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By H. Utsunomiya, J. Su, K. S. Tamimi, S. Yue, M. Sanjari, L. Kestens, Hara, A. S. Kabir, R. Petrov

Manufacturing of thin sheet is difficult in industries. Some approaches, such as small-draft multi-pass rolling, intermediate annealing, isothermal rolling and high-speed rolling were proposed to overcome the deformability. In this study, different rolling speeds from 15 to 1000 m/min were employed to twin rolled cast AZ31B magnesium alloy to different reductions. The results show thatAZ31B sheets rolled at 15 m/min and 100 °C has fractured for reductions of more than 30% per pass. However, by increasing the rolling speed to 1000 m/min the rollability was improved significantly and the material can be rolled to reductions of more than 70% per pass. The high speed and heavily deformed materials are fully recrystallized even at 100 °C.

Jan 1, 2014

By Michael S. Moats, Alex Luyima, Tomas Oliveira

Some commercial copper electrowinning facilities use Cyquest N-900 (a polyacrylamide) or HydroStar (a modified polysaccharide) to improve the density and smoothness of copper electrodeposits. However, the effects of these additives have not been studied extensively in the open literature. Thus, the electrodeposition of copper at 40 oC from a non-stirred synthetic electrowinning electrolyte (40 g/L Cu2+, 160 g/L H2SO4, and 20 mg/L Cl-) in the presence of various concentrations of either additive was evaluated using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). CV results show that neither additive has much effect on the nucleation overpotential of copper electrodeposition on stainless steel. However, Cyquest N-900 polarized the copper deposition reaction upon the return sweep. The EIS data indicates that Cyquest N-900 increases the reaction’s charge transfer resistance and creates a second low frequency loop. HydroStar had minimal effect on the electrochemical data generated by CV or EIS. Thus, the mechanism by which HydroStar affects the copper deposition reaction still needs to be determined.

Jan 1, 2014

By B. K. Mishra, P. Patnaik, B. C. Tripathy, I. N. Bhattacharya

Cobalt is an essential metal considering its numerous industrial applications. The demand for the metal is increasing due to its wide range of use in, for example, rechargeable batteries and as an alloying element in super alloys. Cost effective production of Co is critical. Electrowinning from aqueous sulphate solutions is the preferred technology available for the production of Co. Attempts are being made to produce uniform, smooth and bright deposits of cobalt metal. Use of organic additives in the electrolytic bath improves current efficiency and deposit morphology of the metal. We investigated the effect of quaternary amines TEABr, TPABr and TBABr during cobalt electrowinning from aqueous sulphate solutions. Among the additives studied, TEABr yielded the best results. Smooth and bright deposits of cobalt were obtained at low concentration of TEABr (10 mg/L) maintaining a very high current efficiency of 99.6%. X-ray crystallography indicated that (100) is the most preferred plane of crystal growth.

Jan 1, 2014

By Aysan Molaei, Kristian Waters

Solvent extraction is the one of the most common techniques for recovering metal ions from aqueous systems. However, solvent extraction is generally limited to relatively high concentrations and requires a high organic/aqueous ratio. Predispersed solvent extraction (PDSE) is a modified solvent extraction technique in which organic phase pre-comminute into colloidal liquid aphrons (CLAs). In this study, the extraction of copper by the PDSE technique was investigated. The main focus of this study was on the characterization and application of CLAs under different operational conditions, and to investigate the effects of different parameters on the extraction of copper from dilute streams. The effect of phase volume ratio (PVR), initial extractant concentration and initial copper concentration was studied and optimum conditions for copper removal using CLAs generated by LIX 984N as extractant, oil soluble and water soluble surfactants were proposed. Experimental observations indicated that PVR and initial LIX 984N concentrations had a significant effect on copper extraction.

Jan 1, 2014

By Phillip E. Gramlich

Through extensive practical experience and multiple studies, tensioned roof control systems have proven beneficial in difficult mining conditions. Due to increased mining of less desirable seams, tensioned roof control systems have claimed a progressively larger share of the total number of roof bolts installed in the US coal industry. Each tensioned roof control system has its benefits, but also has problems concerning cost, cycle time, stress concentration, load retention, and protrusion into the mine opening. For example, resin-assisted mechanically anchored bolts (also known as resin point anchor bolts) have a fast cycle time and the potential for high tension loading, but the stress from the mechanical shell is concentrated in a small area and can create concerns with certain roof structures (Zhang and Peng, 2001). Resin point anchor bolts can be difficult to fully grout. The cost of resin point anchor bolts can be an issue; a two-piece resin point anchor bolt has a large number of parts (10) and manufacturing steps (9), adding to its higher cost. Tension rebar bolts can achieve high loads and are easier to fully grout but have longer cycle times. In addition, a high percentage of the installed load can ?bleed off? if the resin mixing time or the ?hold time? before tensioning is short-circuited. Tension rebar bolts can be notorious for protruding into the mine opening, creating an obstruction for man and machine (Figure 1), in particular, with reduced mining heights. A new tensioned roof control system has been developed that doesn?t have moving parts, is cost effective, provides fast cycle times, has a low profile, and is simple t install.

Jan 1, 2014

Most of the Indian coking coals are medium coking and of very high ash content. Beneficiation of these coals is a must for their utilisation in coke making. During washing while the ash content of the coal is reduced, the same is expected to affect the reactive-inert ratio and the proportion of various petrographic constituents in the clean coal. This will affect the coking behaviour, including the expansion characteristics, of such coal. An increase in expansion behaviour of coal increases the wall pressure and may damage the battery wall. Therefore, close monitoring of coking properties along with drop in ash is necessary for smooth use of the coal in coke ovens. An effort is, therefore, essential to understand the impact of washing on its coking properties. The studies were carried out with captive coals of Tata Steel, India. Three medium coking coal samples namely, VII A, VI A and XI SEB seam coals of West Bokaro Colliery were used for the study. The coal samples after washing to different ash levels were subjected to the following analysis: proximate, crucible swelling number (CSN), LT GK test, dilatometer and plastometer tests and petrography. The experimental data were then analysed to assess the relationship of various coking properties of the coal with its ash content. The studies clearly show that there is a strong impact of beneficiation of the coal on its coking behaviour. The impacts are more at lower level of ash in the clean coal. In general, the coking properties increase with a decrease in ash. This is primarily due to an enrichment of vitrinte materials in the clean coal and an increase in the reactive-inert ratio in the coals. However, the most important impact of the lowering ash is on the increase in the swelling nature of the coal. The coals with lower ash become highly expanding in nature. This may be very critical from operations of coke ovens point of view, especially stamp charged coke ovens. Necessary precaution should be taken in selecting the other coal blend constituents when these coals are beneficiated to a very low level of ash content.

Jan 1, 2014

By J. Jung, W. Keller, N. Rohn

In hydrometallurgical minerals processing slurries are often processed at very small grind sizes and high solids concentrations. This normally results in flow anomalies of such slurries. Due to flow limits or yield stress the slurry tends to stagnate close to the vessel bottom, the walls and at any internals. The main mixing task therefore generally is not suspending of the solids but the homogeneous blending of the entire vessel volume. If not considered during the agitator design only a fraction of the vessel contents will be mixed. Therefore the knowledge of the slurry rheology as well as the variations in process parameters is vital to design e.g. storage or surge tanks. The integral mixing solution considers the motor power, the choice of the impeller type and number, the impeller diameter as well as the design of the baffles and feed and discharge positions.

Jan 1, 2014

By R. Haecker, S. Bajic, R. Thorpe, A. Palko, M. Kalstrom

"Historically, mineral processors have used inferential data like plant instrumentation, assays, and grind sizes to monitor the performance of their plants. The ability to monitor the minerals themselves on a daily basis has eluded all but the very largest and richest of operations. The advent of a new generation of compact, robust, and user-friendly SEM-based automated mineralogy systems looks set to accomplish this, aiming to bring daily mineral monitoring of plant performance within the reach of all mills from mid-size upwards. This paper describes the use of this machine at Greens Creek Mine, a 2.5 ktpd Ag-Au-Pb-Zn operation with a complex flotation flowsheet. During the trial, the machine provided turnaround from sample collection to reporting averaging 24-36 h for key daily samples. All equipment was located within the compact mill, and proved highly reliable despite the challenging environment. Turnaround time was fast enough for metallurgists to understand, and, where possible, respond to ore and process changes while they were still happening. The plethora of data generated was filtered to a simple report whereby mill management could quickly absorb key daily mineral-based performance indicators. This paper will describe how the data was used to understand the key drivers behind metallurgical efficiency at Greens Creek, and how metallurgists began using the information to enhance daily mill performance."

Jan 1, 2014

By William Kendall

INTRODUCTION Stillwater Mining Company, with its two underground, hard rock mines in South Central Montana, is the largest primary producer of palladium and platinum in the Western Hemisphere. Platinum Group Metals (PGMs) are mined from a specific zone within the Stillwater Complex, a layered mafic/ultramafic igneous intrusion, named as the J-M Reef. Over much of the J-M Reef, the economically minable, mineralized horizon is contained at typical horizontal widths of 6.5 ft to 8 ft wide. This feature of narrow mining widths has made it challenging to safely and effectively mine these areas of the J-M Reef using mechanized cut and fill and sublevel sill development mining methods. Mechanization of most or all of the steps of the mining process is important to Stillwater in the continuous pursuit of high standards in safety and health. Mechanized bolting within the J-M Reef ore production headings is an important piece of reaching these objectives. In general, metal/non-metal mining requires varied mining techniques, as compared to more traditional bedded mineral/resource deposits. Narrow vein mining is a selective mining technique that generates a minimal amount of waste material while obtaining the more valuable ore deposits. Drilling and bolting in narrow vein mining has traditionally been performed with air-powered, hand-held ?jackleg? equipment because mechanized equipment is, typically, too large for the selective narrow vein techniques. In addition, traditional hand-held pneumatic equipment provides significant flexibility for small-opening, narrow-vein developments, reducing waste rock handling and improving ore recovery management. The hand-held equipment is also relatively inexpensive to purchase. Due to its simplicity, it is also relatively easy to train operators to use hand-held equipment. Hand-held equipment has been routinely used to safely install ground support and to develop production faces in hard rock mines for many years. Although it is effective, the hand-held equipment requires operator exposure to certain inherent hazardous conditions in the active face/development mine areas. These include falling rock, tripping hazards, bending/twisting/lifting hazards, high noise levels, and chemical fumes from the hammer exhaust. Based on health and safety statistics from the Stillwater mines, operation of the rotary-percussive hand-held equipment adversely affects the long-term health of the operator?continual jackleg operation frequently results in long term damage to hearing, shoulders, arm and wrist joints, and back injuries. This reduces the quality of life for the operator and also results in higher personnel turnover rates for the mining company.

Jan 1, 2014

By I. C. Spangenberg

The status of sampling practices in the gold mining industry in Africa was determined as an initial step in a process to standardize sampling practices in the mining industry. Twenty-one gold mines, twenty metallurgical plants, and thirteen laboratories were rated for the potential influence of the relevant sampling errors on each component of the particular sampling system. The findings of the study on the status of equipment, standards, procedures, and management principles were presented in a dissertation (Spangenberg, 20121) and are now used by AngloGold Ashanti?s mines in the quest for correct sampling practices. The information is also used to compile a guideline on leading practice procedures for sampling methods in gold mining. This article is an overview of sampling best practice found in African mining Keywords theory of sampling, best practise, sampling errors, sampling standards.

Jan 1, 2014

By Carlos Avalos Casillas, Saul Ortiz Landeros

The current work shows metallurgical results obtained at the Centro de Investigación y Desarrollo Tecnológico (Peñoles CIDT), as a continuation of the work first published in February 2012. With the aim of optimizing the economic values of the products, ores from San Julian (Fresnillo) were selectively floated to produce a lead concentrate and a zinc concentrate containing high silver values. In the laboratory, this included regrinding of the rougher and scavenger lead concentrate to increase the liberation of mineralogical species and thus lower zinc recovery. Cyanide leaching bottle tests were conducted to improve the value of the silver. It is proposed to leach the silver contained in the zinc concentrate and then recover the silver using the Merrill Crowe process. The results show a reduction of zinc recovery in the lead concentrate from 11.3% to 2.0% after regrinding to a P80 of 10 microns, improving the metallurgical quality and economic value of the lead and zinc concentrates. Also laboratory and pilot scale cyanidation tests showed that about 65 to 80% of silver will be leached from the zinc concentrate, after regrinding to a P80 of 10 microns. The proposed processing increases the economic recovery of silver from 72.7% to 78.8%.

Jan 1, 2014

By V. A. Chanturiya

The results study the minerals oxidation were obtained by us during the methods of microscopic, FT-IR spectroscopic, XRD and chemical analyses of sulphides in tailings of copper-nickel wastes in Kola peninsula. Sulphide minerals begin to oxidize already at the stage of stockpiling and initial stages of storing. The proportion of non-ferrous metals and magnesium oxide increases with time, calcium partially precipitating in the form of gypsum. Comparison of heavy metal contents in pore solutions in cur-rent and stale copper-nickel ore concentration tailings has revealed a significant difference in practically all the parameters. The lower metal contents in current tailing pore solutions (by 5~30 times) are probably due to the presence of float reagent residues blocking oxidation. Much lower concentrations of magnesium and calcium can be accounted for by the difference in kinetics: the rate of sulphide oxidation at this stage is much higher than that of solution interaction with non-metallic minerals as the result of which the solid phase ? solution equilibrium is not achieved. It is generally believed worldwide that it the mining wastes with acidic pore solutions that pose the greatest hazard for the environment. Our findings suggest that although the solution pH in all the samples is higher than 7.8, the contain heavy metal concentrations by far exceeding permissible values. The direct determination of the total and silicate Ni contents in the tailings from current production and in storage tailings has shown that both sulphide and silicate Ni forms occur in tailings. However, the role of silicate Ni is much larger in the storage tailings. The average silicate Ni content accounts for 10% of the bulk Ni content in the current tailings and it increases to 40% in the storage tailings. Thus, the storage tailings are marked not only by sulphide oxidation and the removal of water-soluble sulfates, but also by the interaction of sulfates with the silicate matrix. Although complete equilibrium is not achieved even within 30 yr under polar-region conditions, the major part of the Ni in fine-grained fractions passes into silicate form. The probability of Ni transition to the silicate form directly correlates with the dispersion of the material and the amount of chemically reactive serpentine and hydrochlorite. The migration of Ni as sulfates and its precipitation by chemically active silicates distorts the distribution of this component in the coarse- and fine-grained fractions that are typical of tailings from the current production of copper-nickel ores. On the one hand, the variation of the mode of Ni occurrence in storage tailings lowers the value of technogenic raw materials as a source of this metal.

Jan 1, 2014

By M. P. Krasteva

The froth flotation process for separation of mineral ores depends on the establishment of care-fully controlled froth. The formation of very stable froth in the flotation circuit is a problem that may occur in many plants, resulting in down-time, low quality and grade of final product and considerable expenses. Froths build up on the top surfaces of thickeners, tanks and flotation cells until they overflow, or until the efficiency of the circuit is impaired. A similar problem exists in Assarel concentrator, Assarel-Medet PLC, Bulgaria. Copper and copper-pyrite ores are dressed in Assarel concentrator. They are characterized with variable and complex mineral and physical composition. During the flotation cycle, resilient and difficult to break-down froth is formed, which subsequently impedes the process of thickening and clear overflow obtaining. Due to this problem continuous sampling in the cycle of thickening was conducted. The mineralogical, chemical composition, particle size distribution and solid phase content of the products were determined. It was established that the solid phase of the froth build up on the top surface of the thickener differs considerably from this one of the thickener underflow. The data clearly indicates that a separation process takes place on the top surface of the thickener ? fine particles of chalcopyrite are concentrated in the froth. The role of chemical reagent addition in the break-down of the flotation froth is investigated in terms of surface chemical phenomena involved in the stabilized froths. Measurements of the coper minerals wettability and surface tension at the air/liquid interface were performed. The surface active agent AERODRI® dewatering aids were laboratory tested. Bench-scale froth collapse tests were conducted. Reagent addition into pulp-froth system promotes and leads to a bubble coalescence, an improvement of the wetting of the mineral particles and a decrease of the surface tension at the air/liquid interface. The results of the laboratory experiments showed that the presence of the surface active agent leads to considerably decrease of the froth stability and the destruction of the deleterious froths build up on the top surface of the thickeners in Assarel concentrator.

Jan 1, 2014

By A. Roy, T. LeBel, P. Coursol, P. Lind

At the early stage of a mining project, small amounts of concentrates are available for testwork. For gold concentrate or ores containing significant arsenic levels, batch bench scale roasting is often unreliable, leading to highly variable gold recoveries to be used in the project’s financial justifications. With an appropriate bench scale unit using continuous feeding and residence time control for solid and gas phases, reliable numbers can be obtained at small scale with only a few hundred grams per test condition. This paper describes the development of a pilot fluid bed roasting unit by Kingston Process Metallurgy Inc. (KPM) to perform representative trials on gold concentrates containing arsenopyrite, arsenian pyrite and carbonaceous components. Calcines produced under different conditions were characterised by chemical analysis and electron microprobe; the calcine microstructure obtained is described. The most important parameter affecting gold recovery is oxygen content in the roasting atmosphere, with the lowest controlled oxygen level giving the highest gold recoveries. Higher local temperatures in the bed may cause the formation of molten glassy phases which can also reduce the gold recoveries significantly. The impact of roasting conditions in the two inch fluid bed is compared with commercial results obtained in full scale operation.

Jan 1, 2014

By Donovan J. Benton

Photogrammetric methods are advancing rapidly and show considerable promise as a ground control research tool. The ability to quickly capture three-dimensional geometry, especially changes in geometry, in underground and laboratory settings is a significant advance from point distance measurements. Photogrammetry is being applied in both of these settings as part of the NIOSH ground control research. This paper describes these applications and the equipment and software being employed. It also describes tests conducted to quantify the accuracy of these systems. Accuracy varied with system specifics and procedures. A factory-calibrated camera produced results within 1/32 of an inch, plus 0.04%. A user-calibrated camera was found to be less accurate, at 1/20 of an inch, plus 0.24%. These calibrations demonstrate that photo grammetry can produce research quality measurements in laboratory and mine settings.

Jan 1, 2014

By Maurizio Siepi, Fabio Santillan, Lyndon Bedford, Carlo Crippa

"Abstract: Wolf Creek dam, on the Cumberland River in Kentucky, US, operated and maintained by the Nashville District of the USACE, is the Corps' largest reservoir east of the Mississippi river. The 1748 m (5,736 ft) long Wolf Creek dam combines earthfill and concrete gravity sections. Construction began in 1941 and was completed in 1950. The dam showed signs of instability in the 1960’s, and in the late 70’s an in-depth project of rehabilitation was undertaken, using both grouting and secant piles. The works saved the dam, but in the late 90’s further signs of distress worried the Nashville district of USACE which, after a study conducted on the water seepage, concluded that construction of a new concrete barrier cut-off wall was needed. In 2009, the $341.4 USD million contract was awarded to TREVIICOS-SOLETANCHE JV.The new wall, located upstream of the concrete monoliths, has a minimum thickness of 60 cm (24 in.), and runs the length of the embankment, into the right abutment, for about 4,200 feet. The founding depth reaches 84 m (275 feet), well below the zone of solutioning. With a total surface approaching 92,903 sq.m (1,000,000 sq.ft), the Wolf Creek barrier wall is unlike any other project in the world.The construction of the cut-off wall followed a complicated but logical sequence of several operations, involving a variety of technologies: grouting, hydromill, directional drilling, and secant piles with reverse circulation. The intensive rock grouting program was aimed to minimize the risk of slurry loss and extend the positive cut-off further deep. Subsequently, an Encasement Concrete wall was installed with hydromill, toeing into the rock, to protect the embankment during the following phases. Smart holes were then drilled into the Encasement wall down to the final depth. Eventually, the holes were used to install the secant piles by employing the reverse circulation piling method.An extensive verification campaign has confirmed the superior quality of the cutoff wall consisting of 1200 secant piles, exceeding by far USACE’s requirements. The main project was substantially completed in early 2013. A small portion of secant piles wall will be installed downstream of the dam, to close the switchyard, finishing the project in the early months of 2014.IntroductionWolf Creek Dam is located on the Cumberland River in south-central Kentucky. The Nashville District of USACE operates this multipurpose dam to provide hydropower, flood control, water supply, and water quality benefits for the Cumberland River system and surrounding region. Lake Cumberland, created by the dam, impounds 7,400 million cu.m (6 million acre foot) at its maximum pool elevation of 232 m (760 ft) above sea level. This lake is the largest reservoir east of the Mississippi and the ninth largest in the United States, and attracts 4.89 million visitors, more than Yellowstone National Park (2.87 million).This paper describes the recently completed works for the rehabilitation of the dam, accomplished by TreviICOS-Soletanche JV with the construction of a new Barrier Wall."

Jan 1, 2014

By E. L. C. Martins, M. J. Nicol, D. Majuste, A. D. Souza

The effects of organic compounds on the current efficiency (CE), morphology, crystal structure and mechanical properties of the metal deposited during the electrowinning of zinc are described. A flotation collector and lubricating oil were selected based on observations made during the industrial production of zinc from silicate ores, in Brazil. The analysis by Fourier transform infrared spectroscopy of these compounds, which may be present in minor amounts in the electrolyte solution, indicated the presence of a polar amine group in the collector, while the lubricating oil is a non-polar compound. The average CE value obtained from organic-free industrial solution was 91.15 ± 0.26 %. The CE dropped to 54.35 ± 0.73 % in the presence of 100 mg·L-1 of collector in the solution, and a negative effect was also observed in the presence of similar amounts of oil (88.84 ± 0.61 %). The characterization of the deposits by scanning electron microscopy and X-ray diffraction revealed the formation of pores in deposits obtained from solutions containing the oil, while a different growth pattern (perpendicular zinc platelets) was identified when the flotation collector was added to the industrial solution. In the presence of these contaminants in the solution, guided-bend tests revealed that the deposits have a higher resistance to deformation, but lower ductility, properties that may affect the performance of the stripping stage. As a result of this work, simple control and optimization actions were applied in the industrial plant, which resulted in important improvements in the electrowinning process.

Jan 1, 2014

By D. B. Dreisinger, M. Mokmeli, B. Wassink

Dissemination of selenium and tellurium in sulphide minerals results in the contamination of pregnant leach solutions and electrolytes in the hydrometallurgical treatment of sulphide ores and residues. The selenium and tellurium content of the copper sulphate-sulfuric acid solution may be reduced into insoluble precipitates of copper selenides and tellurides using cuprous ion. This study presents the use of the thermodynamics and kinetics for the removal process of selenium and tellurium in real life application. Dominant species of selenium and tellurium in acidic copper sulfate solutions were identified and the reduction rates of species were compared. The findings were applied to industrial conditions by modeling the Vale’s CRED (Sudbury, Canada) plant’s selenium and tellurium purification circuit. Rate reducing factors on selenium and tellurium removal were identified and discussed.

Jan 1, 2014

By K. H. Berget, V. Andersen, H. Tveit, R. Jensen

This paper presents some of the work carried out in order to improve the tapping process in silicon production, with special focus on the environmental and the safety standards. Some of the modelling work that has been done to improve the understanding of the process is described, together with the resulting implementation to improve tapping standards.

Jan 1, 2014

By Q. Zhang

Phosphate tailings through Flotation contains large amount of dolomite which is difficult to be separated from apatite. In this present research, phosphate tailings is recycled by Flotation i.e. re-processing. High-purity dolomite with purity as high as 91.17% is seperated, which contains 19.82% of MgO. The results of orthogonal test show that the effect of various levels of different factors on the high-purity dolomite floatated. Future utilization of purified dolomite is also discussed: magnesium fertiliser especially magnesium phosphate is expected to be an ideal product from high-purity dolomite.

Jan 1, 2014