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By J. A. McKeown, B. M. Sanders, A. Dadgar, R. H. Sergent

This paper describes the leaching of gold with Geobrom® 3400 from a very rich (6.2 kg/tonne) black sand concentrate and its subsequent recovery by ion exchange resins and solvent extraction. The dissolution of gold from black sand ranged from 94 to 96%. Gold loadings and recoveries of nearly 100% were achieved by both ion exchange and solvent extraction methods. The kinetics and equilibrium of loading gold onto ion exchange resins and its elution from the resin were studied. The commercial ion exchange resins PAZ®- 4, DOVEX®- 21K, and Amberlite® XAD- 7, and Great Lakes Chemical experimental GLR-30 were evaluated in this work. Diethylene glycol dibutyl ether was used in all the solvent extraction work for gold recovery from Geobrom leach solution. The consumption of Geobrom was about 130 kg per tonne of the concentrate processed. Therefore, the cost of lixiviant to extract 3.11 x l0-2 kg of gold from the black sand was only about $1.00. Based on the electrochemical regeneration of bromine, the economics of bromine process vs. cyanidation were investigated.

Jan 1, 1990

By Thomas E. Marshall, Roy H. Grau

The U.S. Bureau of Mines has developed an acoustic test for determining if a rock salt sample is from a "normal" nongassy salt face or from a gassy face where an outburst has the potential to occur. The test is based on the observation that a salt sample taken near an outburst-prone zone produces an audible popping sound when it is dissolved in water. The sound is produced when pressurized gas that is trapped in salt samples is released. In the acoustic test, the sound is electronically measured, digitized, and transmitted to a microcomputer; the output is an average decibel value that classifies the sample as "normal" or "outburst." The acoustic test procedure and equipment are described, and raw test results and data analysis are shown. Results are also shown for several salt samples that were analyzed using a laser Raman microprobe.

Jan 1, 1990

By Brinkmann J. R

In the narrow stopes of South African gold mines, rockbreaking is carried out by drilling and blasting with safety fuse and igniter cord being used as the initiation system. The fuse/gniter cord system is used primarily because of its low cost, however several limitations of this method include: inaccurate delay time, unreliable firing, inflexible application to varied configurations, and the absence of dynamic interaction between holes. Alternative initiation systems that incorporate millisecond timing are being developed to overcome the limitations of fuse(tgniter cord systems. Current investigations by the Stoping Technology Division of the Chamber of Mines Research Organization (COMRO) into the effects of millisecond initiation are being conducted at a deep test site. Experimental blasts using various millisecond delays and the independent firing of holes with fuse/igniter cord are being studied in order to quantify the influence of delay time on the blasting process and to identify the best methods of applying millisecond initiation systems. The effect of design variables such as delay time, hole firing pattern, stemming, and panel layout are discussed. Blast results including throw distance and direction, muckpile profile and rock cleaning times are used in the discussion of different combinations of blasting variables.

Jan 1, 1990

By Abrahamsson S, Niklasson B

In a follow-up of 12 production blasts in a quarry at the Mrica project on Java, tightly spaced porous bands were found to govern fragmentation to the extent that the average fragment size k5o was nearly independent of the specific charge within the range 0.30-0.56 kghn3. This fording resulted in a reduction of the running costs for drilling and blasting by 20-40%. Our work has given considerable practical benefits and insights into the blasting process, even if the results were of no direct use to check out fragmentation predictions based on models, which was one of our main Goals.

Jan 1, 1990

By Tom Marttila

During the last few years, when a new tankhouse or a major modernization has been planned, automatic or semiautomatic crane and grab systems have at least been considered. It seems that in the future tankhouse managers for new, modernized and even old tankhouses will be looking for a proven and reliable system for automatically moving and positioning electrode loads in the tankhouse and in storage areas. In this paper, we will describe the Wenmec solution for automatic electrode handling. The advantages of automatic handling and very accurate electrode positioning will be discussed, and the way Wenmec has solved the problems in mechanical construction and in automatic, accurate and reliable positioning will be presented.

Jan 1, 1990

A thick sequence of alkaline intrusions and volcanic rocks underlies a Quaternary caldera on Liliir Island. The sequence is host to a still active sub-aerial hydrothermal system and associated epithermal gold mineralisation. Sub-horizontal alteration horizons exhibit progressively increasing chondrite norma-lised (La/Lu) en and (La/Sm) cn ratios from unaltered shoshonites, to the potassic alteration zone, to the argillic altera-tion zone to the advanced argillic alte-ration zone. The increasing fractionation of HEE, and especially of LHEE, up the alteration sequence is the result of de-creasing pH, temperature and alkalinity of the hydrothermal fluids with increa-sing alteration intensity. HRE3 were especially mobile in argillic and advanced argillic alteration units characterised by acid fluid conditions and large fluid volumes. Abundant Cl, S and CO2 within the hydrothermal fluids and thus abundant REE complexing agents and large fluid volumes favoured the mobility of REE during hydro-thermal alteration of the volcanic rocks and intrusions. Steam escape, mixing of the gases with groundwater and a change from a magmatic neutral chloride hydro-thermal system to a meteoric acid sulphate system was accompanied by liquid/vapour ratio changes, pronounced alkalinity, pH and temperature decreases, and fluid/rock ratio increases. This caused the mobili-sation, fractionation and deposition of PF.F.

Jan 1, 1990

The first geological maps of parts of Australia were produced in the 1830s and 1840s, many being for purely practical purposes, such as indicating the occurrence of coal, iron and other essential materials. Mineral location maps were also first made about the same time.More systematic geological mapping commenced in the 1850s when large parts of New South Wales and Victoria were studied in government-sponsored surveys by geologists such as Samuel Stutchbury, Alfred Selwyn and Reverend William B. Clarke. Their work coincided with the opening up of most of the major goldfields of eastern Australia, which led to the establishment of Departments of Mines in the separate Colonies (later States within the Commonwealth of Australia).A few companies employed consultant geologists at this time, and the mapping by Frederick Odernheimer is particularly notable. Geological study of Australian ore-deposits and mineralisedareas was influenced by the continental European geological ideas of men such as Odernheimer as well as by those from England. Both geological and mineral maps were a feature of Colonialdisplays presented at major international exhibitions during the second half of the nineteenth century. The maps accompanied rock and mineral collections which showed the known and potential mineral wealth of the Colonies. Such displays raised interest in the potential for development amongst government officials, entrepreneurs and investors in Australia and abroad.By the 1880s most of the Colonies had produced basic geological maps, and several maps of the whole continent had been published. Although systematic mapping of the continent become a reality only in the 1950s, the nineteenth century geological and mineral mapping formed the basis for the development of the major coal, artesian water, and metalliferous mining regions of Australia.

Jan 1, 1990

"Batch flotation testwork demonstrated that a low-grade chromite ore from Bird River, Manitoba, was best floated at pH 2 using Armac C (coco amine acetate) collector and sulphuric acid as pH modifier. A grind of 100% minus 150 um was necessary for liberation, and flotation selectivity was greatly enhanced by prior desliming. A concentrate analyzing 24.2% Cr203 with a recovery of 90.2% was obtained, after three cleaning stages, from ore grading 6.05% Cr203. Total rougher collector concentration was 500 g/t and cleaner collector concentration 380 g/t. Similar grade and recovery were obtained during the pitot-plant evalualion, when a concentrate analy zing 22.3% Cr203 with a recovery of 93% (based on deslimed feed) was obtained for a total collector addition of 630 g/t.Selective flotation in a region of positive surf ace charge implies anionic activation, and a possible flotation mechanism is suggested.IntroductionIn an earlier study(1) of the beneficiation of chromite ore from Bird River, Manitoba, several methods of beneficiation were explored. These included ore sorting, heavy-media separation, and gravity concentration with flotation using Armac C (coco amine acetate) collector at pH 2, and sulphuric acid as pH modifier. Because flotation was not fully evaluated, a laboratory study was undertaken to determine the optimum parameters of chromite flotation. Optimization of parameters was established first on a laboratory scale followed by confirmation a t the pilot -plant level. Flotation of chromite using Armac C and sulphuric acid as a pH modifier has been reported as being selective for low-grade chromite ores(2)."

Jan 1, 1990

By Manfred Schmidt

Realizing an invention of Professors Queneau and Schuhmann, Lurgi GmbH has developed a radically new lead smelting technology, which was demonstrated on a ?30,000 tpy scale at Berzelius Metallhiltten GmbH between 1981 and 1986. Designed to treat all grades? of lead concentrates as well as complex secondaries, the novel QSL-Process applied one bottom-blown, refractory-lined long reactor and comprises two basic steps: Continuous oxygen smelting of the green charge is followed by continuous carbothermic slag reduction. Four firm orders and a number of serious inquiries from major lead producers confirm that the QSL-technology has convinced the industry of inherent process advantages. These include low investment and operating costs, flexibility and environmental acceptance. In the fall of 1986 Cominco Ltd. decided to erect a 120,000 tpy QSL plant at the site of the Trail lead smelter. Feed materials will consist of lead concentrates and zinc leach residues. The designed QSL reactor has a total length of approx. 41 m, and working diameters of 3.74 m for the oxidation section and 3. 24 m for the reduction section .. Separate gas offtakes on both sections will enable to? reduce the sulfur dioxide gas volume, and to recover a mixed zinc-lead oxide fume. Operation of the QSL reactor will start end of September 1989. First results will be presented.

Jan 1, 1990

Most text books on rock blasting claim that the relationship between burden and borehole diameter is linear. The statistical calculation presented here with real values from one hundred open pit and underground mines indicates that the relationship is exponential. For underground mines the burdens are consistently lower than those for open pit mines because of higher ore densities, greater confinement in blasting, and finally greater demand for well fragmented rock. The results shown in this paper are recommended to be considered in basic teaching of rock blasting technique. The formulas can be used for a first rough estimation of practical burden and spacing. The formulas do not however give any information about the fragmentation. For that purpose it is necessary to use other formulas not described in this paper.

Jan 1, 1990

By James D. Navratil

Ferrites have been used to separate a wide range of substances such as dissolved metal species, particulate matter, and organic and biological materials; they have been used almost exclusively for metal waste treatment applications. The versatility of the ferrite waste treatment technique is evident in the wide variety of application methods. Furthermore, ferrites can be used to remove selected impurities in feed solutions containing metal products requiring purification. A brief overview of ferrite properties and recent applications for metal recovery and waste processing will be presented.

Jan 1, 1990

One of the important facets of The South African Institute of Mining and Metallurgy is its service to its members. One way of achieving this objective is by pursuing an active branch structure. In this Spotlight, Richard Beck, Holder of the Regional Development Portfolio, gives the aims of the Institute's branches, with a short note on each branch prepared by the regional chairman. Aims of the Branches: The primary aims of the Branches of The South African Institute of Mining and Metallurgy are those of the Institute itself: to further the interest of its members, to uphold the status of the mining and metallurgical profession, and to promote the image of mining and metallurgy. Beyond these 'high' objectives, the branches have a special function in providing a more intimate relationship between the Institute and its members. The branches enable members who live outside the Johannesburg area to participate in the affairs of the Institute to an extent that would not otherwise be possible and that they themselves can define. This is achieved through the holding of social events, colloquia, and visits.

Jan 1, 1990

Recent operating experience from West Australian open pit gold mines has shown that geotechnical input into initial design is rare. As a result, ground stability is poor - almost half the pits designed in this way suffer major failure.West Australian experience shows that geotechnical studies for individual mines are site specific, and therefore empirical experience cannot be transported from site to site. Geotechnical studies performed prior to design have resulted in significantly improved pit stability.

Jan 1, 1990

During the century past geologists have discovered an extraordinary range of mineral resources. It is somewhat surprising, in view of their success, to look back and find that geologists have been concerned through the entire time about the adequacy of resources to meet future needs. They continue to express concern. The basis of their concerns seems to rest as much in social issue as in evaluations of geology.Demand for mineral resources is driven by population and by per capita consumption. Both have grown steadily over the past century, and both continue to rise. In 1890 the global population was about 1.7 billion, people. It has now exceeded 5 billion and the growth rate is such that by the year 2000, the global population will be between 6~ and 7 billion. Demographic projections suggest the global population will approach 12 billion before a steady state is reached dnrino the centiirv ahead

Jan 1, 1990

By Cheryl Hill, Michael Keane, Pamela Mike, Raghoottma Pandurangi, William Wallace, Mohindar Seebra, Val Vallyathan

"Dipalmitoyl glycerophosphorylcholine (lecithin) dispersed in physiologic saline, a model of the primary component of pulmonary surfactant, is adsorbed by respirable quartz and aluminosilicate dusts. Dust cytotoxicity as measured by erythrocyte bemolysis and pulmonary macrophage enzyme release is suppressed by this adsorption. The degree of suppression of hemolytic potential versus specific adsorption of lecithin from dispersion in saline by respirable quartz and kaolin dusts are compared with dusts' BET specific surface areas to interpret the prophylactic effect of lecithin adsorption. Dust hemolytic potential versus medium pH is presented. Fourier transform infrared spectroscopy and photo-acoustic spectroscopy of lecithin on quartz and of lecithin on kaolin are presented and reviewed with results of studies of the time course of removal of lecithin adsorbed on mineral surfaces by digestion by phospholipase enzyme. Results are discussed in terms of a model of prompt neutralization of respired mineral dusts by pulmonary surfactant, and a gradual re-toxification by digestive processes acting on the adsorbed prophylactic surfactant coating following phagocytosis. INTRODUCTIONQuartz dust of respirable size is well known to cause fibrotic lung disease, but numerous questions persist in the understanding of the initiation and progression of this disease. Our approach concentrates on physical and chemical aspects of mineral dusts early-on in their interactions with living organisms, and we have chosen simplified models to investigate that interaction.In the alveolar ·spaces of the lung, tissue is coated with a surface-active material (pulmonary surfactant), which, among other functions, mechanically stabilizes the lung from collapse by reducing the surface tension of water in the alveolar sacs.1 This surfactant is also the material that is first contacted by a mineral particle that is transported to an alveolus and is impacted there. This surfactant material has been studied extensively. The primary components are known to be proteins (about 11 % in dog lavage fluid), and phospholipids (about 88%).2 Pbosphatidyl cholines constitute roughly 80% of the phospholipid fraction; about 70% of the phosphatidyl choline fraction is dipalmitoyl lecithin (DPL).2 Respirable aluminosilicate particles are capable of adsorbing dipalmitoyl lecithin from dispersion in physiologic saline, a model for a possible initial event occurring upon deposition of a particle in a pulmonary alveolus. As may be seen from Figure 1, the DPL molecule has several fixed charges at neutral pH; a positive charge on the trimethylamine (choline) moiety, and a negative charge on the phosphate group. Also evident are the two fatty acid residues of palmitic acid, which are bonded through ester likages to the glycerol segment of the molecule. The fatty acid moieties of phosphatidyl choline make the molecule inso1uble in aqueous solutions under normal conditions, but a colloidal unit of aggregated molecules called a micelle is usually formed spontaneously above a certain minimum concentration. Small micellar vesicles are generally formed in the laboratory by using ultrasonic agitation or by solvent evaporation methods."

Jan 1, 1990

By A. von Röpenack

A forecast of the consequences of our techniques and goods produced, at least a technical assessment will be demanded from us as an industry. The hydrometallurgical winning of zinc is therefore at a crossroads. New processes promise not only better economics, better maintenance of resources and simpler operation, but also more harmony with nature. Pressure leaching promises to eliminate roasting and thus one complete process step. The hematite process solves a difficult and always costly iron problem. HOA opens a possible road to a totally new ,generation of electrolysis. Zinc has a long tradition behind it. Its? importance is as great as ever-. There is still room for new production developments. In my estimation there are good chances for successful new techniques? which will benefit our whole industry. Zinc is a modern and forward-looking metal.

Jan 1, 1990

Buoyant levels of world economic growth and recovery in intensity of metals usage suggest that demand for minerals will remain relatively strong into the 1990's. Supply constraints, low stock to use ratios, financial and political factors imply lower elasticities of supply for minerals in the future. The outlook for minerals and metals prices from a pro-ducers viewpoint is, accordingly, promising.The recent recovery in world minerals prices, following strong growth in the world economy over the last few years, makes it appropriate to consider the structural forces at work in the formation of world demand and supply of minerals. This paper will review past trends and consider some of the main economic issues facing the mining industry in the 1990's.

Jan 1, 1990

By R B. Evans, M G. Townsend

In Northland, New Zealand, localised large deposits of halloysite clay have been produced by in-situ alteration of rhyolite volcanics of Pliocene or Pleistocene age, which were erupted through pre-Pliocene sedimentary strata and locally through Pleistocene basalt; and which were subsequently onlapped by further basalt flows. Alteration to clay has been a result of both hydrothermal and of meteoric processes, and decreases in intensity of alteration with increasing depth. The raw material is crushed and fractionated to produce a product of less than two micron particle size, which is of exceptional whiteness and brightness. The unique properties of the clays render them highly desirable for specialised ceramic purposes.

Jan 1, 1990

By J. E. Dutrizac

The mineral forms of silver, lead and cadmium in the zinc concentrates and the various roaster products made by the Kidd Creek Division of Falconbridge Inc. have been elucidated. In the concentrates, all three elements occur mainly in sulphide form, either in solid solution in the principal ore minerals or as discrete mineral grains. During roasting, Ag, Pb and Cd are preferentially concentrated in the hot cyclone and ESP dusts of the roaster train. Silver is converted to <0.5 µm grains of silver metal and to Ag2S04 which dissolves in or impregnates silicates. Lead is converted to Pb-bearing silicates or to PbS04 and PbO which are present either as tiny free grains in ZnO or as an intergrowth with lead silicate. Lead is also a minor constituent of the ferrite phase. Cadmium occurs mostly as cadmium-bearing zno and ZnFe2o4 , but a significant amount also reports as Cd-bearing silicates or zinc sulphate.

Jan 1, 1990

The Barmac autogenous crushing mill is one of the most successful new comminution technologies to become available to the mining and industrial minerals industries in this decade. &nbsp; The Barmac autogenous crushing mill is an innovative Vertical Shaft Impactor which operates in essence like a high intensity dry ore centrifugal pump with the reduction occurring primarily as a result of high velocity rock to rock impact in a fully rock lined crushing chamber. &nbsp; With applications in a wide range of mining and industrial minerals operations the Barmac autogenous crushing mill presents an opportunity to enhance reduction and liberation whilst providing many cost savings and production increases in new and existing plants. &nbsp; This paper briefly describes the operation of the Barmac autogenous crushing mill and reviews its benefits.

Jan 1, 1990