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By J. A. Herbst

Grinding circuits employed in mineral processing operations are designed to produce feed materials for beneficiation steps such as flotation and magnetic separation, which are sufficiently fine to achieve good liberation of valuable minerals from gangue without over- grinding. In many respects, grinding is the most important unit operation in a mineral processing plant. If adequate liberation is not achieved during grinding, subsequent separation steps will yield low metallurgical recoveries and/or product grades. Grinding energy requirements and operating costs typically exceed 50% of the total expenditures of the entire plant. Because grinding is an inherently energy intensive process and grinding circuit capital and operating costs are high, it is essential that such circuits be run as efficiently as possible. In- creased efficiency in grinding usually translates to a decrease in the energy required to produce a metric ton (short ton) of product size material. It is generally accepted in the mineral industry that efficient grinding circuit performance can not be achieved without the use of some form of automatic control. This is true because all circuits are subject to random disturbances which, if left unchecked, will upset circuit performance and rob a plant of productivity. Such disturbances arise from a variety of sources including natural variations in ore characteristics (particularly hardness changes), uncontrolled water additions, feed-rate upsets, changes in crusher performance, and mechanical upsets such as blockages in pumps and classifiers. Many of these disturbances occur with a frequency which is too high for an operator to detect and react to efficiently. Disturbances which occur on a time scale of several minutes up to several hours can be effectively dealt with using automatic control.

Jan 1, 1979

I wish that in addition to being a Pro- fessional Engineer I was also a communications expert. My principal task this morning, and yours after this meeting, is to convince a wide variety of individuals that steel industry slags are a high quality material that can be used for many purposes; and that their use can significantly alleviate some of the problems facing engineers, public officials, and the general public in our countries. By actual in- place performance over a long period of time steel industry blast furnace slags have proven that they are as good as the best natural aggregates, and better than some, for any type of construction or purpose for which natural aggregates are used. Steel furnace slags have many unique favorable characteristics and prop- erties when compared to other types of aggre- gate even though they cannot be used for all types of construction. We have the facts, all we have to do is present them to the right people in the proper manner.

Jan 1, 1979

By Alan C. Noble

INTRODUCTION Forecasting of metal and mineral prices is a complex and hazardous undertaking. In order to accurately forecast prices, the complexities of both marketing and production must be modeled for each commodity. Even with the most detailed model, the economy may change unexpectedly, invalidating the forecast. Because of these factors, this chapter will not attempt to present specific methods for price estimation. It will, however, review the fundamentals of price forecasting as applied to planning and design of the final pit shell. Recognizing that no price estimate can be exact, sensitivity analysis will be reviewed as an approach to coping with these unknown variations.

Jan 1, 1979

By G. A. Kordosky

The control of pH in solvent extraction circuits is an old technique (1,2) but one which has a large potential for future use. The equilibrium position of any reaction which has hydrogen or hydroxide ions, either as products or as reactants, can be controlled by pH adjustment. Several examples of reaction types which are important in solvent extraction systems and which also show a pH dependence are shown in Figure 1. The examples were chosen to show the wide variety of reactions which fit the above criteria, but it is not meant to be a complete listing of all the possible reaction types, Some of the reactions are presented in a simplified form. It is the intent of this paper to discuss pH controlled solvent extraction reactions for some relatively simple systems through more complex ones.

Jan 1, 1979

By I. Iwasaki

In the flotation of iron ores and nonmetallic ores desliming is the key to a successful operation; the technology of flotation of well-deslimed ores has become fairly well established. When finely disseminated ores are ground to liberation, however, conventional desliming of the fully dispersed pulp results in an excessive loss of valuable constituents. Selective flocculation of iron oxides followed by removal of dispersed siliceous slimes is a new development and is one of the most promising approaches to the treatment of finely disseminated, oxidized iron ores, available in vast quantities both here and abroad (1,2,3). To apply selective flocculation to the variety of refractory iron ores or to cope with the fluctuations in an individual ore and the make-up water, the factors governing this technique must be clearly formulated. For the removal of siliceous and clayey slimes from oxidized iron ores by selective flocculation, the optimum conditions are extremely sensitive to the mineralogical characteristics of the ore, the type and the amount of soluble salts in pulp solutions, and the mesh-of-grind. Certain starches appear to function better than others (4, 5). Selection of the proper reagents and their judicious use is important not only for their efficient utilization but also for minimizing the adverse effects they might exert on the flocculation and flotation steps, and the pollution the effluents might cause when discharged, either intentionally or accidentally, into lakes and streams. In the present article some of the major factors that influence the selective flocculation of iron ores are summarized.

Jan 1, 1979

By John W. Harshbarger

The Upper Santa Cruz Groundwater Basin lies in the drainage area of the Santa Cruz River in Arizona, and extends upstream from the community of Rillito to the international boundary, see Figure 1. The principal water use area lies between and includes the cities of Tucson and Nogales. A subsurface geologic barrier near Rillito provides a reasonable dividing line between the groundwaters of the Upper and Lower Santa Cruz Basins. The Upper Basin contains the Tucson and Sahuarita-Continental critical ground- water areas. The Tucson Water Use Area encompasses the Tucson metropolitan area and extends from the northern boundary of the Basin south to the boundary between the Tucson and Sahuarita- Continental critical groundwater areas near San Xavier. The San Xavier Use Area is the San Xavier Indian Reservation. The north and south boundaries of the Continental Use Area coincide with the limits of the Sahuarita-Continental critical groundwater area. The first study of groundwater in this valley was initiated by Dr. G. E. P. Smith in 1905 and the results were published in 1910, followed by a series of bulletins of the Arizona Agricultural Experiment Station, University of Arizona, covering the general field of groundwater development and utilization. Beginning in 1939, the Ground Water Branch of the United States Geologic Survey, in cooperation with the Arizona State Land Department and the Arizona Water Commission (AWC), have published a series of bulletins concerning groundwater occurrence and utilization in various areas of the state. In 1975 and 1977, the AWC published the "Arizona State Water Plan" (1), comprising a detailed inventory of water availability and use in the State of Arizona, and a study of alternative futures.

Jan 1, 1979

"2.1. General Considerations and Properties2.1.1. IntroductionOur present knowledge of the platinum-group elements (POE) is extensive, the reason being two-fold. The elements have many uses and, moreover, they exhibit extremely varied chemical behaviour, depending on their state of oxidation and chemical environment. The present chapter reviews a selected body of material which is of particular relevance to mineralogy and geochemistry.Comprehensive treatises on the POE include those by Mellor (1956-1957), Gmelin (1938-1957) and Pascal (1958). The inorganic chemistry, particularly coordination chemistry, has been dealt with in works by Griffith (1967), Hartley (1973) and Livingstone (1975), and the analytical chemistry by Walsh and Hausman (1963), Beamish (1966) and Beamish and Van Loon (1972, 1977). Darling (1973) and Savitsky (1978) have reviewed the metallurgical properties and applications of the metals. Goldberg and Helper (1968) have reviewed the thermochemistry and oxidation potentials of POE systems, and Wagman et at. (1969) have also provided selected values of their thermodynamic properties. The geochemistry of the POE has been reviewed by Yushko-Zakharova et at. (1967), Cousins (1973), Cabri (1974), and Naldrett and Duke (1980).Platinum was used briefly as a coinage metal in ImperialRussia. Otherwise, the principal early use for platinum and its alloys was in the fabrication of chemically resistant apparatus. Subsequently, a large part of platinum production was utilized for catalysts in the sulphuric acid and ammonia industries. Platinum has been replaced by vanadium pentoxide in the manufacture of sulphuric acid, but, in recent times, catalytic upgrading of petroleum and emission control systems for automobiles have opened further huge markets for the metal. All of the POE find uses either as reagents or catalysts in the synthesis of organic compounds, e.g., in the Wacker process, which uses palladium chloride to catalyze the production of acetaldehyde from ethylene. There are, of course, a large number of specialized uses for the elements, particularly in alloys, temperature measurement devices, cancer therapy and so on."

Jan 1, 1979

By Walter Nummela

INTRODUCTION By the end of 1979 pellet productive capacity from the processing of low grade iron ores in the Lake Superior-District will total 86 million tons per year. Of that tonnage, 72 million result from the processing of magnetic ores such as taconite, about 6 million tons from the flotation processing of relatively coarse grained specular hematite, and 8 million tons from the processing of fine grained non- magnetic ores at Tilden. The Tilden flowsheet represents a break- through in the processing of this type of crude ore and hence is unique in the Lake Superior District (1). Operations at Tilden started in late 1974 with Algoma Steel, J&L Steel Corp., The Cleve- land-Cliffs Iron Company, The Steel Company of Canada, Ltd., Wheeling- Pittsburgh Steel Corp., and Sharon Steel Corp. as participants. Cleveland-Cliffs operates and manages the operation. Other companies have conducted extensive pilot plant tests or are in commercial production in the processing of fine grained non-magnetic ore materials (2). Flowsheets and reagent schedules may be different for each particular application, but some of the problem areas in the processing of Tilden ores have also been experienced at operations such as the IOC Plant at Sept-Isles, at Lamco and at Bong in Liberia, and in pilot testing of Fabrica ores of Ferteco Mineracao in Brazil. With a grind of about 80-85% -500 mesh resulting in 50% of the particles in the concentrate being less than 15 microns, a discussion of the pro- cessing of Tilden type ores fits the topic of this workshop. There are very large tonnages of fine grained non-magnetic crude ores which exist throughout the Lake Superior District and other iron ore producing regions. These fine grained non-magnetic materials constitute an important source of iron minerals. Before going into specifics of the flowsheet, it is important to

Jan 1, 1979

By F. L. Wilke

Bong Mining Co. Ltd. in Liberia, West Africa, operates an iron ore open pit some 60 miles northeast of Monrovia. The production is at present about 40,000 t/d (metric tons/day) from which about 18,500 t/d concentrate with 65.5% Fe is produced. The ore waste ratio is about 1: 1.5 to 1:2. The technical layout and the equipment are very similar to those in many modern open-pit operations as described by Jacobs and Thomson (1967). As described by Lersch in detail (1966), the deposit is a very irregular one. The quality of the ore changes within very short distances with regard to both physical conditions (hardness) and chemical properties. Very soft and very hard ore as well as high-grade and low-grade ore are found adjacent to each other. In addition, there are enclosures of sterile rocks. For the purpose of identification and production scheduling, 12 different types of ore are distinguished.

Jan 1, 1979

By David R. Flinn

This Bureau of Mines report describes methods to electrodeposit erosion-resistant titanium diboride coatings from molten alkali metal borate baths at 900° C. These coatings have been shown to be highly resistant to material loss during impingement with high-velocity alumina and silicon carbide powders, and they show promise as protective coatings to reduce metal loss in erosive chemical environments, such as coal gasification systems. The most erosion-resistant coatings were prepared on nickel, Inconel, and molybdenum from an electrolyte containing LiBO2, NaBO2, Na2Ti03, and TiO2. The best coatings were deposited at current densities of [~]20 ma/cm2, using titanium or titanium diboride anodes. Erosion-resistant coatings were shown to exhibit (1) a high degree of crystallographic orientation along the (100) or (110) planes, (2) a chromium impurity level of less than 3 pct, and (3) a uniform, smooth, consolidated surface appearance when viewed under a microscope or by scanning electron microscopy. Optical spectroscopic studies of the molten electrolyte suggest that the lower valent (+3) titanium ion predominates in the baths.

Jan 1, 1979

By Jan M. Mutmansky

While production scheduling for both surface and underground mining operations is similar in nature, a rather large array of techniques is applied in solving such planning problems. The techniques consist of both rigid operations research (OR) methods and practical procedures which are not mathematically based. In the following sections, a short summary of some of the techniques that are applicable to production scheduling problems in mineral operations is presented. The techniques discussed are: linear programming, integer programming, dynamic programming, graph and network theory, simulation, and heuristic methods. For an in-depth comprehension of these techniques, the reader is referred to any of the available textbooks on these subjects. One or more references will be listed for each topic to provide a starting point.

Jan 1, 1979

By Walter P. Hansen

Belt conveyors offer a reliable means and often do the most economical job for providing continuous bulk material transport, whenever the terrain permits their installation. The ore processing, construction and mining industries use belt conveyors to carry all types of material, from small to large tonnages. Most of the conveyors Fluor Mining & Metals, Inc. designs for metallurgical plants are in the in-plant category, of limited length and medium tonnages, and use fabric carcass conveyor belting. Belt widths can range from 24 to 60 inches Generally, the layout and design of these belt conveyors present no unusual problems. However, calculations for belt tension and horsepower, design of materials transfers, and the sizings and layouts of belt pulley stations and their drives are time consuming.

Jan 1, 1979

By R. C. Fox

The geophysical aspect of reconnaissance marks the beginning of extensive computer applications supporting development of a mine. Although there are some storage and retrieval applications in geology, and some statistical analysis in geochemistry, large-scale compilation, reduction, and interpretation of mineral resource data are initiated in reconnaissance geophysics. The reasons for this fact are quite simple. Geophysics is oriented toward quantitative evaluation of areas of interest, and methods of data collection are automated to the extent that large amounts of analog and digital information are recorded. The large volume of data must be interpreted in a reasonable time. Furthermore, some modeling problems involving complex numerical solutions could not be attempted without the computer. Therefore, the computer is essential to the success of an exploration project using geophysics. For example, aeromagnetics is a common technique for reconnaissance examination of areas associated with sulfide systems and porphyry deposits. An area covering 161 X 161 km (100 X 100 miles) may be flown with a 1.6-km (1-mile) line spacing yielding 10,000 line miles (16,093 km) of data. If only 10 measurements are recorded per mile, 100,000 data points, including location and magnetic field intensity, must be reduced and stored for quantitative interpretation. Computer applications often represent a significant investment in manpower and hardware. It is desirable, therefore, to initiate an engineering approach to the application of computers to geophysics. By this it is meant that computer programs and systems should be formulated, developed, and implemented in a disciplined manner such that their usage is dependent only on the application and not on the individual doing the programming. In other words, computer application, development, and usage should evolve beyond the personal gadget phase to an important applied technology. Geophysics has evolved over the past two decades in a course parallel to computer hardware development. During the sixties, the computer became large enough and fast enough that complex models required by geophysics could be solved. Automation also relieved the geophysicist from routine manual calculations. During the seventies, computing power in¬creased and applications expanded from two-dimensional problems to three-dimensional modeling. Moving into the eighties, as computer hardware costs will significantly decrease, the major expense of computing will be the manpower required to develop, implement, and use an application; therefore, improved programming techniques and applications software engineering methods will be used to optimize and preserve this investment. This chapter presents a general overview of computer methods in geophysical reconnaissance; it is divided into two parts: geophysical methodology and software engineering.

Jan 1, 1979

By W. R. McDonald

The U.S. Department of the Interior, Bureau of Mines, conducted field tests on acidic copper tailing as part of its program to devise, improve, and demonstrate technology for stabilizing mining and mineral processing wastes. Results will be presented from successful 1/8-acre and 1-1/2-acre demonstration revegetation plots established in 1973 and 1974 on an abandoned copper tailing pond located on public land adjacent to Holden Village, Wash. The tailing was neutralized with treatments of either dolomitic lime or limerock and fertilized with processed sewage sludge and/or commercial fertilizer. Plant growth covering 60 percent of the surface was achieved on both test plots. Regar brome, Tegmar intermediate wheatgrass, and tall wheatgrass provided the best plant growth and surface coverage. In neutralizing the tailing, the target pH of 6.8 was not achieved; however, good plant growth occurred in areas where the pH ranged from 2.9 to 5.8.

Jan 1, 1979

By H. -F. Krausse

Roof failures in underground coal mines are related to the lithology and geologic structure of the roof. There are two distinct suites of roof rock above the Herrin (No. 6) Coal in Illinois, and each has distinctive patterns of structure and roof failure. In black shale-limestone roof areas, roof instability is correlated with thinning of limestone beds and presence of faults and clay dikes. In gray shale roof regions, the prime roof hazards are posed by rolls, shear bodies, and presence of coal or carbonaceous partings in the roof. Most structural features examined are believed to have formed during early stages of sediment diagenesis and compaction. Structural trends and lithologic patterns are strongly interdependent for this reason. In many cases geologic patterns are so complex and locally variable that prediction of roof stability far in advance of mining is difficult. The need for greater flexibility in roof control planning is apparent.

Jan 1, 1979

By Ernest B. Snyder

The word "line" has been used loosely for many forms of the common steel plant flux. For example, many people use the word "lime" for nigh calcium and dolomitic limestone, for high calcium and dolomitic quicklime (also called caustic lime, calcined lime; burnt lime, pulverized and pebble lime) and ;van for clinkered dolomite. Calcium hydroxide, also called slaked lime and hydrated lime, is called "lime" but is seldom used as a flux except when the quicklime air slakes in open boxes or bins. All of the above forms of "lime" are used in the steel plant. Calcium hydroxide is used for water treatment, acid neutralizing, and as a lubricant for wire drawing. All the other limes are used as fluxes in the sintering plant, blast furnace or steel producing furnaces. In the production of self-flux or super-flux sinter, high calcium and dolomitic limestone fines are used. Where quicklime fines are available, they may be added to the sinter mix also. The blast furnace uses both high calcium and/or dolomitic limestone. A few trials have been made using iron oxide stabilized dolomitic lime in an attempt to reduce coke consumption and to increase the production rate. The trials were very successful but would' not be economical, except in periods of coke shortages, with resulting extremely high coke cost and exceptionally high hot metal demand.

Jan 1, 1979

By Frits Agterberg

Statistical exploration uses statistical methods to identify targets for more detailed investigation by estimating the odds of occurrence of mineral deposits. The study area which contains the possible targets may be as large as 1 000 000 km2 or as small as 100 km2. Results are presented in terms of a probability index for the existence of a deposit or, more precisely, in terms of expected dollar value for a unit area, or even in terms of number, size, and grade of deposits remaining to be discovered. Typically, selected geological, geophysical, or geochemical information is systematically quantified and statistically analyzed by using the computer in order to distinguish between geological environments on the basis of the probability that they contain undiscovered deposits of a specific type. All possible targets are compared with one another by using information on areas known to contain deposits. The information on the known areas is either a set of control data consisting of values for the same parameters as are quantified for the entire study area, or it embodies a specific model for the occurrence of a given deposit type. Examples of both procedures will be discussed in this chapter.

Jan 1, 1979

By George N. Aul

This report describes a method developed by the Bureau of Mines for sealing horizontal degasification holes so that they do not create a gas explosion hazard when intercepted by mining. A cement slurry is pumped into the hole through an injection pipe that extends to the back of the hole. Pumping continues until the slurry returns through the annulus to the hole collar. The hole is then shut in and the grout allowed to harden. Application of the procedure to six horizontal degasification holes at Eastern Associated Coal Corp.'s Honey Run shaft is discussed.

Jan 1, 1979

By Douglas A. Sloan

Who would believe that young elementary school children could understand something as complex as the mining industry? THE CHALLENGE The challenge of accomplishing this is tremendous. An examination of Canadian school children indicated that they knew very little about the world of work in general, and hardly anything about the mineral resource industry in particular. It calls to mind the story about two youngsters who decided to play house. The little girl played her role well as she went about the house doing things she had watched her mother do every day. When it was the little boy's turn, he grabbed his lunch, waved goodbye to his "wife", jumped on his bicycle and pedalled furiously down to the end of the driveway -- where he stopped. The youngster explained that he saw his dad go out of the driveway each morning, but he didn't know where he went, or what he did on the job. When you stop to consider the number of families today with two working parents, you can begin to appreciate the importance of the opportunities for role identity provided by this project.

Jan 1, 1979

By R. P. Beyer

[The Bureau of Mines has measured the low-temperature heat capacities and high-temperature enthalpies of crystalline K2Si2O5 as part of a program for advancing mineral resources technology with energy economy. High-temperature enthalpies of glassy and liquid K2Si2O5 and crystalline K2SiO3 were also mea¬sured. An adiabatic calorimeter operating over the range 5 to 308 K was used for the heat capacity measurements for K2Si2O5 from which the standard entropy at 298.15 K, S°298 = 45.55 ±0.05 cal/deg-mole, was calculated. Tabulated values of Cp°, S°, -(G° -HO°)/T, and H°-HO° from 5 to 300 K are given for K2Si2O5. A copper-block drop calorimeter was used in the enthalpy measurements, operating from 298.15 to 1,198 K for K2SiO3 and from 298.15 to 1,453.8 K for K2Si2O5. No transitions were found for K2SiO3. The KI2Si2O5 showed two reversible first order transitions, one at 510 K with a heat of transition of 0.29 kcal/mole and one at 867 K with a heat of transition of 0.38 kcal/mole. The heat of fusion for K2Si2O5 20 5 was calculated to be 8.42 kcal/mole. Relative enthalpies are given in equation form, and high-temperature values are tabulated for Cp°, S°, - (G°-H°298 )/T, and H°-H°298 . Also tabulated are ?H°, ?G°, and log K for formation of K2SiO3 and K2Si2O5 from both the elements and the oxides.]

Jan 1, 1979