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ALAN W. CZARNOWSKY RMCMI PRESIDENT 1988-1989 on behalf of the RMCMI Board of Directors and Officers of The Rocky Mountain Coal Mining Institute cordially invites you and your family to attend the 85th Regular Meeting and Convention to be held June 25, 26 and 27, 1989 at Tamarron Durango, Colorado

Jan 1, 1988

Results of investigations on adsorption and desorption of CO M CH and a mixture of the two gases are described.4 Results showed that even when the equilibrium conditions contains 50% Co and 50% CH4, the gas emission in the initia' stages will contain as much as 80% CH . 4 The temperature has a small effect and so also particle size for 1.4-11.2mm. The ratio of CO2/CH gases adsorbed in coal samples depends upon t4he equilibrium pressure and this ratio decreases with pressure. Results of field tests support laboratory studies.

Jan 1, 1988

By E. G. Noble

The effects of HBr concentration and temperature on the solubility and hydration state of AlBr3,' CoBr2, PbBr2, MnBr2, KBr, and NaBr were investigated by the Bureau of Mines. Saturated aqueous solutions of the AI, Pb, K, and Na bromides were sparged with HBr gas at 20°, 40°, and 60° C, and saturated solutions of Co and Mn bromides were sparged at 20° C. Increased HBr concentration caused decreased salt solubility because of the common ion effect for all the investigated bromides except PbBr2. Aqueous solubilities at 20° C were, in percent, 51.7 for AlBr3, 53.2 for CoBr2, 1.1 for PbBr2, 59.6 for MnBr2' 39.5 for KBr, and 47.4 for NaBr. At 60° C, the solubilities were, in percent, 53.3 for AlBr3, 2.2 for PbBr2' 46.0 for KBr, and 53.8 for NaBr. Solubilities in solutions sparged to HBr saturation at 20° C were, in percent, 0.5 for AlBr3, 42.0 for CoBr2, 32.2 for PbBr2, 21.0 for MnBr2, 0.6 for KBr, and 0.3 for NaBr. At 60° C, the solubilities at HBr saturation were, in percent, 1.8 for AlBr3, 41.4 for PbBr2, 1.3 for KBr, and 0.4 for NaBr. CoBr2 precipitated out to a minimum solubility of 27.2 pct at 28.7-pct-HBr concentration. Further increases in HBr concentration increased CoBr2 solubility because of the formation of bromide complexes. PbBr2 in-creased in solubility as HBr concentration increased.

Jan 1, 1988

Humic acids adsorb on coal and depress coal floatability in the acidic pH range. In alkaline solutions, their effect is not pronounced. In the neutral pH range, a second small addition of kerosene plus MIBC leads to a significant increase in coal yield and better selectivity. Humic acids present on oxidized coal surface were found to be responsible for the inhibited floatability of the? coal. As expected, the flotation of such oxidized coal also strongly depends on the method of pH adjustment.

Jan 1, 1988

By T. W. West

A description of a coal washing spiral is presented, together with a discussion of the parameters which define the envelope within which the spiral can be successfully applied. The correct process engineering, installation, operating and maintenance parameters are addressed as well as actual results for new and retrofit installations on USA coal capital and operating costs of spiral circuits are compared to those of traditional fine coal circuitry.

Jan 1, 1988

By George A. Morgan

There was little change in the mineral industry of Benin in 1986, as the economy remained in the grip of a regional recession exacerbated by failing oil prices, which nullified much of the income from Benin's oil production. Benin's industrial sector accounted for less than 10% of the gross domestic product (GDP), with the mineral industry providing about one-half of that total. Several major projects initiated over the last several years continued to perform and/or progress below Government expectations. These included the Save sugar refinery, the Dassa-Parakou section of the Dassa-Cotonou highway, the Benin-Togo Nangbeto hydroelectric plant, the Onigbolo cement plant, and the Semé Oilfield. Funding for these projects is the major source of the Beninese external debt, which was estimated to be over $800 million.2

Jan 1, 1988

By H. Y. Sohn, M. K. McCarter, Bradley C. Paul

"A computer model was constructed for bacterial leaching of the major sulfides found in porphyry deposits, including bornite, chalcocite, chalcopyrite, covellite, cubanite, enargite, native copper, pyrite, and pyrrhotite. The model incorporates equations for the sulfide minerals dispersed in the rock matrix. Leaching occurs by reactions with ferric ion diffusing into the rock fragment: Ferrous ion is resenerated to ferric with oxygen by bacteria at a temperature dependent rate. The model keeps track of the net acid generated, oxygen consumed by the bacterial oxidation of ferrous ion, heat generated, jarosite and hematite precipitated, and copper leached. The model was used to predict the rate of copper recovery, heat generation and oxygen demand for a variety of run-of-mine sized porphyry ores. These results were used in the design of a ventilation system and the economic analysis of a modified in situ extraction method that may be cost competitive with conventional copper production involving open pit mining.IntroductionA study was undertaken at the University of Utah to evaluate the technological and economic feasibility of mining copper by a method referred to as Flood Drain Leach Cell (FDLC) mining. Cells 60 by 75 meters in plan and 70 meters in height are created throughout the ore body by a modified Vertical Retreat Mining technique that includes the removal of 25% swell material. The swell material is leached in finger dumps on the surface while the cells underground are bulkheaded, flooded, drained, and artificially aerated to promote bacterial ferric sulfate leaching. Solutions are cycled through several cells to reach pregnant grade of 1 gram copper per liter of solution. These solutions are then fed to an underground solvent extraction plant and then a surface electrowinning tankhouse."

Jan 1, 1988

The South African Institute of Mining and Metallurgy mourns the passing of one of its most distinguished sons. Professor J. de V. Lambrechts died at Franschoek on 30th January, 1988, at the age of 76 years after a long illness. Mintek Application Reports A new series of Mintek reports made its appearance in 1987. These are Application Reports, which present an overall perspective of each of Mintek's technical thrusts to ensure that the existing expertise can continue to be readily accessed. The successful development of an industrial process for the recovery of platinum-group metals from the UG-2 Reef. Application Report no. 1. 1987. 16 pp. The development and implementation of a computer control strategy for conventional milling circuits. Application Report no. 2, 1987. 15 pp. The development of an integrated carbon-in-pulp process for South African conditions. Application Report no. 3. 1987. 17 pp.

Jan 1, 1988

By D. A. Dahlstrom

Crushing and grinding consumes about 1.3% of the nations produced electrical energy.( Furthermore, only one in the first ten highest consumers comes from an industry other than mineral processing. This is the grinding of wheat to make flour. The other nine are all in the metallurgical industry and are easily the largest consumers.

Jan 1, 1988

By John B. Bennett

In this report estimates are presented of the impact of the passage of five recently proposed "acid rain" bills on electric utility costs for coal-burning utilities servicing the domestic aluminum smelting industry, and on the costs of production for affected aluminum smelters. As aluminum smelting is an energy-intensive industry, domestic increases in electricity prices could affect the industry's competitiveness. Energy costs in U.S. aluminum smelting are compared to aluminum smelting energy costs in the rest-of-the-world. Governmental policies affecting these energy costs are discussed.

Jan 1, 1988

Regolith, the blanket of bedrock weathering products and surficial sediments, covers almost all of the landsurface. In Australia extensive areas are covered by regolith up to several hundred metres thick which is relatively old (extending back to the Mesozoic or possibly earlier) and largely complex. As such, it is poorly understood and is presently regarded as a significant hindrance to resources exploration. The regolith: obscures bedrock lithology and structure blankets ore deposits in the bedrock hosts surficial mineral deposits ranging from placers (gold, diamonds, platinum, mineral sands ....) to chemical precipitates (uranium, opal, gold, bauxite....). contains important groundwater resources. The application of surface exploration techniques without recognition or understanding of the regolith could result in wasteful expenditure. The understanding of the distribution and characteristics of the regolith in the context of its evolution and geomorphic history and its relationship to underlying bedrock will promote development of suitable geological, geophysical, geochemical and remote sensing techniques. It also will assist exploration industry with the interpretion of data from: geological mapping soil geochemical surveys stream sediment geochemical surveys airborne remote sensing airborne radiometric surveys other airborne geophysical surveys some ground geophysical surveys shallow drilling and so improve mineral exploration Strategies.

Jan 1, 1988

By Maloszewski J, Kidybinski A, Sawka B

A forecast of mining conditions in Upper Silesia collieries for the beginning of the 21st century has special focus on average depth of mining, energy of seismic tremors induced by mining and energy of dynamic loads on roadway supports. A method of dynamic loads calculation is based on volume of failed rock surrounding an opening and the seismic energy of tremors anticipated. New types of yielding steel arch supports have been designed to resist massive static and dynamic loads and a system of supports has been tested both on 1 : 10 scale models and in natural size. The support sections used are 29, 36 and 44 kg/m.

Jan 1, 1988

The following contributions were received to the paper entitled 'Safety in South African mines: An analysis of accident statistics', by H.S. Eisner and J.P. Leger, which appeared in the J. S. Afr. Inst. Min. Metal., vol. 88, no. 1, Jan. 1988, pp. 1-7. Contribution by H. WAGNER* The paper by Dr H.S. Eisner and Mr J.P. Leger is critical of the safety situation on South African mines and portrays the industry as having little concern for the health and safety of its workers. Moreover, the casual reader gains the impression of deliberate misinformation by the industry to the public concerning safety maters. Furthermore, certain socio-economic reasons are advanced for the apparent differences between the fatality and injury rates reported for coal mines in South Africa and those for the United Kingdom. Contribution by S.A. WATTS. Authors Eisner and Leger are to be commended on their paper, which highlights, according to their interpretation, various shortcomings of both the Chamber of Mines accident statistics and those published by the Department of Mineral and Energy Affairs. Authors' Reply We gratefully acknowledge Dr Wagner's contribution to the discussion on our paper. For convenience, we shal use his sequence of comments in our reply. Before doing so, however, it may be useful to explain how our paper came to be written. After the explosion at Hlobane Colliery in 1983, one of us (HSE), in February 1984, was retained by the lawyers acting for some of the dependants of the victims to advise on technical maters relating to the explosion. Contribution by Ms S.A. Wats Some of the points made by Ms Wats have already been answered in our comments on Dr Wagner's contribution. We are fully aware that the number of accidents leading to absences of less than 4 days would be much greater than shown in our bar chart, and are grateful to Ms Wats for drawing attention to the specific exceptions that can make a 1-3 day accident compensable and that are clearly responsible for the relatively low count in that category of the chart.

Jan 1, 1988

By S. Meng, R. Jin, W. Hu

In alkaline pulp, galena is depressed by sodium carboxymethyl cellulose (NaCMC), while Cu(II) -activated sphalerite exhibits a high floatability so that satisfactory separation can be achieved. In addition to hydrogen bonding, chemical bonding of NaCMC with galena is confirmed by infrared (IR) spectra; only hydrogen bonding is involved between NaCMC and Cu(II)-activated sphalerite. It is also found that the greater the degree of substitution and polymerimtion of NaCMC, the stronger the depressive effect of NaCMC and that lower stirring speed favors the depression.

Jan 1, 1988

By James R. Arnold

Over the past few years several commercial wetting agents and drying aids have been tested in the lab and in the plant at Gold Fields Mining's operations at Mesquite and Ortiz. The major goal was to increase recovery with these surfactants by improving the permeability of the pad and increasing the rate of penetration through the rock.

Jan 1, 1988

By Robert D. Pehlke

"The evolution of oxygen steelmaking is reviewed and new operating processes are described. The developments which could impact this technology are summarized. Staged and continuous steelmaking are considered in the light of new technologies. The future opportunities for oxygen steelmaking processes are overviewed. IntroductionThe use of oxygen in steelmaking was originally brought on the scene by the development of pneumatic steelmaking. Sir Henry Bessemer in England originally conceptualized the use of gaseous oxygen in steelmaking, and then he and William Kelly in Eddyville, Kentucky independently developed the original pneumatic process which involved blowing air through a bath of molten pig iron to oxidize the carbon and silicon and produce steel. This process and many following processes, including those which would use pure oxygen gas, have been proposed.Beginning with the first commercial oxygen steelmaking vessels at Linz, Austria in 1952, the world steelmaking industry has adopted this style of processing. In general, the process has involved the use of steel scrap in amounts from 20 to 35% of the metallic charge with molten pig iron produced in blast furnaces making up the remainder. The impurities in the charge are oxidized through the use of oxygen gas injected into the steelmaking vessel.However, currently being adopted into commerical practice and on the horizon are a number of advances in this process which include the use of iron ores as a source of iron and oxygen, the use of an all scrap charge, incorporation of pre-reduced iron, the use of auxillary fuels to change the balance of cold and liquid iron-base charge materials and numerous refining techniques."

Jan 1, 1988

By D. S. Loubser

The technique of backfilling in the gold mining industry is dependent on the dewatering of slurry to form a solid support system. In many cases flocculants are added to the slurry to increase the rate of dewatering. To ensure that a stable support is obtained it is important that the chemistry, application and limitations of these flocculant additives are understood. Flocculant additives have to be added at a point where minimum shear will occur. (Shear occurs when a flocculant is exposed to excess energy resulting in breakdown, of the floc.) To ensure that optimum results are obtained it is important that personnel involved are trained to use the flocculant additives and dosing equipment correctly.

Jan 1, 1988

By E. Wiewiorowski

A new technology for recovery of metals from spent catalysts containing aluminum, cobalt, molybdenum, nickel and vanadium was developed. The catalysts are decomposed in two consecutive pressure leaching steps. Sodium aluminate-sodium hydroxide systems are lixiviants in both leaching steps. Selective extraction of molybdenum and vanadium is achieved in the first leaching step. The leach liquor is processed for separation and recovery of these two metals. The residue from the first leaching step is further processed in a second leaching step where alumina is solubilized. The residue from this operation is a nickel-cobalt concentrate. Alumina is separated from the second stage leach liquor by precipitation; the depleted liquor, a sodium aluminate solution, is recycled to the first and second leaching step. This technology has advantages over other approaches for the recovery of metals from spent catalysts because no solid waste is generated.

Jan 1, 1988

By Dai Yongnian

"The feasibility to vacuum distillation of a crude metal or an alloy was discussed. The equilibrium relationship between vapor phase and liquid phase in A-B system - - - - - PA/PB =BAa*/b has been derived. The separation coefficient, BA = rAPA/(rBPB) is a judgment criterion. By calculation PA/PB, the equilibrium composition diagram of vapor phase and liquid phase was drawn. By use of the equation derived by M. Olette, the relationship among the volatilization amounts of various impurities in a crude metal (yi) was further solved. 1-(X/100)= C =(1-Y1/100)1/02i . From yi value obtained in practice, 2i, Pi and then can be calcu-lated. The correct volatilization order of various impurities was obtained. These results can be applied to determine the practical conditions (temperture, vacuum degree, type of distilla¬tion furnace, times of distillation and control of product composition) in distillation of a crude metal or an alloy.INTRODUCTIONRefining and separation of various impurities from nonferrous crude metals by vacuum distillation have many the advantages of high metal recovery, impurities recovered in metallic state, flowsheet simplified, good enviromental protection, low operation costs and in complex equipment. So in recent years this method has been adopted widely.Vacuum distillation has also been studied and used in separation of various elements from non-ferrous alloys and the area of its application is being extended rapidly.At this situation, some problems have been put up: What kind of impurities can be removed from crude metals? What kind of alloys can be separated by vacuum distillation? In present paper, attemps have been made to answer these problems and combine with practical results to analyse some valuable data obtained from testwork on vacuum distillation of crude tin and Pb-Sn alloy."

Jan 1, 1988

By Arthur S. Klein, Hugh R. Lowry

"The Levitation Casting Process is a new continuous casting method that uses an electromagnetic levitation field, instead of a mold, to support and contain a column of solidifying metal. By counteracting gravitational forces and hydrostatic pressure on the metal column, this process eliminates friction and adhesion at the interface between the solidifying metal and the cooled walls of the casting chamber. The process inherently provides high casting speeds, excellent dimensional control and smooth, continuous emergence of solidified product from the top of the casting chamber.Of major importance is that the electromagnetic field produces an intense stirring of the liquid metal both before and during solidification. As a result of this stirring, the cast product has a homogeneous, equiaxed, fine grain structure generally suitable for immediate drawing or other forming operations without the need for hot rolling or other expensive additional processing.This paper reviews the fundamentals of the Levitation Casting Process, results obtained in casting various pure metals and alloys, and the production sized system at Lowell, MA, that uses this process. IntroductionThe Levitation Casting process was specifically developed to meet several requirements including:• Economic at low casting rates• Usable with pure metals and alloys• High, uniform product quality suitable for fine wire drawing or cold rolling into flat strip and tape• Easy cast product shape and size changes• Process inherently stable and easily automatedIn meeting these criteria it was also desired to retain the advantages of General Electric's well known Dip Forming continuous casting process; namely the inherent ""fail-safe"" properties of upward casting, solidifying metal by means other than pressure contact with a cooled mold, and use of a sealed furnace, casting chamber and cooling tower, filled with a protective atmosphere, to prevent oxidation of the molten metal or cast product."

Jan 1, 1988