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By R. F. Waters

The Bureau of Mines developed laboratory-scale processes to recover sodium phosphates and metal values from waste sludges generated by the phosphate treatment of automobile and appliance components. After treatment of the sludge with NaOH, followed by coke or hydrogen reduction and sintering, zinc and lead were recovered as fume; the sinter was separated by leaching into a metallic product, chiefly iron and nickel, and high-purity disodium or trisodium phosphate.

Jan 1, 1971

By Robert S. Shoemaker

The development of a metallurgical project is a business venture rather than a technical exercise, and its real objective is to obtain the maximum return on investment consistent with the limitations imposed by company policy and the requirements of society. Demand for profits is the driving force for technical advances and naturally leads to improvements in processes, equipment and plant designs. In the mineral dressing field there have been virtually no new processes developed since the introduction of flotation, and the steady erosion of profits by inflation has been offset only by increasing equipment size. Unfortunately, in recent years, plant designers have not always utilized the largest equipment or the opportunities for functional and economic design presented by the development of larger equipment. Lower cost plants can be developed providing that unrealistic restraints arising from the prejudice of past practices are avoided. As an illustration of this premise, three different approaches were taken toward the design of a clearly delineated but hypothetical copper concentrator of 20, 000 tons per day capacity. While the same flowsheet was used in each case, designs were produced for a conventional plant, an alternate using the largest available equipment, and a third scheme utilizing large equipment and the most functional design which could be developed, including features derived from many plants in many different industries. Capital costs were developed for the three separate designs based on a location in the southwestern United States. Ancillary facilities were identical in each case and included a mine truck shop, a maintenance shop, a general office, and a nominal starter dam for tailings disposal within 5000 feet of the plant. Water supply within 1000 feet of the plant, and power furnished to the property boundary has been assumed in each case. The flowsheet of the three plants is shown in Figure 1 and represents the treatment of a typical sulfide copper ore by three- stage crushing followed by single-stage ball milling. Concentration is by flotation roughing and scavenging followed by regrinding of the concentrates and two stages of cleaning.

Jan 1, 1971

By H. A. Dierks

The work and costs involved in controlling three large fires in abandoned mines in the anthracite region of Pennsylvania are presented in detail. The work was done under authority of Public Law 89-4. Three basic control techniques were successfully employed by the Bureau of Mines: (1) forming underground fire-containing barriers by systematically flushing incombustible material into mine voids, (2) excavating an isolation trench around the fire area, and (3) complete excavation of hot and burning material in the fire area. When methods 2 and 3 were used, the excavations were subsequently back- filled with incombustible material. Preliminary location of fire perimeters by the standard use of patterned 6- and 8-inch-diameter boreholes is discussed. Investigations into air-borne infrared scanning, shallow subsurface thermal anomalies, and the use of helium to trace the movement of mine air currents are covered. Although they are costly and time consuming, boreholes have proven to be the most efficient means to date of obtaining necessary subsurface fire data. Infrared scanning was ineffective in delineating fires under more than 30 feet of cover. Helium-tracing was shown to have a good potential for determining possible hazards to adjacent residential areas from traveling mine fire gases.

Jan 1, 1971

A digital computer program has been developed to mathematically simulate the effect of limited changes in feed rate on the grinding circuit of an operating mill. The data on which the program is based was supplied by the staff of the mill in question. Samples taken around the complete grinding circuit were analyzed for solids content and particle size distribution for two feed rates. Matrix models were used to represent the grinding units: rod mill and pebble mills. Parameters for these models were computed using a method developed by Mular(l). Classifier parameters were computed by the Powell search method(2) for the Plitt model (3) . The simulation program, which permits the computing of the size distributions in the circuit resulting from the changes in feed rate between the two measured values, assumes that a linear relationship exists between the corresponding parameter coefficients. The program uses an iteration method to bring the simulated grinding circuit to a steady-state material balance for any specified' feed rate between those measured. The program is, in addition, extremely fast and economic in computing time. The results show that the simulations are not everywhere consistent with practice. For example, higher feed rates on simulation predict finer products. These errors are shown to be attributable to anomalies in data gathering techniques. An improved sampling procedure for grinding-circuit data gathering is suggested for future simulations of this type. It is concluded that the

Jan 1, 1971

By A. Sobering, G. N. Carlson

"This paper describes the conversion of the grinding section of the W a bush Mines pelletizing plant from conventional wet, open-circuit trunnion overflow ball milling, with filtering, and bentonite mixing on a common conveyor belt, to dry, open-circuit, grate discharge grinding, with pug mill mixing of bentonite and water at individual mills.The test work and data on operating economies to justify the cost of conversion are given. It is too early, at the time of writing, to have complete operating confirmation, but data are available. A brief description of the original plant is included."

Jan 1, 1971

By H. E. Blake

An evaluation was made to determine the economics of utilizing waste fluosilicic acid for production of (1) calcium fluoride, and (2) anhydrous hydro-gen fluoride. Two versions of each process were considered and compared. The evaluation showed that both products could be produced and marketed competitively. Lowest estimated product sales prices required to yield a 25-percent return on investment before taxes (discounted cash flow basis) was $339.34 per ton of hydrogen fluoride and $48.64 per ton of calcium fluoride.

Jan 1, 1971

By D. S. Flett, A. W. Fletcher

Equilibrium studies on the extraction of nickel and cobalt with kerosine solutions of naphthenic acid have shown that an exchange extraction reaction occurs at pH 5.5. The nickel/cobalt separation factor is constant at 1.8 for constant total metal molarity and varying nickel/cobalt ratios. The separation factor decreases with increasing total metal molarity in the organic phase beyond 0.2 M and also decreases with increasing temperature. From the equilibrium data, it has been possible to derive a mathematical model for the separation of nickel from cobalt by exchange extraction in multistage systems. Experimental data from a continuously operated multistage mixer/settler apparatus has shown a reasonable correspondence with computer-calculated data. The effective separation of nickel and cobalt in sulfate solution remains a problem in hydrometallurgy and the hope that this would be solved by solvent extraction has not yet been fulfilled. With chloride solutions, advantage may be taken of the ability of cobalt to form anionic complexes with the chloride ion. It can then be readily separated from nickel, which does not form stable chloro complexes, by extraction with a suitable long chain amine. However, in hydro metallurgical operations, sulfate solutions are generally obtained in which no extractable anionic species are present. Thus, the possibility of using cationic extractants must be considered, and in this paper attention is directed to the use of carboxylic acids. The method of separation studied has been termed exchange extraction, which involves replacement of a metal in the organic phase with a more acidic metal in the aqueous phase. Thus, (BR2).+ (Az+)aqt=(AR,).+ (B2+)aq (I) where metal A is more acidic than metal B, R represents the acidic radical derived from the acid RH, and the subscripts e and aq refer to the organic and aqueous phases, respectively. Ashbrook and Ritcey' have used this method for the separation of cobalt from nickel using the sodium salt of di-2 ethyl hexyl phosphoric acid, which preferentially extracts cobalt. Some nickel is coextracted, and this is removed by exchange with cobalt ions in the feed solution by suitable countercurrent operation in a pulsed column. Much work has been carried out by a number of workers in Russia on the general use of exchange extraction for the separation of metal ions using car-boxylic acids. Gindin et aL a have demonstrated that this technique could be applied to the separation of nickel from cobalt using a C--C. carboxylic acid and have applied the technique to the production of high purity cobalt solutions for electrolysis. Further worka was concerned with the development of a process for the separation of nickel from cobalt in a pulsed column. This system permitted the separation of iron and copper from nickel and cobalt in one system. The procedure involved center feeding with acid backwashing at the top and alkali addition lower down the column. Thus the system operated under a pH gradient and the metals were distributed in the column in the order of their basicities. A similar application was studied by Gel'perin et al,4,5 for the removal of copper and iron impurities from a nickel anolyte by means of a C10-C,12 fatty acid fraction. Ginden et al,' and Fletcher and Wilson' have studied the effect of pH on the extraction of a number of metals with carboxylic acids. These studies showed that metals such as iron, copper, lead, zinc, nickel cobalt, and manganese are extracted at pH values close to the pH of hydroxide precipitation. Nickel is extracted at a slightly lower pH than cobalt and thus the nickel/cobalt separation factor has a value not much greater than 1. More basic work on complex identification has been reported by Fletcher and Flett: by Tanaka; and Jay-cock and Jones." These studies have suggested that at low loadings in the organic phase, the nickel and cobalt carboxylates appear to be dimeric and solvated by free carboxylic acid molecules. As the concentration of metal in the organic phase increases, the complex changes and larger polymeric species are formed. In order to permit assessment of the potential of carboxylic acids as extraction reagents for separation of

Jan 1, 1971

By Hulbert A. Lee

"A REVIEW OF MINERAL DISCOVERIES IN CANADA, and in particular the Canadian Shield, using the physical aspects of overburden reveals a trend in the art of exploration. At an early time of exploration (1847-1954), float and heavy clasts were used successfully to find ore deposits with little knowledge of Quaternary environments. At a later time (1955 to present) , use of Quaternary rock-units for sampling have made possible tracing indicator trains of float, heavy clasts and other ore-type clasts to the source bedrock. The basal till of retreat ice is now recognized as a1l favourable sampling environment and as such has been used to successfully discover hidden orebodies. The esker massive gravel is beginning to be recognized as a favourable environment and use of it has met with technical success. An understanding of those changes that have taken place during the transportation of the material and after its deposition is essential to proper sampling and treatment of the samples from the basal till and the esker massive gravel. Use of float and heavy clasts in search of orebodies is continuing in present-day exploration on the Shield. Lessons learned from it are being incorporated into exploration using favourable Quaternary rock-units for sampling. Hence, both subjects have a need for review and are discussed in this paper."

Jan 1, 1971

By M. C. Fuerstenau

Each year during the AIME Annual Meeting, the MBD Division has its Business Meeting. Because many members cannot attend, it has be- come policy for the secretary of the Division to present highlights of the business conducted at the Meeting in Fine Grind. This year the Meeting was held on March 1 in the Americana Hotel. Five major items of business were brought up for discussion. These were: (1) the proposed name change for the Division, (2) institution of the Taggart Award, (3) a name change for a Unit Committee, (4) MBD funding of scholarships, and (5) authorship of Fine Grind articles. The Matter of What We Should Call Ourselves A lively discussion was held on the issue of a name change for the Division. Two names have been proposed: (1) Mineral Processing Division, and (2) Mineral Engineering Division. A number of strong reasons for changing the name from Minerals Beneficiation Division have been pointed out. Perhaps the most important of these is that the term "beneficiation" does not describe all of the functions that engineers in our Division perform. Further, there are inherent problems associated in the term, in that beneficiation is a long word which has the twofold disadvantage of being both difficult to pronounce and difficult to spell.

Jan 1, 1971

By Thys B. Johnson

A three-dimensional dynamic programing method is presented for determining the optimal ultimate open pit limit. The method given is based on the block concept and is an extention of the two-dimensional Lerchs-Grossmann approach. The three-dimensional technique presented herein is fast and simple and may be used for an initial open pit evaluation when only limited data are available or as a more refined model when the entire deposit is well delineated. The method is illustrated by simple numerical examples and is also presented in algorithmic form. A computer program was written in Fortran IV which implements the three-dimensional algorithm and some computational aspects are discussed.

Jan 1, 1971

[Adams, Dell H Consolidation Coal Co., 3300 One Oliver Plaza, Pittsburgh, Pa. Adams, Douglas K General Electric Co., P.O. Box 2331, Denver 1, Colo. Adams, Kenneth L Peabody Coal Co., 33 Carnation Dr., Belleville, Ill. Ahlborg, William Joy Mfg. Co., 580 Denver Club, Bldg., Denver, Colorado Albrechtsen, Ray H Mt. States Resources Corp., 2330 S. Main, Salt Lake City, Utah Allen, Dr. Harry C U. S. Bureau of Mines, Washington, D. C. 20242 Amerman, Richard W Utah Cons. & Mining Co., Box 155, Fruitland, New Mexico Anderson, G. A Walker Bank & Trust Co., 848 N 3rd E, Price, Utah Anderson, John S. Utah Cons. & Mining Co., 550 California St., San Francisco, Calif. Anderson, Robert Mine Safety Appliances Co., 1881 West N. Temple, Salt Lake City, Utah]

Jan 1, 1971

By Norbert R. Morgenstern

INTRODUCTION An understanding of the role of water in controlling the stability of rock masses is central for a rational approach to the subject. The presence of water can hinder mining opera- tions in two ways: 1. excessive discharge 2. excessive pressure It should be noted that if the rock mass is very tight, excessive pressures can exist without large discharges. Alternatively, if abundant water is available and the rock mass is open, then substantial discharges can occur under quite small pressures. The problems associated with excessive discharge are usually well understood by the mining engineer. Vehicle mobility is inhibited, some areas are flooded and hence become inaccessible; at best, a costly nuisance exists. The methods of solving these problems are also well-known to mining engineers. They generally involve tapping the source of the excessive discharge and channeling it away in such a manner that any hindrance to the mining operation is minimized. The effects of water pressure on the stability of rock masses are less obvious and the following will be devoted solely to this aspect of the problem. The manner in which water pressures enter into the consideration of stability is made clear by an understanding of the concept of effective stress. THE CONCEPT OF EFFECTIVE STRESS The simplest mechanical model for the problem of rock slope stability consists of a rough, rigid block sliding down an inclined plane under the influence of gravity. This is illustrated in [Fig. 1]. The down-slope component of the weight of the block tends to produce movement which is resisted by the shearing force generated by friction along the base of the block. The shear stress per unit area inducing movement is

Jan 1, 1971

By J. Grumer

Nine dust and gaseous inhibitors of propagating coal dust-air flames (lean, stoichiometric, and rich) were evaluated in a newly developed 15-cm-id, 3.6-meter-long instrumented flame duct, under conditions such that wall quenching was virtually absent and the dust concentration was temporally and spacially uniform to within about t5 percent. Listed roughly in order of increasing efficiency, the inhibitors evaluated were rock dust (calcium carbonate), powdered oyster shells (calcium carbonate), Halon 1301 (trifluorobromomethane), Halon 1211 (difluorochlorobromomethane), sodium chloride, Super-K (potassium chloride), regular-grade fire extinguishant powder (sodium bicarbonate), Purple-K (potassium bicarbonate), and Monnex (potassium bicarbonate combined with urea). Experiments were extended to clouds containing 1 and 2 volume-percent of methane. The inhibition of lean, stoichiometric, and rich methane-air flames without coal dust was also examined in a few instances; results agreed with those obtained for coal dust-air flames.

Jan 1, 1971

Previous methods for measuring the flow of solids in Jnrdraulic conveying have not considered the important effects of slip velocity and particle concentration. In this paper an extension of the method proposed byShirato et al. (J. Chem. Engng. 'Japan, 1: 164-167) for determining mass flow in a vertical conduit is outlined.The present method consists of measuring' the volumetric flow of the slurry (by a magnetic flow meter for instance) and the density of the slurry in two pipe sections of different diameters. Effects of variation of slip withparticle concentration, not previously considered, are allowed.Problems involved in estimating the density of a slurry from differential pressure measurement are discussed.The major problem is the uncertainties in estimating frictional losses due to the wall in two-phase flows. The greater reliability of a more "direct" technique, such as by 'Y-ray absorption, for measuring solid concentration is emphasized.

Jan 1, 1971

By Jacques B. Wertz

However excellent the geologic map of an area is, it can only show what is exposed on the ground. It cannot and should not generalize the information nor complete the picture by inference: this is left to the examiner. Consequently, it becomes justified for him to use all expressions of geologic structure in order to gain an additional dimension in geologic interpretation, and particularly so in mineral exploration. In previous studies related to Arizona, the known faults were the starting points and a host of interpolated, supporting geologic factors described in earlier publications ascertained the presence of a series of structural trends and lineaments found to be rather continuous and persistent, even though unsubstantiated by geologic maps. In present studies pertaining to the humid environment, with the same aim of seeking major structural trends and lineaments, the starting points are morphologic expressions such as straight lakes and straight segments of rivers, among others, because there generally is not enough geology available. An example is given herewith for an area that straddles the International Border, north of Spokane. In both semi-arid and humid environments, one observes that mineral deposits quite often occur close to the intersection of a major fracture or lineament with some secondary trend.

Jan 1, 1971

By J. M. Stuve

Calorimetric determinations of the low-temperature heat capacities, standard enthalpy of formation, and high-temperature enthalpies were made of (Na20)4 ?Fe20,(c). The resulting values of entropy (S°), enthalpy of formation (?Hf°), and free energy of formation (?Gf°) at 298.15° K are 104.676 cal/deg mole, -656.2 ±.kcal/mole, and -603.4 A kcal/mole, respectively. Tabulations of Cp°, S°, - (G°-H°298)/T, H°-H°298, ?Hf°, ?Gf°, and log Kf are given to 1,200° K.

Jan 1, 1971

By Joe B. Rosenbaum

New applications and concepts of solvent extraction as a unit operation in extractive metallurgy have been developed in the last decade. Wider use is being made of established solvent extraction techniques in processing spent nuclear fuel elements and in winning columbium-tantalum, hafnium-zirconium, thorium, tungsten, uranium, and vanadium. Commercial application has been extended to recovery of beryllium, boron, bromine, copper, molybdenum, phosphorus, rare-earth metals, and rhenium. Systems in use and proposed typically extract metals or salts as anion, cation, or neutral species from aqueous media by reaction with a recycleable organic reagent.

Jan 1, 1971

A process was developed, on a laboratory scale, for the removal of iron oxides from Weipa pisolitic bauxite. The technique involves the chemical reduction ofthe iron oxides by carbon, followed by selective removal of the iron species by acid leaching or chlorination.To remove more than 90 per cent of the iron it is necessary to reduce the iron oxides substantially to iron metal by heating the bauxite, pre-calcined at 650-800°C, with reactive carbon at 1040-1100°C. Reduction proceeds via the intermediate formation of hercynite (FeO.Al2O3) and difficulties have been encountered in reducing hercynite formed under less favourable reduction conditions.Following reduction, efficient selective removal of iron species is readily effected by acid leaching using dilute hydrochloric acid at 100°C, or chlorination at 500-750°C using Cl2, Cl2/N2, or Cl2/N2/CO mixtures.After removal of unreacted carbon, the final products contain 0·5-1.0 per cent Fe203 and 87-92 per cent Al203.

Jan 1, 1971

By M. M. Tilman

The Bureau of Mines conducted research into the dispersion strengthening of lead by the coprecipitation method. Commercially available reagents in water solutions were reacted to form homogeneous precipitates of lead and aluminum compounds. The resulting precipitates were roasted to oxides and reduced in hydrogen to form mixtures of lead powder and alumina. The powders were isostatically pressed into billets which were extruded into rods. The rods were rolled into strip to provide material for testing. Alloys containing 0.5, 1, 2, and 3 nominal volume-percent A1203 were tested in short-time tensile tests and in tensile creep tests. An alloy of Pb-3 volume-percent A1203 exhibited an average tensile strength of 8,570 psi after rolling to 75-percent reduction at 125° C but had no measurable elongation. Alloys of lower A1203 content provided a better compromise between tensile strength and ductility. For example, an alloy of Pb-0.5 volume-percent A1203 had an average tensile strength of 6,590 psi with 9-percent elongation after rolling to 75-percent reduction at 125° C. Creep rates of dispersion-strengthened Pb-A1203 alloys were below 1 percent in 10,000 hours at stresses of 2,000 to 4,000 psi.

Jan 1, 1971

Christmas Island "C"-grade phosphate consists essentially of the minerals crandallite and millisite. Although containing over 25% P205, this material is not suitable for the manufacture of water-soluble phosphate fertilizers by conventional processes, because of its high iron and aluminium content Cover 25% total R203). In order to produce a water-soluble fertilizer from such material it is necessary to separate the iron and aluminium from the phosphate, which must report in a product acceptable as a fertilizer. Several processes were studied in detail. The first used ion exchange for dissolution and separation and yielded diammonium phosphate; processing costs were high compared with conven- tional processes based on apatite. The latter processes have basically simple flowsheets and cost of processing is low when compared with the costs of the raw materials. The need to separate iron and aluminium from the phosphate introduces additional complexity into the treatment of the C-grade material. The higher processing costs might be justified, however, if alumina could be produced as a byproduct. Two proposed processes have been developed in which: 1. hydrochloric acid is used for dissolution, and solvent extrac- tion for the separation of ferric chloride from phosphoric acid. Aluminium chloride is precipitated and hydrolysed to recover alumina and hydrochloric acid. 2. sulphuric acid is used for dissolution and aluminium is crystallized as ammonium alum. The phosphate is produced as an ammonium phosphate-sulphate fertilizer. High purity alumina can be obtained by treatment of the recrystallized alum. The technology of these processes is described, and their broad economics discussed briefly.\

Jan 1, 1971