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By B. Govindarajan, L. S. Rao, T. C. Rao, B. R. Rao

Laboratory leaching experiments were conducted to extract potassium from glauconitic sandstone, and the effects of important variables were studied. The reduced time plot (RTP) for all of the variables obtained from the experimental data has been quantified by this simple equation: R = 100 (1 - exp (-0.693 *(T/T50)0.605) The time required for 50% extraction (T50) has been correlated by a regression equation to variables such as acid strength, temperature, fluorite: glauconite ratio and % solids. Both of these equations were used to predict the extraction percentage at different process-variable levels. In addition, several other experiments were conducted at arbitrary levels of the variables to verify the equations developed.

Jan 1, 1994

By B. A. Bancroft

A quality assurance program consists of all those activities aimed at providing confidence to the purchaser that the suppliers quality system will provide a product that will satisfy the purchaser's stated quality requirement. An organizing principle is necessary for prioritizing the quality control activities of quality personnel in the face of a myriad of technical possibilities, data-analytic applications, and an overwhelming number of possible activities promoted in the literature and by quality "gurus". The organizing principle I like is that quality assurance exists when those involved in the quality process: (1) know what they are supposed to do, (2) can tell if they are doing it and are set up to continue doing it and, (3) if they are not, they can remedy the situation in a timely fashion. Any incremental activity which facilitates this organizing principle is a continuous improvement activity. That activity which has the chance to facilitate this principle to the greatest extent is the next one to work on. In these days of lean corporate and regional staffs it is as important to know what not to work on as it is to know what to work on. In this paper I shall discuss in general terms the implications of this organizing principle for the design of Quality Assurance (QA) Programs for coal mines and also provide some comments about the application of Statistical Process Control (SPC) methodologies in the coal industry.

Jan 1, 1994

By R. A. Plumbridge

I am deeply honoured by your invitation to address your great Institute on this centenary occasion. Mining is a cyclic industry that continuously faces enormous challenges as it wrests the treasures of the earth from an often reluctant mother nature. Throughout the ages, those challenges have demanded great skill from mining men and women, who are required to blend a mixture of robust determination with art and science. Pioneer Miners and Scientists It is not surprising therefore that the first blush of euphoria surrounding the discovery of gold on the Witwatersrand quickly gave way to consternation about the need to increase the metallurgical recovery of gold from the then readily identifiable conglomerate. The rugged pioneer miners had to turn to scientists for their salvation.

Jan 1, 1994

By G. G. Richards

The zinc slag fuming process is used to recover zinc from molten iron-calcium silicate slags by treatment with pulverized coal and air. The rate of zinc fuming is controlled by the complex interaction of several kinetic factors including the rate of entrainment of coal in the slag, the extent of the coal-slag reaction and the rate of ferrous oxide oxidation to ferric oxide. This paper briefly outlines the mechanism of fuming and, on this basis, optimization of process parameters is discussed. Modelling analysis and recent industrial trials at Cominco show that coal entrainment in the slag, bath temperature, and bath depth are critical variables affecting process rate and efficiency. The first step in process optimization is to assess coal bypass of the bath. In general, changes which promote operation at a higher temperature, greater coal entrainment in the slag and extended residence time of the coal in the bath increase fuming performance. Coal entrainment is controlled by injection conditions whereas bath temperature is a function of coal combustion and ferrous oxide oxidation. Residence time of the coal is largely a function of bath depth. The implication of model predictions for continuous fuming is shown.

Jan 1, 1994

By Jeffrey M. Christian

Gold prices are rising, in what is coming to be seen as the beginning of a longer term upward trend. After languishing between $325/oz and $364/ oz from early 1991 into early 1993, prices began rising in the first half of 1993. Gold rose from a low of $326/oz in March 1993 to $414/oz on an intraday basis in early August. There was a speculative sell-off at that point, which took gold prices quickly back down to $350/oz briefly in October 1993. At that time, there still was a fair degree of skepticism about gold's price prospects. Many banks believed that gold prices could not mount a sustained rally. As prices dropped in August and September of last year, these suspicions seemed to be confirmed. Gold prices quickly rebounded, however, reaching $395/oz by early January 1994. The strength of this renewed increase led many banks, investors and others that had held negative views of gold to grow more positive. They began buying gold and trading it from the long side of the market. The result was that gold prices remained strong during the first quarter of 1994, trading between $375/oz and $390/oz.

Jan 1, 1994

By R. G. Benson

The San Luis deposit of Costilla county, Colorado contained 11,021,000 tonnes (12,149,000 tons) of ore at 1.4 g/t (0.040 oz/st) gold in two minable zones. Gold mineralization is associated with silicification and quartz-sericite-pyrite alteration localized in breccias along a low-angle detachment fault zone in Precambrian gneiss. Gangue minerals include chlorite, specular hematite, chalcopyrite, chalcocite, and fluorite. Mineralization is mid-Tertiary in age and has a direct genetic relation to the emplacement of felsic intrusions. Portions of the ore body are unconformably overlain by sedimentary rocks of the Tertiary Santa Fe Formation. The deposit formed during the early stages of extensional tectonism along the eastern edge of the present day Rio Grande rift.

Jan 1, 1994

Resource developers in Papua New Guinea (PNG) are now, more than ever before, confronted with land-owner related issues that can hinder their corporate objectives.Development of PNG's custom-arily owned land since independence has brought sudden changes with mixed success. Exploitation of mineral resources has had its share of problems, and Highlands Gold Limit-ed's (HGL) endeavours in the central Highlands of PNG are no exception.

Jan 1, 1994

By C. G. Anderson

Extraction of valuable resources from complex orebodies will become more common. This is obvious for two reasons. First, the cleaner and more readily processed ores have continually been depleted through centuries of mining. Second, new technologies have evolved for effectively handling complex ores. One of these new processes has been in place at Sunshine since 1984. Based on sulfuric acid oxygen pressure leaching with nitric acid as an oxidizer, this patented technology allows silver and copper to be efficiently recovered from a complex sulfide concentrate. As efficient as it is, this process represents novel technology found nowhere else on an industrial scale. As such, a research program was undertaken in 1989 to optimize this leach process and to better understand it. From this study, several potential plant improvements were found and recommended. As a result, two of these options, nitric acid replacement by sodium nitrite and concentrate regrind are now used in day to day operation at Sunshine. Patenting of these changes was recently accomplished (1). Thus, the development, perceived mechanisms, plant integration and potential applicability of this technology will be covered in this paper.

Jan 1, 1994

By Robin Perry, Claude Bazin

"Discrete transfer functions which use the grinding circuit feed tonnage to predict mass flowrates at reagent addition points in a flotation circuit were calibrated using a dynamic grinding/flotation circuit simulator. Predicted mass flow values are multiplied by reagent addition ratios to obtain actual reagent flow. The transfer functions are currently integrated into the distributed control system of Les Mines Selbaie.IntroductionThe development of adequate tools for the control of flotation processes is a continuous challenge. Since the early 1970s there have been numerous publications dealing with practical aspect of control of flotation processes. Most plants use a combination of feedback and feedforward controls to reduce the effect of the following flotation process disturbances (McKee, 1991):• changes in throughput;• changes in feed grade;• changes in particle floatability (size, liberation, surface oxidation ... ); and • deliberate changes of setpoint;Feedforward control manipulates variables such as reagent and/or air flow rate to attenuate the effect of disturbances such as changes of feed rate and mineral content. The feed forward strategy is driven by measurements of these disturbances. Feedback control is used to maintain process variables to targeted set-points of concentrate or tails grades. The feedback control action is driven by deviation from the set-point, caused by a deliberate change of set-point or disturbances.This paper proposes a method to improve feed forward control schemes by the addition of a simple model for solids transportation. The feedforward strategy considered in this paper is the ratio type, in which the manipulated variable is changed according to a predefmed ratio between this variable and the measured disturbance. A typical example is the ratio of the reagent addition to mass flow of ore.The paper reviews the state of the art in feed forward control strategy applied to flotation processes and describes the method used for predicting mass flow rates. The last section shows an application of the method in the Les Mines Selbaie flotation circuit."

Jan 1, 1994

By Jacques Monette, P K. O'Connell, Keith Boyle

The mine contracting industry in Canada is no different from any other industry in its quest for productivity improvements. Dynatec Mining Ltd. has focused on drilling and blasting of rounds as an area for improvement. This paper describes the development of blasting long rounds in shaft sinking as well as a description of the lateral excavation system as applied at Aur Resources Inc., Louvicourt Project.

Jan 1, 1994

By R. J. Chase, C. Davies

"Abstract- The Merelani graphite-tanzanite deposit is located in northeast Tanzania, 14 kilometers south of Kilirnajaro International Airport and in close proximity to the towns of Moshi and Arusha . The graphite mineralization is hosted by relatively undeformed linear Proterowic metasedimentary gneisses, several of which have been subjected to hydrothermal alteration resulting in tanzanite mineralization. Exploration work comprised detailed geological mapping coupled with pit and trench channel sampling and a subsequent 1500 meters of diamond drilling. In addition, metallurgical tests have shown the graphite to be of unusually coarse flake size, crystallinity and high purity.Feasibility studies have shown the economic viability of a major coarse flake graphite deposit with the measured resource to 50 meters in excess of 9 million tonnes assaying over 8o/o graphitic carbon . Production is due to start by the end of the first quarter of 1994 with the processing plant design capacity initially set at 15 000 tonnes per annum.ln addition to graphite production, tanzanite will be produced through selective mining within the graphite open pit in the upper horizon and from underground workings within the lower horizon.The Merelani graphite-tanzanite deposit will be the first major orebody to be exploited through means of private funding since Tanzania gained independence."

Jan 1, 1994

By Craig M. Sams

Dry grinding circuits and factors influencing the selection of the most appropriate grinding system for a given ore selection are discussed. Comparisons of the drying, grindability, installed costs and operating costs are presented for several grinding systems.

Jan 1, 1994

By Eupene GS

The valuation of exploration properties which contain no identified resources or reserves is the most subjective of all valuation tasks likely to be carried out by a geologist. The geoscience rating method proposed by Kilburn (1990) recognises this inherent subjectivity but also attempts to apply some discipline to the valuation process. Some other methods used for valuations of this type clearly lack discipline and are open to misuse and abuse. The Kilburn method essentially requires the practitioner to justify all aspects of the valuation process. The valuer must specify and, more importantly, quantify aspects which enhance or downgrade the intrinsic value of each property. The intrinsic value is called the ""base acquisition cost"" (BAC) and it represents the average cost to identify, apply for and retain a base unit of area of title. The BAC and base unit of area both vary with different types of exploration and mining title but remain constant for similar types of titles in the same mineral tenure regime. In the Kilburn Method the enhancement/ downgrading factors are determined by the geotechnical prospectivity (Kilburn Method) within the title. A modified version of the Kilburn Method presented here (""Modified Kilburn Method"") also focuses attention on other real variables besides the geotechnical attributes which influence valuations of this type, viz., competition for tenure and activity in the markets in which the exploration properties are being traded. The most active such market at present is the stock market. By utilising uniform BACs and base units of area (for similar titles) for all exploration properties (in practice in Australia this is only possible within a particular State or Territory), the method exposes the valuer's opinions of each of these variables to the scrutiny of the investor. The investor (or his professional adviser) is afforded the opportunity to directly compare valuations on different properties by different practitioners and can assess how the final valuation is weighted in respect of geotechnical prospectivity, competition for tenure, and stock/financial market sentiment. No other method currently employed in Australia to value mineral exploration properties affords the investor this `luxury', which some may argue is their right.

Jan 1, 1994

By D. M. Larsen, N. D. King

Since start-up in 1985, the Cannon Mine has produced and shipped a 170-g/ton (5 oz/ton) gold flotation concentrate to various smelters for gold and silver recovery. Several processes have been investigated to economically produce dore' at the mine site from the refractory concentrate. This paper describes laboratory and pilot scale test work used in the process design and engineering feasibility study of a 73-t/d (80 stpd) pressure oxidation and carbon-in-leach (CIL) facility. The designed pressure oxidation circuit utilizes a series of vertical autoclave units operating at 170°C (338°F) and 1.4 MPa (200 psig). Projected operating costs are discussed.

Jan 1, 1994

By R. P. Viljoen, A. L. Sokolov

"The distribution of mineralized provinces is analyzed on the basis of their genetic link with specific blocks of the earth's crust including ancient platforms, mobile belts and zones of tectonicmagmatic activation. Mobile and fold belts surround the Siberian platform in Russia and the Kaapvaal craton in South Africa, with decreasing age zoning away from ancient platform margins. The main differences in the geological development of the two cratonic areas are: (1) the long period before the final stabilization of the Siberian platform (3600 Ma to 1600 Ma) and the comparatively short period of time for the stabilization of the Kaapvaal craton (3600 Ma to 3050 Ma) and (2) the intensive multiple activation of the marginal zones of the Siberian platform and the tectonicallycontrolled, magmatic sedimentary, intracratonic activity, typical of the Kaapvaal craton. Mineralization of the Siberian platform is largely characterized by marginal reactivation zones of differing ages although mineralized intracratonic Cu-bearing basins of Proterozoic age are also known. Mineralization of the Kaapvaal craton is mainly related to the formation of the intracratonic basins i.e., Witwatersrand (Au, U) and Transvaal (Au). The latter is characterized by multi-age volcanic-intrusive activity including the emplacement of Bushveld Complex (Cu, Ni, Pt, Cr, Au, V). The Siberian platform is characterized by the prolonged development of inherited mineralization from Archean until the late Mesozoic. The main period of mineralization in the Kaapvaal craton is restricted to the middle Proterozoic.The Baykal-Patomskaya and Namaqua-Natal mobile zones occupy similar positions adjacent to the Siberian and Kaapvaal cratons, respectively, and demonstrate similar modes of metallogenic development: i.e., the early formation of exhalative Pb-Zn-Cu deposits during the early stage and magmatic Cu deposits during the late stage. The more remote mobile belt near the Siberian platform, the Trans-Baykal, is characterized by intensive multi-age mineralization (Wo, Mo, Sn, fluorite), related to a period of tectonic-magmatic activation. The Saldania Belt occupies a similar position near the Kaapvaal craton but is known for its poor Au, and Cu mineralization. It does, however, have some similarities with Trans-Baykal Belt in regard to Mo-W bearing granitoids.The phenomenon of interference of geosynclinal, orogenic, platform, and tectono-magmatic activation regimes is known for the Russian section of the Pacific Ocean Volcanic Belt."

Jan 1, 1994

By C. D. Adams, R. T. Tuenge, C. N. King, J. A. Samuels, B. F. Espinoza, R. C. Dye, C. F. Schaus, D. C. Smith, N. M. Peachey

"Recently, doped calcium thiogallate (CaGa2S4) phosphors have been investigated for use in electroluminescent flat panel displays. The current technique used for the deposition of thin film calcium thiogallate is sputtering. Unfortunately, this requires a high temperature annealing process to provide the desired crystallinity of the phosphor. Recent efforts have focused on the possible use of metal-organic chemical vapor deposition (MOCVD) to produce the CaGa2S4 layer. The use of MOCVD provides an attractive alternative to sputtering since it does not require heating above the strain point temperatures of the glass substrates used for the display panels. To accomplish this, the deposition of both Ga2S3 and CaS is investigated as these compounds are intermediate steps in the development of the phosphor deposition. Uniform, crystalline films of both Ga2S3 and CaS were deposited and the process shows promise for successful deposition of the CaGa2S4 phosphor.IntroductionThe lack of a satisfactory blue phosphor having sufficiently high luminances at low power has hampered the development of high resolution flat panel displays. Recently, a new series of blue emitting materials have been investigated for use in thin film electroluminescent (TFEL) devices. l ,2,3 These phosphors are based on a series of alkaline earth thiogallate host materials of the form MGa2S4:RE where M can be either calcium, strontium, zinc, or barium and RE is a rare earth ion. A full-color VGA TFEL panel using CaGa2S4:Ce as the blue phosphor has recently been fabricated and tested. l This FPD provided a luminance of 10 cdlm2 at 60 Hz. The enhanced blue in this display allowed its color capabilities to approach those of the conventional CRT.The method of depositing the phosphor onto the display panels in these test devices has been sputtering. Unfortunately the phosphor as deposited does not possess the crystalline properties required for optimum luminance. The crystalline structure is achieved by subsequent annealing of the deposited material. Although this post deposition anneal provides the desired crystal structure, it occurs above the strain point temperature of ordinary glass. Consequently, the implementation of these phosphors requires the use of glasses capable of withstanding high temperatures, adding to the cost of the final display unit."

Jan 1, 1994

By Stephen K. Pave1

Over 1,100 tons per day of Fluid Catalytic Cracking Unit (FCCU) catalyst is used worldwide. During the cracking reaction, catalyst is contaminated by deposited metals including nickel, vanadium, potassium, copper, iron, sodium, etc. To compensate for contaminants, a portion of the circulating catalyst inventory is withdrawn for disposal and fresh catalyst is added. The DEMETR process takes spent FCCU catalyst and removes a portion of the metal contaminants, enabling the refiner to recycle demetallized catalyst, thus reducing the solid waste from the refinery. Through August, 1993, the operation of one unit for one refiner has resulted in the recycling of over 7,500 tons of spent catalyst.

Jan 1, 1994

By K. A. Wheeler

To evaluate the effects on groundwater of a proposed in-pit disposal operation at an east Texas lignite mine, the local geologic, hydrogeologic, and geochemical features were thoroughly characterized. Resultant data were used in a flow and transport model (SWIFT) to simulate migration of the ash leachate. Computer simulations indicate that the leachate plume will travel 61-152 meters from the disposal area in 100 years after resaturation of the spoils. A 61-meter buffer zone of mine spoils without ash will surround the disposal area. The proposed landfill operation received regulatory approval and is currently operating as a Class 2 non-hazardous landfill.

Jan 1, 1994

By Zvi Rivlin

Classical nucleation theory states that in first order phase transformations, such as liquid to solid transition, nucleation of the product phase starts with the formation of small, unstable clusters (embryos). When the thermodynamic barrier to nucleation is overcome, the embryos grow and attain a critical size, beyond which they are stable, i.e. they become nuclei. If nucle- ation does not occur, the parent, liquid phase remains in metastable equilibrium. At temperature lowers, undercooling increase and atomic mobility decreases. The viscosity change in the undercooled liquid may result in the formation of glassy state. As demonstrated in previous papers [I-21, in solidification involving surface nucleation of the product phase, as the case is in rapid quenching by melt-spinning, both nucleation temperature and nucleation time depend upon the number of atoms available at the isothermal surface in contact with the substrate. As a result of the thinness of the melt-spun ribbons, the embryo clusters that form at the freezing temperature may not be supplied by the amount of atoms necessary for their growth to critical nuclei sizes. In such extreme conditions, the liquid does not crystallize, it forms a metallic glass. A numerical simulation method is proposed for the reactions involved in embryo cluster formation and growth, at the atomic level. The simulation enables the caIcuIation of either the nucleation or the glass transition temperatures. Calculations made for the well-known glass forming CuZr and FeB systems afford prediction of the geometrical and thermodynamically conditions necessary for the formation of either crystalline or amorphous ribbons in melt-spun ribbons.

Jan 1, 1994

By J. Shahabpour

"Abstract - Breccias with angular and rounded clasts of a late-mineralization, ""barren"" hornblende porphyry dike set within a comminuted matrix consisting of rock fragments and quartz, cemented by quartz and K-feldspar of hydrothermal origin is observed in diamond drill cores from the Sar Cheshmeh porphyry copper deposit. Studies of age relationship between vein types, phyllic-altered clasts and the breccia groundmass suggest that the brecciation is a late event. The breccia clasts record evidence of hydrothermal reaction between the clasts and fluids responsible for the brecciation.Formation of bornite, in the breccia clasts of the originally barren hornblende porphyry dike, and in the breccia matrix, along with the scarcity of bornite in the Sar Cheshmeh deposit itself suggest involvement of fluids which are later and of different composition from the fluids responsible for the known mineralization at Sar Cheshmeh. These later fluids may be related to a later plutonic event and suggest the possibility of a later, and concealed deposit."

Jan 1, 1994