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By H. Y. Sohn, M. Y. Mohassab-Ahmed

"As part of research to develop a novel flash ironmaking process using reduction of iron ore concentrate by natural gas or hydrogen, sulfur and phosphorus distribution ratios between MgOsaturated slag and iron were determined in the temperature range 1550-1650°C under three different gas atmospheres: H2/H2O, H2/H2O/CO/CO2, and CO/CO2. The distribution coefficients of sulfur (Ls) were 4.0, 2.0, and 0.8, respectively, under these atmospheres. The distribution coefficients of phosphorus (Lp) were, respectively, 8, 17, and 20 under these atmospheres. In the flash process over -25 wt% P and S volatilize during ore concentrate downward flight in the reactor shaft in addition to avoiding coke. Therefore, iron produced by the flash ironmaking process would have much lower sulfur contents than the typical hot metal produced by the BF.IntroductionGiven the issues related to large carbon dioxide emissions and energy consumption in the existing ironmaking technologies, a novel flash ironmaking technology was conceived by Sohn [1-3] at the University of Utah. This technology is the first ironmaking process that will convert iron ore concentrate directly to metallic iron in-flight. This process will produce iron directly from concentrate without requiring pelletization or sintering and avoid the need for coke. In addition, this process concept takes full advantage of the fine particle size of concentrate with a large surface area, which permits rapid reduction by a gas. In this novel ironmaking process, potential reductants and fuels are H2, natural gas, and coal gas. Therefore, an iron-slag bath is expected to be at equilibrium with gas atmospheres of mainly H2/H2O or CO/CO2/H2/H2O, respectively, corresponding to the use of H2 or natural gas/coal gas. Since the effects of an H2O- containing atmosphere on slag properties have not been studied before, it is critical for the development of the novel flash process to determine these effects. In H2-H2O-CO-CO2 gas mixtures under ironmaking conditions, H20 was found to have the most pronounced effect on the slag chemistry [ 4, 5]. In addition, it was found in this laboratory that water in the gas atmosphere affected the distribution of Mn between slag and molten iron [6]. Most previous work used CO/CO2 gas mixture to control oxygen partial pressure (p02) [7, 8]. Others used only inert atmospheres [9], although Kor and Richardson [10] used a mixture of C02/H2 to control p02. For phosphorus, previous research focused on Ar [11], Ar-CO mixture [12], CO [13], CO/CO2 [14] or N2/CO [15]. Therefore, it was necessary to investigate the effect of water vapor content in H2-H2O-CO-CO2 mixtures on the equilibrium distribution of sulfur and phosphorus between CaO-MgOsatSiO2-Al2O3-FeO- MnO (0.2-0.8 wt%)-P2O5 (0.1-0.9 wt%) slag and molten iron as part of the development of the novel flash ironmaking technology."

Jan 1, 2014

By Marianella Perez, Williams Calderón, Gonzalo Montes-Atenas

The lack of fresh water sources, particularly in the Northern part of Chile, has driven the mine sites to search for new and sustainable paths to obtain water resources to run minerals processing operations. Among them, the use of seawater in concentrators appears as an interesting solution to this problem. However, the presence of seawater will have an impact onto the operation, not only because it will enhance corrosion reactions in the equipment installed in a plant, but also because it may affect how particles will effectively be processed across the numerous unit operations existing in the mine site. Among such unit operations, the grinding stage is a highly regarded as it defines the success of the separation of valuable minerals from gangue material in the froth flotation operation. Then, one important aspect to be addressed is to understand how the presence of seawater will affect the different mechanisms acting during the operation of a ball mill. The aim of this research work is to assess the effect of changing the aqueous matrix from process water to seawater in ball mills onto the mill performance. The methodology considered the use of Fluent® software and its capabilities to run numerical simulations with heterogeneous media. On one hand, from the data analysis, it is possible to infer that breakability mechanisms should not be significantly affected. On the other hand, the high ionic strength of the matrix should impact importantly particle transport mechanisms within the mill. Particularly, when transporting finer particles. Rheology results were in agreement with previous published research studies suggesting the suspensions to behave as Newtonian, Dilatant o Pseudo-plastic fluid depending on the amount of fine particles present in the grinding media. The latter will result in changes in the residence time of particles in the mill producing overgrinding or an excess in the circulating loads.

Jan 1, 2014

By B. K. Mishra, Subrat Kumar Padhy, B. C. Tripathy, I. N. Bhattacharya

Manganese is a difficult metal to electrodeposit due to its high electronegativity and continues to possess unique process challenges. Manganese deposits of high quality are electrodeposited on 316 grade stainless steel from sulphate solutions in the presence of organic additives such as tetra ethyl ammonium bromide (TEABr), tetra propyl ammonium bromide (TPABr), and tetra butyl ammonium bromide (TBABr). The concentrations of these additives were examined over a relatively broad range to evaluate their effect on current efficiency, specific energy consumption and deposit morphology of the electrodeposited manganese metal. A maximum current efficiency of 68% was achieved in the presence of TEABr in the bath. X- ray diffraction studies revealed that (330) (411) planes were the most preferred planes of crystal growth during manganese electrowinning at a current density of 500 A/m2 resembling alpha-manganese irrespective of the nature of additive. Scanning electron micrographs showed smooth and uniform deposit morphologies when manganese was electrodeposited in the presence of TEABr.

Jan 1, 2014

By I Wilkomirsky, F. Parada, R. Parra, E. Balladares

"The neutral roasting of As bearing copper concentrates is confirmed well established and promising option for the treatment of this type of complex concentrate. The AS elimination by volatilization allows subsequent treatment of the calcines produced in a conventional pyrometallurgical process, by blending this product with standard concentrates.Several tests were performed using the fluidized bed pilot plant at the University of Concepción with different types of concentrates. Calcines, fines from two hot cyclones and flue dust from the ESP were collected. These materials were characterized using QEMSCAN® and the results used for the development of a mass and energy balance which took into consideration the specific chemical transformations that occurred in the reactor.A physico-chemical/kinetic model is proposed to explain the formation of bornite, chalcopyrite and magnetite. The mechanism involves solid-gas reactions between chalcocite, pyrrhotite and gaseous sulfur that without the mineralogical characterization would not have been possible to propose"

Jan 1, 2014

By U. Ulusoy

Surface roughness and acuteness are known as the two of the main properties of the particle morphology affecting the behavior of the powders in the process. Since the techniques used for the morphological characterization of powders by 2-dimensional microscopic measurement from the polished sections that have some disadvantages, the 3-dimensional analysis has often relied on measurements of particle morphology. A review of literature data was presented for high-grade barite and pyrite particles ground by ball and autogenous mills to determine the morphological properties using a new 3-D approach based on BET nitrogen gas adsorption and Permaran methods. Micromeritics Flowsorb II 2300 instrument which employs BET nitrogen adsorption technique was used for the specific surface area measurements and the roughness of the particles. Permaran (manufactured by Outokumpu Oy) was used for the measurements of airflow resistance of powder samples for the acuteness. Spherical glass beads were used as reference sample for the acuteness measurements. The obtained parameters, which are surface roughness and acuteness, were corre-lated with the floatability performance of those mineral particles. The flotation performances of those particles ground in different mills (ball and autogenous) were also evaluated by a Hallimond tube. The results showed that lower roughness and acuteness values caused higher flotation recoveries for both barite and pyrite particles that were tested independently in different type of the mills. In other words; particles with smooth surfaces resulted in better floatability for barite and pyrite minerals studied.

Jan 1, 2014

By P. Pyykkö, E. Peuraniemi, J. Järvi, P. V. Latostenmaa, V. Törölä, S. Junnikkala

"Nickel concentrate smelting started in Harjavalta in 1959. First, flash smelting - Peirce-Smith converting route was applied, and the high-grade converter matte was further refined to nickel cathodes. In 1995 the original smelter flow sheet was simplified with the novel DON (Direct Outokumpu Nickel) technology. In Harjavalta with the DON technology, high-grade nickel matte with low iron content is produced in flash smelting furnace directly without subsequent converting stage. The metal values in the smelting slag are recovered in an electric furnace as an iron containing bottom alloy. Main special features in Boliden Harjavalta nickel smelter are smelting of high-magnesia concentrates, the high recoveries of nickel and copper, as well as those of PGM`s and cobalt.Sulfur and dust emissions to air can be seen generally as one main disadvantage of nickel smelting operations. In Harjavalta continuous improvements in environmental performance has been rewarded by minimum sulfur and dust emissions to the environment and working atmosphere. Today Boliden Harjavalta’s nickel smelter is presenting state-of-art-technology at nickel smelting.This paper describes the nickel smelter process and includes recent production and emission data. It describes features required to achieve environmental and occupational hygiene goals and compares environmental performance data to that published on other smelting operations. General description of New Boliden Way is presented and a case example of production stability project is also presented."

Jan 1, 2014

By Lesley Andrews

"Electron microbeam analysis of metallurgical samples covers a broad field and has applications in the areas of minerals processing, hydrometallurgy, pyrometallurgy, physical metallurgy and corrosion.Some idea of the possibilities of microbeam techniques can be illustrated by examining the following example of a run of mine gold ore sample. Milling and bulk chemical analysis of the ore will provide major and minor element analysis as well as the gold grade. More detailed chemistlY can also reveal the presence of trace elements that may be advantageous or deleterious to downstream processing. Electron microbeam analysis can provide additional information in the form of - size, liberation, association and composition of the gold, the percentage of refractory gold, the size, liberation, association and composition of enclosing sulphide or arsenide phases and the levels and association of the trace elements that may affect processing. In most cases electron microbeam analysis compliments bulk chemistry, and does not replace it. Both techniques should be used in parallel for maximum effect.This paper touches on the origin and history of electron microbeam techniques, as well as the theory behind microbeam analysis and processing. The more common types of instruments and their applications will also be dealt with briefly - more details on, and examples of, the applications and choice of technique will be covered in the presentation.Mosely first discovered, in 1913, that the frequency of emitted X-radiation excited by an electron beam is a function of the atomic number of the analysed element. This discovery led to the development of spectrochemical analysis. The forerunners of the electron microanalysers of today, however, were only invented during the nineteen fifties. The electron microprobe was developed in parallel by Castaing and Guinier in France and by Borovski in Russia, but Castaing's design was the basis of modern microanalysers. The initial area of analysis was brought down from over 1 mm2 to less than 2 µm, as it is today. In 1956 Cosslett and Duncumb invented the scanning electron microprobe, where a beam of electrons could be scanned across an area of a sample. This, in turn, led to the development of the electron microprobe with both scanning and point analysis capabilities that we know today.Essentially, all electron microbeam instruments operate by the production of a beam of electrons from a filament in a vacuum (i.e. an electron gun). The electron beam leaves the gun and is accelerated and focused by a series of electromagnetic lenses while passing down an evacuated column. The electrons eventually strike the surface of the sample to be analysed and may travel through a thin sample (transmitted electron microscopy) or react with a thicker sample to produce several reflected kinds of radiation."

Jan 1, 2014

By Gunhild Hennum, Tewodros Tefera, Gisle Håland, Annette Jahr

"Abstract The Gudrun field is located west of Stavanger in the North Sea at water depth of 109 m. A jacket substructure was selected to support the topside and was installed in 2011. The jacket shall be able to support 16 of 0.762 m (30 in) diameter conductors and is equipped with a drilling deck to allow for pre-drilling by a jack-up rig through the jacket. In general the soil conditions below mudline comprise of a thin top layer of very loose to dense sand overlaying several layers of sandy clay, ranging in stiffness from firm to hard. Below some 30 m depth the soil consists of layers of medium dense to dense silty sand overlaying very hard sandy clay containing thick beds of sand to 100 m depth or more below mudline. The jacket is secured to the seabed by twelve 2.438 m (96 in) diameter steel pipe piles, three at each pile cluster located at the four legs of the jacket at sea floor. Different design methods were used to determine the pile penetration depth. Pile drivability was evaluated using best estimate and upper bound soil parameters. The pile driving and blow count record show that the target penetration was reached as predicted. This paper discusses the different methods used to determine the pile capacity, target penetration depth and the drivability analyses made for the Gudrun jacket piles. The soil resistance during pile driving is back-calculated from the pile installation data and compared with the prediction made.IntroductionThe Gudrun platform is located west of Stavanger in the North Sea at water depth of 109 m. A jacket substructure was selected for the Gudrun platform. The general Gudrun platform jacket configuration is to a large extent dictated by the topside layout, the requirements for support points enclosing the well slots and access for the jack-up rig. The Gudrun platform jacket is a traditional 4 legged structure with a vertical side towards the jack-up rig. At the seabed the jacket is quadratic with a base dimension of 40 by 40 metres. Figure 1 shows the Gudrun jacket during load-out from the fabrication yard to the transport barge. At the site the jacket was lifted off the barge, upended and placed on the seabed by the installation vessel. The jacket is secured to the seabed by twelve 96"" (2.438 m) diameter steel pipe piles, three at each pile cluster located at the four legs of the jacket at sea floor. The target penetration of the piles is 47 m."

Jan 1, 2014

By Mark S. Rayson, Jessy Lee, David O. Johnson, Matthew R. Rawls

The ability to manipulate the structure of liquid chemicals in an explosive is important in mining applications, where precision blasting is crucial for the safe, reliable, economical and eco-friendly extraction of ores. Static mixers allow explosives, emulsion-based in particular, to be custom-made as they offer precise and reproducible mixing without the need for moving mechanical parts. In this paper, we perform numerical simulations on the laminar mixing of two nitrate-based fluids in a Kenics static mixer unit for various mixer parameters. Two numerical methods were investigated in the study of the mixing pattern: solving the mass transfer equation and using particle tracking. The former introduces artificial numerical diffusion which can lead to spurious smearing of the component boundaries, a problem that can be avoided with the latter technique. We have also demonstrated that the particle tracing method is capable of qualitatively predicting the blending patterns under the conditions studied.

Jan 1, 2014

By Rolf Lauten, Yongjun Peng, Yufan Mu

"Biopolymers, produced from cellulosic biomass, have promising prospects of application as depressants in mineral processing. In this study, three different types of biopolymers (i.e., DP-1775, DP-1777 and DP-1778) were used to study the effect of polymer structure on flotation of un-activated pyrite, copper activated pyrite and chalcopyrite. It was found that the depressing effect of DP-1775 and DP-1778 was much stronger than that of DP-1777, and pyrite was depressed to a greater content than chalcopyrite with the same biopolymer at the same dosage. The biopolymer concentration played a vital role in determining the degree of depression. For each biopolymer, the higher the concentration, the greater the minerals were depressed. The mechanism underpinning the depressing effect of these biopolymers was explored in this paper. The concentration of biopolymers could determine the properties of the adsorption layer and the confirmation of biopolymer chains on mineral surfaces. The biopolymer molecules may aggregate when polymer concentration was over a critical value. Molecular weight and functional groups of biopolymers were the key factors characterizing the depressing capability of different biopolymers. Differences between the tested biopolymers and features of the adsorbed layer might account for the observed trends in ability to depress pyrite and chalcopyrite flotation. The greater depressing effect of biopolymers on pyrite over chalcopyrite might result from the preferential adsorption of biopolymers on pyrite over chalcopyrite."

Jan 1, 2014

By Christopher Mark

Colombia is 11th largest coal producing nation in the world, and the world?s fifth largest coal exporter. But while most of Colombia?s coal is mined at large modern surface mines located near the Caribbean coast, there are also underground mines that produce high-grade metallurgical coal. These mines employ traditional hand-loading techniques in a variety of geologic environments, and they have some of the highest accident rates of any Colombian industry. The National Institute for Occupational Safety and Health (NIOSH) has been collaborating with POSITIVA, the primary provider of worker?s compensation insurance to the Colombian underground coal industry, to reduce the economic and social cost of rock falls in these mines. The specific goals of the collaboration are to 1) document practices and conditions in Colombian underground coal mines, 2) identify relevant international best practices, and 3) provide recommendations for developing a national campaign to reduce fatalities and injuries associated with roof falls. NIOSH conducted a survey of seven underground coal mines in four separate coalfields. Five of the mines were characterized by steep dips and weak roof and floor rock. The coal was loaded by hand at all seven mines, though two employed partially mechanized longwall techniques. Wood posts were by far the most common ground support. Roof bolts were not observed in use at any of the mines, and they are unlikely to replace timbers any time soon. While long-term entries generally appeared to be adequately supported, the survey found that less attention was paid to the temporary support that is installed right after the coal is removed. This temporary support is critical for protecting the workers from rock falls, however, because with hand-loading mining methods most of the activity takes place between the permanent supports and face. The study concluded that improving the temporary support in the working faces would be the most effective way to reduce the number of rock fall injuries. The key principle should be that every worker is protected by planned roof support at all times. Ground Support Management Plans, consisting of specific rules about when, where, and what roof support is to be installed, should be the focus of the campaign. Each Plan should be tailored to a specific mine based on the geologic conditions and mining methods in use. The Plan provides miners with clear, simple rules that can be easily understood, while management can easily check to see if it is being followed. Ground Support Management Plans will also provide the campaign with a concrete focus for the necessary cultural change.

Jan 1, 2014

By Lon Santis, David Buckwalter, Ken Steinmetz

This paper describes a magazine security system using two readily available cellular telephone-based technologies. The system is comprised of vibration sensors and remote cameras. The system is used at a Bureau of Alcohol, Tobacco, Firearms, and Explosives (ATF) licensed explosives storage location in Pennsylvania to comply with PA Department of Environmental Protection (PADEP) regulations. The system provides instant notification to the licensee via cellular modems, text messaging, phone call, and e-mail. Likewise, the licensee can control the system remotely over the internet and using text messaging commands. The vibration sensors attach to the door of the metal type I magazines magnetically and detect any movement or vibration. The cameras trigger on movement and thermal radiation changes and can also be triggered manually to check alarms received from the vibration sensors. The previous system was comprised of a base unit and magnetic strips. The magnetic strips were powered by a hard line from the control unit and mounted on the doors and top of magazine creating a bond, that when broken triggered an alarm. Our main issues with the unit were the delay in alert times and tech support. Because of these issues, we decided an upgrade was necessary. Compared to that previous system used at this site, these new systems are highly affordable, carefree and reliable.

Jan 1, 2014

By A. C. du Preez

Mintek has been involved in extensive test work since the early 1990s on the recovery of nickel and cobalt from leach liquors saturated in calcium, using synergistic solvent extraction systems. During this period the Nicksyn? reagent was developed, optimized, commercially manufactured, and tested by Tati Nickel on a demonstration plant for more than 2800 operating hours. Efficient recovery of nickel without the co-extraction of calcium, thus avoiding gypsum formation in the extraction and stripping circuits, was illustrated. This synergistic system was recently evaluated on a laboratory scale for the recovery of nickel and cobalt from synthetic lateritic sulphate leach liquor containing about 3 g/L nickel, 0.5 g/L cobalt, 0.7 g/L manganese, 20 g/L magnesium, and with calcium at saturation. Extraction and stripping parameters were determined for this feed liquor and are discussed in this paper.

Jan 1, 2014

By Andre Zingano

The coal seam strength and the failure criteria that represent the behavior of the coal seam are very important for mine section and pillar design. Additionally, mine section and pillar design take into account roof and floor layers, which form the roof-pillar-floor system. Therefore, underground ground control design begins, most importantly, with rock mass characterization. Another issue is the distribution or behavior of the coal seam strength for the whole mine area. Sometimes, the coal seam strength is assumed to be the same for an entire area, but this is not true because the coal seam is heterogenic and anisotropic, and also the coal strength is affected by faults and spacing between fractures. The objective of this paper is to demonstrate the use of the methodology for geomechanics characterization to determine the strength for the Bonito coal seam, and discuss the coal seam strength distribution around the entire mine area. The intact coal strength was determined by laboratory tests that were completed during the last 17 years, including triaxial and uniaxial strength tests. It was noted that there is a strong correlation between all laboratory strength tests with 90% confidence interval. The explanation for this coal seam strength variation is the presence of the discontinuities and their variation in quantity and quality at each location in the mine area, because the coal seam rock classification and its behavior will be affected by the quantity and quality of fractures.

Jan 1, 2014

By T. Deng

Flotation of rare earths is complicated by the number of mineral classes that carry rare earth elements, including carbonates, phosphates, and silicates that often co-occur within the same deposit. Gangue constituents often belong to the same mineral classes as the rare earth minerals themselves. Chemical regimes developed for specific separations employ customized combinations of collectors, modifiers, and depressants that are not directly translatable to other operations. In this rougher flotation case study, a reagent suite including phosphate ester and sulfosuccinamate, originally developed for the recovery of bastnasite and monazite from silicate hosted ore, could not be applied to a synchysite ore hosted in carbonate gangue because the suite was aimed at silicate gangue rejection only. The separation of a fluorocarbonate mineral from carbonate gangue required a different chemical regime involving the use of hydroxamate and sodium silicate. Maximizing rare earth recovery was complicated by the presence of slimes. The effect of desliming and the increase in grind size was explored.

Jan 1, 2014

The re-use of waste water from coal preparation plant tailings is always desirable, but is generally problematic in terms of solid-liquid separation. Dewatering and disposal of coal slurry at a high percentage of moisture poses a major technological and environmental challenge to mining and mineral processing industries world-wide. Characterization and flocculation of these coal tailings reveals that the separation of fine coal tailings depends on factors such as size distribution, slurry viscosity, zeta potential, pulp density, circuit design, plant operating parameters, and the behaviour of solid particles in an aqueous medium. The present study was carried out on -600 mm coal tailings collected from a coking coal preparation plant of Jharia Coalfield, India, using anionic flocculent. Characterization studies revealed that the zeta potential was highest (-44 mV) at a pH of 9.0, the size range of the particles was 1.1?700 m, and the average ash content was 62.57%. Flocculation studies were performed at different solid concentrations, pH values, and polymer dosages. The results indicated an efficient settling rate of 178.15 mm/min at 8% solid (w/w) at a flocculent dosage of 32.50 g/t solid. The turbidity of the clear liquid obtained was 7.42 NTU.

Jan 1, 2014

By Kr. J. Dedelyanova

Selective flocculation of iron minerals could improve the economics of high intensity magnetic separation as concomitant process. When the minerals are finely disseminated is necessary a finer grinding to be applied which generates a lot of slimes. The HIMS is not enough efficient for particles below 20 microns ? territory where the selective flocculation is already well known industrial practice, so the combination of these two methods of beneficiation can bring a higher grade at high recovery to be achieved. The dynamics and selectivity of the precipitation process is studied in batch tests with flocculant starch and dispersants sodium silicate and sodium hexametaphosphate. The influence of preliminary conditioning with nitrogen acid at pH 2 before flocculation is also investigated. Flowsheet including these two methods is tested and the distribution of iron is shown.

Jan 1, 2014

By L. A. Alcorn, H. E. Camargo, G. Gwaltney

"One of the most pervasive diseases in the mining industry is noise-induced hearing loss. The exposure of miners to noise levels above the permissible exposure level results in hearing loss in approximately 80% of coal miners by retirement age. In this context, the U.S. National Institute for Occupational Safety and Health (NIOSH) is conducting research to develop noise controls for longwall mining systems, which are used to extract half of the national underground coal production.From field measurements, previous research determined that the dominant sound-radiating components at the shearer of a longwall system are the two cutting drums used to remove coal. Due to the dimensions and complexity of longwall mining systems, the NIOSH project developed a validated finite element model of the cutting drum to use in predicting the sound radiated by the drum due to the excitation forces experienced in underground operations. This same model will be used to develop engineering noise controls for the drum. The excitation forces arise from the interaction of the cutting bits and the coal and are transmitted to the cutting drum through the bit holders. Due to the adverse conditions at the face, and a lack of instrumentation approved for underground use, the operational coal cutting forces have not been assessed before. To this end, NIOSH, in collaboration with Michigan Technological University, developed a self-contained, intrinsically safe instrumented bit to measure these forces.This paper describes the development of the instrumented bit and the measuring of operational coal cutting forces at three working coal mines. The measurements revealed that the forces have a flat spectrum, representative of the impact nature of these forces, up to around 100 Hz. Above this cutoff frequency, the force magnitude decreases at a rate proportional to the inverse of frequency squared."

Jan 1, 2014

By Çisem Tuba, Ismail Girgin

"Comparative atmospheric H2SO4 and H2SO4 + H2O2 leaching experiments were performed using a Turkish lateritic nickel ore containing 1.52% Ni. In the leaching tests; acid concentration, temperature and leaching time were considered as main variables and the dissolution behaviour of the ore were studied by Ni, Fe, Co and Mg analyses. The dissolution values in the H2SO4 leaching experiments were observed to increase up to 60% (w/w) acid concentration and a temperature of 95°C. Increase of H2SO4 concentration above 60% at 95°C caused decreases in all the dissolution values and this was attributed to the formation of Fe2(SO4)3 and Fe2(SO4)3•HSO4•H2O type compounds. At the considered optimum H2SO4 leaching conditions ([H2SO4]= 45%, T=95°C, t=45 min); dissolution values reached for Mg, Ni, Fe and Co were determined as 99.12%, 95.58%, 92.63% and 78.37%, respectively. An activation energy of 30.57 kJ/mole was determined for nickel dissolution from the evaluation of the kinetic data obtained for H2SO4 leaching showing that the dissolution was controlled by external diffusion and chemical reactions. Caro’s acid solutions were prepared at H2SO4/H2O2 mole ratio of 3 for varying initial H2SO4 concentrations and leaching tests were performed at 25°C. Co behaved very differently and a dissolution value of 83.94% was obtained even at 5% acid concentration in 60 minutes reaction time. Complete dissolution of Co was obtained after 30 minutes of reaction time at 60% initial H2SO4 concentration and the corresponding dissolution values for Mg, Ni, and Fe were reached to 96.16%, 94.27% and 89.46%, respectively. Although the H2SO4 + H2O2 leaching experiments were conducted at 25°C, it was realized that the temperature of the leaching medium was increased to 122°C after four minutes of reaction time due to probable exothermic reaction(s) at 60% initial acid concentration."

Jan 1, 2014

By E. Haccuria

Due to the growing share of electrical cars, the use of lithium ion batteries significantly increased. Recycling of these batteries is essential to safely dispose hazardous materials as well as to recover valuables (Cu, Ni, Co, etc.). In order to optimise the recycling process, accurate information is required on the slag phase equilibria for battery smelting. The slag is a multi-component system containing alumina from the battery cases, silica and lime from fluxes, and manganese and lithium from the electrode materials. The present study accurately determined the phase equilibria in the "MnO"-Al2O3-SiO2 sub-ternary system at metal alloy saturation. Particular attention was given to the accuracy and reliability of the final results by highlighting the different reaction pathways, mass transfer- and reaction mechanisms taking place in the system during experiments. This attention enabled improved experimental methodology and measurements. Based on the present study, further measurements will be undertaken in the quaternary "MnO"-Al2O3-CaO-SiO2 system at low "MnO" concentrations, which closely represents the future recycling industrial slags.

Jan 1, 2014