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By S. M. Bradshaw, R. Smith, J. H. van Vreden, C. A. Snyders

"The re-treatment of gold tailing heaps has shown to be a potentially significant revenue stream for both large and small scale gold companies. Limited access to capital and lack of skilled labour remain restrictive especially when dealing with a refractory ore and/or where limited amount of material are available. Alternative techniques such as low temperature pre-leaching options to unlock value are therefore in demand. Several low temperature pre-leaching experiments in acidic and alkaline solutions, followed by cyanidation were performed which ultimately led to the further investigation of a caustic pre-leaching step. It was found that the Au recovery from a refractory ore tailings heap could be significantly improved from ˜ 15 to 20% to greater than 60% with a simple atmospheric NaOH pre-leaching step. It was further considered, that since the NaOH pre-leach liberate the Au associated with refractory sulphide minerals, the overall process may benefit by the inclusion of a froth flotation step to separate refractory sulphides from the free milling ore. Froth flotation on weathered tailing heaps are, however, known to be difficult, ultimately resulting in poor recoveries. A process flow sheet, incorporating a caustic pre-leaching step and a process which includes flotation and caustic pre-leaching of the concentrate, are technically evaluated and ultimately compared to simple cyanide re-processing. INTRODUCTION South Africa consists of a large number of gold tailings dumps. Janse van Rensburg (2016) estimated that there was about 517 dumps in the Gauteng area, covering approximately 320 000 ha of surface area. Recovering value from the dumps has received a great deal of interest but can be problematic due to the dumps often being refractory, preg-robbing and weathered. High recovery of valuable metals (Au and Ag) are possible (Fleming and Brown, 2010) but would most likely require pressure oxidation and subsequent neutralisation which can be very capital intensive demanding a high skill set to operate and maintain. In addition, these flowsheets target high processing tonnages due to the economy of scales at the lower grade feed materials, further increasing the capital requirement."

Jan 1, 2018

By A. H. Mumin, A. Prikhodko

"This paper provides an understanding of interpreting and evaluating airborne time domain electromagnetic (TEM) surveys as applied to massive sulfide exploration. Variations in the conductive morphologies of massive sulfide ore systems are discussed, followed by forward modelling exercises examining the derived TEM response to these morphologies and discussion of the subtleties of data interpretation. Deposit morphology in the orientation at formation and the variations occurring due to later deformation are considered. Images of corresponding resistivity–depth models are provided. The combined modelling results provide a low-cost method for initial interpretation and screening of TEM anomalies. RÉSUMÉ Cet article nous permet de mieux comprendre l’interprétation et l’évaluation des levés élec-tromagnétiques aéroportés en domaine temporel (TDEM, de l’anglais time-domain electromagnetic) appliqués à l’exploration du sulfure massif. Y sont débattues les variations au niveau des morphologies conductrices des systèmes de minéralisation du sulfure massif, suivies d’exercices de modélisation prospective qui examinent la réponse dérivée des TDEM à ces morphologies et d’une discussion sur les subtilités de l’interprétation des données. L’étude envisage la morphologie de l’orientation originelle non déformée des gisements ainsi que les variations résultant d’une déformation ultérieure. Des images des modèles correspondants de résistivité-profondeur sont fournies. Les résultats combinés relatifs à la modélisation proposent une méthode peu onéreuse d’interprétation et de contrôle initiaux des anomalies dans les TDEM.INTRODUCTION Electromagnetic geophysical surveys are an indispensable foundation of many mineral exploration programs and can account for as much as half of the predrilling exploration costs. Quantitative mass interpretation of the survey results remains difficult due to the infinite variation of deposit morphologies, their complex physical properties, and the presence of barren conductive materials that can mimic or mask the response of targeted ore. Many modern geophysical investigations that focus on time domain electromagnetic (TEM) data interpretations are devoted to problems with inversion and modelling and their algorithms. Although a few of these investigations have resulted in commercial software products, these require highly qualified and experienced users and usually include geometric assumptions. Furthermore, without the input of known physical properties and geometric constraints, the inversion results are highly ambiguous. A number of case studies document the geophysical responses to known targets in well-defined and diverse geo-electrical environments, providing a high degree of correlation between field obser-vation and the results of the modelling used in this style of investigation (Hone, 1980; Schneider & Emerson, 1980; Tyne, Idnurm, & Malone, 1981; Bishop & Lewis, 1992; Hopgood & Hungerford, 1994; Meju, 2002; Yang & Oldenburg, 2016). The uniqueness of the target/environment parameters and their specific features limits the use logy is poorly understood. The responses are therefore that are devoid of complicating environmental factors (e.g., highly conductive overburden and hostrocks or nonuniform target conductivity) as a first approach to the interpretation process of such case studies as the main reference for interpreting TEM survey responses in areas where the underlying geomodelled from generalized and typical geological models"

Jan 1, 2018

By W. D. Guo, Y. M. Zhu, B. B. Luo

The main chemical constituents of waste cooking oil are higher fatty acid glycerides, which can be used to produce anionic fatty acids for most non-sulfide flotation. However, using the mixed fatty acids (MFA) produced by waste cooking oil as collectors directly, the flotation effect is usually not satisfactory, especially at lower temperature or room temperature. There are very rare systematic studies about the reason for poor flotation performance of waste cooking oil. This study aims to investigate the flotation and adsorption characteristic of different types of fatty acids in waste cooking oil to find out what kind of fatty acids results in the poor flotation performance. This will provide technical supports and theoretical guidance for the waste cooking oil application in the field of mineral processing. In this study, MFA were produced from the waste cooking oil, and then separated into saturated fatty acids (SFA) as well as unsaturated fatty acids (UFA), which possessing different flotation properties. The properties of the MFA, SFA and UFA were analyzed by iodine value, melting point measurement, Fourier transform infrared (FT-IR) spectroscopy and quartz micro-flotation tests. The results showed that UFA was composed of fatty acids containing group—(CH=CH—CH2)n—, having an iodine value of up to 162.90, a melting point as low as -17.3 ? and stronger low-temperature floatability. In contrast, the SFA was made up with saturated fatty acids and a few oleic acids, with an iodine value of 48.97 and a melting point of 38.8 ?. SFA had shown poor collectability and required a flotation temperature higher than 35 ?. The results of zeta potential measurements, solution chemistry calculation and FT-IR spectra revealed that both UFA and SFA can be adsorbed on the quartz surface activated by CaCl2 via the chemical and hydrogen bonding. The reason MFA having a poor flotation performance is the SFA has an extremely high melting point which affecting the dissolution of the dispersion.

Jan 1, 2018

By J. Kwon, D. Lee, H. Cho

"The use of the combined grinding and liberation model to predict liberation characteristics of iron ore comminuted by a ball mill was studied. Comminution characteristics were obtained using the one-size fraction method. The iron ore samples were crushed and separated into a number of narrow size fractions by screening. The size fractions were further divided by magnetic separation into three classes: concentrate, middling, and tailings. Subsequently, various size-grade classes were subjected to ball milling, and the results were analyzed in terms of the kinetic grinding model. The mineralogical textures of the grinding products were analyzed using mineral liberation analysis. The distribution of iron content within the size fractions was characterized by the beta distribution combined with the Andrew–Mica diagram. It was found that the grinding characteristics of the iron ore samples varied slightly with the iron content. However, the liberation characteristics were well described by the same set of liberation model parameters, regardless of composition. The variation in grinding kinetics with composition and the liberation model parameters was used in the combined comminution–liberation model to predict the evolution of the size-composition matrix as grinding proceeded. The predicted results agreed well with the experimental results. The developed model can be used to construct the yield–recovery graph and to calculate the liberation efficiency to determine the size reduction threshold for efficient separation. INTRODUCTION In mineral processing, comminution is usually the first step that ores undergo to liberate valuable minerals from gangue minerals. Generally, as the particle size decreases, higher liberation can be achieved. However, excessively small particles are unfavorable to subsequent processes, such as separation. Moreover, comminution is a highly energy-consuming process itself that accounts for approximately 60% of all energy used for processing. Therefore, there is a definite need to increase energy efficiency by applying adequate stress so that a high degree of liberation can be acquired at the coarsest size without overgrinding. To this end, it is essential to develop a model to predict the liberation of minerals as a function of size reduction."

Jan 1, 2018

By U. A. Peuker, T. Mütze, F. Shayo, A. Wikedzi

"Buzwagi Gold Mine (BGM) is operated by Acacia Mining and located in the Lake Victoria Goldfields of central Tanzania. The mine treats a sulphide copper-gold ore to produce gold in form of doré bars and a concentrate containing gold, copper and silver. The BGM comminution circuit includes a primary crushing stage with a gyratory crusher and two grinding circuits using a Semi-Autogenous Grinding (SAG) mill and a ball mill. Currently, the grinding circuits are inefficient in achieving the aspired product fineness of xP,80 = 125 µm even at low to normal throughputs (450-600 t/h). An optimization study of the circuit performance was conducted to improve product fineness through circuit surveys, experimental lab work and simulations. The analysis of survey data revealed inefficient grinding operation characterized by ball mill product (xP,80 > 400 µm) coarser than designed and higher hydrocyclone cut sizes (xT > 200 µm), too. In MODSIM several options were simulated such as reduction of vortex finder and apex diameters, reduction of SAG screen aperture, and modification of cyclone feed density. An improvement of product fineness could be achieved by simulation of the cumulative changes but it was also concluded that the current equipment cannot achieve the target. Further simulations showed that a second ball mill might help to achieve the desired fineness as well as an increase of grinding throughput by up to 26 %. INTRODUCTION Simulation of comminution, particularly grinding and classification, has received great attention for many years, due to the fact that the unit operation is by far the most important both in terms of energy consumption as well as overall plant performance (King, 2001; Wills et al., 2006). The use of simulation is advantageous due to low cost as well as its ability to consider many variables simultaneously. Moreover, there are some benefits for optimizing grinding operations by simulation like decreased unit operating costs, increased capacity, and improved performance of downstream processes due to improved feed size distribution. This paper presents an optimization study for the grinding efficiency at Buzwagi Gold Mine. This was achieved through three full scale circuit surveys, lab work and simulations with MODSIM."

Jan 1, 2018

By Federico Pagliacci, Marco Chiarabelli, Salvatore Miranda

The paper describes the adopted technologies and performance controls related to a special geotechnical engineering solution provided within the scope of the Galataport Project, in Istanbul, Turkey. The scheme is the one applied to the new quay of Salipazari, which is a combination of retaining structure and ground improvement, formed by a combi-wall, a reinforced concrete diaphragm wall and a soil improvement by deep soil mixing (Turbojet). The paper highlights the importance of employing cutting-edge technologies within the foundation engineering field and state-of-the-art electronic control devices, in parallel with the essential human expertise, in order to obtain the desired results in this high profile Project. The results of the in-situ and laboratory tests carried out on the improved soil are also presented. Main discussed points are: • History of Galataport and main Project details. • Design principle and soil condition for the new quay of Salipazari. • Difficulties encountered during execution of DSM. • Preliminary field trial tests conducted to establish the operational parameters, with relevant in-situ and laboratory tests executed. • Preliminary tests on material used for DSM (seawater and CEM IV SR). • Electronic equipment mounted on the rig, which allows the automatic execution of DSM columns. • Final QA/QC tests conducted to verify the performance of DSM, mainly consisting in: coring with relevant laboratory tests on samples (UCS + Es), seismic refraction tomography and seismic cross hole tomography. Correlations between UCS and Es, and between Es and Edyn are also presented. • A cross section of the executed treatment could be inspected on site during excavation. Photos and considerations are also presented.

Jan 1, 2018

By Wenqing Qin, Yunfan Wang, Ximei Luo, Fen Jiao

In order to investigate the effect of nanobubbles on adsorption of surfactant on mineral surface, the nanobubbles on the surface of calcite with -37µm fraction in the sodium oleate system were controlled by pressurization and decompression to mixing vessel. Subsequently, the adsorption amount of sodium oleate on the surface of calcite were detected by ultraviolet spectrum at different stirring times and different pressures. At the same time, the nanobubbles on the calcite surface were imaged with atomic force microscopy (AFM). In addition, a homemade vacuum Hallimond tube device was used for the flotation of single mineral, and the grade and recovery of minerals in concentrate was used to determine the influence of the nanobubbles on flotation. The experimental results showed that a large number of nanobubbles were found on the calcite surface by AFM under the dissolved oxygen difference (DOD) condition of -4 mg/L. And a large difference in adsorption capacity of sodium oleate on the surface of calcite was observed under different air pressure conditions. It indicated that the ambient pressure had a certain effect on the adsorption of sodium oleate on the calcite surface, and this effect did not depend on the constant low pressure or constant normal pressure, but depended on the changing process of pressure. The single mineral flotation experiment results indicated the recovery of calcite under decompression condition (formation condition of nanobubbles) was 1.5-2 times that under constant normal pressure, and the flotation time is much shorter. Moreover, the recovery under constant normal pressure was greatly influenced by flotation time. In this paper, only one aspect of the effect of nanobubbles on mineral flotation was preliminarily explored. It was confirmed that after vacuum-pumping, the adsorption of sodium oleate on calcite surface could be increased, the flotation time also was greatly reduced and the recovery of calcite was increased.

Jan 1, 2018

By Chen Jianhua, Shen Zhenchang, Zhang Ming, Chen Feifei

"With flotation cells scale-up, the performance of flotation cells is increasingly variated for short-coming and dead zones existing. The residence time distribution which shows the movement of tracers can assess the unexpected flows such as short circuit and dead zone in a flotation cell. In this paper, the residence time distribution of pilot flotation cell is investigated with CFD simulation. Based on the theoretical model, the short-coming probability and dead zone probability are quantitative. The ideal average residence time is similar with the actual average residence time. The mixing effect of the flotation cell approaches the ideal continuous stirred tank reactor. The operating parameters such as speed and feed velocity have complicated influence on residence time distribution. The research would be helpful to understanding flow in flotation cell and improving performances of flotation cell.INTRODUCTIONFroth flotation is a method which purifies minerals according to difference of physical and chemical surface characters of different mineral particles (Shen, Z., Chen J, 2012). Flotation cell is a key equipment for froth flotation method. The flotation cell performances have great influences on flotation index.It is difficult to evaluate flotation cell how to improve flotation procedure to complexity.The main flotation cell performances are aeration volume, air dispersion, solid suspension and residence time distribution, etc (Shen, Z., Lu, S., 2008). Residence time distribution is an important fluid hydrodynamics which could reveal the flow of pulp, mixing of particles and air bubbles. In the flotation cell, the ideal average residence time of pulp could obtain easily. But the fluid differential units would be different flow paths. The residence time of the fluid differential units is variation and would be longer or less than the average residence time. The residence time distribution would reveal the mixing effect and predict the not ideal flow in the flotation cell such as shorting cutting, dead zone, etc. As we know, the shorting cutting and dead zone would be decreased the real flotation time and it is disadvantage to better flotation effect, especially for large flotation cell. It is impossible to eliminate the not ideal flow totally. It is very important to reveal and decrease the shorting cutting and dead zone probability in the flotation cell."

Jan 1, 2018

By B. Li

"Sepiolite is a magnesium-rich, porous, and fibrous clay mineral with broad applications. These applications take advantage of sepiolite’s high specific surface area and unique nano-sized channel structure. Over the past years, numerous materials and techniques based on the structure and property of sepiolite have been developed. This article reviewed the recent achievements in developments and applications of sepiolite in environmental protection, catalysis area, and nanocomposites. The prospectives of sepiolite applications is also discussed. INTRODUCTION Sepiolite is a magnesium-rich, porous, and fibrous clay mineral. The typical chemical formula of sepiolite is Si12Mg8O30[OH]4[OH2]4·8H2O [1]. Sepiolite has a high specific surface area and nano-sized channels because of its special structure [2]. This unusual crystal structure projected onto the [001] plane is shown in Fig.1 [3]. As it can be seen, silicon and oxygen atoms make up for the tetrahedral structure and magnesium and oxygen atoms form octahedral structure, respectively. Those tetrahedral-octahedral-tetrahedral ribbons expand boundlessly in one direction, leading to the special fibrous structure of the sepiolite. Every tetrahedral-octahedral-tetrahedral ribbon is combined to the next by an inverted Si–O–Si bond, which causes an interlaced layer with a continuous tetrahedral sheet and a discontinuous octahedral sheet. Terminal MgO at the edges of the ribbons is coordinated with two structural water molecules, which can form hydrogen bonds with zeolitic water molecules that are located in the channels running parallel to the fiber axis [3,4]. The Mg2+ ions inside the channels can be exchanged with other cations in solution. Therefore, sepiolite can be used to remove metal cations from aqueous solutions [5,6].It can be seen from Figure. 1 and Table 1 [7], the unique structure endows sepiolite with a substantial surface area and nanoscale channels. Its specific surface area reaches 320 m2/g and channel dimensions up to 3.7×10.6 Å. There are three active adsorption sites on the surface of sepiolite: one is oxygen atoms of the Si-O tetrahedron. The second is the structural water molecules paired with magnesium ions at the edges of the ribbons, which can form hydrogen bond with adsorbent. The last one is the Si-OH groups due to the breaks of the Si-O-Si bonds on the surface of Si-O tetrahedron. Thus, sepiolite has strong adsorption ability which has been widely used in environmental protection. Moreover, sepiolite has many significant features such as good mechanical and thermal stability, rheological property, porous, and easily modification, making it be a hotspot in chemical and biological researches. However, with the development of technology, broader and more advanced applications of sepiolite have been carried out in recent years. In this study, the recent achievement in sepiolite applications is summarized, the further tendency is also discussed."

Jan 1, 2018

By A. V. Myaskov, V. S. Valavin, K. D’Elia, I. O. Krylov, Vu Van Toan, T. I. Yushina

"The purpose of this research is the development of a technology for processing the concentration tailings of limonite ores at Kamysh-Burun Mining and Processing Complex into an iron- containing product for ROMELT process. In the concentration and metallurgical processing of iron ores, substantial amounts of waste are generated (tailings, slimes, slags, metallurgical dust, etc.) that can be converted into a commercial product if is properly processed. This article presents the results of experimental studies of the feasibility of processing iron- containing tailings of Kamysh-Burun deposit (slimes from Verkhne-Churbash storage facility (VCh sample) and dumped waste of Kamysh-Burun (KB sample)) to obtaining valuable components for further uses. Applying Mossbauer spectroscopy has been shown that the iron minerals in the studied samples are technogenic varieties of iron hydroxides. The most suitable technology is the magnetic roasting process, since iron hydroxides are easily transformed into a magnetic, easily recoverable form. Have been shown the advantages of a two-stage magnetic separation, in a strong field and with polygradient separators. Concentrating this material through magnetic methods makes it possible to increase the iron content to 20-21 %. Magnetic concentration of the deeper layers materials results in iron- containing concentrates with a total iron content of up to 58% whit a phosphorus content of about 2%. Reducing the phosphorus content is possible by blending upper and lower layers of the material at a ratio of 1:1. Thus, it is possible to process the material accumulated in the slime storage facility using the ROMELT process combined with preliminary three-stage magnetic concentration and disposal of tailings with the permissible iron content of less than 5%. Wastes from smelting will be slags suitable for use in construction industry. The Kamysh-Burun material preparation for ROMELT process should be performed applying gravity-washing with separation of the -0.4 mm fraction and additional blending for dephosphorizing the concentrate. The smelting will produce pig iron and slag."

Jan 1, 2018

By A. Morrison, P. Brito-Parada

"The separation of valuable and gangue minerals according to their surface hydrophobicity in a froth flotation tank occurs in both its pulp and froth phases. In the pulp phase, hydrophobic particles must be brought into contact with rising bubbles introduced at or near the bottom of the tank. In a mechanical froth flotation tank, this is primarily achieved through the agitation of the pulp by an impeller or by a rotor-stator system. However, the turbulent and mixing effects of such an impeller or rotor-stator system, necessary to promote bubble-particle interactions in the pulp, are not confined to the pulp zone, but are transmitted into the froth zone at the pulp-froth interface. This impeller-induced turbulence at the pulp-froth interface is compounded by the impulse of buoyant bubbles entering the base of the froth phase, reducing the stability, and thus separation performance, of the resulting froth. Hence, turbulence improves separation performance if it occurs deep in the pulp phase, but diminishes it if it occurs close to the pulp-froth interface. For this work, a performance-enhancing pulp phase insert was designed to isolate the impeller-induced turbulence from the pulp-froth interface in a laboratory-scale, continuously-operated froth flotation tank. The result was a shifted grade-recovery curve that allows the insert to be designed to maximize the recovery from the system without sacrificing the grade of the concentrate, or vice versa, along a spectrum of improved performance. This paper will present the insert design and development process that resulted in this improved grade-recovery curve, as well as a set of heuristics that could be used to design a similar insert for pilotand industrial-scale validation and deployment.INTRODUCTIONAn almost ubiquitous design feature of commercial flotation tanks is the enclosure of the impeller to create a concentrated turbulent zone (Mavros, 1992). These turbulent zone enclosures are varied-- from the rotor-stator design of, for instance, Outotec cells, to the air disperser design of Wemco cells-- but all share the same rationale: that turbulence is desirable to promote bubble-particle interactions (Ralston, 1999), and to produce smaller bubbles (Wills, 2006), but also undesirable because it promotes the detachment of valuable mineral particles from bubbles, and exacerbates entrainment-inducing mixing at the pulp-froth interface (Jameson, 2010)."

Jan 1, 2018

By Ivar Eskerud Smith, Ole Jørgen Nydal, Niranjan Reddy Challabotla, Svein Sævik

INTRODUCTION Airlift pumping, utilize compressed air that is injected at the bottom of a vertical pipe submerged in the water, reduces the mixture density inside the pipe and lifts the liquid or mixture of liquid and solids. This type of pumping technology, which is simple and without moving parts submerged in water, which provides several advantages compared to the mechanical pumping. Airlift is used in various difficult pumping applications such as transport of fluids corrosive to metals, explosives, nuclear and toxic materials in chemical industries, diamond mining and coal transport. Application of airlift to deep sea mining conditions was investigated by extensive laboratory experiments [1], theoretical analysis [2], and limited proof of concept field studies [3] starting in 1970’s with the discovery of huge amounts of manganese nodules discovered on the seabed at a depth of ranging from 4000 to 6000 m . Even after extensive investigations over the last five decades, there exists no commercial application of airlift technology for lifting of minerals. The major problems with the application airlift for deep ocean mining was (a) lack of control over the expansion of the injected gas, which increases the velocity in upper part of the riser pipe (b) lower efficiency compared to mechanical pumping [3]. Different flow regimes are encountered in airlift pumping: bubble, slug, churn and annular flow. Annular flow regime is the least efficient in lifting of particles and churn flow has better efficiency [3].

Jan 1, 2018

By V. K. Kuppusamy, M. Holuszko

"Lamps and lighting products are the most commonly used electrical products around the globe. With the improvement in lamp technologies, lighting products have grown complex and hence require an improved recycling process. The LED lamps consist of various valuable metals such as iron, copper, aluminum, chromium, silver, and gold, as well as non-metals such as glass, plastics, and fibers. In addition, there are also traces of hazardous substances such as lead, arsenic, and mercury. A major step in the recovery process is size reduction, and researchers have suggested that up to 40% of the total valuable material is lost during the shredding and grinding processes. SELFRAG is a high voltage selective fragmentation comminution technology that uses high voltage pulses in a water medium to efficiently separate the metals at a coarser size without generating many fine particles. It has been proposed that during the fragmentation process of electronic waste (e-waste), the metals can be separated without fine grinding. This research considers the applicability of high voltage pulse fragmentation for LED lamps. Eight different types of LED lamps were processed through the SELFRAG unit at varying pulses to study metal liberation. The product obtained was characterized for metal liberation, metal grades, and liberation analysis. The specific energy consumption for this size reduction process was also monitored. INTRODUCTION Lamps and bulbs are the most commonly used electrical products in homes, offices, industrial operations, and streets. According to Energy Star research (2006), an average US household has more than 40 sockets for light bulbs and consumes approximately 2100kWh every year for lighting. The development in lamp technology has pushed the boundary for newer products. The LED lamps have been taking over the market from the incandescent bulbs and compact fluorescent lamps (CFL). According to the US Department of Energy (2012) and myLEDlight.com (2007), LED lamps have several benefits over other lamps. LEDs produce light hemi-spherically, which increases their efficiency in directional light emission. It has higher breakage resistance from vibration or transportation. LED lamps use up to 90% less power than incandescent bulbs thus making them highly energy efficient; They have a longer lifespan, lasting 10 times longer than a CFL and 133 times longer than the traditional incandescent bulb. Because of all the benefits, Smallwood (2014) suggested that the market of LED lamps will grow to $12.2 billion by 2018."

Jan 1, 2018

By E. Guerrini, M. Maccagni, J. Nielsen

"Lead is the most important material able to meet the current demand for energy storage. The lead acid battery is reliable, efficient and inexpensive. Continuous developments in battery construction are providing improvements in all aspects of the batteries’ performance. The lead acid battery is both the main lead product and the main raw material for lead production. More than half of the lead produced is from secondary smelters where batteries are the most important feed material. The environmental pressure on lead production has been increasing for many years, and continues to become stronger and stronger. The lead production processes and technologies themselves will require updating to meet the new regulations. Although they are very strict now, they will become even more so and current technologies may not be sufficient. Because recyclability is a strong point for the lead acid battery, the secondary smelters need to reduce the environmental impact as much as possible. In recent years, the secondary smelters underwent impressive changes in this direction, but some more improvements are possible. Electrochemistry can offer a step change improvement in making secondary lead production more environmentally friendly. Engitec has developed an electrochemical process base on a very high current density (high productivity) cell using an inexpensive electrolyte and at a relatively low cost. In this paper, the latest update on the technology is provided. INTRODUCTION The lead acid battery is considered the “walking dead” by some new technologies trying to replace it. It has played and will continue to play a very important role in our lives because it is inexpensive, fully recyclable and the existing lead and the mine reserves guaranty enough material for the extended future. According to the life cycle, the lead acid battery is the cheapest and the most effective system to store energy. Lead is practically a close loop where lead battery production consumes more than 80 % of the produced lead but contemporarily it is the most important raw material for the production of metallic lead. In fact, nowadays, the secondary production has overcome primary production and this trend is expected to continue. Primary lead is the make-up material for the existing battery production and the source of lead for the construction of the new ones."

Jan 1, 2018

By M. McClintock

"High Pressure Grinding Rolls (HPGR) is increasingly being chosen for comminution circuits for its energy-efficiency for hard rock mining operations. Despite HPGR’s growing popularity, geo-metallurgy programs are still prohibitively expensive because of large sample requirements. Traditionally, sizing HPGR application requires a significant amount of sample, in the order of 1 to 10 tonnes, depending on the level of study and complexity of the resource. Therefore, engineering and design of HPGR circuits typically are reliant on few composites that are required to be representative of the resource and mine plan. Three bench scale HPGR test methodologies were developed in 2015 at NBK Institute of Mining Engineering at the University of British Columbia (UBC) capable of defining the energy size breakage relationship of pilot HPGR. These methodologies were developed to allow bench scale testing for different levels of study from PEA (Preliminary Economic Assessment) to detailed design and operations. The Piston Press test defines the energy size reduction relationship by measuring specific energy consumption and corresponding feed and product size distributions. The advantage of Piston Press testing is the small sample requirement of 5 to 10 kg. Small sample requirements allow multiple samples to be tested across a deposit. Piston Press testing allows extensive geo-metallurgy programs that can determine ore variability and inform in optimization and production planning. To date, the Piston Press methodologies have been validated on a pilot-scale HPGR unit located at UBC. Recently, testing was conducted to calibrate and validate the Piston Press test against full-scale HPGR on a gold sulphide ore deposit. The program included the collection of operational data with the respective HPGR feed and recycle sample. Sample collected was used both for Piston Press testing and HPGR piloting. This paper discusses the test-work and results as carried out during this program, using the aforementioned methodologies."

Jan 1, 2018

By Jeff Jackson, Paul Axtell, David Graham

The Montana Department of Transportation recently awarded a contract to construct a replacement bridge across the Clark Fork River in Heron, MT. Both abutments and both intermediate bridge bents were to be founded on 6-ft and 8-ft diameter, permanently cased drilled shafts with rock sockets, respectively. Two drilled shafts per substructure location were designed for a total of eight drilled shafts. The original design included 6-ft diameter drilled shafts at the abutments but the Contractor elected to submit a Value Engineering proposal that increased them to 8-ft diameter. On the basis of the subsurface exploration program, extremely challenging subsurface conditions were known to exist, including the potential presence of large boulders within the predominantly sand and gravel soil matrix. The successful bidder elected to use an oscillator to install the permanent casing to the top of bedrock, while simultaneously removing the spoils from inside the casing with a clam-grab. On seven of the eight shafts, this approach worked well. Unfortunately, on one of the shafts, the casing met refusal on one or more boulders encountered in the predominantly sand and gravel soil overburden. Following several attempts, and despite several variations of approaches, it was determined that the casing could not be advanced beyond the obstruction without unacceptable risks to the pile-supported temporary work trestle (i.e., loss of soil and reduction in pile capacity for the foundations supporting the work trestle). To mitigate the problematic drilled shaft, a unique solution was designed and successfully constructed. The solution involved the construction of seven 16-in diameter micropiles constructed within the confines of the obstructed casing. The micropiles were drilled to bedrock through the sand, gravel, and boulders and include rock sockets to satisfy axial design requirements. The micropile casing thickness, grade and grout strength were designed to provide adequate flexural strength as well as to satisfy other design requirements. Upon completion of the micropile installation, the upper portion of the drilled shaft above the boulders and within the permanent casing was constructed as usual. This paper discusses the difficult subsurface conditions at the site, the drilled shaft construction difficulties, and the design and construction of the micropile solution.

Jan 1, 2018

By D. Vega, P. R. Brito-Parada

"Small diameter (10 mm) hydrocyclones have been applied successfully for the separation of particle suspensions in the micron size range. These hydrocyclones are attractive because they show a bypass fraction larger that the water recovery, resulting in a high particle recovery to the underflow as well as low water recovery. However, this is a disadvantage when the purpose of the hydrocyclone is classification because of the large amount of fine particles that are misplaced in the underflow. The aim of this study is to explore, experimentally and computationally, the influence of design parameters on the classification process. In this work, a full factorial experimental design was defined to carry out comprehensive experimental tests using glass beads (0-20 µm) as the particulate system. We show that the dimensions of spigot and vortex finder diameter can be effectively manipulated to change the separation performance of the system and the energy consumption. A CFD model was developed that is able to predict particle size distribution. The numerical results for the partition curves showed very good agreement with the experimental data. INTRODUCTION Small diameter hydrocyclones are a very attractive separation technology for fine particle suspensions. Since the hydrocyclone diameter is directly proportional to the cutsize that can be achieved, 10mm hydrocyclones have been shown to be very effective in collecting particles in the micron-size range. In addition, while in large hydrocyclones the bypass, i.e. the fraction of particles that report to the underflow without classification, is similar to the water recovery, in 10mm hydrocyclones the bypass fraction is considerably larger than the water recovery. Its high particle recovery and low water recovery makes small hydrocyclones ideal for ultrafine particle classification and dewatering applications in mineral processing. The separation of mineral suspensions achieved using small hydrocyclones has been the focus of various studies. Pasquier and Cilliers (2000) derived a general classification model from experimental data of fine silica concentration in 10mm hydrocyclones; the model was able to describe the fish-hook partition curve. The effect of operating conditions has also received some attention in the literature. Cilliers et al. (2004) showed that an increase in temperature positively effects the recovery of fine silica particles in small hydrocyclones, by increasing the bypass and decreasing the cutsize. Neese et al. (2015) showed that the cutsize in 10mm hydrocyclones can be further decreased by operating at higher pressure, which also trebled the throughput."

Jan 1, 2018

By R. F. Favreau, Patrice Favreau

In many quarries and construction sites visited by the authors over the last 50 years, the latter have observed muck piles from blasting with explosives, which included numerous large blocks, in some cases of dimensions larger than the input to the crusher. The names of these sites cannot be given in the article because the owners insist that data obtained on such visits be kept confidential. Often the blasters felt that the natural fissures in the rock would compensate for the use of a low powder factor, and they asked the authors to explain why such blocks were present. A detailed analysis of the situation often indicated that the cause of the blocks is that explained by figures such as 6 and 7 below in the article.

Jan 1, 2018

By Kazutoshi Haga, Atsushi Shibayama, Altansukh Batnasan

"The aim of this study was to develop a hydromellurgical processing for removal of arsenic from high-arsenic copper sulfide ores and concentrates, providing increase in copper recovery. In this study, three different enargite ore samples containing 28.2–46.7% copper, 1.9–15.0% arsenic and 10.6–27.5% iron were used to determine optimum conditions for the extraction of copper and removal of arsenic. High pressure oxidative leaching process was preformed using various leaching reagents such as sulfuric acid (H2SO4), ferric sulfate (Fe2(SO4)3), hydrochloric acid (HCl), ferric chloride (FeCl3), sodium sulfate (Na2SO4), sodium chloride (NaCl) solutions and distilled water (DW), respectively, under the fixed conditions which were selected to be as follows: NaCl concentration, 0.34 M; concentrations of other leaching reagents, 0.1 M; particle size, -45 ?m; pulp density, 100 g/L; agitation speed, 750 rpm; leaching temperature, 160 ?C; leaching time, 60 min and total pressure (oxygen gas and vapor pressure) into an autoclave, 1 MPa. Results show that under the leaching conditions, more than 90% of copper leaching was achieved with lower than 2% arsenic content as a consequence of the formation of arsenic precipitates in a solution of Fe2(SO4)3–NaCl. It was determined that copper, arsenic and iron concentrations in the pregnant leach solution were 42 g/L, 0.3 g/L and 0.3 g/L, respectively. As a result, it can be concluded that the Fe2(SO4)3 solution in the presence of NaCl or FeCl3 are more efficient leaching media compared to other leaching agents under the high pressure oxidation conditions, because of their high copper recovery and lower arsenic level in the pregnant leach solution.INTRODUCTION Generally, copper is usually produced from copper sulfide ores by a combination of several processes which are flotation and smelting followed by refining [1-3]. Arsenic content in copper sulfide ores tends to increase due to the depletion of high grade copper deposits, hence conventional mineral processing and metallurgical processes cannot effectively treat these ores containing high levels of arsenic to obtain consistently high purity copper concentrates. Because high levels of arsenic in copper ores/flotation concentrates reduces the value of concentrates due to the restriction of smelting process and causes it to be a source of environmental pollution [4-6]. From this point of view, the known way of prevention against high-arsenic copper sulfide concentrates in further metallurgical treatments is to develop economically and environmentally competitive technologies for removal of arsenic impurity from copper sulfide ores before treating the ores/flotation concentrates by the pyrometallurgical routes."

Jan 1, 2018

By V. A. Zhilina, I. V. Shadrunova, O. E. Gorlova

"The aim of the study is to develop and scientifically justify a new adaptive approach to the separating processes of deep and complex processing technogenic mineral raw materials. Technogenic mineral resources as a waste of mining and processing industry are mostly complex objects that have specific features of material composition and technological properties and make it processing ineffective with traditional schemes of mineral raw materials enrichment. Mineral wastes are regarded in this study as a complex object with a large number of signs in conditions of uncertain environment and object. However, adaptation is regarded as the process management system’ adaptation to the specific the properties of the object and the environment that has several hierarchical levels corresponding to different stages in the management of complex object. An adaptive approach is considered as a methodological basis of multivariate schemes for opening the mineral resources and creating mechanisms that could transfer these potential technogenic resources to the actual that significantly expand the mineral resource base of the country's black, coloured, rare, noble metals and construction materials. In this case, potentially the solution to the most pressing social and environmental problems associated with the adverse effects of past economic activity simultaneously with the commercial objectives. This approach to the wastes mining and related processing manufacturers meets the core idea of sustainable development as the balance of interests of State, society, business, private enterprise and each person in the areas of rational use of resources, economic efficiency and environmental safety. On the example of metal-containing raw materials in the form of slags of ferrous and nonferrous metallurgy, ferrous metallurgy sludge, mature fine tailings, the application of adaptive approach illustrates to the development of technologies of its deep and complex processing as phased, thoughtful movement from a comprehensive study of technogenic raw materials to build optimal topologies of technological schemes for processing the mineral wastes. INTRODUCTION Involving the Russian economy in the system of global economic relations significantly changes the nature of the country's competitiveness in the development of the world market and urgently requires competent management of its own natural and mineral resources. The latter at the present time in real economic processes cease to be a passive material foundation and become the producing basis in the production processes in the status of so-called natural capital. Introduced in the field of economic theory at the end of the 20th century, this term means both the flow of natural services and real natural resources. Consequently, natural objects, which act as natural resources of a certain production, today must necessarily be evaluated in a strategic sense. Modern standards of sustainable development presuppose that the economy should equally be oriented to balance the interests of the state, society, business, individual enterprise and each person in the spheres of rational use of resources, preservation of healthy ecosystems, ensuring well-being, high quality of life and environmental safety of not only the current generation, but also respect for the rights of future generations, that is, intergenerational equality. Most types of minerals are classified as non-renewable resources, therefore resource-saving in the sphere of mineral and raw materials complexes is one of the most important factors-indicators characterizing the degree of approximation to the model of rational subsoil use, and, consequently, sustainable development (State Report, 2017)."

Jan 1, 2018