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By P. B. Queneau

An operating problem encountered at the Moa Bay operation in Cuba, where nickeliferous laterite ore is processed by sulfuric acid pressure leaching, is the formation of alunite and hematite deposits on the autoclave walls. The AMPX Extractive Research & Development, Inc., metallurgical laboratory (Golden, Colorado) has made substantial improvements in the Moa Bay process in the areas of metal recovery, energy consumption, and feed versatility. One of the advantages of AMAX's process is its ability to treat substantial portions of nickel- and magnesium-rich serpentine while maintaining acid utilization efficiency. The process minimizes scale formation by combining staged acid addition with vigorous agitation and 270°C operation, but does not eliminate scaling. This paper describes how advantage can be taken of MgSO4?XH20 precipitation both to inhibit alunite scaling and to disperse hematite scale within the MgSO4?XH20 matrix. Cooling the autoclave from its 270°C operating temperature down to 180°C takes advantage of the reverse solubility of magnesium sulfate. The magnesium dissolves, liberating entrained hematite, thus providing a means for control of autoclave scale with minimum process disruption.

Jan 1, 1984

By G. R. Alther

Finely ground dried bentonites were compacted with a laboratory size Komarek roller compactor. Before compaction the moisture content of the bentonite was adjusted from 8-12% by adding water in a mixer. Predetermined amounts of Nat CO3 activator were dissolved in that water and added to the bentonite. Comparative rheological tests were then run with the compacted, activated bentonite versus unaltered bentonite. Compaction and activation of the bentonites improved their viscosity and water loss properties considerably, more so than extrusion and slurrying. It was concluded that, by using a compactor, bentonite reserves can be extended because low quality material can be improved without adding organic polymers. Introduction Many bentonites mined in Wyoming, South Dakota, and Montana are naturally of drilling mud quality. Those of low sodium content, and those of predominantly potassium, calcium, and magnesium exchangeable cations need altering to meet drilling mud requirements. Most foreign bentonites require sodium activation to meet drilling mud standards set by the American Petroleum Institute (API).

Jan 1, 1984

By William X. Chavez

The Mantos Blancos copper-silver district is located in northern Chile about 45 kilometers northeast of Antofagasta, as shown in Figure 1. Disseminated and veinlet copper and copper-iron sulfides containing economically significant silver values are hosted by andesitic to rhyolitic volcanic rocks of probable Jurassic age (Chavez, 1983). Field, mineralogical, textural and lithochemical evidence show that three major alteration types may be recognized within the district: (1) district-wide sodium metasomatism, manifested as albitization of feldspars and development of albite veinlets and pore-fillings, (2) local to widespread, incipient to intense addition (chloritization) or removal (bleaching) of magnesium and iron and (3) local to widespread, moderate to intense hematitization, usually spatially associated with bornite-digenite-covellite (as specularite) or digenite-covellite-chalcocite (as red hematite staining with or without specularite) mineralization. Carbonatization, occurring as veins, veinlets, vesicle fillings and irregular patches of calcite, varies in magnitude of development but is widespread. Sericitization of feldspars and groundmass is only locally intense yet is generally present as incipient alteration throughout the district. The district-wide albitization of the Mantos Blancos volcanic sequence has altered what were originally more potassic and calcic, less sodic, rocks to what are now more properly referred to as keratophyres (Battey, 1955; Gilluly, 1935, Hughes, 1975). The petrographic and lithochemical characteristics of the three major alteration types noted above are summarized below.

Jan 1, 1984

By Macaulay J

The recovery of gold from cyanide liquors is frequently effected by using activated carbon. Process economics however require non destructive methods of gold extraction from the carbon so that it may be recycled.Stripping at atmospheric pressure usingthe method of Zadra et al(l) suffers from the disadvantage of unfavourable kinetics with strip times of the order of 48-72 hours. Subsequent research has led to development of processes which strip the gold more rapidly namely: A.A.R.L. process, (2,3) organic solvent (4,5,6) and pressure stripping (7,8)This paper reports on a development of the pressure stripping technique in which stripping and electrowinning are carried out at elevated temperature and pressure.

Jan 1, 1984

By P. Campbell, E. M. Gardy, L. Hachkowski

Introduction The efficient process control of a uranium mill and its associated mining operation requires a nearly continuous knowledge of the uranium concentration in the ore. Generally, the approach is to use laboratory assays of grab samples from the mill feed belt. In some cases, elaborate and expensive systems have been used to ensure random sampling, but even with these systems, mass-balance discrepancies still exist. There is a requirement for an on-line instrument that can give a prompt, accurate analysis of a large portion of the feed stock. The authors have recently evaluated a laboratory system that achieves these goals using neutron activation and delayed neutron counting. The development of the on-line uranium ore analyzer is a consequence of previous work done at the Whiteshell Nuclear Research Establishment (WNRE) (Campbell et al., 1978 and 1981), and is based on the emission of delayed neutrons after the neutron irradiation of fissionable materials. The mechanism of delayed neutron emission has been described (Keepin, 1965), but briefly is as follows. The fission fragments resulting from irradiation are in an excited state. Certain of these delayed fission products, precursors, decay to a more stable state by the emission of a delayed neutron. The delayed neutrons can be divided into six groups with effective half-lives ranging from 0.2-55 sec. It is important to note that more than 50% of the delayed neutrons are emitted within the first 6 sec after irradiation; this has an influence on the design of the analysis instrument. Measurement Cycle The measurement cycle involves a neutron irradiation, a delay time, and a counting period. The laboratory demonstration model of the ore analyzer comprises a californium-252 neutron source, a source chamber, a pneumatic transfer facility, and a neutron irradiation and counting module (Fig. 1). The ore sample is placed in the irradiation chamber. The neutron source is transferred to the center of the chamber for a 5-sec irradiation while the helium-3 thermal neutron detectors are switched off. As the source returns to the storage chamber, the detectors are switched on and the delayed neutrons counted. The total assay cycle is 16 sec. The current instrument design calls for the ore to be cut from the main belt every 16 sec by a mechanical arm and dropped into the analyzer directly, or via another belt. The cycle starts when there is a sufficient mass of ore in the irradiation chamber to depress a switch and stops when the delayed neutron count is finished. The ore is then dropped through the bottom of the analyzer chamber and returned to the main belt. The counts from each cycle are accumulated and the data reduced to give the desired information. Key for Fig. 1 A-Helium-3 neutron detector B-Wax moderator for neutrons C-Irradiation chamber D-Funnel for receiving ore E-Gate F-Transducers G-Biological shield for neutron source H-Transfer tube for neutron source I-Neutron source J- Microprocessor K-Accumulator for hydraulics L-Control panel M-Electro-hydraulic servo valve to control movement of the source N-Electro-hydraulic proportional valve to control movement of the gate O-Hydraulic power unit Irradiation and Counting Equipment Irradiation of the ore is achieved using a 1 X 10 7 neutron*s-1 californium-252 neutron source. The source is contained in an iron capsule and pneumatically transferred between the irradiation/counting and storage chambers. The irradiation/counting chamber possesses 12, 600-mm (24-in.) long helium-3 thermal neutron detectors embedded in an annulus of wax (Fig. 1). Two sets of six detectors are each interfaced to a preamplifier, amplifier and single-channel pulseheight analyzer system, and the two systems are connected to a scaler. A special timing unit controls the transfer of the source and the on and off switching of the detector assembly, in sequence with the movement of the source. Results and Discussion In the experimental demonstration, using the 107 neutron.s-1 source, a 10% uranium ore was measured to ± 10% (2o total error) in 10 cycles and ±6% (2o) in 100 cycles. Since a larger source was not available, it can be statistically predicted that a 109 neutron-s-1 source could be used to measure a 0.1% ore to ± 10% (20) in 10 cycles. The uranium can occur as discrete nonhomogeneous particles in the ore, and the error caused by such a distribution of particles is ± 4% (2o), as determined by

Jan 1, 1984

Jan 1, 1984

By Donald E. Zipperian

The studies described in this paper have established that flotation conducted in a column cell provided with gas generation by aspiration into surface tension lowered water, may considerably increase the efficiency and particle size range of a flotation process. Operation of a DEISTER FLOTAIRE ® Cell at several Southwest United States flotation plants under continuous rougher, scavenger and cleaner conditions has demonstrated the main positive features to be: (a) higher capacity per unit volume than conventional flotation equipment, (b) improvement of flotation of plus 0.210 m particles, (c) improved flotation of particles minus 0.037 m.

Jan 1, 1984

By Luis E. Vallejo

Experimental and theoretical analyses are presented to study the mechanics of growth and interaction for three inclined left-stepping, three inclined right-stepping and two inclined non-stepping cracks in a brittle material subjected to uniaxial compression. It was found that the non-stepping cracks did not interact and they propagated individually in a direction parallel to the uniaxial compressive stress. The propagating cracks formed in regions where tensile stresses developed. The left-stepping cracks interacted and formed branching cracks as a result of failure in tension of the material between them. Also, they propagated from their tips in a direction parallel to the uniaxial compressive stress. The right stepping cracks did not interact, but extended themselves from their tips following a direction parallel to the uniaxial compressive stress. The extended cracks formed in areas of compressive stresses.

Jan 1, 1984

By Edward D. Thimons

A remote-actuated stench gas fire-warning system has been designed and tested by the Bureau of Mines. This system makes use of the hard-wire network for the mine's phone pager system, thus greatly reducing the system cost. By locating stench gas canisters with remote-actuation release capabilities near working sections, the fire-warning time can be greatly reduced. In a test of the system in a Missouri lead mine, the time required to warn miners of a fire at two working faces was reduced from about 20min with the conventional system to less than 4 min with the remote-actuated system.

Jan 1, 1984

By Butcher NM, Walker GS

Argyle Diamond Mines Pty. Limited (ADM), manager and operator of the Argyle Diamond Mines Joint Venture (ADMJV) will recruit approximately 400 employees during 1985 to operate the new large-scale, open-cut diamond mine and treatment plant being developed at Argyle, in the East Kimberley Region of Western Australia. These employees will live in Perth or environs and will commute to work at Argyle via chartered jet aircraft. On site, they will be accommodated in self-contained single person's quarters, with central messing and recreational facilities. Rostering systems have not been finalised, but it is likely employees will rotate through a cycle of 14 days at site and seven-days on leave in Perth. ADM spent three years evaluating residen- tial options before deciding to commute its workforce from Perth. Another 70 senior staff will reside in Kununurra (the nearest established town, 250 km from Argyle) and commute to the mine daily by air.

Jan 1, 1984

This paper refers to the open cut mining practice developed at Western Mining Corporation's Kalgoorlie Gold Operations (K.G.O.). Mining activity was centred attwo areas, namely W.M.C.'s Siberia "Sand King" and"Missouri" open cuts plus W.M.C.'s "Great Boulder" and K.M.A.'s "Horshoe" and "Morrison -Hannan's Star" open cuts in Fimiston.Kalgoorlie Gold Operations was set up initially to look after W.M.C.'s open cut interests in and about the Kalgoorlie area. The first mine commenced was, the Sand King open cut, approx 75 km NW of Kalgoorlie. it was here that the requirement for a highly selective form of mining first became apparent.

Jan 1, 1984

By Wilfred M. Kenan

The relationship of various genetic classifications of graphite, their properties and general applications are reviewed. The classifications being amorphous, flake, high crystalline (vein) primary synthetic graphite and secondary graphite. The properties discussed are size, carbon, sulfur, ash content, general chemical analysis and degree of graphitization of each type. The major sources for natural and synthetic graphite powders are discussed in addition to factors which govern the cost as well as the supply. The economics of graphite are basically determined by the consumer and the end application. Graphite is a strategic mineral and is on the government stockpile list.

Jan 1, 1984

By Jose A. Ruiz

INTRODUCTION For heterogeneous non-catalytic solid-gas reactions carried out in fluidized bed reactors, nominal bed temperature is an average value between gas and solid. For highly exothermic reactions, actual particle temperature can be up to hundred degrees above termocouple temperature, since heat dissipate at slower rate than heat generation during some steps of transformation. These micro instabilities at particle level can displace thermodynamic equilibrium from the desired phase to others. This effect is important when relatively narrow range of phase stability exists, like in sulphation roasting of sulphides, where bed discharge contains, in addition to the desired sulphate others metastable phases such as basic sulphate and ferrite. For example, for copper-iron sulphide concentration roasted below 680°C, no cupric ferrite is formed, as shown by Jakob et al., therefore the separate Kellogg's stability phase diagrams Cu-S-O represent the roasting (Fig.l). At temperature above this one, like 760°C for example, phase stability changes from CuSO4 to the basic sulphate Cu0•CuSO4. Solid state reaction between Cu0•CuSO4 and Fe203 also occurs to form cupric ferrite, Cu0•Fe2O3, therefore the Cu-Fe-S-O Kellogg's phase diagram of Fig. 1 (continuous line) represents this condition of roasting. Although both Cu0•CuSO4 and Cu0•Fe2O3 are metastable phases under normal operating conditions of sulphation roasting(1-10% SO2, 1-10% 02 and 680°C, points A and B,Fig. 1) sulphation of these species and particularly ferrite are slow and limited due to diffusional control. This explain why reactors discharge contains several phases: CuSO4, Cu0•CuSO4, CuO•Fe203 plus small amounts of CuS and FeS due to the baclonixed conditions of fluidized bed reactors. The presence of cuprous ferrite due to reducing conditions inside individual particles also occurs, but in very limited extent at the reaction interface, as it is demonstrated by the low soluble iron levels of calcines. On the other hand, the presence of cupric ferrites can be explained only due to the higher temperature achieved by particles, since below 680°C cupric ferrite formation does not take place. [ ] This phenomena also occurs for others non-ferrous metal sulphides concentrates roasted under sulphation conditions, such as 7n, Co and Ni. Therefore the prediction of discharge composition of fluidized beds is not possible based only on kinetics and mechanistics models alone or purely thermodynamical considerations, since all factors should be integrated to describe the overall phenomena. SINGLE PARTICLE TRANSFORMATION Assuming a first order reaction with respect to the gas and zero for solid, such as

Jan 1, 1984

By R. P. Vinson

The Bureau of Mines examined the effects of high humidity and water droplets on the GCA Corp. real-time aerosol monitor (RAM--l). which uses a lO4mm cyclone preseparator. Tests were conducted both in a laboratory and in a full-scale model mine entry. The laboratory tests were conducted in a test chamber saturated with moisture and water droplets. Under these extreme conditions. the RAM-I responded by indicating dust concentrations of 1-1/2 to 2 mg/m3? although the air was dust free. Within the first 2 h of each test. water accumulated in the cyclone and affected the cyclone particle separation characteristics. resulting in readings of 3 to 4 mg/m3. In addition. condensation formed inside the RAM-I case and affected the liquid crystal display (LCD). However. the full-scale mine entry tests revealed that the RAM-I can function ac-ceptably in an atmosphere of water vapor and water droplets similar to the most severe conditions found in an underground mine.

Jan 1, 1984

By DiStefano AB, Dale SG

This paper describes the laboratory study implemented to investigate the application of the subaerial technique to tailings disposal for the proposed Olympic Dam Mine. The results of the study and the resulting design parameters are presented. The subaerial technique of tailings disposal is described and the advantages of the method for disposal in arid climates highlighted.

Jan 1, 1984

By W. A. Haley

Wheel loaders became important bulk materials handling tools in the early fifties. As they grew in stature, productivity, reliability, and acceptance, the demand for larger, more rugged machines evolved. In the early sixties, the introduction of a 6-yard model by a major equipment manufacturer led quickly to widespread experimenting and rapid worldwide acceptance in loading blasted rock in stone quarries and smaller metal mines. As the wheel loaders grew in popularity for shot rock loading, larger models, 12- to 15-yard size were developed and saw widespread use by 1970. In the past 20 years, at most quarries and small to medium size mines, most cable operated power shovels have been replaced by large wheel loaders and more recently, hydraulic excavators as the primary loading tool. Wheel loaders larger than the 15-yard class are not used widely. Until about 1970, very few overburden haulage trucks were used in domestic coal mines. About that time, many states started enforcing stringent mine relcamation regulations and in 1977, even more stringent federal legislation was passed. These controls brought about drastic changes in coal surface mining methods in the mountainous areas of Appalachia, in smaller midwestern mines and in the large mines of the western states. Basically, simple material casting methods were replaced at most eastern mines by "haul-back" and "mountain top mining" methods using controlled placement of overburden as it is removed from the coal. These methods dictated much more extensive use of loaders/ shovels and trucks to the point that most coal mining in those areas is now by loader/shovel trucks methods. And those areas have become the home of the country's largest population of large wheel loaders and trucks in the 35- to 85-ton size class with a trend to even larger trucks and shovels. To maintain equal production or provide for growth, the new methods have caused a sharp increase in machine intensity to the extent that at some mines, up to three times as many machines were required to mine a million tons of coal in the late seventies as compared to the machine needs in the sixties. Mining costs and coal prices also took a big jump in the mid-seventies, paralleling the drastic price increases in oil and other forms of energy.

Jan 1, 1984

By J. L. Osiensky, R. E. Williams, J. Linehan

The hydrostratigraphy of uranium in situ leach sites consists typically of interbedded layers of sand, silt, clay and gravel deposited by fluvial processes. 'These layers usually form leaky multiple aquifer systems where sand and gravel aquifers are separated by silt or clay confining layers (aquitards). It is very important to evaluate the hydraulic properties of the ore zone aquifer and the confining layers by aquifer pump testing to ascertain the effects that in situ leach mining will have on the multiple aquifer system. The degree to which current methods of aquifer pump testing will provide the information necessary to adequately characterize the hydraulic properties of the ore zone aquifer and its confining layers is dependent upon the hydrostratigraphic conditions at the site and the limitations of the testing methods. The primary objectives of the aquifer testing program should be to evaluate the vertical hydraulic conductivity of the confining layers and to quantify leakage into or out of the ore zone under mining conditions.

Jan 1, 1984

By Robert B. Fulton

Summary of data and estimates for 52 fluorspar properties in the following 13 foreign countries: Mexico Thailand China (PRC) Morocco Tunisia Italy Spain South Africa France United Kingdom Kenya Namibia Federal Republic of Germany Data includes deposit type, resource tonnage and grades, mining and beneficiation methods, annual production, fluorspar products and by-products, manpower requirements, capital and operating cost estimates. For operating properties, engineering and cost data have been developed for present and anticipated levels of production. Hypothetical operations have been assumed for undeveloped deposits.

Jan 1, 1984

By K. Haramy

Coal mine bursts or bumps involve the violent, rapid failure of coal and rock in or around a mine excavation. Failure is normally associated with high stress and brittle or brittle-elastic materials; in coal mining, bursting may also be associated with desorbing gas, and this type of failure is termed an outburst. This paper discusses factors affecting coal mine bursts and several methods to predict bursts, including microgravity, microseismic, rheological, rebound, and drilling-yield methods. Methods to avoid burst conditions using volley firing, hydraulic fracturing, and auger drilling are also discussed. A case study is presented in which the redistribution of stresses and displacements was found to be associated with a burst at a deep longwall coal mine. The research showed that stresses are redistributed following the burst.

Jan 1, 1984

Although the flotation cell has been under continuous development over the past 80 years, an understanding of the precise roles of a cell in produc- ing the flotation result had evolved slowly. In fact, detailed studies of cell dynamics began only in the 1940s when flotation practice had almost reached the half-century mark. The earliest generalizations related cell capacity to power intensity (hp/vol- ume) (Rose, 1946), and specific operating features such as aeration and power ' consumption to impeller submergence and operating speed (Read, 1933). In the 1950s hydrodynamic characterization of cells through power coefficients and air flow numbers began (Arbiter and Harris, 1961) and has continued to the present, with increasing industrial use of these concepts (Degner, 1982; Degner and Treweek, 1976). Liquid flow measurements in Wemco cells (Degner, 1982) made liquid flow numbers and turnover frequencies available for more complete under- standing of cell dynamics. The present overview of flotation technology is a critique of cell design. The cell process represents the interactions between cell dynam- ics, cell geometry, and ores, with the latter prepared for that interaction through size reduction and reagent treatment. While previous invest- igations of flotation cells have accepted all cell designs uncrit- ically, the present study considers the physical process components that an effective cell must provide, and then compares a limited number of

Jan 1, 1984