful separation of the iron and aluminium chlorides produced by the chlorination of bauxite. The results, presented in the form of isothermal vapour pressure curves covering the range of temperature 160-200°C, support the earlier findings of Semenenko et al (Dokl Akad Nauk SSSR, 154: 42-43 (1964)) that the solid phase contains two terminal solid solutions.The equilibrium constant for the formation of the mixed dimer, FeAICI6, was approximately 4. The latent heat of sublimation of aluminium chloride varied from 18 to 26 kcal/mole AI2CI6 for solid compositionsfrom 0.9 to 0·5 mole fraction FeCls3.

Jan 1, 1979

A number of cooperative studies have been carried out as preliminary work for drafting a standard for application of granulated slag sand for concrete, and the following conclusions were reached 1 The ten kinds of granulated slag sands pro- duced in Japan satisfy the national standard for fine aggregate in terms of physical and chemical properties. 2 Mortar and concrete tests conducted with granulated slag sand revealed that, although with slight differences in the extent, gran- ulated slag sands used in these tests were applicable'as fine aggregate for concrete, 3 The pumpability test by a concrete pump carried out on concrete with two kinds of now commercially available granulated slag sand demonstrated that the pump pressure feeding is applicable in the same manner as in the case of ordinary concrete. These tests permitted' preparation of a draft standard for application of granulated slag sand, and the results formed the first step toward utilizing this material as a sub- stitute for natural sand.

Jan 1, 1979

By Omar Abd el Fattah Ramly, Abdallah Mohamed Sourour

FOREWORD In 1974, the Ministry of Housing and Reconstruction (The Client) which subsequently became the Ministry of Development and New Communities of the Government of the Arab Republic of Egypt assigned responsibility to the Arab Contractors (Osman Ahmed Osman and Company) for the design and construction of the tunnels under the Suez Canal. For this project the Arab Contractors of Cairo and Tarmac International of London formed a joint Venture, called Osmac. Sir William Halcrow and Partners of London are responsible for the design of the Ahmed Hamdi Tunnel as a Sub-Contractor to the Contractor. The advisory consultant of the client is a joint Venture between Tippetts-Abbett-McCarthy-Stratton (TAMS) of New York and Arab Consulting Engineers (ACE) of Cairo. INTRODUCTION A site investigation was carried out between Km 141 and Km 150 Suez Canal chainage to determine the ground conditions relevant to design and construction of a road tunnel under the Suez Canal. A feasibility study included aerial surveying, geological mapping and the drilling of 8 boreholes. Detailed investigation included the drilling of 105 boreholes, sampling, piezometer installation, pumping tests, and the digging of trial pits and trial excavations. In-situ work comprised SPT, permeability tests and dilatometer tests. Laboratory testing included soil classification tests, compaction tests, California Bearing Ratio tests, shear strength determination and oedometer consolidation tests as well as chemical analysis of both soil and ground water. The investigation revealed that the ground conditions at the first proposed El Shatt site (Km 148.5) were not favourable for bored tunnelling, whereas they were more favourable at the southern El Shatt site (Km 150.0).

Jan 1, 1979

By C. A. Olivier

Le Ministère des Richesses naturelles du Québec has continued development work on the process/or direct reaction 0/sodium carbonate with lithium-bearing silicates(Canadian Patent No. 643,843). Recent process improvements have involved continuous pressure leaching, rather than batch leaching, and higher solution concentrations (over 55 g/l Li2CO3. These improvements have been demonstrated on a pilot scale operating on decrepitated spodumene from the Sullivan Mining Group's Quebec deposit. The new process is expected to be very competitive with the conventional sulphuric acid route. The improved flowsheet and main process steps will be described along with pilot-plant results.

Jan 1, 1979

Fines and unnecessarily small rock fragments are created by as many as four identifiable breakage mechanisms which operate close to the charged section or sections of the blasthole. The peak blasthole pressure (Pb) should not exceed that value at which the rock starts to fail in compression. Excessive Pb values can be prevented by carefully selecting:1. the composition, density and/or diameter of the charge, and2. the initiation/priming system.The percentage of fines increases with:1. increases in the charge diameter:blasthole diameter ratio, burden distance, blasthole diameter, effective sub-drilling and size of blast, and2. decreases in blasthole spacing, stemming height and the length:width ratio of the blast block.Decked charges tend to reduce the percentage of fines.Excessive fragmentation is more evident in buffer blasting and sinking cut shots than in blasts fired to a clean free face. Initiation sequences which give effective burdens considerably less than drilled burdens encourage the minimization of fines, as does an inter-row delay time which promotes good progressive relief of burden.The wastage of explosive energy in creating fines is most pronounced where fully-coupled, energetic charges are fired in weak and/or highly porous rocks. This is especially so where forward movement of the strata is impeded by buffer rock, excessive burden distances and/or inadequate inter-row delay times.

Jan 1, 1979

By Bengt L. Stillborg

INTRODUCTION This paper summarizes the result of a two and a half year research program. The objective of the research was to develop a fundamental understanding of the Rib-in-Roc method. Through the development of a new model technology, namely three-dimensional physical models which powerfully exploit the results of dimensional analysis Stillborg, Stephansson and Swan (1), it has been possible to establish the contribution to both permanent and immediate stabilization of a large underground opening pre-reinforced by the Rib-in-Roc method. Using the results from these physical models and earlier work by Stillborg and Stephansson (2) and Åkesson (3), a conceptual synthesis is given in this paper so demonstrating the Rib-in-Roc method to be a practical working system of pre-reinforcement. DESCRIPTION OF THE RIB-IN-ROC METHOD To give the reader an idea of how this method of pre-reinforcement is performed, a short description will be given, Figure 1. Before any full-scale excavation takes place an entry is made in the host rock and rib raises are driven around the proposed opening. These raises are made at a spacing that is dependent upon rock quality; an opening in poor rock needs more ribs per length of opening. As the ribs are driven they are used as a site from which very competent rock bolting can be done. As a rib is excavated it is filled with reinforced concrete. Finally after having in this way reinforced the zone around the proposed opening, (a reinforced arch is formed) the displacements are automatically controlled as the opening is being excavated. Using this method openings with a span of 50-60 meters (160-200 ft) and a height of 60-80 meters (200-260 ft) are likely to be realised.

Jan 1, 1979

By Charles G. Howard

Accidents involving underground rail transport were analyzed to quantify the magnitude and the operational requirements for individual mine car braking systems. The results showed that the brake preventable accidents represent only 2% of the total underground fatal accidents and less than 1% of the total underground nonfatal accidents. In addition, the brake preventable accidents are expected to decline over the next decade. The costs of accidents involving deaths and Injuries were determined using various well accepted methods. The costs of a brake retrofit program for all operating underground coal cars were developed separately for small and large coal mines. Costs of retrofit brakes, new car brakes, maintenance, inspection and repair facilities were included in the esimates. The analysis showed that a retrofit program would not significantly increase safety, and that the program cost would greatly exceed the corresponding expected benefits.

Jan 1, 1979

Toward the goal of maximizing minerals and metals recovery from domestic resources, the Bureau of Mines, U.S. Department of the Interior, has conducted in situ corrosion studies at the Salton Sea Known Geothermal Resources Area (KGRA) in the Imperial Valley, Calif., to evaluate and characterize materials of construction for geothermal resources recovery plants. General-, pitting, and crevice-corrosion characteristics of 13 commercially available alloys were investigated for periods of 15 and 30 days in seven process environments expected to be found in typical geothermal resources plants. Stainless steel alloy 29.4, Inconel 625, and the Hastelloys G, S, and C-276 were the most resistant to general corrosion, did not pit, and exhibited little susceptibility to crevice corrosion. Stainless steel alloys 430, E-Brite 26-1, and 6X had low general corrosion rates, but pitted and were susceptible to crevice corrosion. Stainless steel alloy 316 L had a low corrosion rate, but corroded intergranularly, pitted, and was susceptible to crevice corrosion and to stress-corrosion cracking. Titanium-1.5 nickel and TiCode-12 had low corrosion rates, did not pit, and were not susceptible to crevice corrosion. Carbon and 4130 steels had high corrosion rates, pitted, and had high susceptibilities to crevice corrosion. The major scale-forming mineral on the corrosion samples in most of the process environments studied was galena mixed with lesser amounts of other minerals.

Jan 1, 1979

Exploration of new resources and development of new equipment and designs are an ever changing facet of mining. New equipment to handle specialized operations is being developed and new techniques for its use explored. One such system is reviewed. Another is a potential system for handling the thinner stray coal seams between the more profitable thick seams. The availability of federal coal leases in the West is reviewed and current planning discussed. Gulf Coast lignites have been of much interest in recent months and are overviewed.

Jan 1, 1979

By L. Keith Hudson

The purpose of this study is to provide data that demonstrates that the Alcoa flash calciner design can be used for the decomposition of AlCl3?6H2O to A1203. Heat and material valance data for calcination provides data on the partial pressure of HCl in the off-gases. Experimentally determined data for the HCl partial pressure, over solutions expected in producing alumina from clay by the hydrochloric acid process, show that HCl can be absorbed from the off-gases into process solutions to effect crystallization of AlCl3?6H2O.

Jan 1, 1979

By Lawrence L. Davis

This paper describes current research by the Bureau of Mines to develop technology for improving efficiency and productivity in metal/ nonmetal mines. The research program addresses a wide variety of problems associated with each of the major categories of mining: underground mining, surface mining, in situ mining, and premining investigations. An overview of the Bureau's research activities is given with emphasis on underground mining. In particular, two innovative and promising concepts currently under development are described: a unique shaft sinking system that uses an impact hammer for rock fragmentation, and a low-profile, portable crusher for underground hard-rock applications.

Jan 1, 1979

By Colleen A. M. Gibbs

On July 30, 1979 New Council on Environmental Quality (CEQ) regulations for implementing the procedural provisions of the decade-old National Environmental Policy Act went into effect. These new regulations replace approximately seventy different sets of agency regulations, providing some uniformity throughout the Federal government in the conduct of environmental reviews and preparation of environmental impact statements (EIS). This attempt by the Federal government at a general improvement in the preparation and quality of EIS's presents an opportunity for the mining industry to evaluate how the EIS process for mining proposals can be expedited. The environmental impact statement is often a key element on the critical path of a major mining project. Preparation of the EIS is ordinarily the responsibility of the Federal agency with primary decision-making authority over the project. Still, the proponent, i.e. the mining company, can play a major role in the process and have a major impact on the timeliness and adequacy of the effort. Typically, the Proponent will conduct (or will hire consultants to conduct) environmental baseline studies of, for example, air quality, wildlife, geology, water quality, vegetation and archaeology. These studies are then compiled into an environmental report and submitted to the agency. The agency verifies the data and incorporates them into the environmental impact statement.

Jan 1, 1979

The construction, commissioning and operation of a continuous pilot-scale selective agglomeration (oil agglomeration) unit are described. This plant has been used to recover fine coal from an effluent stream that is produced by a jig plant which scalps the coal from a New South Wales (Australia) colliery. The reject slurry is extremely fine (66.5% minus 53 um) and has an ash content of approximately 40%. The pilot plant can treat up to 0.3 tonne/h of this slurry, producing average product ashes as low as 9.1% and tailings ashes greater than 80%. The average yield observed was62%, which corresponded to a recovery of coal material of 88%. The operation of this pilot plant yielded data that enabled an economic assessment of this type of processing to be carried out. This study showed that selective agglomeration is an economically viable process for eliminating the substantial losses of coal to tailings ponds and minimizing consequent disposal and environmental problems. A commercial plant has been constructed and commissioned on the basis of the data obtained from this pilot-scale operation.

Jan 1, 1979

By F. Kitzinger

Electromagnetic testing of wire rope has become more and more reliable over the past two decades. This improvement is partly a result of an unprecedented progress of electronic technology, which permitted the development of a new breed of testing instruments. There are two basic methods for the electromagnetic testing of wire ropes, the AC method and the DC method. Both methods rely on magnetic field disturbance caused by mechanical anomalies in the rope structure. The wire rope under test is passed through a magnetic excitation field, which can be a weak alternating field or a strong static field. Because the alternating field is produced by an alternating current, these instruments are of the AC type(l). In the early days of ND-testing, strong permanent magnets were not yet available; therefore, the static magnetic field was produced electromagnetically with direct current. Instruments based on static excitation are still called DC instruments(2), even though the field is now produced by a permanent magnet. Both these methods have certain characteristic features. The AC method can detect loss of metallic area caused by corrosion or other effects, whereas localized faults such as broken wires are better detected by the DC instruments . The basic principles of the wire rope testers have remained unchanged over the years and the improvements present in the new instruments usually reside in the signal processing and recording sections. The Instrumentation Department of the Noranda Research Centre* has been involved in a four-year development program which resulted in a new type of wire rope tester, the Magnographv** . This new instrument in many ways represents a considerable departure from the traditional wire rope testers. The Magnograph has already been patented in Canada and the U.S.A.(3), and patent applications are pending in other countries.

Jan 1, 1979

By Michael F. Werneke

While the use of synthetic polymers for solid/liquid separation is not raw technology (1)(its history goes back to the mid 1950's), its importance has increased dramatically over the past decade. This can be attributed to two major factors. The first of these was a change to mechanized mining (strip mining and continuous underground miners) which resulted in a lower quality (higher reject) preparation plant feed, as well as a higher percentage of smaller size particles in the feed. The second factor has been the greater restrictions imposed by governmental agencies on effluent discharge and solids impoundment, requiring pre-treatment of recirculating water before reuse and treatment of refuse before disposal. Today, synthetic polymers find utility in almost all applications requiring separation of solids from aqueous suspension, including "in-process" as well as waste treatment applications. In spite of the fact that there are over several hundred commercially different flocculants available in the marketplace (2), there are a limited number of chemically different materials available which are useful from a cost/performance standpoint. The potential reasons for using flocculants in a coal preparation plant are summarized in TABLE 1.

Jan 1, 1979

By Anthony Edey

It is a generally accepted and widely discussed fact that the world in general, and the United States in particular, face a shortage of energy at the present time which will become worse in the future. There is, however, no sign of a similar concensus as to the actions which would prevent or overcome this expected shortage. An immense variety of solutions has, however, been put forward, ranging from the purely political to the outer fringes of sophisticated technology. One resource which surprisingly is often only cursorily included in this discussion is the immense known petroleum reserve lying within the United States. When this subject is discussed, indeed, it is usually in the context of the improvements in production or new discovery rate that could be expected to result from possible politico-economic actions that would raise the real price obtained for domestic crude. This interest in the potential for improved domestic production is undoubtedly justified, but very little attention is normally drawn to the fact that even under the most favorable policy framework the majority of the oil that has been, or will be, discovered will remain in the ground due to the inherent limitations of production through surface wells.

Jan 1, 1979

By R. A. Gannicott

Trend surface analysis was used to investigate the geochemical dispersion patterns of Si, Ai, Fe, Mg, Ca, Na, K, Ti and Rb in the footwall of the Seneca massive sulphide prospect in southwestern British Columbia. Surfaces for various element ratios were also produced to see if the distributions of the elements are related to each other. Trends developed by the elements redistributed during hydrothermal alteration may be difficult to detect for various reasons, such as too few and widely separated sample points, random analytical errors or local variations in rock chemical composition that are not related to regional trends. Trend surface analysis is useful to distinguish regional trends from local fluctuations. The computer program used in this study is capable of calculating surfaces up to the 6th degree polynomial, but provides for automatic termination when the variables in the equation for successive surfaces become effectively collinear. With the relatively small number of data points used (21 samples) in this study, such termination occurred after the quadratic surface. Results show that, at the Seneca prospect, Mg and K increase, and Na and Ca decrease, toward a common centre which corresponds closely with the best drill-core intersections of ore. The centre is interpreted as a volcanic vent and as the source of mineralization . Quadratic surfaces for element ratios show that K/Ca decreases and Fe/Mg increases away from this vent. Thin-section and X-ray diffraction analyses indicate that these variations reflect sericitization of plagioclase and an increase in the Mg content of chlorite near the vent. The mineralization , rock types and element dispersion patterns at the Seneca prospect are similar to those reported for volcanogenic massive sulphide deposits at Bathurst, New Brunswick, and in the Hokuroko district of Japan.

Jan 1, 1979

By Dennis W. Leonard

Let us begin our discussion by looking at historical and current levels of sales of both natural and synthetic zeolites on a world-wide basis. Due to the understandable reluctance of some companies to disclose sales data, some estimation has been necessary regarding the tonnages and values shown in Table 1. We are confident, however, that they are within acceptable limits, especially the numbers referring to natural zeolite.

Jan 1, 1979

By R. D. Brown

On November 16, 1978, Finance Minister Chretien delivered his second formal budget in the House of Commons. Over-all, the provisions of the budget should provide moderate stimulus to the Canadian economy. With respect to the mining industry, the budget offers some welcome changes in the form of' improved write-offs for development expenses and social assets; higher investment tax credits; and a reduction in federal sales tax. On the other hand, income bond financing of new mineral ventures may be restricted.

Jan 1, 1979

Measure the leakage through individual crosscut stoppings quickly and economically so that the worst ones can be identified and repaired. (Typically 60 to 80% of the air supplied to a mine short circuits before reaching a working face.) Approach Most of the leakage through a permanent stop-ping is channeled through two windows in a temporary stopping, and air velocities through the windows are measured; leakage is determined from a formula. How It Works A temporary stopping made of plastic brattice is erected in the same cross cut as the permanent stopping, either upstream or downstream. The brattice is fastened to the roof, bottom, and ribs of the entry with spads. Normal leakage of brattice was allowed for in deriving formula, and does not effect results. For best accuracy the brattice and the stopping should be separated by a distance of one hydraulic diameter.

Jan 1, 1979