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By O. A. Olaseinde

The 2101 lean duplex stainless steel has wide potential application in storage, heat exchangers, and in the oil and gas industries. This work investigates the electrochemical behaviour of 2101 duplex stainless steel with an addition of 0.15 wt% ruthenium, using potentiodynamic techniques in 1M H2SO4 at 25º, 40º, 60º, and 80ºC. The microstructures of samples were characterized using optical metallography and scanning electron microscopy. The results showed that the ruthenium addition moved the corrosion potential of alloy 2101 to a more positive potential. All samples containing ruthenium displayed longer passive regions at 25°C and 80°C compared to those without ruthenium. Alloys without ruthenium had higher critical current density (icrit) values when compared to the alloys with ruthenium. Ruthenium additions decreased the passive current densities and inhibited anodic dissolution. At room temperature the corrosion rate of alloys with ruthenium was lower than these without ruthenium.

Jan 1, 2012

By L. Dufourm

This paper presents a review of plant layout considerations incorporated into recent designs of SAG/Ball mill circuits for two medium sized concentrators. The plant layouts presented and the design concepts discussed, relate to smaller SAG circuits, but can equally apply to larger milling circuits. Included are design concepts and ideas introduced by the various project teams, and the focus is on the primary factors of any layout design which are safety, constructability, operability, and capital cost.

Jan 1, 2012

By Michaela Dina Stanescu, Emilia Visileanu, Eftalea Carpus

"The recovery and reintroduction into the economic circuit of the textile material resources must be considered as component parts of the strategies of harmonizing the relationships between the economic growth, consumption of natural resources and environmental protection of the existing socio-economic system.The waste recovery for ensuring a sustainable development is a major concern of all industrial researches. In the textile domain, the concern in this matter is becoming more evident. An important role in manufacturing textile products it has the notion of eco-design, which has grown considerably over the last twenty years with increasing awareness of environmental and social problems in the industry.Introduction“Humanity must learn from the global financial and economic crisis experience""- is the conclusion of the policy makers who should develop a strategy designed to reinvigorate the economy and make possible an"" intelligent, sustainable and favourable to inclusion” growth, by a better coordination of national and European policies.The new vision for social market economy is based on three priority areas: smart economic growth, the development of an economy based on knowledge and innovation; sustainable economic growth, the promotion of a competitive economy with low carbon emissions and an efficient use of resources, as well as an inclusive economic growth, the promotion of an economy with high degree labour employment, which would generate social cohesion. The recovery and reintroduction into the economic circuit of the textile material resources must be considered as component parts of the strategies of harmonizing the relationships between the economic growth, consumption of natural resources and environmental protection of the existing socio-economic system.The waste recovery for ensuring a sustainable development is a major concern of all industrial researches. In the textile domain, the concern in this matter is becoming more evident. It is obvious that at the origin of pollution there are the technological processes of textile processing with impact on air, water, soil, as well as the storage processes. In all phases of obtaining a product, a series of secondary products and textile wastes with impact on the environment occur. The product used becomes also a factor of environmental pollution, which in most cases fails to assimilate."

Jan 1, 2012

By Rene Klymowsky, Norbert Patzelt, Egbert Burchardt, Johann Knecht

"The challenge of ""ore bodies getting steadily harder and lower in grade"" was brought to light during the first oil crisis in the 70's. Shortly afterwards, HPGRs appeared on the scene with the promise of saving energy. This combined with developments in wear protection for the rolls ushered in a period of trade-off studies that considered the HPGR as an option to improve project economics or to even make projects feasible at all.Since then, applications of HPGRs at Cerro Verde (Freeport), PTFI Grasberg (Freeport), Mogalakwena (Anglo Platinum), Tarkwa (Goldfields), Boddington (Newmont), Penasquito (Goldcorp), and others have contributed to the creation of a formidable basket of operating experience. Collected through years of successful operation, this information has been used to validate design criteria, scale-up factors and establishing a clearer picture of what ""to do"" and what ""not to do"".This paper compares results from various mining operations using HPGRs in their processing plants. Some of the lessons learnt in different operating environments are reviewed in order to support proper implementation and operation of HPGR's. Some of the development programs that have been initiated to improve wear life of the tyres and to reduce overall operating costs are reviewed. It is timely to summarize today’s experience and analyse its implications for existing and new operations"

Jan 1, 2012

By Wenbing Xie

At Renlou Coal Mine, Huaibei Mine Area, the track entry deformed significantly after longwall mining in an overlying multiple seams. The supporting characteristics of primary roof bolts and shotcrete with wire mesh are closely related to the movement of the mine?s surrounding strata. A case study of a track entry deformation was monitored during the longwall mining of a selected overlying panel. The measured data showed the unique entry deformation pattern during the longwall mining in the overlying seam. Underground extensometer measurement showed that entry stability was mainly affected by the periodic roof weighting of longwall mining in the overlying seam. The displacement of the deeper strata occurred a head of the immediate vicinity of the entry. Thereafter, deformation of the roof and floor strata was in the form of shearing of the shallower strata. Due to the use of heavy-duty roof bolting with wire-mesh, the roof-tofloor and rib-to-rib convergences were small, but the floor heave was large, greater than 80% of the roof-to-floor convergence. The measured displacement from extensometers varied with the position of the monitored cross-sections and depth into the roof. There were several deformation patterns, such as shearing movement, compression, and expansion, and the variations between compression and expansion. Strata compression at the entry surface was always accompanied with shearing movement at the deeper strata. During the longwall mining, the whole surrounding strata of the entry moved toward the opening. Underground practical experience indicated that prior to mining, the entry was supported very well in excellent conditions. After mining, however, it deformed greatly. The current entry support technology was not effectively control the severe deformation incurred in entries driven in soft strata due to the following reasons: (1) little is known about the entry deformation behavior of the strata surrounding the opening and (2) the degree of interactions between entry deformation and roof bolting with wire mesh is not well understood. Consequently, effective supporting systems cannot be properly selected to control its deformation and maintain a stable supported surrounding structure.

Jan 1, 2012

Rock mass classification systems are extensively used in rock engineering design work, and mine design is no exception. Among the systems most widely used for mining-related design work are the NGI 0-system (Barton et al., 1974), the RMR system (Bieniawski, 1976), the MRMR system (Laubscher and Taylor, 1976) and, more recently, the GSI system (Hoek et al., 1998). Classifying the rock mass is widely seen as being the fieldwork required to characterize the rock mass and enable the application of empirical design methods associated with the different classification systems. This paper argues that it is fundamentally important to recognize the distinction between rock mass characterization and rock mass classification. These two processes should, in most cases, be separated from each other. Rock mass characterization should be used to determine the intrinsic properties of the rock mass independently of the application; i.e. independent from the infrastructure to be designed, the size, shape, and orientation of the excavation(s) or pillar(s), etc. Rock mass characterization should also be compatible with most classification systems and empirical design methods to be used. Rock mass characterization is the background fieldwork required to perform rock mass classification and/or engineering design work. Rock mass classification is the subsequent step to the characterization, and an integral part of the design process. Parameters that vary according to the design, such as the relative orientation of geological structures compared to the opening or the mine-induced stresses, should be calculated as part of the rock mass classification and design process, rather than during the rock mass characterization process. The failure to distinguish between rock mass characterization and rock mass classification can lead to major design errors and poor results.

Jan 1, 2012

By G. A. Brooks, R. W. Matusewicz, Nazmul Huda

"A computational fluid dynamic (CFD) model of a conventional tuyere blown slag fuming furnace has been developed in Eulerian multiphase flow approach. The model was developed by coupling CFD with kinetics equations developed by Richards et al. for zinc fuming furnaces. The model integrates submerged coal combustion and chemical reactions with the heat, mass and momentum interfacial interaction between the phases in the system. The model predicts the velocity, temperature field of the molten slag bath, generated turbulence, vortex and coal utilization behavior from the slag bath. The highest coal penetration distance was found to be at l/L = 0.2, where / is the distance from the tuyere tip and L is the total length (2.44m) of the modeled furnace. The model also predicts that 10% of the injected coal bypasses the tuyere gas stream un-combusted and carried to the free surface, which contributes to ZnO reduction near the free surface.IntroductionSignificant metal values are often discarded with slag in the form of metal oxide produced by the smelting industries. These metal values can be recovered from the slag by proper treatment. Zinc slag fuming is such a process, where a reductant source (usually coal) is injected in the molten slag bath to reduce dissolved ZnO from the bath into metallic zinc vapour. The process can be carried out in either conventional tuyere blown furnace or top submerged lance (TSL) smelting furnace. Conventional slag fuming processes are carried out on batch basis in a rectangular tuyere blown furnace. Approximately 50 tonnes of charge (either molten slag or solid slag) is fed to the furnace at the beginning of each fuming cycle. Two opposing sets of submerged tuyeres are employed to inject air and pulverized coal into the molten slag bath to carry out combustion and reducing reactions."

Jan 1, 2012

By Oleksandr Liaskovskiy, Sergey Beringov, Sergiy Yatsuk, Timur Vlasenko, Iryna Buchovska

"Working with solar-grade silicon for solar cells application usually meets some difficulties in comparison to polysilicon produced by Siemens method: higher impurities content leads to lower yield, worse electro-physical parameters and poor performance in solar cells application. However some adjustments in ingot production can show significant improvements in quality of final product: crystalline wafers and cells.Recent investigations have shown that solar-grade silicon is suitable for high effective production process such as mono-like multicrystalline wafer production. Production-scale lots made at Pillar show promising results for solar-grade silicon application: high-quality wafers with significantly big crystalline grains of <100> orientation.IntroductionThe standard technology of producing multicrystalline silicon ingots by directional solidification method in quartz crucibles has a number of disadvantages resulting in limited efficiency of solar cells made of multicrystalline material: crystallites of multicrystalline ingot are relatively small (down to 5 mm size), grain borders of crystallites contain parasitic impurities such as metals, silicon nitride etc., crystallographic orientation of crystallites is random. The listed deficiencies are an integral characteristic of the technology which affects the efficiency of solar cells, such as presence of solar cells with low efficiency even at a high level of average efficiency, problems with shunted cells, silicon nitride inclusions, which adversely affect cell efficiency and are centres for silicon carbide formation, impossibility of application of high effective alkaline texturing etc. Also with regard to the targets set by photovoltaic to reduce the cost per Wp in the nearest future, standard technology of multicrystalline silicon ingots production by directional solidification faces certain challenges some of which are hard to overcome due to rather low efficiency of solar cells made of multicrystalline wafers. Therefore alternative methods of multicrystalline silicon production for photovoltaic application having a number of advantages in comparison to traditional technology are developing rapidly."

Jan 1, 2012

By Lucas Nana Wiredu Damoah, Lifeng Zhang

"Increasing demand for Solar Grade Silicon (SoG-Si) due to rising interest in renewable energy has lead to increased SoG-Si Top – cut scraps generated from the multi-crystalline silicon making process. Due to the high cost of SoG-Si and the potential to use the top-cut scraps as feedstock material, there has been increased effort to develop cost effective and efficient technologies. As a result, several methods to recycle the top-cut scraps are currently been applied, and researched. These include settling under gravitation field, which is a slow process to be industrially applicable. Natural settling of inclusions by gravitational force is a slow process and not attractive to the industry. Recent experiments on Top-cut SoG-Si scrap under high frequency, high voltage, electromagnetic field showed that SiC inclusions settled within a short time to the bottom of the crucible and the characteristic rod-like morphologies of Si3N4 inclusions in SoG-Si were not detected. This study investigates the enhanced settling of SiC inclusions and the behavior of Si3N4 particles under the influence of high frequency, high voltage, electromagnetic field in Top-cut SoG-Si.IntroductionThe photovoltaic industry depends on silicon based PV materials either as single-crystalline silicon, or multi-crystalline Si (MC-Si), or amorphous Si [1] for over 90 % of its market share. [2] MC-Si produced by directional solidification of solar grade silicon melt dominates the silicon PV market. During the directional solidification process, SiC and Si3N4 particles within the melt are pushed by the solidification front to the top of the ingot which is the last to solidify. Therefore the top of the ingot is cut generating what is known as top-cut solar silicon scraps. The Si3N4 particles are mainly from the coating material at the inside surface of the silica crucible and from air absorption during the solidification process. The SiC particles mainly stem from the carbon reduction process of the primary production of silicon [3]. Due to the growth of the PV industry as a result of global demand for clean, reliable, and affordable energy [4], there is the need to develop new methods to compliment exiting ones to recycle SoG-Si waste (e.g. top-cut) for sustainability."

Jan 1, 2012

By Dan Wang, Yuanbo Zhang, Guihong Han, Guanghui Li, Tao Jiang, Yanfang Huang

"Hematite concentrates are characterized by bad high-temperature reactivity and poor balling index, which restrict their large-scale application in the production of oxidized pellets. An organic additive, namely MHA, was authorized and used as binder recently in China. Compared with bentonite, the effects of MHA on compressive strength of hematite pellets at various firing conditions were investigated in this study. Experimental results showed the compressive strengths of preheated pellets with different binders were increased with increasing the preheating temperature and time. The compressive strength of preheated pellets with MHA binder was lower than that of pellets with bentonite, which can be ascribed to the high porosity of pellets with MHA binder. However, the compressive strength of roasted pellets with MHA binder was higher than that of pellets with bentonite. The compressive strength of finished pellets balled with MHA binder 1.0 wt% could meet the operation requirements of grate-kiln process.IntroductionHematite concentrates are characterized by bad high-temperature reactivity and poor balling index, which can lead to the appearance of those problems with increasing the energy consumption, shortening the useful life of equipment, and finally increasing the operation cost of oxidized pellets plants [1-2]. Some investigations have been conducted based on improving the pelletizing technique of hematite concentrates, such as pretreatment of raw materials [3-7], optimization of ore proportioning [8], addition of solid fuels [9-16], and so on. Employing high pressure grinding roller for the treatment of hematite concentrates revealed that the mechanical strength of wet green pellets could be improved. However, the mechanical strength of fired pellets was not improved obviously [7]. Huang, et al., pointed out that the preheating and roasting temperature may be decreased and the compressive strength of fired pellets could be increased by blending a certain proportion of magnetite concentrates with hematite [8]. Nevertheless, there are a variety of magnetite ores different in physical and chemical properties in China, resulting in the instability operation [17]."

Jan 1, 2012

By L. Echeverri

Research studies have shown that the flow within feedwells displays a vortical structure and high velocities at the locations where standard tangential inlets force its way into the feedwell swirling flow, producing high local shear rates and flow non-uniformities. These hydraulic deficiencies can be attributed to the discrete feeding through a few entrances, usually one or no more than a few tangential feedpipes, which practically project jets into the vortex within the feedwell. The main consequences are unequal flocculation with aggregates subjected to different amounts of shear and a non-uniform discharge from the feedwell. This paper presents results on the application of CFD and small-scale models to develop a new design that overcomes these problems by using an involute shaped inlet that converges around the feedwell. The result is a new feedwell with enhanced hydraulics that perfectly couples with the FLSmidth E-Duc® Feed Dilution system by protecting the flocculated aggregates that have been carefully produced upstream, and that favors uniform sedimentation conditions within the thickener thanks to a uniform discharge, while maintaining a practical and trouble-free geometry with excellent turndown.

Jan 1, 2012

By A. Noble

Traditional simulations of mineral processing circuits are solved by straightforward numerical techniques which require iteration to accommodate recirculating loads. Depending on the complexity of the simulated circuit, this solution technique can be inexact, computationally intensive, and potentially unstable. In this communication, an alternate calculation approach is presented, wherein an exact analytical solution is determined as a function of the individual units? separation probabilities. All the stream data, including recirculating loads, may be solved simultaneously, negating the need for iteration. Furthermore, with an analytical solution available, circuit analysis may then be utilized to diagnose the relative separation potential of the circuit. By integrating these tools, the authors have developed a software package for evaluating circuit configurations. This paper presents the theory, development, and limitations of the software?s methodology along with industrial examples which highlight the tool?s applicability to industrial circuits.

Jan 1, 2012

By P. Dent

"Rare earth permanent magnets (REPM) have become virtually indispensible in hundreds of applications including aerospace, automotive, electronics, energy, medical and military. An understanding of REPMs is important since they are key drivers of demand for the overall rare earth sector. Rare earth permanent magnets stand out due to their superior magnetic properties of high induction and coercive force. We will discuss the past, current and future of the permanent magnet market and supply chain. We will summarize present and potential new nanocomposite and lower content or non rare earth magnet technologies and customer options which may mitigate rare earth usage.INTRODUCTIONRare earth permanent magnets are ubiquitous and often unseen critical components in many civilian, green energy and military technologies. They have become imbedded in applications such as hybrid electric vehicles, computer hard drives, direct-drive high power wind generators, audio speakers, motors, energy conversion systems, most weapons systems and hundreds of other uses. Several rare earth elements including neodymium, samarium, dysprosium, praseodymium, terbium and gadolinium are essential ingredients in production of the highest performance magnets available in the world today. They have enabled vast miniaturization and the significant increase in power density in hundreds of applications.China has become the dominant source of rare earth elements over the last two decades. Today, nearly 100 percent of the world’s rare earth metals and more than 95 percent of the rare earth oxides come from China. China’s near worldwide monopoly on the production of downstream materials such as rare earth oxides, metals and magnets severely impacts the supply chain in this growing global market. The past decade has seen an unmistakable trend toward increased dominance in raw material production and manufacturing by China, and a steep decline in U.S. production capabilities, most notably in the neodymium iron boron (Nd-Fe-B) market where there is currently no domestic production. This Chinese dominance is further demonstrated with over 65 percent of hard ferrite and roughly half of aluminum nickel cobalt (Alnico) and samarium cobalt (Sm-Co) production in that nation (Figure 1). In addition, China has imposed export quotas and export taxes of up to 25 percent for rare earth elements, arguably in violation of their covenants made with their protocol of accession to the Word Trade Organization. These export quotas have been decreasing steadily over the last several years in spite of rising global demand and were slashed by 72 percent in July 2010 (Bradsher, 2010) causing many recent news stories."

Jan 1, 2012

By J. R. Goode

ABSTRACT Aurora Energy Ltd. is considering a 10,000 t/d process plant to produce 97 million lb (43,998,460 kg) of U3O8 over a 17-year project from uranium deposits in coastal Labrador. This paper summarizes the test work, mostly done by SGS Mineral Services in Lakefield, Ontario, and the economic studies supporting flowsheet selection. The proposed flowsheet includes semi-autogenous grinding (SAG) and ball milling, acid leaching using air/SO2 as an oxidant, and resin-in-pulp (RIP) extraction of uranium from the leached slurry. Other unit operations examined include ore sorting, heap leaching, liquid- solid separation, solvent extraction, and nanofiltration for eluate upgrading. We also review the extensive environmental test work and studies that were completed.

Jan 1, 2012

By T. Möller

Grinding mills are the heart of the mineral processing plant, and are production-critical machines which are required to achieve high availability. Liner wear life and a liner design that promotes ease of installation are important variables to achieve a high level of mill availability. Increased mill size results in more mill internal surface to protect, and more liner components to install and remove. This drives designers toward an increase in liner size to minimize the number of components to be installed by the liner handler. The liner attachment method can also have a large impact on mill availability as well as safety during installation. This paper outlines the experience from the development, installation and follow-up of liners installed in two 38&apos; x 45&apos; AG Mills at Boliden Aitik in Sweden. A new Poly-Met shell liner concept has been developed to minimize the number of liner components. The new Poly-Met shell liner components are made much larger than conventional Poly-Met or steel liners. This reduces the number of components to be installed/removed by the liner handler and helps to minimize installation time and consequently down- time. A new attachment system has also been developed to eliminate the need for the installation crew to be in the ?drop-zone? of the shell liners while installing the liner bolts. One interesting aspect of this project was the requirement to predict liner life for these new large format AG mills. The existing 22&apos; diameter mills at Aitik provided a base-line reference for this purpose, and DEM studies were used in the project development stage to predict the wear life of shell liners for the new 38&apos; diameter AG mills. The results from this study are included.

Jan 1, 2012

By Tristan H. Jones

Beginning in 1987, miniature dataloggers approved by the Mine Safety and Health Administration (MSHA) were publicly available for sale. The principal among these was the model CR21XQM, manufactured by Campbell Scientific, Inc. These dataloggers had been tested and were deemed permissible by MSHA and thus could be installed in the return air of an underground coal mine. In 1996, production of all permissible Campbell Scientific dataloggers ceased due to lack of sales. Data collection with these dataloggers has been a staple of ground control research in the United States for decades, and, without them, or a replacement, the capability to monitor ground behavior is severely impacted. Since that time, any party requiring a permissible datalogger has needed to borrow one that was purchased during the production years. In order to fill this technology gap and ensure its own data-gathering capabilities, the National Institute for Occupational Safety and Health (NIOSH) has developed and refined its own miniature data acquisition system (MIDAS). On February 16, 2010, MSHA deemed the MIDAS to be permissible and approved it for use in the return air of an underground coal mine. The MIDAS is an intrinsically safe, 16- or 24-bit datalogger, compatible with a wide range of resistive, single-ended, and differential-type instrumentation. It contains enough data storage memory to operate for over a year with typical data rates and is efficient enough to do this on a single C-sized alkaline battery for that entire period. It is menu-driven and requires no programming knowledge to operate. It supports wireless or hardwired communication for datalogger setup and data download. This paper describes the design, field and laboratory testing, and capabilities of the MIDAS datalogger. While not as fully -functioned as the CR21XQM, it is the only new permissible datalogger available, and there is intent to make it available to the mining industry for purchase.

Jan 1, 2012

By Z. Duan

A novel concept involving the deployment of chemical stabilization has the potential to eliminate the need of slurry impoundments and significantly reduce the release of trace elements from the high surface area fine coal waste. The process involves mixing the fine waste generated from the underflow of a thickener operation with chemical stabilization agents to tie up the water and to create a solid waste material that can be discharged directly. Portland cement, sodium silicate, F type flyash, C type flyash and hydraulic lime were evaluated as stabilizing agents. A detailed experimental study has been conducted to identify the conditions that provide the maximum compressive strength within a short curing time. Results to date show the ability to achieve compressive strengths adequate for equipment to maneuver on using a Portland cement concentration of around 10% by weight. Quick-setting concrete was not found to enhance stabilization time and compressive strength.

Jan 1, 2012

By J. Kramer, T. Hartmann

In the Hydrometallurgical processes, the presence of the so-called “crud” is a constant challenge in solvent extraction. Crud is a stable emulsion which forms along the interface between the aqueous and organic phase. The spread is influenced by the following parameters: first, wind blows the dust and impurities into the open sedimentation tanks. Second, the undissolved solids such as sand transported in the PLS causing problems in conjunction with incorrect agitator design. The crud fraction can decisively impact the efficiency of the hydrometallurgical extraction because the phase interface can constitute a large fraction and the sedimentation tanks cannot react flexibly to it. In the downstream process of the seriesconnected sedimentation tanks, they are thus all contaminated with crud. At the same time, the necessary mass transport is significantly impeded at the phase boundary between organic phase and aqueous phase due to the crud formation. The transfer of the organic phase into the electrolysis cell can result in a “burnout” of the cathode. The carry-over of this electrolyte into the extraction can cause problems with the pH regulation. The carry-over of the organic components into the raffinate also leads to contamination of the leaching circuit. The continuous treatment of the crud with a 3-phase decanter centrifuge is extremely effective in combating this problem. This technology splits all three phases from each other and they are consequently continuously separated. All subsequent process steps exhibit a stable, uniform effectiveness. The main advantage for the customer is that fluctuations in the process are eliminated and the organic phase can be recirculated back to the extraction. The recycling of the solvent alone justifies the investment in less than 6 months as examples from South Africa and Chile show. To operate solvent recovery in daily operation fully automated online at the optimum limit, the decanter centrifuge is equipped with a concentration-dependent pond adjustment called DControl®. By this means, we can guarantee our customers the maximum possible solvent recovery and minimise the solvent costs in this process step. This system is presented in detail in this paper.

Jan 1, 2012

By H. Z. Liu, J. M. Zhao, F. C. Wang

"Novel silicate-alginate composite beads containing 2-ethylhexyl phosphonic acid mono-2- ethylhexyl ester (P507) were synthesized and applied for the adsorption of Nd3+ from aqueous solutions. The adsorption amount of Nd3+ has been increased owing to the introduction of P507. The effect of equilibrium pH (pHe), the kinetic and isotherm experiments were investigated. The adsorption reaches equilibrium at 9 h and the maximum uptake capacity is up to 195.4 mg/(g dry adsorbent). The Langmuir isotherm equations are used to describe the adsorption process. Complete desorption can be realized with 0.2 M HCl within 20 min. INTRODUCTIONRare earth elements (REEs) have found various applications in different domains, such as metallurgy industry, ceramic industry, nuclear fuel control, photo-electro-magnetic functional materials owing to their unique properties. Neodymium (Nd), as a representative of all of the most valuable REEs, is widely used as catalysts, laser crystals, capacitors, rubber additives, Nd-Fe-B magnets, hydrogen storage and so on. Thus, the separation and purification of neodymium is significant. Unfortunately, Nd always coexists with other REEs and selective separation of the individual Nd from the REEs mixtures is still extremely difficult owing to their strictly similar atomic structures and chemical properties.Liquid-liquid extraction (LLE) and solid-liquid adsorption (SLA) are the most widely adopted techniques for the separation of REEs in the hydrometallurgical fields. The LLE process is well suited for large-scale continuous operation because of its inherent high capacity and fast kinetics. Nowadays, as a commercial extractant, 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester (P507) has been extensively studied for extraction and separation of REEs since it has considerably good extractability and high separation efficiency (Xu et al., 1992). SLA is one of the effective and green separation methods with some prominent advantages, such as easy regeneration of adsorbents, small footprint size, less industrial wastes, higher enrichment factors and column efficiency,rapid solid–liquid separation without emulsion and so on. Hence, the introduction of extractants with excellent performance into adsorbents will integrate the advantages of LLE and SLA (Lee et al., 2009)."

Jan 1, 2012

If one can embrace the medical analogue, much of the mining industry currently suffers from a massive bacterial infection. When pyrite-bearing or sulfide-bearing rock formations, tailings, or mine wastes are infected by Acidithiobacillus ferro-oxidans, the likelihood of forming acid rock drainage (ARD) is almost guaranteed. The ?pharmacy? of antibiotics available is extensive, ranging from solid alkaline amendments like limestone to liquid ?medicines? such as sodium lauryl sulfate, sodium thiocyanate, waste milk, and bipolar lipids. Unfortunately, the ?geo-medical? teams of geochemists, microbiologists, engineers, and mine managers lack the tools to surgically apply these active ingredients where they are needed most with a minimum of waste. Distribution of fine grained limestone on the surface of an acidic mine waste dump is analogous to applying a bandage soaked in antacid to treat an upset stomach. The implementation of up-to-date best management practices has not healed the patient; an equivalent combination of hypodermic needle, cyber knife, and arthroscopic probe is clearly needed. Using an engineered, flow-able or pumpable foam or pHoam? as the medicinally analogous ?dextrose delivery solution? for solid and/or liquid ?geo-antibiotics?, the authors have combined off-the-shelf technologies that have been previously applied in solving geotechnical problems in the mining industry. A patent for the innovative process is pending. This paper discusses method concepts and the advantages it could provide over conventional BMPs.

Jan 1, 2012