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By Noriyuki Fujii

It is no need to say that exploitation of industrial minerals has a close relation to development of the industries related. In the first stage, a small scale manufactures were initiated in areas producing some main raw material minerals. China and cement manufactures, for example, were established depending on the local occurrence of raw materials such as kaolin and limestone without exception. That is, the industrial development is greatly influenced by the local production of the raw materials in the stage. With the development of industrial technology, various kinds of raw material minerals are explored to meet the demands of industries in the second stage. New materials become indispensable, and low-grade raw material minerals, which were left as useless, are developed as useful materials. In the stage, the development of raw material minerals is accelerated by that of industrial technology related. However, industries mainly rely on domestic production of the min raw material minerals.

Jan 1, 1981

By L. C. Stone, J. C. Parr, T. N. Anderson, D. Metcalf

An increase in the importance of low-grade materials as sources of gold and silver has led to the need for improved analytical methods on leach solutions, ores and various effluents, residues, and in-process streams. These are required by plant operators as guides to process control and for accounting pldrposes. Atomic absorption spectrophotometry (AAS) and AAS preceded by pre- concentration have been applied successfully to resolve many such problems. However, AAS is no panacea and imprecision or loss of accuracy can result if adequate precautions are not taken to prevent losses and eliminate interferences. The recent methods are discussed together with methods for overcoming difficulties. Comparisons with more classical analytical techniques are also given.

Jan 1, 1981

By B. Gillenwater

This report describes the results of investigations into four specific areas related to trolley wire power distribution systems in coal mines. These are: 1. Partially insulated (shielded) trolley wire 2. High-speed insulator fault detectors 3. Dual-wire trolley systems 4. Insulator failure indicators. Prototype devices or designs were developed in each area. In addition, a brief survey was made in an attempt to assess the Future of mine trolley systems, and data was collected and reviewed in an attempt to analyze the nature of trolley wire related accidents. Other options for decreasing the risks associated with trolley systems that arose .during the study are briefly described in appendices. These include insulating equipment and miners from return and/or energized conductors and use of a segmented trolley wire with local control of current delivering capability.

Jan 1, 1981

By Eric R. Skonberg

"Technology exists today to blind drill a mine shaft 20 feet in diameter, unlined, over 3,000 feet deep. These shafts must be lined in the most economical, safe and expedient manner possible. A new technique of stacking precast concrete cylindrical sections in the unlined shaft has been developed to yield a dry and hydrostatically lined shaft .These sections must withstand an external radial pressure of 3,000 feet of water yet take up as little room as possible in the shaft . Using high-strength concrete, wall thicknesses may be kept at 2 feet. The outside diameter of the sections has been chosen to be 18 feet to allow for some annular space between the liner and shaft wall. The concrete sections are produced in segments 10 feet long weighing 75 tons each. During drilling operations, the concrete sections are cast and cured. After drilling operations are complete, a headframe is situated over the shaft. The unlined shaft remains full of fluid. A special liner running tool is mated with the section in three steel ports at the bottom of the section. The section and running tool are lowered into the hole, and the tool is disconnected and returned to the surface. Subsequent sections are lowered and stacked using the same operation. Grout is placed behind the liner to result in a dry shaft."

Jan 1, 1981

By G. H. K. Pearse

Long range transport of pollutants, particularly of sulphur dioxide and the associated acidic precipitation, has received much attention in the press and in international discussion during the last few years. Studies revealing increasing acidity of lakes and the dying out of fish populations over broad regions of the eastern half of North America have created alarm. In this paper, I will not attempt a description of the acid rain phenomenon. For this r recommend the balanced treatment of the subject by Gene Likens et al (1979) in Scientific Americana For my purposes I accept that the problem is serious and direct my attention to exploring a solution. Ultimately, the key lies in the answer to the question; "What do we do with the enormous tonnages of pollution abatement byproducts, chiefly sulphur compounds, that would arise from pollution control?"' Little thought has been given to this most limiting factor to environmental clean-up. This is symptomatic of a basic flaw in the [philosphy] that under-ins environmental policy. Although this paper is to propose a solution to the abatement byproduct problem, the basic flaw - the firmly entrenched, universally adopted, 'polluter pays [philosphy] as it is currently [understood] - needs some comment.

Jan 1, 1981

By Thomas J. Mason, Geno Saccomanno, Victor E. Archer, Philip C. Prorok

INTRODUCTION A population of several thousand uranium miners in the Colorado Plateau region of the United States has been under surveillance since 1957 using sputum cytology and other procedures. Attempts were made to collect sputum samples annually for those miners showing normal sputum or only minor abnormalities, and on a semi-annual schedule for miners having more severe cytological abnormalities. For individuals having carcinoma in situ or malignant cells in their sputum, samples were taken more frequently. As in any human population, however, these schedules were not always adhered to, and samples were often acquired less often than scheduled. On the basis of the thousands of sputum readings that have resulted from this surveillance, one can calculate the durations or sojourn times which individuals spend in the various cytologic states into which the sputum readings are classified. This paper presents some preliminary, descriptive results concerning relationships among the cytologic state duration distributions in this population, and their associations with other variables such as radiation exposure and cigarette smoking. There are several reasons for studying cytology results in this observational setting. Of considerable interest is the opportunity to gain insight into the preclinical natural history of lung cancer. Such information would be valuable in the future design and interpretation of screening programs for the early detection and treatment of lung cancer, should this activity prove to be of benefit in experimental trials. Secondly, it is of interest to determine if some characteristic of sputum cytology readings can be utilized to determine a decision point at which to transfer a uranium miner to another job category within the industry in order to effectively reduce his probability of developing lung cancer. For example, a reading of moderately atypical cells in the sputum has been suggested as a possible decision event which would be sufficient to warrant such a transfer. In the analysis which follows, an attempt will be made to develop information relevant to these issues. The data base for our analysis, largely developed over a period of more than 20 years by Drs. Geno Saccomanno and Victor Archer, contains sputum readings classified into one of eight cytologic states: normal, metaplasia, mild atypia, moderate atypia, marked atypia, suggestive, suggestive-equivocal, and malignant. The two suggestive states will not be considered as these categories seldom contain enough observations to generate meaningful results. The duration in a given cytologic state for a given individual is calculated as the sum of the intervals between consecutive sputum readings in that state. When two consecutive readings are in two different states, half the between-readings interval is assigned to each of the two states. Among all individuals in the data base, only those having at least two sputum readings are used so that a duration can be calculated. Furthermore, the analysis is limited to individuals whose successive readings are no more than 24 months apart, so as to focus on a population which was under surveillance on a reasonably regular basis. RESULTS The overall distributions for the cytologic states are displayed as histograms in Figures 1-3.

Jan 1, 1981

By Dyson N. F

Mixed cobalt-nickel sulphides precipitated from ammoniacal process liquors derived from nickel sulphide concentrates, mattes, and reduced nickeliferous laterites have been characterized.The mixed sulphides are prone to oxidation on standing and are rapidly leached under relatively mild conditions. The kinetics of the leaching reactions are controlled principally by temperature and oxygen partial pressure. Although the samples have different CO:Ni ratios and have undergone varying degrees of oxidation, there is little difference in their leaching behaviour. The results suggest that a single plant would be able to process mixed sulphides of varying composition. Any copper and zinc present in the mixed sulphides as impurities also go into solution and must be removed prior to recovery of the cobalt and nickel in metallic form.

Jan 1, 1981

By P. K. Kaiser

The purpose of deformation monitoring for the evaluation of the stability of underground openings is reviewed briefly and some results from laboratory tests of small tunnels are presented. The ground behaviour is described by comparison with the response of structural systems and illustrated by the data from the testing of small tunnels. It is concluded that the main objective of a deformation monitoring system for stability evaluation is to determine the actual process of deformation and instability in the area surrounding the opening. Only when this process has been established is it possible to use deformation measurements to design support systems or to improve construction or mining procedures. Present monitoring practice is not sufficiently orientated toward the aim of process description.

Jan 1, 1981

By D. Mills, W. H. S. Lawson

"The need to make repairs is seldom a major consideration in the design, fabrication and installation of major components of electrical generation plants. Repair welding, however, is a fact of life in the electrical generation industry, for restoration of degradation in service, from cavitation of hydraulic turbine runners, to corrosion and fatigue damage in pressure vessels. In making weld repairs to carbon and low-alloy steels, the largest source of trouble is hydrogen embrittlement and related post-weld cracking. Various strategies have been developed to control problems from this source, including post-weld heat treatment, the use of nickel-base alloy filler metals and the temper bead welding technique. Each of these basic strategies is being applied as circumstances require; each strategy must, however, be implemented in a manner that reconciles weldment structure and hardness, degree of restraint and service environment with the consequences of unsatisfactory performance of the repaired component.IntroductionMajor working components of electric generating plants are specified and installed on the basis that, wherever technically and economically feasible, they will retain functional capacity without major repairs for the twenty-five-plus years of normal plant lifetime. Nevertheless, repairs are often required, and welding is usually an essential feature of the work. Remedial welding may be performed to correct design or fabrication errors which become evident only at the time of component installation. The most common causes of requirements for repair involve corrosion, fatigue or related processes which prove more aggressive than expected during service. Increasingly, our planning for future repair requirements is related to continual improvements which are occurring in nondestructive evaluation technology. As components are periodically reinspected during their service life, fabrication induced defects may be revealed for the first time quite late in the life of the component. When this occurs, repair must be considered wherever inaccessibility of a flaw makes it impossible to prove its inactivity. Finally, there are certain components, for instance in hydraulic turbines, which cannot be economically made or used without the expectation of service induced wear. Here, periodic maintenance welding must be regarded as a normal event."

Jan 1, 1981

By Ralph B. S

Bacterial leaching of low grade quartz felspar porphyry copper ore was studied in large-scale laboratory percolation leaching columns.Limitations in the release of soluble copper showed up before fifty per cent recovery, due to occluding precipitates of iron oxides and hydroxides. Precipitates were removed by increasing the acidity of irrigation feed four-fold with respect to sulphuric acid. However, irrigation at low pH (pH 1.5) inhibited copper leaching. Resumption of bacterial leaching at pH2 was achieved by introducing a period of non-irrigation. The results suggest a 'direct' attack by bacteria on the chalcopyrite substrate rather than an 'indirect' ferric-leach mechanism.

Jan 1, 1981

By James L. Poole

The gold and silver markets from the late 1960's to the present are reviewed and the outlook for these metals in the 1980's is presented. Included in this discussion is a summary of the basic supply and demand balance for gold and silver since the mid-1960's. an explanation of the price formation for the metals, some of the relationships between the prices of these metals and selected economic parameters, and how these factors affect the outlook.

Jan 1, 1981

By P. W. Percival, J. J. Janssens

"Whitehorse Copper is a 2600-ton-per-day underground copper mine located within the city limits of Whitehorse, Yukon . In early 1978, due to increasingly difficult ground conditions. it was decided to investigate the conversion from longhole open stoping to vertical crater retreat mining. On-site crater testing by C-I-L demonstrated the feasibility of V.C.R. mining at Whitehorse Copper.After some investigation. a down-the-hole drilling rig was chosen and drilling began in November /978. Blasting began in June /979. and to September 1980 approximately one million tons of ore had been blasted. In-field changes to both drilling and blasting techniques have been implemented. Some of these changes were dictated by problems encountered; others were made to improve efficiencies.To date. V.C.R. mining has proven successful from a drilling and blasting aspect.IntroductionWhitehorse Copper Mines Ltd ., a division of Hudson Bay Mining and Smelting Co., Limited , is a 2600-Lp.d. underground copper mine. The plant site is located I mile west of the Alaska Highway, and approximately 7 miles south of Whitehorse city center. Production is from the Little Chief orebody, and total output is from vertical crater retreat stopes.The Little Chief and Middle Chief orebodies at Whitehorse Copper had original reserves in excess of 6 million tons, most of which graded 2.00/0 copper or higher . The orebodies are typical skarn deposits that have developed along the contact between an intrusive diorite and a limestone-quartzite flank pendant. The limestone has been metasomatized to form a calcium-magnesium skarn which, along the limestone / quartzite contact, has locally further developed into a mineralized magnetite-serpentine skarn. The principal copper minerals are bornite and chalcopyrite, with minor chalcocite and valleriite. Skarn gangue minerals are serpentine, diopside, garnet, epidote, calcite and wollastonite. Appreciable values in gold with some silver are present and recovered as well."

Jan 1, 1981

By W. D. Felix, R. D. Smith, J. A. Campbell

The mechanism most consistent with available information on atmospheric trace element emissions involves the volatilization of a significant fraction of many trace elements during coal combustion, with subsequent condensation on fly ash as the combustion gases cool. The larger surface-td-volume ratio of the smaller particles leads to an enrichment of the volatile trace elements. From an environmental viewpoint, the submicron size particles are of greatest concern. These particles show the highest concentrations of trace elements, are least efficiently collected by pollution control devices, have high atmospheric mobilities, and are deposited preferentially in the pulmonary and bronchial regions of the respiratory system. The mechanisms for trace element enrichment and formation of submicron particles will be described.

Jan 1, 1981

Methane is present in varying degrees in nearly all underground coal mining operations. At mixtures with air near 5-15% it is explosive and consequently since it is not usual for these levels of contamination to be reached in the general body of a mine ventilation system it is not unusual to experience it in specific places. On longwall faces the most used power loader is the shearer machine and because of its general shape, situation and operation it is likely that all the factors which are required to cause a frictional ignition can be present. This paper makes a general appreciation of the causes of these ignitions and methods which are and have been used to control these situations on and around these machines.

Jan 1, 1981

By F. L. D. Cloete

The Relix process is based on direct contact between an ion-exchange resin and undiluted pulp, thus avoiding prior solid-liquid separation. The resin particles float near the surface of the pulp, forming an inverted fluidized bed with the pulp flowing downwards. The basic idea was demonstrated on a full-scale pachuca tank at Stilfontein Gold Mine in 1970, followed by a small-scale demonstration run in a laboratory at the National Institute for Metallurgy. A pilot plant based on a throughput of 60 tons of ore per day was subsequently operated at West Driefontein Gold Mine for several periods over two years. Although the plant proved operable from a mechanical point of view, the metallurgical performance was not up to expectation. The basic cause of the poor metallurgical performace was shown to be backmixing of both the resin and the pulp between stages. The values obtained for resin losses were inconclusive. Further development of resin-in-pulp processes for the recovery of uranium should be focused on the performance of various techniques for the screening of resin from pulp.

Jan 1, 1981

By G. A. Swanquist

INTRODUCTION This article describes the yellow cake drying, packaging and dust collection circuit of the United Nuclear Church Rock Mill. It also describes the layout and floor plan of this section as well as the operation and performance of the various equipment. In order to place the yellow cake section in perspective of the mill as a whole, the mill circuit is described briefly. CHURCH ROCK MILL GENERAL DESCRIPTION The Church Rock Mill contains six operating sections shown in Figure 1 in block diagram form. The grinding section consists of a semi-autogenous mill in closed circuit with a hydrocyclone. The slurry is then routed to the leaching tanks. Sulfuric acid and sodium chlorate is added to dissolve the uranium. The pulp is transferred from the leach tanks to the thickeners where the uranium bearing liquid is separated from the barren solids. The uranium bearing solution is then filtered and pumped to the solvent extraction section. [ ] In the solvent extraction section, the uranium bearing aqueous solution is brought into contact with an organic solution composed of kerosene, amine and isodecanol. The amine extracts the uranium from the aqueous solution. This organic solution is then routed to the stripping section, where the uranium is removed from the organic solution with an ammonium sulfate aqueous solution. The pregnant stripping solution now concentrated to 30 gpl U308 is routed to the precipitation tanks where ammonia is added to precipitate the uranium. The yellow cake is then washed in a counter current circuit of two thickeners and one centrifuge to remove impurities, mainly sulfates in order to meet specifications. The centrifuge centrate is routed to the second wash thickener for forward wash. The centrifuge cake at approximately 50% solids consistency is transferred to the yellow cake dryer via a screw conveyor. YELLOW CAKE DRYING, PACKAGING AND DUST COLLECTION Figure 2 shows the flowsheet of the integrated circuit of drying, packaging and dust collection. This section of course centers around the yellow cake dryer as the main equipment. The other main units are the dust collectors for the dryer and packaging respectively, a yellow cake storage bin and the yellow cake packaging facilities. Physically, all of this equipment occupies four floors, beginning at the top floor: 1. Both dust collector fans, the centrifuge and the screw conveyor to transport the yellow cake to the dryer. 2. The dryer, fire box and both dust collectors occupy the third floor. Figure 3 shows the floor plan of the third and fourth floors. 3. The yellow cake storage bin and dryer dust collector sump are located on the second floor. 4. The ground floor houses the loading facilities consisting of two load out ports from the bin to barrels, a roller conveyor loop, drum weighing scale, and change room facilities. Figure 4 shows the ground floor plan. Figure 5 is an elevation view of this section showing the overall equipment arrangement.

Jan 1, 1981

By J. W. Howland

To determine their effectiveness in different climate and soil conditions, a demonstration of dozer blades specifically designed for recontouring mine spoil was conducted at an East Texas surface coal mine. The specialized equipment included a 48-foot angle blade, a modified 24-foot "U" blade, a 13-foot deep "U" blade, and a 24-foot grading bar. Both the 4b-foot and the 24-foot "U" blades were mounted in a two-tractor, single-operator configuration. To meet flotation problems common in this mining region, a 22-foot lightweight blade was developed and demonstrated for use on a 400-430 hp tractor. The demonstration involved 1,185 acres and showed a 50% reduction in reclamation costs and a 47% reduction in fuel requirements for this mine site over conventional equipment. Improved equipment, trained operators, good supervision, and improved monitoring techniques contributed to the savings. Procedures and results of the demonstration are presented and analyzed here along with guidelines for application of findings.

Jan 1, 1981

By Daryl R. Tweeton

This Bureau of Mines publication provides information to assist in selecting a lixiviant (leach solution) for in situ uranium leaching. The cost, advantages, and disadvantages of lixiviants currently used and proposed are presented. Laboratory and field tests are described, and applications of geochemical models are discussed. Environmental, economic, and technical factors should all be considered. Satisfying environmental regulations on restoring groundwater quality is becoming an overriding factor, favoring sodium bicarbonate or dissolved carbon dioxide over ammonium carbonate. The cheapest lixiviant is dissolved carbon dioxide, but it is not effective in all deposits. Technical factors include clay swelling by sodium, acid consumption by calcite, and the low solubility of oxygen in shallow deposits. Laboratory leaching tests can provide useful data. However, they can be misleading if, for example, the ore is allowed to oxidize before testing or if distilled water instead of formation water is used for making solutions for permeability tests. Geochemical models presently are more useful for indicating trends in solubility than in reliably predicting concentrations.

Jan 1, 1981

By Friedrich Steinhäusler

RADON SOURCES AND CONTROL MEASURES IN THE MINING ENVIRONMENT Most of the contamination of the mine atmosphere by radon 222 is due to radon emanating from solid or fractured ore surfaces of walls, roof and floor. Also radon gas emanates from broken ore either from storage in backfilled mined-out areas as applied in e.g. shrinkage stopping methods or from ore spillage along intake airways mainly due to the use of trackless haulage. To a lesser extent water itself can represent an additional source of radon, which emanates into air from open drainage ditches or seepages along intake airways. The contribution from water can be controlled effectively by isolating the water from the primary intake air system, e.g. by diverting the water through pipes and/or sealing of seepages by grouting. However, control of radon emanating from rock surfaces creates a major technical problem with significant impact on the economic aspects of mining operations, if adequate radiological conditions must be maintained. Basically this can be achieved by suppressing the emanation process itself, confining already emanated radon or by removal of radon from the mine atmosphere. Extensive research has been carried out on the rate of radon emanation as a function of barometric pressure changes (Pohl-Rüling and Pohl, 1969). It could be shown that the radon supply consists of a permanent and variable component. The former results from the surface of the rock and depends mainly on the emanating fraction of its radium 226 content; the latter originates from within the rocks and is a function of the suction effect of decreasing barometric pressure, rock porosity and fissures. The practical application of this barometric pump effect for depressing the rate of radon emanation, e.g. by pressurizing the mine atmosphere, is limited due to high costs for providing a sink for absorption of radon and air as well as lack of permeability in most uranium ore bodies (Schroeder et al., 1966). Mine air cleaning by removal of radon can be achieved with the use of cryogenic methods, chemical removal, adsorption into charcoal beds, use of a gas centrifuge or general ventilation techniques. Technical problems have so far prevented the application of any of these methods other than ventilation. It is common practice to use the age-of-air concept, i.e. fresh air is delivered to the worker as directly as possible and removed quickly afterwards thereby maintaining the air "young". Engineering principles for quantity distribution of air through underground working areas are straightforward for general mining situations where radon constitutes an environmental contamination problem. However, in cases of high uranium ore content this concept may result in high costs with regard to installation and energy requirements for effecting both frequent air changes as well as sufficient heating of the air in cold seasons. Taking into account that the investment in ventilation systems is a major cofactor for the overall ore production costs this can be a limiting and decisive component in the assessment of the economic feasibility of specific mining operations and mineral reserves in general. Effective control of the radon flux from the rock surface prevents the initial contamination of the mine air with radon directly at the source. A radon diffusion barrier for practical application in mining requirements should fulfill the following requirements: - reduction of radon emanation rate by at least an order of magnitude - high mechanical strength - ease of sealant application onto surface to be coated - water resistant - low fire hazard - resistant to temperature changes encountered in mines - high cost efficiency in relation to exposure reduction achieved (direct and indirect costs) - low degree of maintenance. In the past several materials have been tested as sealants for controlling the emanation of radon from surfaces of rock and building materials. Epoxy paints reduce radon emanation rate only by a factor of 2 to 6 (Auxier et al., 1974; Eichholz et al., 1980; Keith Consulting Engineers, 1980). Although it is possible to prevent the escape of more than 99 % of the radon to the environment with gel seals over 80 mm thick (Bedrosian et al., 1974), practical applicability is very limited. Multilayer coatings of epoxy resins with various additives require meticulous preparation and flawless application of seamless four-layer coatings in four days to impede radon diffusion (Culot et al., 1976), otherwise results from this method have not been totally satisfactory (Leung, 1978). Aluminium foil laminated with polyethylene and paper on each side is under test as radon barrier but results are not available yet (Ericson, 1980). However, this method has the inherent disadvantage that possible malfunctioning electrical installations can cause fire or electrical shock through the sealant. Polyurethane foam coatings have been used on stoppings as very effective sealants. It does, however, represent a potential danger of spontaneous ignition and it is expensive (Rock, 1975). Thus, there is still need for a material which has similar properties as outlined above. In the following results are reported from investigations on the suitability of various materials as radon diffusion barriers.

Jan 1, 1981

The diverse nature of inadvertent mine fires does not lend them to general treatment. But evolving from the unfortunate fires over past years is a simple principle in dealing with all fires to bring combustion under control. Control, in brief, means that the products of combustion, themselves possibly still with fuel values, are not revitalised by addition of fresh air. There are problems with fire- fighting, especially with water, as this may lead to production of CO and H2. Panel ventilation upstream of the fire must be controlled to direct all air over the fire. Some advantages in fire fighting are found by the use of "sails". Early diagnosis of fires and early treatment are essential for safety of personnel and safeguarding and recovery of property. Preparedness extends to up to date documentation, but first hand knowledge also is invaluable to the diverse personnel gathered to fight a fire, and in the decision making Involved.

Jan 1, 1981