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By E. Fiset, T. Hennebel, F. Verbruggen, A. Prévoteau, K. Rabaey

Arsenic (As), bismuth (Bi) and antimony (Sb) are known to affect the quality of copper deposits in copper electrowinning operations. The codeposition of As was previously believed to occur only at current densities far exceeding the range of typical current densities for copper electrowinning. In this study, we investigate the copper electrodeposition on different pretreated stainless steel (SS) substrates from bleed electrolyte in galvanostatic mode at –45 mA/cm². Scanning electron microscopy (SEM) micrographs illustrate that during the initial phases of copper nucleation and growth, the current density was locally increased due to the pretreatments. It was reasoned that the codepostion of As could possibly occur in normal electrowinning conditions, but the risk can be substantially reduced by good SS substrate handling and maintenance practices. INTRODUCTION The presence of As, Bi and Sb is known to have a deleterious effect on the copper cathode quality in copper electrowinnings (Hiskey & Maeda, 2003; Hoffmann, 2004; Xiao, Cao, Shen, & Volinsky, 2012; Xiao, Cao, Mao, Shen, & Ren, 2014; Jafari et al., 2017). They are known to influence both the chemical and physical quality of the copper as they can contaminate the copper (Jafari et al., 2017) and affect the copper deposit structure (Hiskey & Maeda, 2003; Kim, Kim, & Chung, 2009), which contributes to a degraded market value of the copper (Tuddenham, 1984). The incorporation mechanisms of these impurities are believed to occur mainly through slime inclusion (F. Xiao et al, 2012) and electrolyte inclusion (Hiskey & Maeda, 2003). Other studies suggested that codeposition of these impurities is possible by their standard reduction potential being close to the one of copper (Xiao et al, 2014). Hiskey and Maeda (2003) investigated the copper electrodeposition on a copper electrode substrate in Cu electrolytes with a Cu, H2SO4, As, Bi, Sb composition representative for commercial copper tankhouses. The combination of voltammographic techniques and Auger electron spectroscopy showed that As was the first impurity to be electrodeposited from this electrolyte, yet at potentials where the limiting current density of the copper electrodeposition reaction is exceeded. The copper tankhouses usually operate at a current density ratio of 0.3 to the limiting current density in order to achieve tolerable copper quality deposits. The codeposition of As could be considered impossible in this current density condition. However, it is known that during the initial phases of electrodeposition on foreign substrates, a substantial part of the reaction proceeds by growth of individual nuclei where the current density is locally high and diffusion limited (Radisic, Ross, & Searson, 2006). Furthermore, it was observed that copper nucleation on TiO substrates occurred preferentially in the scratched oxide free areas which could serve as parts with high localized current densities (Chang, Choe, & Lee, 2005).

Jan 1, 2019

By S. Hopkins, J. Nolan, S. Gillis

"Cast in place concrete shaft linings have been used in many salt and potash shafts sunk in North America over the last 100 years. A large number of these shafts have exceeded their initial design lives and as producers look to extend the life of their operational assets, maintenance costs and shaft downtime will, in many cases, continue to rise unless repair work is undertaken. Successfully implementing concrete liner repair schemes in operating salt and potash shafts is complicated due to their age, environment and time constraints during inspection, detailed design and construction. This paper outlines a general approach to the repair of concrete-lined portions of these shafts, based on lessons learned from the authors’ involvement in a recent repair project. INTRODUCTION Prior to the recent boom in potash mine construction many of North America’s potash mine shafts were entering their sixth continuous decade of production (Table 1). Of North America’s salt mines, one has been in continuous production, for nearly nine decades.As would be expected, considering the environment in which these liners operate and the age of the material, the concrete-lined sections of the shafts outlined in Table 1 have been noted by the authors to have lost both cross-sectional thickness and strength over time. Since construction, three principal factors have contributed to this loss in section/strength; (1) physical degradation (impact, freeze/thaw or rebar expansion), (2) chemical degradation from brine/water inflows (Neville 1969; Bothwell, 1972) and (3) overstressing of the liner. These factors may act in combination, in which case they can produce more significant distress than individually. Physical degradation There are three main causes of physical degradation of concrete shaft liners. The first is impact from falling debris/tools or equipment (whether large or small), which may damage specific sections of concrete lining as they fall through the shaft. Impacts tend to damage infrastructure fixed to the shaft liner more than the liner itself, so damage from this mode of failure is usually localised, for example, where bolts fixing a shaft services bracket to the wall have been pulled away, pulling out the concrete around the bolts with them."

Jan 1, 2019

By A. Pearson, Auld. F. A., S. O. Colbeck

"To minimise mine shaft maintenance over the long-term, some potash mine shaft sinking projects have required the provision of a continuous fully welded waterproof steel liner over a substantial depth to achieve zero water ingress. This brings many challenges, including the implementation of a bottom-up construction sequence incorporating extensive waterproof welding and how to ensure the integrity of the welded liner when subject to substantial temperature fluctuations that are likely to occur with a composite steel-concrete liner placed within an artificially frozen shaft excavation. This paper highlights the key challenges and discusses multiple mitigation measures including vertical shaft movement joints and a combined structural-thermal analysis approach. INTRODUCTION Whilst the application of combined steel and concrete shaft liners using a fully welded steel liner is not new and has been used in several previous projects, most notably at Lanigan (Storck, 1968 & Roesner, 1980), recently the need to provide a continuously welded steel waterproof liner for over 800 m length of shaft for a potash mine has been considered. The need for a fully continuous welded steel liner arises from the perceived benefits of providing a fully dry shaft environment to; increase the life expectancy of the shaft; reduce routine maintenance particularly combatting salt accretion and minimising wash down practices; and improve long-term ground stability by preventing salt dissolution. Whereas previous projects have employed discontinuous sections of steel liner, when a fully continuous liner is employed longitudinal shaft strains from thermal changes result in significant deformations that must be either explicitly accommodated or resisted. Note, these thermal vertical expansion forces are more than capable of lifting the shaft collar and head frame structures should they be fixed in place. Typically, shafts are designed to resist vertical forces (collar loads and self-weight) by creating mechanical interlock with the adjacent ground. In competent rock this occurs incrementally with the construction of the shaft liner, and occasional hitch/crib structures are constructed as intermediate foundations to guarantee the transfer of vertical forces at distinct horizons. Usually this means cribs are constructed at first rock head, above the station level, and at the sump, although sometimes additional cribs are formed when entering and exiting weak strata or when a change in shaft liner construction is required."

Jan 1, 2019

By C. Cristonffanini, S. Nazari

"In the past, simulation was considered to be an offline tool disconnected from plant operation. Advancements in the computation power combined with utilizing physics and chemistry sciences have allowed us to significantly improve the modeling and simulation technology for mining and mineral processing. This paper investigates the benefits of first principle models and simulation by connecting them to real time operation. Process data are connected to high fidelity models executed in parallel to the operation. In recent literature, this concept is known as Digital Twins. The Digital Twin is used for various purposes such as optimization, virtual instrumentation and condition monitoring. Using IDEAS™ simulation software we are able to construct a digital twin for different equipment inside a mineral processing plant. Two case studies for building a digital twin for the primary hydrocyclone feed pump and thickener underflow are presented. Using the pump’s model, a digital twin is developed and is installed in a gold extraction plant that is able to infer the slurry density in real time. Additionally, it is used for detecting sanding in the pipes and impeller condition monitoring.INTRODUCTION Since the eighties, thanks to advances in computation technologies, computer based simulation of processes using first principle models has become a well-known engineering tool for various industries. As our understanding of processes has increased, their representative models have become more realistic and more sophisticated. Due to this increase of accuracy, use of simulation is becoming more fundamental in process industries. The main goals to use accurate simulation is to decrease the engineering and construction cost, optimize the process design and improve the operation performance by decreasing operation cost and increasing efficiency. The term Digital Twin was first introduced in 2010 by NASA (Shafto et al., 2012) in aerospace industry. Subsequently, the concept quickly spread through other industries. As of today, no standard organization has provided an official and unique definition of Digital Twin for process industries. However, there are three important aspects that are common throughout various descriptions. When simulation is core functionality of the process (1) along the entire life cycle of the plant (2) with direct linkage to operation (3), it is called that process has a Digital Twin. According to Gartner, the concept of Digital Twin has elected as fourth most important disruptive technology for the year 2018 (https://www.gartner.com/, 2017)."

Jan 1, 2019

By Gamal Rashed, Zorica Radakovic-Guzina, Khaled Mohamed

"Underground coal mines use mechanical bolts in addition to other types of bolts to control the rib deformation and to stabilize the yielded coal ribs. Limited research has been conducted to understand the performance of the mechanical bolts in coal ribs. Researchers from the National Institute for Occupational Safety and Health (NIOSH) conducted this work to understand the loading characteristics of mechanical bolts (stiffness and capacity) installed in coal ribs at five underground coal mines. Standard pull-out tests were performed in this study to define the loading characteristics of mechanical rib bolts. Different installation torques were applied to the tested bolts based on the strength of the coal seam. A typical tri-linear load-deformation response for mechanical bolts was obtained from these tests. It was found that the anchorage capacity depends mainly on the coal strength. Guidelines for modeling mechanical bolts have been developed using the tri-linear load-deformation response. The outcome of this research provides essential data for rib support design.INTRODUCTIONThe design of rib bolting in U.S. coal mines is based on a trial-and-error process, which is insufficient to eliminate injuries and fatalities caused by rib falls. In the last 10 years, rib failures have resulted in 17 fatalities, representing 52% of the ground-fall fatalities in underground coal mines in the United States (MSHA, 2018). Recently, NIOSH researchers surveyed 90 sites in 14 underground coal mines in the Eastern United States and found that 11 mines are bolting coal ribs, with 4 of those mines using the conventional mechanical bolts and the others using fully-grouted bolts. NIOSH researchers are developing an engineering design procedure for rib support. Pull-out test programs for mechanical and grouted rib bolts were conducted to understand the rib control mechanisms of rib bolts. Only the test results of mechanical bolts are presented in this paper.Mechanical bolt (or point-anchored bolt) is a tensioned bolt anchored down the borehole with a mechanical expansion shell or a resin-grouted medium (Peng and Tang, 1984). The mechanical anchor bolt consists of a plug, a shell anchor, a headed bar with the top end threaded, a bearing plate, a hardened washer, and occasionally a friction-reducing washer. The shell anchor can be either standard or bail type (Figure 1). The standard type shell is held in place by a nut, while the bail anchor uses a strap to hold the shell in place (Peng, 2008). The diameter of the bar is generally 16 mm (? in) for the #5 bolt or 19 mm (6/8 in) for the #6 bolt. The diameter of the hole that the bolt is inserted into must be carefully controlled, since an oversized hole can result in poor anchorage (Moss, 1971). The anchorage is obtained by applying torque to the bolt head, which in turn pulls the plug down in the shell and expands the serrated leaves against the sides of the hole-wall. In the resin-grouted anchor, the resin replaces the mechanical expansion shell at the end of the hole. The anchorage is achieved by bonding between the resin, bolt, and the hole-wall."

Jan 1, 2019

By M. Li, T. H. Dubaniewicz, H. N. Dougherty

"INTRODUCTION Underground mines have the risk of accumulation of gases if not ventilated properly or during and after emergency situations when ventilation controls become damaged or stop working. Common gases that are monitored in underground coal are carbon monoxide (CO), oxygen (O2), and methane (CH4). Methane is a gas found in coal and released through mining; its explosive range is between 5% and 15%. Methane is commonly monitored on all mining equipment and with handheld gas sensors carried by most underground coal miners. Fiber optics (FO) is a popular technology applied in underground mining, particularly for its electric isolation. Many miners are familiar with FO cables hung throughout the mine, which are primarily used in the communication of voice and data (Taylor et al. 2010). Advancements in laser and fiber optics have made this technology well suited for gas sensing the harsh environment of mining applications. The work of the U.S. Bureau of Mines on the use of fiber optic monitoring of gases in mines started in 1992. Dubaniewicz et al. (1992, 1993, 1995, 1999, 2003) developed prototype gas sensors, including methane gas sensors, for research purposes. Previous research (Dubaniewicz & Chilton 1992) identified potential fiber optic gas detection cross-sensitivities associated with the index of refraction of various gases. Index of refraction effects was noted for carbon dioxide (CO2), which is produced in significant quantities by mine fires or explosions. NIOSH released a broad agency announcement (BAA) for the development and demonstration of mine safety and health technology (CDC NIOSH 2017). The objective of this announcement was to validate a sensor, specifically fiber optic, for the mine environment and test it in an actual working mine. The RSL FO sensor “OptoSniff” provided from this work is capable of hundreds of sensing points over distances of up to 20 km, has a measurement range of 0.05% to 100%, senses in an oxygen- deficient environment, and has no gas cross-sensitivity (RSL, 2014). The RSL system is totally electrically passive outside the central control unit (CCU), which can be housed in an MSHA-approved explosion-proof (XP) enclosure or in a control room outside of the permissive area. The sensor was tested in dusty and signal loss situations, showing it is tolerant of dust, has functioned at signal losses up to 90%, and was successfully tested in a mine environment for a five-month period (Walsh et al. 2014). This paper describes how the RSL FO sensor is used for testing using smoke and its contaminants for applicability in emergency situations. The testing investigates individual contaminants such as CO2, temperature, and smoke. Each test was performed separately and methane concentration, laser power, and response time data were collected."

Jan 1, 2019

By Andrew Artzer, Michael Moats, Jack Bender

Antimony and bismuth in copper electrorefining electrolytes can cause cathode contamination, leading to the careful control of their concentrations. This study examined the laboratory scale removal of bismuth and antimony from an electrorefining electrolyte using a solvent extraction mini-pilot plant. The ability of a proprietary phosphonic acid ester extractant (REX-2) in a commercial diluent was studied in a simulated commercial setting. Antimony and bismuth were both extracted effectively from the electrolyte (72% Bi and 70% Sb removed) and Bi was effectively stripped (92% Bi recovered) with 400 g/L sulfuric acid. A final strip solution was obtained from the SX circuit containing 0.36 g/L Bi, 0.043 g/L Sb, 1.3 g/L Cu, and 0.18 g/L As. Unfortunately, most of the extracted Sb remained in the organic phase. Following the pilot study, experiments were performed to examine the precipitation of bismuth from the aqueous strip phase and the removal of antimony loaded on to REX-2. INTRODUCTION For many years, antimony and bismuth have been some of the most problematic impurities in copper electrorefining (ER) (Bardwell & Lapee, 1933). Along with surface roughening, high concentrations of Sb and Bi can contaminate the copper cathode and precipitate at the copper grain boundaries. This drastically reduces the drawing ability of the metal (Bender & Emmerich, 2016). For these reasons, it is necessary to control Sb and Bi concentration in the cathode, which is done by controlling their concentration in the electrolyte. Conventionally, Sb and Bi concentrations are controlled by maintaining a proper As/(Sb+Bi) molar ratio in the anode and arsenic concentration in the electrolyte. Antimony and bismuth are removed during electrolyte purification using liberators (electrowinning cells) and/or ion exchange. Liberators treat an electrolyte bleed stream from the ER circuit and electrodeposit increasingly impure copper as the copper concentration of the solution decreases. Traditionally, first stage liberators reduce the copper concentration from ~45 g/L to ~15 g/L and produce saleable copper. Second stage liberators decrease the copper concentration to ~8 g/L (Biswas & Davenport, 1980) which results in contaminated cathode that is returned to anode production (Biswas & Davenport, 1980; Wang, 2004). Further electrolyte purification is not always required but third stage liberators can be used to reduce copper concentration below 2 g/L which results in significant removal of As, Sb and Bi and very impure deposits which are recycled to a smelter or used for As production. However, liberators do not have very high energy efficiency (Acharya, 2014; Ando & Tsuchida, 1997) and below 0.5 g/L copper, highly toxic arsine gas may form (Biswas & Davenport, 1980).

Jan 1, 2019

By J. Navoyski, B. Macdonald, W. J. Helfrich, J. L. Bellanca, B. Demich

DISCLAIMER The findings and conclusions in this paper are those of the authors and do not necessarily represent the official position of the National Institute for Occupational Safety and Health, Centers for Disease Control and Prevention. Mention of company names or products does not constitute endorsement by NIOSH. ABSTRACT Recent advances in computing, rendering, and display technologies have generated increased accessibility for virtual reality (VR). VR allows the creation of dynamic, high-fidelity environments to simulate dangerous situations, test conditions, and visualize concepts. Consequently, numerous products have been developed, but many of these are limited in scope. Therefore, National Institute for Occupational Safety and Health researchers developed a VR framework, called VR Mine, to rapidly create an underground mine for human data collection, simulation, visualization, and training. This paper describes the features of VR Mine using self-escape and proximity detection as case studies. Features include mine generation, simulated networks, proximity detection systems, and the integration and visualization of real-time ventilation models. INTRODUCTION There are many definitions of virtual reality (VR) that include various levels of immersion and features [1]. Some definitions refer to specific technologies [2], while others are limited to visualization [3]. For this paper, a more general definition of VR will be adopted. VR is defined as the collection of hardware and software that interactively engages users and stimulates their senses within a synthetic or virtual environment. From a hardware standpoint, this can include anything from a phone to a head-mounted display (HMD) to a large-scale theater as well as speakers, microphones, haptic sensors, and interaction devices. The software used to create virtual environments (VEs) generally includes a game engine, custom software components and libraries, and two-dimensional and three-dimensional graphical assets. Recent hardware and software advances have increased the fidelity and availability of VR. New and improved technologies including HMDs and high-resolution monitors and projectors can display sharper, more detailed visualizations. For example, in the past five years between the release of the Oculus Rift DK1 (2013) and the HTC Vive Pro (2018), there was a three-fold increase in resolution along with a 50% increase in the refresh rate. Furthermore, despite early claims that low-cost VR technology was readily available [4], computational power has not been sufficient to handle the large amount of data generated by these systems [5]. In the past five years, however, rendering speeds have more than doubled and memory has more than tripled [6], allowing these visualizations to be incorporated into higher-complexity and -fidelity VEs that more closely mirror the real world. Similarly, software capabilities have also significantly improved through game engine advancements and feature development. In the past several years, game engines have added and improved features such as physics, lighting, platform support (e.g. Android), and asset development integration. Some of the current leading commercial game engines are Amazon Lumberyard, CryEngine, Unreal, and Unity, but this can quickly change as is evident in the literature [7, 8].

Jan 1, 2019

By Greg Canivan, Bernie Hertlein, Les Chernauskas, Joram Amir, Garland Likins, E. Anna Sellountou, Tim Kovacs, Peter Kandaris

Nondestructive testing of drilled shaft foundations via Crosshole Sonic Logging (CSL) is often performed as part of the quality assurance process to assess the soundness of concrete. The intent of CSL testing is to identify irregularities such as soil intrusion, necking, soft bottom, segregation, voids and other defects that could result in poor structural performance of the foundation. Over time, CSL rating criteria based on first arrival time and relative energy have incorrectly evolved to often be the sole means of determining the acceptability of a shaft. Some of these criteria have found their way into regulatory agency specifications, with acceptance values often differing from agency to agency.The purpose of this document is to review the state of the practice (including experience gained over the past 20 years), propose improved CSL rating criteria and make recommendations for additional assessment, as well as educate the industry on the proper interpretation of CSL test. CSL test results alone should not be the sole means of rejecting or accepting a shaft. A task force of industry exerts was formed to review the existing CSL rating criteria and propose improvements where appropriate. The recommendations presented herein are the consensus of the task force, which believes that they should be incorporated into future criteria, codes and specifications. This paper was produced as a joint effort between the Codes and Standards Committee, the Drilled Shafts Committee and Testing and Evaluation Committee. A task force was authorized under Testing and Evaluation Committee. The task force contributed their expertise in web-based discussions often every two weeks over a period of three years. Interested participants were invited to participate at any time. The document had two rounds of broad industry review, two rounds of DFI Technical Advisory Committee reviews, and a Public Comments process. All comments were considered in producing the final document.

Jan 1, 2019

By Y. X. Li, L. R. Xiao, S. Gong, S. S. He

Porous copper and porous copper based alloys with controllable pore structure have been manufactured successfully by sintering evaporation process. This process consisted of mixing copper or copper based alloys with NaCl powders, hot pressing and final high-temperature sintering to evaporate the filler material of NaCl powders. NaCl was eliminated completely during vacuum sintering, and strong metallurgical bonding in the walls was achieved. The pores’ structural parameter (pore size, shape, and direction) and porosity can be controlled effectively. These porous copper and porous copper based alloys with controllable pore structure have great potential in many fields. Including heat dissipating materials, heat absorbing materials, chemical catalyst carriers, electromagnetic shielding materials, filtering materials, damping materials, silencing materials, battery electrode materials. INTRODUCTION The development of porous materials began in the 1960s. The research of activated carbon with high specific surface area made porous materials enter the stage of material research (Belyakov et al., 2008; Ferey et al., 2008). With the rapid development of science and technology, porous materials play an important role in material research, and gradually become an indispensable part of the material research field (Wu et al., 2012). The research of porous materials has gradually extended to metal, ceramics, plastics and glass and other fields. It has been successfully applied in many fields, such as functional materials, industrial production, aviation, medical materials, biochemistry and electronics, which fully shows that porous materials have considerable development prospects. Porous silicon, plastic porous materials and glass porous materials are the most widely used in the field of non-metallic porous materials (Capelle et al., 2012). Compared with non-metallic porous materials, metal porous materials have developed rapidly in the late 1980s and become new materials with good mechanical properties and excellent physical properties. Porous metal materials have many advantages, such as large specific surface, small specific gravity, good silencing effect, high stiffness, high electromagnetic shielding performance, good shock absorption performance, etc (Li et al., 1999; Ferey et al., 2008). Among its many applications, metal porous materials can be used as both functional materials and structural materials. In some cases, metal porous materials have dual functions and structures. It is a multi-purpose engineering material with excellent performance. At present, porous copper, porous aluminium and porous nickel are the most concerned materials (Chen et al., 2002; Yang et al., 2017; Liu et al., 2018). The preparation methods of porous copper and copper-based alloys mainly include self-propagating high temperature synthesis (SHS), capsule-free hot isostatic pressing (CF-HIP), spark plasma sintering (SPS) (Kvanin et al., 2008; Takahashi et al., 2008; Zhang et al., 2014). However, these methods can not accurately control pore structure parameters (including pore size, shape, orientation, distribution, etc.). In porous materials, pore structure plays an important role in the overall performance of materials. In order to control pore structure parameters accurately and optimize material performance, it is necessary to explore and develop new preparation technology. In this paper, the sintering evaporation process (SEP) was introduced for the preparation of porous copper and copper-based alloys. The core process of the preparation method is hot pressing and evaporative desalination. Hot pressing can make the pore orientation consistent. Evaporative desalination can ensure the complete removal of NaCl in the form of vapor in a short time, thus eliminating the corrosion of residual NaCl on the matrix metal (Gong et al., 2011).

Jan 1, 2019

By S. K. Kawatra, S. Valluri

With increased CO2 emissions from steel and coal industry, there is great opportunity to capture CO2 and utilize the captured CO2 for economic advantage. The primary goal is to develop energy-efficient processes that reductively couple CO2, an abundant and renewable carbon source, for the production of value-added chemicals such as methanol, ethanol, and oxalic acid. These chemicals can be used elsewhere in the refining process or sold as valuable by-products. Geological sequestration, in comparison, has no economic return. Current CO2 utilization research at Michigan Technological University focuses on electrochemical reduction of CO2. Electrochemical reduction of CO2 to hydrocarbons and other chemicals is a complex multistep reaction with adsorbed intermediates. The exact reaction mechanisms leading to various products are not clear from the literature to date and will likely change over the range of conditions like pH, electrode potential, electrolyte medium, catalyst, etc. This paper will present different ideas and their viability to utilize CO2 as a feedstock to produce several value-added compounds. INTRODUCTION Carbon dioxide (CO2) emissions into the atmosphere will need to be drastically reduced to curb the various undesirable effects of climate change. The large contribution in total CO2 emission originates from coal or natural gas power plants, and a considerable amount from steel plants. Average CO2 emissions in the US from steel industry is 2.9t CO2/t steel (Global CCS Institute 2013). Capturing the available CO2 from the steel and coal industries for economic advantage is a win-win situation for the industry. This technology is not only important scientifically but is also vital for a sustainable future. The various ongoing investigations can be categorized as biochemical, thermochemical, photochemical, and electrochemical approaches. Among these, the electrochemical method shows the most promise as an efficient form of CO2 conversion technology, because of its many advantages like high reactivity under ambient conditions and good extensibility from small- to large-scale processes1 BACKGROUND Extensive research has been done on the chemistry of transforming carbon dioxide into more useful products. Methods are known to convert carbon dioxide into a wide variety of substances, including methanol, isobutanol, carbohydrates, methane, carbonates, urea, formic acid, oxalic acid, carbon monoxide, epoxides, formaldehyde, and so on. Several of these (carbohydrates, formaldehyde, isobutanol etc.) are primarily results from biological processes. The rest are results of strong reduction reactions or electrolytic reduction. In short, electrolytic reduction can be used to form methane, methanol, formic acid, oxalic acid, carbon monoxide from carbon dioxide2. CO2 reduces at the cathode in an electrolysis cell. These processes have the general form of generating the carbon dioxide anion radical (2⋅−) and allowing it to react with itself or the electrolyte3. Catalysts can be added to influence the formation of the anion radical or to suppress side reactions3. The electrolyte, catalyst, voltage, electrode material and CO2 content are all known to effect the reaction pathway. Table 1 shows the overall reactions and energy requirements for electrochemical conversion of CO2 to chemicals

Jan 1, 2019

By Kalyani Devabhaktuni, Mike Minton, Mark T. Howe, Yan Zhang

During the procurement phase of a Design-Build (DB) project, design-build contractors must often commit to a fixed price based on limited or incomplete geotechnical information. This lack of information can result in an inaccurate assessment and allocation of project risk to either the contracting authority or the DB contractor. This paper presents a case study of an elevated water tank supported by mixed ground improvement techniques, including Vibro-Compaction (VC), Aggregate Piers (AP) and Compaction Grouting (CG) in East St. Louis, Illinois. An adaptive design and contracting approach provided the best value solution for a complicated set of geotechnical problems, including static bearing capacity and settlement concerns as well as liquefaction induced settlement. Close cooperation between the owner, the tank contractor, the geotechnical engineer and the ground improvement contractor was essential to produce an effective solution. Ground Improvement techniques resolved the geotechnical challenges at the site through adaptive design methods, utilizing progressive rounds of verification and real time data acquisition to achieve performance objectives. This paper details the evaluation of geotechnical criteria, the selection of ground improvement techniques, the adaptive design and implementation of ground improvements, as well as contracting methodologies used to ensure that the best value was provided. PROJECT INFORMATION In November, 2016, CB&I Storage Tank Solutions (McDermott) submitted a design/build proposal for an elevated water tank for Illinois American Water Company (IAW) in East St. Louis, Illinois. The purpose of this tank was to have backup water capacity for power generation. In the RFP, IAW requested two alternate styles of tank: Option 1, a 1250 Million Gallon (MG) Composite Elevated Tank or Option 2, a 1250 MG Waterspheroid tank. Option 1 consisted of a steel tank supported on a concrete tower. Option 2 consisted of a steel tank supported on a steel shaft. The height (determined by IAW) was 140 feet to the top capacity line measured from top of floor slab.

Jan 1, 2019

By Brandon Smith, William Bohlen

Riverbank erosion along the Brazos River has modified the structural support conditions for an existing bridge structure in Southeast Texas. The 8-span, 1,200-foot long bridge was completed in 1992 along Highway 99, a key corridor for the Houston area. Foundation support conditions have been altered due to natural, ongoing river morphology for three bents on the affected riverbank. Recent events include three storms within a three-year period that each exceeded the 500-year return probability. This resulted in accelerated erosion along the northern riverbank. Over forty vertical feet of soil has been removed in some locations. Drilled shaft foundations are now functioning as columns. This review considers the behavior of columns and deep foundation elements due to the modified support conditions. The review ultimately presents a rational methodology for the review of the present and anticipated future bridge configuration with respect to current strength, service, and extreme event limits, with corresponding safety factors for the design. Introduction and Background The Fort Bend Grand Parkway Toll Road Authority (Owner) oversees the State Highway 99 Judge Jodie Stavinoha Bridge over the Brazos River. The 8-span, 1,200-foot long bridge was originally designed with four southern approach spans of 115 feet; a three-span continuous river crossing with span lengths of 195 feet-235 feet-195 feet; and a single northern approach span of 115 feet. Figure 1 provides an overview of the northern portion of the bridge. Table 1 provides a summary of the original bridge substructure configuration. When the bridge was completed, the centerline of the Brazos River was located at midpsan of the main span and the northern high bank was originally located at Bent 7. Erosion process has forced the northern high bank to Abutment 9 (also called Bent 9), and the river centerline during normal flow conditions is located south of Bent 8. The overall estimated river excursion at present day is approximately 270 feet to the north from its original location. An erosion wall that was installed in 2017 limits further erosion of the north river bank within the 300-foot width of the roadway corridor right-of-way. This study was developed to better understand the existing conditions, and to forecast the need, nature, and criteria for potential future improvements.

Jan 1, 2019

By John R. Grillo, Gordian Ulrich, Franz-Werner Gerressen

Most geotechnical construction professionals are aware of piling using hydraulic drill rigs and the so-called Kelly drill mode. Kelly drilling has many advantages as it can work with a wide range of tools facing almost all types of soil and rock conditions. Kelly drilling can also deal with diameters up to 10 ft (3.00 m) and bigger or depths of more than 330 ft (100 m). Nonetheless, there is a concern about Kelly drilling as it is a relatively slow installation process. Therefore, an alternative piling method like Cased CFA (CCFA) Piles (Cased Auger Cast Piles) provides a significant advantage in terms of installation performance, schedule and cost saving potentials. Major application for the Cased CFA system is the secant pile wall construction. Against the traditional secant pile wall systems like fully cased bored piles or CFA secant piling the Cased CFA secant pile wall system has the advantage in cost and time against the fully cased system and in quality against the standard CFA system. This paper will describe the methodology and installation process in general as well as first reference projects carried out in the United States. This paper will present the results in cost and schedule saving using this method. In addition, we will also describe the limitations of this method. INTRODUCTION In the changing construction environment, companies are searching for new technologies or improvement of existing technologies to complete their projects in shorter time frames to provide a good economic solution. Especially with the focus of increasing urbanization, the aim of fast construction becomes more and more important. When thinking of piling, most people will have the same picture in mind: that of a hydraulic drill rig working in Kelly drilling mode; however, the perpetual drill rig development provides a number of options for the execution of specialist foundation projects, either for foundations or for pile walls when using single pass applications like CFA, Cased CFA and Full Displacement Piling (FDP). Single pass means, in general, that the tool is pushed and rotated into the ground to the final depth in one stroke. After reaching the final depth, concreting is started and concrete is pumped continuously while the tool is withdrawn.

Jan 1, 2019

By Babak Mamaqani, Pirooz Barar

Regional Connector Transit Corridor (RCC) is part of the Los Angeles metro expansion project under construction which adds three new stations into the system. PB&A was responsible for the design of the support of excavation (SOE) systems for two stations, 2nd/Broadway and 2nd/Hope, in RCC. In this paper, challenges and lesson learned from SOE design of 2nd/Broadway station with a main focus on underpinning design are discussed. 2nd/Broadway station required to cut and cover excavation of 500 ft long by almost 100 ft deep, underneath 2nd Street. SOE systems consisting of drilled soldier beams with tiebacks and/or struts. The main challenge in 2nd/Broadway station was to underpin the LA Times building which was partially protruded into the station. A chellenging underpinning system consisted of concrete panels and ground anchors was designed to support the building surcharge and prevent settlement. The underpinning system was designed based on METRO design criteria and the deflection was evaluated by Finite Element Analysis (FEA) program, PLAXIS 2D. A maximum deflection of 0.4 inches was calculated to occur at the top of the underpinning system. Data from settlement and tilt sensors showed minimal movements which aligned with PLAXIS outputs. PROJECT DESCRIPTION The Regional Connector Transit Corridor (RCC) is Los Angeles Metro’s ambitious Light Rail Project. It runs under the City’s main thoroughfares, Flower and 2nd Streets, and when complete will alleviate traffic and parking congestion in downtown Los Angeles. The Regional Connector will connect thousands of residents living in the bedroom communities of the Inland Empire and Long Beach to their jobs Downtown. The rail line will serve 1.9 miles, using the $1.756 Billion budget to construct the underground rail line, including 3 new stations, at 2nd & Hope Street, 2nd & Broadway, and 1st St. & Central Ave (Fig. 1).

Jan 1, 2019

By Chu E. Ho, Paul Napoli

A new waterfront park was developed on Long Island in close proximity to the East River and Newtown Creek. The existing ground consisted of fill over soft organic clay, medium dense silty sand, glacial till and schist bedrock. The ground was initially raised to preload the underlying soft soils to stabilize the ground in preparation for site development. The ground was subsequently cut down to temporary grades for installation of foundation piles for the overlook structures and construction of reinforced concrete cantilever retaining walls forming pathways located adjacent to the water bodies. The retaining walls were located in two rows at different elevations along the sides of a steep embankment. Where the pathways converge, some of the walls were too close to each other, and were redesigned as a combined U-wall with a common base slab. The individual retaining walls were designed for adequate bearing, sliding and overturning resistance. Ground anchors were installed to enhance global stability of the retaining walls. This paper presents the design considerations for the retaining walls for various loading conditions, and evaluation of the trial and proof tests for the anchors. INTRODUCTION The New York City Master Plan included the transformation of an approximately 30-acre parcel of land in Long Island City, Queens, New York from a former manufacturing zone into a residential, commercial and recreational zone for middle-income community. The site was located at Hunters Point South along the eastern shoreline of the East River and Newtown Creek (Figure 1). The development included low to high- rise residential buildings, a public school, and retail structures. Open spaces were provided along the East River and Newtown Creek waterfronts in the form of a continuous park providing for recreational and community-related activities. Waterfront structures included small park buildings, walkways and viewing platforms. The shoreline was surrounded by revetments as part of the flood mitigation strategy. The project involved extensive site re-grading and several retaining walls were constructed. The earthwork volume amounted to approximately 47,000 cubic yard of imported fill and 93,000 cubic yard of cut. The exposed height of the retaining walls ranged from 3 to 15 feet. This paper focuses on the design and construction of the retaining walls for the project.

Jan 1, 2019

By Andres M. Baquerizo, Jeremiah J. Filjones, Nicholas Feldt

The Estates at Acqualina located in Sunny Isles Beach, FL, is comprised of two, ocean-front, 50-story, luxury towers with podiums and villas. With city regulations now requesting that above-grade floors be limited to commercial or residential units, parking facilities for the tower structures were situated within two levels of underground basement parking. However, ensuring dry excavation through south Florida’s highly pervious limestone, immediately adjacent to the beach where the groundwater table is very shallow, can be extremely challenging and costly for developers. In recent years, significant advances have been made to overcome this challenge with the innovative use of deep soil mixing to create a “dry hole”, assisting in the construction of foundations and underground usable space for parking, storage, etc. The “dry hole” system includes a soil mix bottom seal, with soil mix secant pile walls in combination with auger cast deep foundation elements to support the future structure. This approach enables groundwater control to greater depths than can be achieved by conventional sheetpiling and dewatering. For the Estates at Acqualina, a successful turnkey, design-build joint venture between two foundation and geotechnical contractors resulted in a dry excavation to 34 ft (10.4 m) below grade and to a record- breaking auger cast pile depth of 182.3ft (55.6 m), all within an aggressive 26-week schedule to deliver the “dry hole” excavation for the first tower. This presentation will discuss the logistics, quality control, design, and safety for the different techniques involved. INTRODUCTION AND BACKGROUND The Estates of Acqualina is a pair of 50-story luxury towers located on Sunny Isles Beach in Florida with a two-level underground basement for parking. The project’s location just steps away from the Atlantic Ocean, geology, and high-water table created a challenging project. The owner, Trump Group, contracted the joint venture of HJ Foundation and Hayward Baker (HJ/HB) to design-assist-build a system to control the groundwater, allowing the 2-story underground parking structure to be constructed. In order to accomplish this task, the JV utilized an installation technique known as deep soil mixing. This technique mixes the in situ material with a cement slurry to create a very impermeable material called “soilcrete”.

Jan 1, 2019

By Diane Reid, Antonio Marinucci, Robin Mao

Super Cells are an innovative, open-shaped bi-directional static load testing device used to promote concrete flow during placement while utilizing greater cross-sectional area of the pile to achieve large applied axial loads at relatively low hydraulic pressures (≤ 250 bar). This paper describes the results of multi-level load testing performed on a sacrificial drilled shaft that was 3.8 m (12.7 ft) in diameter and 110.6 m (363 ft) in length for the Jiaxing-Shaoxing River Crossing Bridge that spans Hangzhou Bay in Shaoxing, China. The test shaft was instrumented with embedded strain gauges and telltale rods along with displacement transducers at the top of the pile to measure the load-induced displacements along the length of the shaft. Load testing was performed twice using a Super Cell placed near the tip of the shaft, prior and subsequent to tip post-grouting, and then again using a Super Cell placed higher in the shaft. The axial resistance for the tested conventional drilled shaft was more than 5 times greater than the estimated axial resistance. In addition, the axial resistance after tip post-grouting (347,100 kN (39,033 ton)) was about 5.3% greater than the ungrouted axial resistance (329,600 kN (37,050 ton)). INTRODUCTION During the past few decades, the magnitude of axial, lateral, and flexural loading has considerably increased due to updated design codes, larger superstructures, and the manner in which extreme event loading (e.g. seismic and scour) is incorporated into design. The diameter and depths to which bored piles or drilled shafts are constructed have increased considerably during the last three decades due to the advancements in equipment technology and capabilities. In addition, monoshaft foundations have become increasingly used, as one large drilled shaft is able to replace a group of smaller diameter piles connected by a cap. Correspondingly, adequate strata, for both side and end resistance, must be discovered/determined as well as achievable to be able to construct the required foundations to support the greater design demands. As design demands have increased, the need to ensure integrity, quality, and performance of a constructed drilled shaft has become ever more crucial. Load tests are essential to validate design assumptions of side and end resistances, to assess the behavior and load transfer characteristics of the constructed drilled shafts, and to evaluate construction methods. Load tests utilizing a bi-directional static load testing (BDSLT) device can achieve considerably large applied axial loads and can be performed more economically, in less time, and in a much safer manner than conventional top-down static load testing methods.

Jan 1, 2019

By M. Drozd, M. Somppi, Z. F. Yamak

"Activated carbon is used to recover gold in solution from various gold circuit designs including carbon-in-pulp (CIP), carbon-in-column (CIC), and carbon-in-leach (CIL) processes; however, the characteristics and durability of the activated carbon can vary. Handling this medium poses challenges when fine carbon losses occur in the CIP, CIC, and CIL circuit discharge. Additionally, adsorbed gold on carbon fines can be lost to the discharge. The studies in this paper aim to standardize laboratory methods for testing activated carbon qualities specific to the gold industry. The investigation focused on size distribution, platelet content, wet attrition resistance, gold kinetics, and gold loading. The results demonstrate that a 96 h attrition test and a gold loading test form a basis for ranking carbon samples based on expected economic performance of the plant. ¦ KEYWORDS Activated carbon, Carbon attrition, Carbon ball-pan hardness, Carbon evaluation, Carbon fines loss, Carbon turnover RÉSUMÉ Le charbon actif sert à récupérer l’or en solution dans diverses conceptions de circuits de broyage d’or, notamment les procédés de charbon en pulpe (CIP, de l’anglais carbon-in-pulp), de charbon en colonnes (CIC, de l’anglais carbon-in-column) et de lixiviation au carbone, ou charbon au lixiviat (CIL, de l’anglais carbon-in-leach). Toutefois, les caractéristiques et la durabilité du charbon actif varient. La manipulation de ce milieu pose des problèmes dès lors que se produisent des pertes de carbone à grain fin dans la décharge des circuits CIP, CIC et CIL. Par ailleurs, l’or adsorbé sur les fines de charbon peut se perdre durant la décharge. Les études réalisées dans le cadre de cet article visent à normaliser les méthodes de laboratoire pour tester les qualités du charbon actif spécifiques au secteur de l’exploitation aurifère. L’étude portait sur la composition granulométrique, la teneur des plaquettes, la résistance au frottement humide, la cinétique de l’or et l’adsorption de l’or, à savoir la capacité du charbon actif à adsorber l’or sur une période spécifique. Les résultats ont montré qu’un test de frottement de 96 heures et un test d’adsorption de l’or constituaient le fondement d’un classement des échantillons de carbone du point de vue économique en vue de trouver l’échantillon générant le meilleur rendement des usines. ¦ MOTS CLÉS charbon actif, dureté de la batée des billes de carbone, évaluation du carbone, perte de fines de charbon, renouvellement du carbone, résistance au carbone INTRODUCTION The use of activated carbon for gold extraction is among the most common processes in modern gold-milling plants. Although gold losses are inevitable in the milling process, operators often focus on reducing gold loss to tailings. One focus area that is important in gold recovery is optimizing the use of activated carbon and examining potential changes to realize improved economics for carbon-in-pulp (CIP), carbon-in-column (CIC), and carbon-in-leach (CIL) processes. Granular activated carbon (Figure 1) is widely used for gold extraction from slurries containing gold-cyanide complexes. This activated carbon—produced from charred coconut shells—is well suited because of its adsorption kinetics, gold-loading capacity, attrition resistance, and ability to be reactivated. The extraction process using activated carbon technology involves adsorbing gold from an aqueous leachate; the gold is dissolved using a cyanide salt and consequently a dicyanoaurate(I) ion (Au(CN)2–) is formed, as noted in equation 1."

Jan 1, 2019

By T. Wulleman, M. Ansriou

Integrity testing is a primary quality control check on a product that is for the most part not accessible to visual examination. Their cost can be expensive when using direct methods of inspection (like coring a pile) or more economical when using indirect methods (e.g. acoustic testing). All indirect methods operate by “inference” which means that they do not directly measure the defect of integrity. Indirect methods measure the variation of physical values (temperature, impedance, speed, ect.) correlated to the integrity of the pile allowing the detection of integrity defects, although these methods do not allow for the characterization of the defect. 1. INTRODUCTION Cast-in-place piles are particularly prone to integrity defects. The reasons for this are multiple, including lack of high quality of contractor workmanship, experience and supervision necessary in construction, variable soil and groundwater conditions on site, etc. Furthermore, visual inspection of the finalized pile is usually impossible. Therefore, special care has to be taken both during the execution process and during the subsequent quality control campaign to detect any defects of executed piles. Today, a lot of methods do exist to assess pile integrity. It is thus essential to understand the mechanism governing those devices to both make an engineering choice of the pile integrity testing method and to interpret correctly the provided results. 2. QUALITY IN PILE FOUNDATIONS 2.1 Pile anomalies A pile having an anomaly is a pile which has a different behavior from what is normally expected. The presence of a pile anomaly does not necessarily imply that a pile cannot be used for its intended purpose (Gordon & Chapman 2004). An anomaly can be considered as a defect, or a “performance” depending on the ability of the pile to fulfil the following three criteria (3C): C1 - Meet the Service Limit State (SLS) requirement and support the proposed working load without settling more than admissible by the superstructure ; C2 - Meet the Ultimate Limit State (ULS) requirement and carry a specified load with an adequate factor of safety against failure ; C3 - Remain durable throughout the design life of the structure such that the pile is not affected by time dependent activities (chemical attack, corrosion of steel reinforcement, ect.), which would jeopardize its ability to maintain its compliance with the first two criteria.

Jan 1, 2019