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By Ault A. R

The recent modernisation program at the Risdon electrolytic zinc smelter of Pasminco Metals - EZ (PMEZ) inyolved significant changes to the composition of cell electrolytes. The most significant were increased acidity and sulphate level, a reduction in Co level, and the replacement of 2-naphthol in the additive mixture with licorice. In determining acceptable operating ranges, a relatively large number of industrial deposition tests under controlled conditions was required. The cathode zinc deposits so produced were examined in terms of overall appearance, crystal structure according to X-ray diffraction, and a micro-roughness parameter. Beginning with typical deposits produced in the presence of an excess of one of the addition agents glue or antimony or a mist suppressant (licorice or 2-naphthol), a simple classification system was developed. In this system, the deposits are divided into the following types: Doughy, Pinholed, Compact and Stressed. There was a weak correlation between deposit type and crystal orientation. In terms of ease of stripping, observations in plant operations showed that only Compact and Pinholed were consistently acceptable. Current efficiency was normally maximised by producing a Compact deposit. Process variables such as zinc concentration, temperature and the use of strontium carbonate were found to cause changes in deposit type if the reagent mixture used was unchanged. From the knowledge gained, guidelines were developed to allow glue and antimony additions to be altered to fit new circumstances. The simple classification system was first used to expedite recovery from undesirable morphologies and then to optimise individual cell units operated under substantially different conditions. It is believed that finer control could be exercised by determining the micro-roughness of Compact deposits. However, difficulties can arise if sudden, large deviations occur and go undetected. Suggestions are given for an improved additive control system. The classification system developed has been compared with published information in the literature, and good correspondence was noted suggesting a predictable relationship between short-term, laboratory deposition tests and observable phenomena in industrial electrowinning cells run under steady conditions.

Jan 1, 1993

By B. C. Bhowmick, B. B. Dhar

Central system of ventilation, adopted almost universally in coal mines of India and elsewhere in the world, has often proved deficent in providing a cost effective solution to the acute ventilation problems of remote workings in many mines. Loss of air due to leakage through a number of stoppings, doors etc. and accumulation of heat and moisture by intake air on its way to a working through long and circuitous route are the main unavoidable reasons for low efficiency of the system, sluggish and oppressive ventilation of workings. Multi-zonal ventilation system using large diameter bore holes for feeding fresh air in the mine close to a working has been proposed as a viable economic alternative. The method promises to provide congenial environment at working faces without resorting to air conditioning or use of booster fan. Optimum location and diameter of bore holes as well as general design procedure have been dealt in the paper. Finally, the technical as well as economic advantages of the method over the conventional design have been highlighted with the help of a case study where ventilation system of an extensive shallow mine in Central India has been redesigned according to the old and the new concepts. The methodology is general enough for adoption elsewhere in other mines under similar circumstances.

Jan 1, 1993

By Thomas W. Camm

The U.S. Bureau of Mines has developed a system for estimating mining and processing costs as a function of process feed rate with the objective of applying this system to abandoned mine tailings and to evaluate the benefits, if any, of metal recovery. Cost analysis was applied to the mine wastes of Smelterville Flats: an extensive area of mine tailings in the Bunker Hill Superfund Site with high concentrations of lead, zinc, and other sulfide minerals. Results from previous site characterization and metallurgical processing studies were used as the input for the cost analysis. This analysis indicated that processing this site at an optimum production rate of 3,500 short tons per day (st/d) could generate a positive cash flow.

Jan 1, 1993

Shear-flocculation is one of a munber of potential processes for upgrading deposits of finely-grained minerals and, more generally, for separating different types of particles suspended in a fluid.The smaller the particle the more likely it is to follow the fluid streamlines, or be entrained within turbulent eddies, and the less likely it is to deviate from the streamline and attach to bubbles (froth flotation), other particles (selective flocculation) or magnetic poles (wet magnetic separation). As shown in Figure I, a number of ingenious ideas have been proposed to overcome this effect. The suspended particles are assumed to be 1 - 10 µm.Thus, the efficiency of attaching ultrafme particles of the valuable component (solid circles) to air bubbles, as in process A, is poor. The efficiency may be improved by attaching the particles to oil droplets (Ralston, Kart and Newcombe, 1984) to form agglomerates that rise or sink (B), to magnetic particles (C) (Parsonage, 1988) to allow recovery in a magnetic separator (D), to other particles to form aggregates (E) that are then either attached to bubbles (F) or recovered by sedimentation (G) (Warren, 1992), and to pieces of polyethylene (Rubio and Baltar, 1991) that rise or sink (H).In A, C, E, F and H, the forces that are generally used to ensure collisions result in adhesion are hydrophobic forces, hydrodynamic forces and inertial forces (Warren, 1992). These drag particles from the streamlines to allow particle-particle adhesion. In B and E, soluble polymeric molecules have been added to bridge between particles as they approach closely during a collision.The second major consideration is selectivity. Selective adsorption of the hydrophobe or polymer onto the valuable particles is the key. Many subtle effects of surface chemistry are involved in obtaining adequate selectivity. A complication in real systems is that the initial suspension is often naturally coagulated and needs to be dispersed before being selectively flocculated.

Jan 1, 1993

By J. A. Brierley, C. L. Brierley

The history, current applications and future of biotechnical developments in the metals' extraction industry are reviewed. Bioleaching of copper minerals continues to be the most significant application. Uranium bioleaching was successfully demonstrated at industrial scale. Developments are now being made in biooxidative pretreatment of refractory gold concentrates, ores and low-grade materials. Advancements are forthcoming in water and solid mine waste bioreclamation, including metals' biosorption, wetland treatment of acid mine drainage, and biodegradation of cyanide in spent, heap-leach operations. Better understanding of the types and functions of microorganisms involved in metal interactions could advance genetic engineering applications in bioleaching and bioreclamation.

Jan 1, 1993

By Oliveira JF

Thiourea is an alternative reagent for cyanide in gold leaching. The recovery of gold from acidic thiourea solutions by adsorption on activated carbon is based on methods similar to those applied for the extracting of gold from cyanide solutions, but the mechanism involved in the process is not completely understood. In the present work, studies were carried out to evaluate the adsorption of gold onto activated carbon. Experimental data showed good agreement with both the Freundlich and Langmuir isotherms. The adsorption of gold from acidic thiourea solutions proved to be an endothermic process, while the adsorption from cyanide is known to be exothermic. The isosteric heat of adsorption of -11.3 kcal/mol in the early stages of the adsorption is an indication of a process involving chemisorption. The effect of temperature was studied between 15¦C and 55¦C. An activation energy of 3.5 kcal/mol was determined by the Arrhenius plot, which indicates that the controlling step in the kinetics of adsorption is the diffusion onto the porous structure of the activated carbon.

Jan 1, 1993

By J. M. Goris

The U.S. Bureau of Mines, in a cooperative project with the University of Utah, Salt Lake City, UT, and Homestake Mining Co., Lead, SD, conducted in situ monitoring and numerical modeling of rock masses supported with cable bolts in two mechanized, cut-and-fill stopes and a shaft pillar at the Homestake Mine. Extensometers were used to measure rock displacement, while cable bolt strain gauges were installed to measure loads on both conventional and birdcage cable bolt supports. These instruments provided an assessment of rock mass behavior during mining as well as essential data for verifying results from computer analyses. The numerical modeling program FLAC was used to analyze cable bolt patterns and supports. Results from the evaluation study indicated that cable bolt strain gauges and extensometers were effective instruments for monitoring the behavior of rock masses supported with cable bolts. Also, numerical modeling of the 4S-48N stope using the FIAC code provided displacement values comparable with measurements from field extensometers.

Jan 1, 1993

By G. Andrews

This case study details the process that was used for project planning and permitting for the Greens Creek Mine, located near Juneau Alaska, as seen through the eyes of one of the primary environmental consultants. This case shows how a Company could involve the public and the agencies in the early 1980's and develop a project sensitive to concerns expressed with a high level of environmental protection. Comparisons are made to the current environmental permitting situation. Initial baseline studies performed during the exploration phase provided helpful information for more detailed environmental work in 1980-1981 as planning and permitting formally got underway. Since the mine was in a National Monument and abuts up to a designated wilderness, the Monument Manager administered the project for the lead agency, the USDA Forest Service. Planning and permitting progressed smoothly to a Final Environmental Impact Statement (FEIS) in 1983. Metal prices were depressed when the FEIS was completed and the project permitting proceeded slowly. Ownership changed several times in the mid-1980's. New owners re-evaluated the project and suggested five changes that required a supplemental EA prior to development. The project was fully permitted and started construction in 1988. Operation began in 1989. Today the environmental process in southeast Alaska is now much more complex, detailed, expensive, and time consuming than in the early 1980's. Significant issues discussed that may impede development and operation include overlapping agency jurisdictions, personal agendas of agency staff, conflicts between agencies that impede project progress, changing regulations, and a well organized environmental opposition.

Jan 1, 1993

By D. W. Ashman

Today the electrolytic zinc industry is facing unprecedented environmental pressure and low metal prices. Zinc plants have to decide how they will dispose of iron residues in an environmentally friendly way without major capital expenditures. Only low-cost producers will survive, so companies must continuously improve to stay competitive. Therefore, the challenge of the process engineer is to find innovative solutions to the industry's problems. This paper reviews the status of electrolytic zinc processing and provides some insight into how the industry will respond to the pressures facing it

Jan 1, 1993

By John L. Edwards

The underground coal mines in the Lake Macquarie area of the Newcastle Coalfield, New South Wales, Australia are constrained by surface subsidence restrictions as low as 150 mm. The mining environment is shallow, generally between 100 m and 200 m, often multi-seam and commonly overlain by residential development or tidal waters. Most mines use partial or panel and pillar extraction techniques to meet the subsidence restrictions and allow maximum resource recovery. This paper gives an overview of the results of a recent two year government funded research project aimed at developing a mechanistic, geomechanically based mine design criteria for subsidence control. Three extraction layouts were monitored in detail to assess the relationship between mining geometry, pillar behaviour and surface subsidence. Pillars at each site were instrumented with stress cells, convergence monitors and extensometers. Field data was used to initially calibrate, and subsequently, verify stress and displacement predictions made by the three-dimensional displacement discontinuity code, SUBSOL. Back-analysis of the modelling results indicate SUBSOL's capability as a tool to satisfactorily predict surface subsidence magnitudes and pillar loads for alternative pillar and panel layouts.

Jan 1, 1993

By R. V. Ramani, K. V. K. Prasad

Forecasting mined grade variability from exploration information is a challenging task in mine planning. For effective planning of activities, such as workplace scheduling, ore grade quality control, etc., development of realistic numerical simulation models of in situ variability from exploration information is an essential first step. Geostatistical conditional simulation (GCS) is one of the well known methods to develop such simulations. Recently, stochastic fractal models based on the assumptions of scale-invariance and self-similarity have been used for developing simulations of several natural phenomena. It has been suggested that these models might permit the generation of short-scale variability information from exploration data with greater fidelity when the data satisfies the attendant assumptions. In this paper, stochastic fractal models are reviewed, and their relationship to geostatistical variogram models is examined. A comparison of the two simulation techniques has been performed using coal sulfur data from a mined-out coal property. The results of this comparative analysis are also presented in the paper.

Jan 1, 1993

By McConachy G. W, Wright J. V

During the 110 years since the discovery of the Broken Hill PbZnAg deposit six major mining companies have mined the ore body and explored the ore environment. Despite this activity, no new orebodies have been found at Broken Hill. The failure to discover large new resources cannot be attributed to a lack of activity because major companies have maintained substantial exploration commitments over many decades. This suggests that not only was a unique coincidence of conditions required to form the deposit but also that full recognition and definition of the critical parameters may not yet have been recognised. In an attempt to illuminate some of the more unusual and poorly studied characteristics of the ore environment some new areas of investigation are presented here which may contribute to understanding the ore deposit setting and focus exploration towards different and perhaps more productive targets. Sedimentological characteristics of the host succession of the Broken Hill deposit are apparently unique along the line of lode. An upward-coarsening megasequence reflected in the development of clastic psammites stratigraphically below the ore deposit is one important ingredient which has received little exploration focus. These psammites also host mineralisation and form part of a spectrum of quart-zrich rocks collectively referred to as gametiferous psammites, garnet quartzites and blue quartz lodes. Sedimentological data interpreted from outcrop, drill core and downhole geophysical well logs support a elastic origin for some of these rocks; an interpretation which is at variance with traditional interpretations favouring an exhalative origin. A clastic origin for many of the footwall psammites, and their close spatial association with the orebodies suggests their role in ore formation was important. It is interpreted as a critical part of the fluid flow architecture within the sedimentary basin, which focussed ore forming fluids into an unique environment favourable for trapping mineralisation. Detailed stratigraphic correlation near the deposit has also highlighted that quartzofeldspathic rocks (Potosi gneisses and lode pegmatites) have complex relationships with ore. Suites of stratabound quartzofeldspathic pegmatites have received limited study, but their distribution and voluminous development suggests they may be as important to ore formation as the psammitic lode rocks which host the orebodies. These associations are not in conflict with some recent ore forming models invoking deposition in a shallow water environments of deposition. The geochemistry of parts of the host sequence has been studied extensively in the past but this has not been merged with current stratigraphic subdivisions. A large drillhole data base now permits the geochemistry to be related to the sedimentary succession and reveals that a signature involving stratigraphic vectors best illustrated by changes in MnO, Na2O, Pb and Zn can be detected. This is interpreted to reflect sedimentary basin processes as opposed to a classical volcanic hydrothermal alteration pipe associated with seafloor venting. The stratigraphic setting together with characteristics of some of these poorly understood areas is discussed to emphasise that construction of sound models for exploration requires the total ore environment to be studied with attention directed to the geometry and setting of the full range of host rocks. Control of the greater portion of the line of lode by a single company, Pasminco Australia Limited, now permits disparate datasets and observations to be merged and presents new opportunities and encouragement for model refinement and exploration success.

Jan 1, 1993

By Gemmell J. B

Zinc-bearing massive sulphide deposits have been mined in Tasmania since 1900. The current major producers are Hellyer and Rosebery, with total resource tonnages (mined plus reserves) of 16 Mt (million tonnes) and 24.8 Mt respectively. These deposits belong to the class of seafloor volcanic-hosted massive sulphides (VHMS) and are located within the Mt Read Volcanics, a narrow belt of continental margin calcalkaline volcanics of Cambrian age. Compared to other Australian VHMS deposits, and world-wide MVT and Sedex deposits, the Tasmanian examples clearly stand-out due to their high metal grades, averaging over 17 per cent Pb+Zn. The deposits vary in morphology from mound style (Hellyer) to sheet style (Rosebery) with other combinations including stacked lenses (Que River) and disrupted cross-cutting bodies (Hercules). All deposits show the classic VHMS zonation from an Fe-Cu-bearing base to a Zn-Pb-Ba-rich top. Zinc, gold and silver tenor commonly increases toward the stratigraphic top of the deposits. The ores have been deformed during regional metamorphism, resulting in folding, shearing and recrystallisation of sulphide lenses. In addition to the major deposits, a number of small massive sulphide prospects occur throughout the volcanic belt and the potential for the discovery of further large, deeply buried deposits remains high.

Jan 1, 1993

By H. M. Breza

Utilization of Bucket Wheel Excavators and Overland Conveyor Systems to remove overburden provides increased productivity and flexibility to a surface mining operation. The utilization of such a system at the Texasgulf Inc. Aurora, North Carolina Mine has significantly improved the overall productivity of the mining operation. System flexibility is evidenced by adaptation to operation requirements such as mining area moves, movement of excavated overburden to designated sites, selective handling of overburden, spoil placement contouring, and providing an environmentally sound and safe operation. System productivity is evidenced by actual case studies relating to overall production, excavation rates, and cost effectiveness.

Jan 1, 1993

By Alan G. Mayton

A prototype end-cab shuttle car (SC) design has been developed to improve protection and address ergonomic concerns of the SC operator in low coal mines. The new design features an end cab transversely mounted to the SC and equipped with a closed-circuit video system. The end cab was retrofitted to a low-coal SC and evaluated in surface trials at the U.S. Bureau of Mines. During surface trials, test operators evaluated the end-cab SC relative to visibility; cab features-space, seating, controls, and operator position; tramming-inby, outby, and turning corners; and dumping. Trials were conducted using 12 test subjects; 6 were experienced SC operators. Results of the trials were promising. Of the experienced operators, the only operator with low-coal experience gave the new design the highest rating. Four experienced operators rated the end-cab design "better" to "much better" than a standard center-driven, side-cab SC for visibility when tramming, protection from roof and rib hazards, and no change in seat position with direction of travel. This report discusses research to modify a used 21SC JOY SC, retrofit the SC with the Bureau-developed end-cab, and evaluate the retrofitted end-cab SC in surface trials.

Jan 1, 1993

By Schommarz KH, Dunne RC, Goodall CM

Column cells are widely used today for the recovery of base metals by flotation. Their use for the flotation of iron sulphides has not been as rapid. Australia has pioneered the use of large rougher flotation columns. During the last six years, seven rougher columns have been installed on gold mines treating iron sulphides and the technical viability of this technology has been demonstrated. Laboratory column testwork on a gold bearing iron sulphide ore demonstrated the effects of both physical and chemical parameters. In general the large commercial columns operate over a broad range of conditions depending on the downstream treatment of the flotation concentrate. The addition of wash water to commercial columns is not universally applied and there appears to be a need for a better wash water System.

Jan 1, 1993

From a personal view that encompasses both research and assessment of major projects the author outlines the two competitive pressures that will force more rather than less metallurgy viz the increasing difficulty in purchasing the latest overseas developments and environmental concerns. This paper then goes on to argue that Australian metallurgy or more precisely process engineering may be in a unique position to deliver the required results.

Jan 1, 1993

By P. M. Keyser

Column flotation continues to make inroads into applications traditionally dominated by mechanical flotation cells. For example, columns are becoming more visible as rougher flotation devices. At Royal Mountain King Mine in California, two 2.9 m (9.5 ft) diameter columns are used for rougher flotation of carbon from a gold ore (Orlich et al, 1992). In addition, work performed at BRGM in France demonstrated the superiority of column flotation over mechanical flotation with respect to design of new plants (Morizot et al, 1991). With the mounting evidence, columns can succeed in any flotation application. The primary reasons for this acceptance of columns are a general improvement in design, scale-up and operation as well as improvements in sparger design and performance. With these advances, the full benefits of column flotation can be realized. The benefits of properly designed, aerated and operated flotation columns include: ? Lower Capital Costs ? Reduced Operating Costs ? Fewer Processing Stages ? Improved Metallurgical Performance

Jan 1, 1993

By Gurgenci H, Slifirski M

The Centre for Mining Technology and Equipment was established in 1991 to develop innovative technologies for the mining and processing industries, to introduce these technologies to the industry, and where appropriate, to co-operate with equipment manufacturers to transform these technologies into equipment products. It is an unincorporated joint venture between the University of Queensland, CSIRO and the Australian Minerals Industries Research Association. Base funding for the CMTE is provided by the Federal Government as a Co-operative Research Centre.

Jan 1, 1993

By E. Finch

Beneficiation tests were conducted on samples from three ore zones in the Los Monos, Navay orebody in Táchira State, Venezuela as part of an overall feasibility study. The scope of work included ore sample characterization, flowsheet development, and optimization of beneficiation variables on a bench scale followed by confirmation on a pilot plant scale. Phosphate in the ore samples occurred primarily as francolite and was associated with quartz, kaolinite, and feldspar. Liberation of the phosphate began at 589 microns (28 mesh) for the main ore zone sample and at 295 microns (48 mesh) for the lower-grade ore zone samples. Development tests on simulated mining composites demonstrated that the samples responded well to 589 micron (28 mesh) grinding, two stages of high intensity scrubbing, conditioning at high % solids with caustic and equal amounts of tall oil and fuel oil, and separate coarse and fine flotation circuits with one stage of roughing and two stages of cleaning (reflotation). Concentrates in the range of 31.5-34% P205 with recoveries from 64-70% were obtained from the mining composites. Product quality for all concentrates in the range of 31.5 % P205 was good; 1.40 CaO/P205 and 0.04-0.05 minor element ratios. Confirmation testing in a continuous pilot plant produced results similar to those achieved in the laboratory.

Jan 1, 1993