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By Charles M. Wilk

"Mass stabilization involves mixing binding agents into marginal or contaminated soil to improve the subject material’s physical and/or chemical properties. This paper concentrates on the principles of soil mixing and benefits and application to new and existing rail right-of-way. Successfully applied in Scandinavia and other European countries, the soil mixing is now being applied in right of way in the northern latitudes of the U.S. and Canada. These regions have significant areas of “peaty” soils that can complicate construction and maintenance of rail and structure foundations. Mass stabilization can be used to improve the bearing strength of these soft soils for subsequent construction of railroads, pipelines, roads, and buildings. In civil engineering, the technology is often used to improve the construction properties such as bearing strength, of a marginal soil. In environmental engineering, stabilization is remediation treatment technology that protects human health and the environment by immobilizing hazardous constituents within the treated material. . The treatment is conducted while the subject material remains in-place (insitu). Mass Stabilization is often used to accomplish both civil and environmental purposes on the same project effectively addressing marginal soil while eliminating the expense of soil removal and replacement. This paper presents the principles of mass stabilization technology, implementation in the field and recent completed railway projects. The example rail projects will present the various benefits that soil mixing provides to railway construction and maintenance. Bench-scale studies and full scale implementation as well as soil construction properties before and after mass stabilization will be discussed. The paper and presentation will include information on the advantages of mixing methods and binding agent delivery systems.INTRODUCTIONNew or existing railroad right-of-ways may cross ground with low bearing capacity. Right of way subgrade undergo deflection (strain) as loads (stress) are applied. The amount of strain or deflection of the subgrade caused by loading of a train is proportional to the stiffness of the subgrade materials. Some soils, such as tamped ballast, are very stiff and resist loads well. Other soils such as soft clay, peat, or loose sand have low stiffness and undergo substantial movement under loads. It is very desirable to have the stiffest possible material in a track subgrade. Stiff subgrade material limits deflection under load, reducing track roughness and occurrence of track defects. Mass stabilization is a geotechnical method that can be used to improve the bearing capacity or stiffness of soil in these right-of-way. Mass stabilization involves mixing binding agents into soil subject to treatment while the soil remains in-place or insitu. Variations in the design or areas subject to treatment can be used to address transmission of vibration to adjacent structures."

Jan 1, 2015

By J. P. Rider, T. W. Beck, J. A. Organiscak

"The National Institute for Occupational Safety and Health (NIOSH), Office of Mine Safety and Health Research (OMSHR) has recently developed a series of models utilizing Computational Fluid Dynamics (CFD) to study gas distribution around a continuous mining machine with various fan-powered flooded bed scrubber discharge configurations. CFD models utilizing Species Transport Model without reactions in FLUENT were constructed to evaluate the redirection of scrubber discharge toward the mining face rather than behind the return curtain. The following scenarios are considered in this study: 100% of the discharge redirected back towards the face on the off-curtain side of the continuous miner; 100% of the discharge redirected back towards the face, but divided equally to both sides of the machine; and 15% of the discharge redirected toward the face on the off-curtain side of the machine, with 85% directed into the return. These models were compared to a model with a conventional scrubber discharge where air is directed away from the face into the return. The CFD models were calibrated and validated based on experimental data and accurately predicted sulfur hexafluoride (SF6) gas levels at four gas monitoring locations. One additional prediction model was simulated to consider a different scrubber discharge angle for the 100% redirected, equally divided case. These models identified relatively high gassy areas around the continuous miner which may not warrant their use in coal mines with medium to high methane liberation rates. This paper describes the methodology used to develop the CFD models, and the validation of the models based on experimental data.INTRODUCTION Methane gas and respirable dust are two hazards frequently encountered at continuous miner (CM) operations. An accumulation of both methane gas and coal dust may lead to massive explosions underground [1], and overexposure to respirable coal dust can result in pneumoconiosis (commonly referred to as “Black Lung Disease”) in coal workers [2]. Current U.S. federal coal mine regulations limit concentrations of methane gas to below 1% at the face area and require exposures to respirable coal dust to be at or less than 2.0 mg/m3 for an 8 h shift average. Begin on August 1, 2016; the overall respirable dust standard in coal mines is reduced from 2.0 to 1.5 mg/m3 for full shift sampling. If the quartz content of the dust exceeds 5% by weight, the dust standard becomes more stringent, reducing the allowable concentration to the value of 10 divided by the % quartz."

Jan 1, 2015

By Cristian Rodriquez, Fernando Fernandez, Rodrigo Fuentealba, Tom BoBo, Maria Rocha, John Kemeny

This paper describes a case study that was conducted at a new mine in South America. This mine has significant geologic variations that will result in different distributions of hard and soft ore being mined at different periods of time over the mine life. A study was conducted to determine the optimum blast design that will meet the mill throughput requirement of 95,000 tonnes (104,720 tons) per day for the first 10 years of the mine life. As part of this study, field rock mass characterization and laboratory tests were conducted. This includes standard rock mechanics tests as well as rock breakage tests used in mill simulations. The geology of the ore body was broken up into four Geologic Units, and statistical variations in the properties were determined for each unit. Using this data along with the data on the occurrence of the different geologic units over time, simulations were made of the run-of-mine (ROM) fragmentation due to different blast designs, and these results were used in simulating the resulting throughput after crushing and grinding. Four blast designs were considered with powder factors of 0.44, 0.54, 0.64 and 0.94 kg/t. The results of this study show that determining the proper blast design is important in ensuring that the mill throughput requirement will be met over the mine life.

Jan 1, 2015

By Ed McConaghy, P. LaRochelle

The Ambatovy Nickel Project comprises the development of mine, hydrometallurgical processing facilities and necessary infrastructure in Madagascar, positioning Ambatovy as one of the world’s largest producers of nickel and cobalt from lateritic ore. SNC-Lavalin successfully provided comprehensive Engineering, Procurement, Construction Management (EPCM) services for this major capital project which, apart from its sheer size, scope, and engineering design, represented significant location, infrastructure, labour, environmental and climatic challenges. Today, the project has reached 90% of its nameplate capacity and is in its final performance optimization stage. This paper will discuss the significant project management effort that was required to successfully address the complexity of this major project. It will cover the main project management control systems and the engineering tools and processes used during the detail engineering, procurement, and construction phases to achieve optimum project execution.

Jan 1, 2015

By E. C. de Beer

"SynopsisA number of important areas in nuclear fuel cycle, at both the front end and back end, offer ideal opportunities for the application of non-destructive evaluation techniques. These techniques do not only provide opportunities for non-invasive testing of e.g. irradiated materials, but also play an important role in the development of new materials in the nuclear sector. The advantage of penetrating radiation used as probe in the investigation and testing of nuclear materials makes X-ray and neutron radiography (2D) and tomography (3D) suitable for various applications in the total nuclear fuel cycle. The unique and different interaction modes of the two radiation probes with materials provide several opportunities. Their complementary nature and non-destructive character makes them most suitable for nuclear material analyses, analytical method development, and the evaluation of the performance of existing nuclear material compositions. This article gives an overview of the X-ray and neutron radiography/tomography applications in the field of nuclear material testing, and highlights a few of the success stories. Several selected areas of application in the nuclear fuel cycle are discussed to illustrate the complementary nature of these techniques as applied to nuclear materials.IntroductionDuring the development of new materials for the nuclear industry, materials testing and characterization are of the outmost importance to maintain safety standards and reliability. No compromise on safety in the workplace in any area within the total nuclear fuel cycle can be tolerated, and therefore most in-situ material characterization and testing is conducted by certified and qualified personnel schooled in destructive and non-destructive testing (DT and NDT) methods. Certification and qualification in NDT can be obtained through many training centres in South Africa in accordance with European, American, and other international standards (SGS, n.d.; SAIW, n.d.; African NTD Centre, n.d.)."

Jan 1, 2015

By H. Huang, R. N. Gow

"Previously, Gibbs’ phase rule was applied to mass-balanced EH-pH diagrams for the Cu-As-S-H2O system. Diagrams were generated using the stoichiometry of enargite as a basis. In this study, the calculations were expanded to cover the stoichiometries of three other Cu-As-S minerals (tennantite, sinnerite, and lautite) and compared to enargite. Stability regions within the resulting EH-pH diagrams were found to change with stoichiometry such that a particular mineral would predominate if its stoichiometry was used in the calculation. Solution speciation was also found to vary, with thioarsenate being the best example. This stoichiometric effect helps to explain results reported in the literature and would be difficult to realize if it were not for mass-balanced calculations. INTRODUCTION A comprehensive thermodynamic review has recently been conducted on the aqueous copper-arsenic-sulfur system (Gow et al., 2014a-d). The free energies of over 100 species were collected from various authors and thermodynamic databases to produce mass-balanced EH-pH diagrams, using the thermodynamic equilibrium calculation software, STABCAL (Huang, 2014). The full database was listed and discussed by Gow et al. (2014A). Resulting diagrams were generated for enargite and confirmed with Raman spectroscopy using bulk mineral electrodes in order to identify reactions spectroelectrochemically. Theoretical calculations agreed well with the experimental results under alkaline conditions (Gow et al., 2014a), acid conditions (Gow et al., 2014b), and alkaline sulfide leaching conditions (Gow et al., 2014c). In this study, additional mass-balanced EH-pH diagrams are generated by changing the copper-arsenic-sulfur stoichiometry from enargite (Cu3AsS4) to tennantite (Cu12As4S13), sinnerite (Cu6As4S9) and lautite (CuAsS). Regions for the thermodynamically stable species are shown to change with the four different mineral compositions. Potential leach conditions, both for co-dissolution and selective dissolution techniques, were examined for differences in predominant species according to changing copper-to-arsenic ratios, sulfur compositions, and sulfur oxidation states."

Jan 1, 2015

By M. Gimpel, R. Galler, T. Antretter, H. Kargl, R. Tichy, W. Ecker, M. J. Mikl-Resch, G. Pittino

"A computational method based on a continuum-mechanical approach to simulate rock cutting is developed and evaluated. The aim is to obtain the local loading acting at the cutting pick during operation. The explicit FEM is chosen to model the pick-rock interaction. The presented method takes advantage of (i) an advanced material model (ii) a robust contact algorithm and (iii) fast calculations due to parallelization. A damage-plasticity law is chosen and modified with user-subroutines. A user integrated element deletion routine evades critical mesh distortions. Infinite elements at the model boundaries avoid unrealistic deformation wave reflection.INTRODUCTIONExcavation in mining and tunneling is a costly and complex process. Special equipment such as the roadheader (Figure 1) is employed to cut the rock in the excavation process but high material strengths limit their usability (Tockner 1999). Nowadays a challenge is to extend their field of application to harder and more abrasive rock materials. The forces on the pick (Figure 2) are of great importance and determine wear and especially the efficiency of the machine. Figure 2 shows the principle of cutting and the predominant forces. The variation of pick geometry, cutting depth or attack angle will result in an alteration of these forces and determine the efficiency of the process (Tockner 1999). The mechanisms of rock cutting follow the principle of indentation (Kou et al. 1999). Directly under the indenter a hydrostatic stress state evolves causing the material to fail only due to crushing and fragmentation mechanisms. In the close surroundings large strains emerge and tensile cracks are formed but in a further distance the material behaves elastically."

Jan 1, 2015

By J. Arzúa, L. R. Alejano, P. Rodríguez

"After six years of successful excavation with a support pattern, some roof failures have happened in a room-and-pillar underground mine excavated in a stratified rock mass. In this paper the authors give explanation to the failure mechanisms and redesign the support in order to solve the recent problems of roof collapse.The mine magnesite bed is approximately 14 m thick, and runs in the E-W direction with an average dip of 18º. Due to mine constraints and the inexpensiveness of the ore, the excavation is performed in the mineral itself, avoiding the need for mining dumps and waste excavation. Rooms and drifts are oriented in the mineral bed to form an angle of 19º to the direction of the strata, reducing the roadway gradients to less than 10%. Rooms are 11 m wide and pillars are 7 m wide. They are designed to leave a 1 meter thick magnesite bed in the roof of the rooms to act as a supporting beam. More often than not there is a layer of very poor quality marly shale up to 1 m thick resting on this magnesite beam. Overlying the poor quality marly shale there is a better quality, self-supporting sandy shale.First, a characterization of the involved rock masses (magnesite, marly shale and sandy shale) is performed, collecting the geotechnical data from previous studies and performing new in situ geotechnical surveys to check the soundness of the previous data. A distinction is made between different quality zones inside the mine by means of the RMR classification, associated to the occurrence of faults.Back-analysis of some of the failed rooms and data from exploration boreholes were used to determine the failure mechanisms (associated to Voussoir type failure or occurrence of sub-horizontal joints crossing the magnesite beam). Based on an understanding of these mechanisms, the method used to design the support and to analyse the stability of the different possible thicknesses of the magnesite beams of the rooms and drifts of the mine were improved.Numerical models of the most relevant conditions found in the mine were performed in order to better understand the behaviour of the roofs and to simulate the supporting solution obtained in the previous analyses.The most relevant conclusions with regard to the main elements causing the instability of the roof include the appearance of sub-horizontal discontinuities crossing the magnesite bed, which causes total instability of the roof and usually leads to collapse; excessive thinness of the magnesite beam in the problematic rooms; and the relaxation of the deepest (around 270 m in depth) zone of the mine because of existing faults."

Jan 1, 2015

By Weihua Song, Hongwei Zhang, Feng Zhu, Sheng Li, Guoshui Tang

"Rock burst is one of the most serious dynamic disasters in coal mining. Rock burst prevention involves two difficult tasks: systematically evaluating the occurrence conditions and effectively forecast for rock burst. This paper systematically studies the effects of natural geological dynamic conditions and mining engineering on and forecast for rock burst. It establishes the evaluation method and index system of rock burst geological dynamic conditions and proposes a method of forecasting rock bursts by monitoring fault activity with anchor cables. Natural geological dynamic conditions are a necessary condition while mining engineering is a sufficient condition for the occurrence of rock bursts. Rock bursts in mine must have suitable geological dynamic conditions, and mining engineering activity is merely an inducing factor. There is a good correlation between anchor cable stress variation and fault activity, when the anchor cable dynamometer indicates that the fault is active. It can forecast a rock burst a few days in advance. This technique has been successfully applied to Panel 83003 of a coal mine in China, which improved the safety production level of the mine and found a new way of rock burst evaluation and prediction.INTRODUCTIONRock burst is one of the most serious dynamic disasters in coal mining. With the increase of mining depth, rock burst disaster is becoming more and more serious. Systematically evaluation and effective forecasting of the occurrence of rock burst in the coal mines are important and difficult work in the control of rock bursts. Chinese researchers have performed numerous researches on rock bursts, Qi et al., established the rock burst model of frictional sliding instability, explained the occurrence mechanism of rock bursts by stick-slip phenomenon in frictional sliding, gave full consideration to the influence of primary rock stress and mining-induced stress on rock burst occurrence, and proposed the stress controlling theory of rock burst. Pan et al., [3] put forward the criterion of perturbation response, explained and analyzed the problem of rock burst in circular openings, put forward the ratio of coal-rock elastic modulus and reduced modulus is the significant parameters for the determination of stabilization; systematically summarized the rock burst distribution, type, mechanism and control in China. They classified rock bursts into three types: coal compression, roof fracture and fault movement. By applying energy transfer principle and conservation of energy, combined with the analysis of the weakening of rock fabric damage, Zhou and Jiang put forward the theory and equation for the occurrence of coal-rock mass impact effect. They analyzed and discussed the formation mechanism of rock burst by combining impact effect theory and energy equation. Wang et al., recognized that the mechanism of rock burst which induced by fault, fold and phase transition is the superposition of tectonic stress and mining stress and that the axes of syncline and anticline and their flanks are the location where rock bursts mostly occur. To prevent stress superposition is the efficient way to control the structural rock burst [7]. Jiang et al., summarized the research achievement of rock burst mechanism and controlling techniques and existing problems in recent years in China, and pointed out the direction to improve the level of prevention of controlling rock bursts in coal mines."

Jan 1, 2015

By S. Gheibi, H. S. B. Duzgun, N. Dadashzadeh

It is widely recognized that there are various uncertainties in the analysis of rock slope stability owing to inadequate information for site characterization and inherent variability and measurement errors in geological and corresponding parameters. Therefore, reliability-based approaches that allow the systematic and quantitative treatment of these uncertainties have become a topic of increasing interest in rock slope engineering. There has been extensive reliability analysis of rock slope stability in the literature. However, all of these analyses are based on the First-Order Reliability Method (FORM). The probability of failure of a rock slope in the First-Order Reliability Method is provided by a linear approximation of the failure function. The FORM is most commonly used because it is efficient; its accuracy, however, deteriorates when the nonlinearity of limit-state function increases. A better approximation of the failure function can establish a more accurate value of the probability of failure. The Second-Order Reliability Method (SORM) overcomes this drawback with a cost of lower efficiency in terms of the number of function calls and computation expenses. Despite considerable studies of the application of the SORM in other engineering fields, a few attempts have been made in the slope stability studies. In this study, a recently published Second-Order Reliability Method with First-Order Efficiency (SORM-FOE) is implemented on a selected rock slope in Amasya, Turkey. The SORM-FOE overcomes the low efficiency of the SORM by decreasing the number of function calls. The probability of failure of both FORM and SORM-FOE are obtained and the results are compared. It is shown that, in high value of failure probability, SORM’s do not significantly affect the analysis and design. However, in very low failure probability, the discrepancy between FORM and SORM-FOE becomes pronounced. It is also shown that, where the second order methods are required, the SORM-FOE is more efficient than the conventional curvature fitting methods in terms of computational costs.

Jan 1, 2015

By Tanai Marin

Modelling of pyrometallurgical processes can become extremely challenging when the process involves complex chemical reactions, phase change, multiphase flows, heat and mass transfer and fluid flow. Traditionally modelling involving complex thermodynamic equilibrium and thermochemistry are treated separately from problems in which transport phenomena are dominant, such as CFD and heat transfer studies. The separation is also necessary due to the lack of modelling tools that can effectively couple both solution thermodynamic and transport phenomena or even multiphysics problems. However, there are, quite often, problems in high temperature process metallurgy in which it is not possible to simplify this two modelling approaches. Typical cases of this are for example, the modelling of slag freezing on furnace walls (electric or flash furnaces) to create a protective layer in front of the refractories hot wall, the formation of build up from the matte or metal phases at the hearth of the furnace, calcine smelting from charging piles into slag phase, etc. The problem is even more challenging in nonferrous pyrometallurgy as most, if not all, of the condense phases are highly non ideal solutions involving several components and exhibiting complex crystallization paths and miscibility gaps, such as the Fe-Ni-Cu-S matte, FeO-Fe2O3-SiO2, FeO-MgO-SiO2 slags, etc. In this paper, an approach to model coupled problems involving multiphysics and solution thermodynamic is presented. The approach consists in developing in-house a library containing the Gibbs energy minimization routines and using the local equilibrium concept for process modelling from a multiphysics commercial software (COMSOL). Simple test cases, such as building a non-ideal binary phase diagram on a CFD package is presented, the limitations and of other classic approaches such as equilibrium or Scheil cooling are discussed and compared to this model.

Jan 1, 2015

By Pedro Pablo Vasquez Coronado, Victor Octavio Tenorio

"Productivity in openpit mines depends on the observation and adjustment of critical phases of operation. As one of the most expensive activities in openpit production, optimization of the load-haul-dump cycle becomes a critical aspect to address. Using simulation techniques and an ad hoc methodology for analyzing the key performance indicators (KPIs) involved in the production cycle, it is possible to compare actual performance and ideal operating conditions and develop an alert system when operating conditions are subpar with the expected production standards.Study objectivesThe purpose of this work is to implement a methodology for optimizing the haulage cycle by identifying and adjusting the factors that affect the cycle time performance. The methodology includes the implementation of an alert system emitting warning messages when one or several trucks are idle, or when the time of completing production tasks is falling outside a predefined value. This alert is compared with predefined KPIs and is used to determine corrective actions.The alert will:• Demonstrate the benefits of time analysis and how this affects the productivity results in the mining process.• Demonstrate the utility of KPIs in the extraction of ore and waste and how they help to identify equipment performance.• Develop software interfaces to visualize the alert system in order to increase awareness in the operations supervisor.• Make recommendations for future applications that can help improve the productive process of an openpit mine.Problem statementTransporting material in openpit mines may require the utilization of high capacity equipment, which also represents an elevated cost per hour. A supervisory system that controls the adequate distribution of trucks and shovels by providing the operational status of each unit shall contribute to increase productivity while subsequently reducing operational costs. Nevertheless, there is an issue with certain dead times such as queue trucks for loading, trucks waiting to be loaded and other delays. This creates inefficiencies in fuel consumption and energy utilization.For the identification of delays, a contextbased system could be required in order to help optimize the haulage cycle time by controlling delays in loading, haulage and dumping. After applying this methodology, efforts were focused in correcting out-of-standard performance values."

Jan 1, 2015

By D. Yuan, M. Sitter, S. St. Jean, M. Collins

The Ambatovy Joint Venture comprises an operating lateritic nickel mine, ore slurry pipeline, pressure acid leach plant and nickel refinery in Madagascar. The hydrometallurgical process selected by Sherritt for treatment of the Ambatovy ore is a long-term, sustainable approach to producing nickel. Sulphur, used to prepare hydrogen sulphide, which is used to produce mixed sulphide intermediate, is recovered in the refinery as ammonium sulphate fertilizer. Additional sulphur is used to generate sulphuric acid for treatment of the ore in the high pressure acid leach (HPAL) step; fossil fuel consumption is minimized by using the heat generated from the exothermic reaction between sulphur and oxygen in the acid plant to produce power and steam. Steam consumption is minimized by design of efficient flashing and preheat systems for HPAL, while the high temperature of the HPAL step serves to minimize acid consumption. Fossil fuel consumption by the operation as a whole is further minimized by locating the leach plant and refinery near the port of Toamasina and utilizing a 220 km slurry pipeline to transport ore from the mine to the leach plant. In addition, Ambatovy has demonstrated a strong commitment to sustainability programs such as the biodiversity management program at the mine and local procurement in Madagascar. In this paper, the hydrometallurgical process for nickel and cobalt recovery from Ambatovy ore is described, along with highlights of Ambatovy’s approach to sustainability in Madagascar.

Jan 1, 2015

By J. A. Halt, E. Larsen

"The Sydvaranger magnetite mine closed in 1996 due to low iron ore prices and was reopened in 2009. The flowsheet has remained more or less as in the old plant, based upon two grinding steps followed by magnetic separation. The magnetite is free of harmful elements and should be attractive on the high quality market. This requires a concentrate containing less than 2% SiO2, which previously was achieved by amine flotation. Amine was preferred because it could be used with sea water. The use of amine is now restricted by the Norwegian Climate and Pollution Agency. Therefore, testwork to replace cationic with anionic flotation was done. Activation of quartz with Ca or Mg ions prior to anionic flotation was shown by research from 1960 to 1980 to be effective under laboratory conditions. The old research results have been followed up in order to make a commercial process for Sydvaranger. Calcium activation works excellently with all Sydvaranger ores, including the ones containing amphibole minerals, but Ca activation requires the high and not environmentally friendly pH of 12.4. Magnesium activation at pH 10.5 is a little more challenging, because the maximum concentration of MgOH+ is about 100 times lower than that of CaOH+. Fortunately, the major impurity in the main Bjornevatn orebody is quartz, which responds well to Mg activation. The process does not appear to depend much upon water quality, as the silicates may already be activated during grinding and magnetic separation in recycled water. The new process is environmentally friendly, as only well-known household reagents are used; oleic acid or tall oil, dextrin, sodium hydroxide and magnesium chloride at pH 10.5.IntroductionThe processing plant of Sydvaranger Gruve AS (SVG) is located in the port town of Kirkenes in the northernmost part of Norway, 10 km by rail from the high-grade deposit of Bjornevatn. This plant has been able to beneficiate magnetite ore to up to 99.5% purity, as described by Sandvik and Malvik (2001). Using the magnetic properties of the ore and making the most out of its enviable liberation characteristics, the original plant consisted of ball mills and 600-mm magnetic separators. The plant was shut down due to market conditions in 1996 but reopened in 2009."

Jan 1, 2015

By M. Ramachandran, R. G. Reddy

"A direct route for the reduction of magnesium oxide to magnesium using thermal plasma processing, with methane as the reducing gas, has been systematically evaluated. A feasibility study of the reduction reaction has been performed on the MgO-CH4 system at different methane concentrations and temperatures. The effects of changes in the key process parameters, such as the oxide-to-methane ratio and plasma power, on the yield of magnesium have been systematically evaluated. A maximum yield of about 61 mol% Mg was obtained using power of 20.0 kW and a molar ratio of MgO:CH4=1:1. Phase, morphological, elemental and binding energy analyses were performed on the product powders to understand the reduction reaction. Surface oxidation was observed in smaller magnesium particles in all the experiments, while the in-situ sintering of magnesium rods was observed at a molar ratio of MgO:CH4=1:1.5. Magnesium carbide (Mg2C3) was observed in the product, and its mechanism of formation is proposed using phase equilibrium data and a predominance diagram.IntroductionMagnesium has an excellent combination of low density and high strength. These properties have increased worldwide demand for and use of magnesium. Two major processes are used in the commercial synthesis of magnesium metal. The first method is electrolytic reduction and the second is thermal reduction using Pidgeon process. These processes can be classified as traditional techniques, but there are numerous emerging technologies that aim at reducing the production cost of Mg, its environmental impact and energy consumption. Thermal plasma processing is one emerging technique that has great potential in all the abovementioned key areas of magnesium production.Traditional reduction techniques. Two major reduction techniques, namely electrolytic and thermal reduction, have been used in the commercial production of magnesium. Electrolytic reduction is typically carried out in electrolytic cells from magnesium chloride (obtained from seawater or well and lake brines) (Tripp, 2009). The following simplified reaction shows the reduction of magnesium chloride to liquid magnesium and chlorine gas:"

Jan 1, 2015

By Marc-André Villiard, C. St-Onge, V. Silla, J-C Milot

Rio Tinto Fer et Titane (RTFT) operates a metallurgical complex in Sorel-Tracey, Canada. In the Ore Preparation Plant (OPP), ilmenite ore is roasted through four parallel rotary kilns generating 95% of the plant wide sulphur dioxide (SO2) emissions. RTFT proactively set an annual emission cap for SO2 to be achieved by 2015. To achieve this targeted SO2 reductions, a technology evaluation and selection exercise was carried out, followed by detailed engineering and implementation. After a detailed evaluation of SO2 scrubbing technologies, the Circulating Dry Scrubber (CDS) system was selected as the most appropriate desulphurization system for this application. The system was implemented and commissioned from 2013 to 2015. General performance testing conducted in May 2015 demonstrated that the system achieved and surpassed the anticipated design values in terms of SO2 removal efficiency and hydrated lime utilisation. This paper summarizes the SO2 technology selection process, design features of the selected technology, project implementation and final performance testing of the SO2 abatement system.

Jan 1, 2015

"A numerical procedure based on Smoothed Particle Hydrodynamics (SPH) is developed for rock blasting phenomena involving multiple intersecting joints. In this procedure, an elasto-plastic damage constitutive model has been applied in the framework of SPH to simulate yielding response of the surrounding rock medium. In this paper, a square shape rock medium with centrally located emulsion explosive in a borehole is numerically blasted with and without the presence of two diagonal rock joints. The model is simulated by assuming all four sides of the rock medium as free surfaces. The paper elaborates the propagation of stress wave, expansion dynamics of gaseous products, and development of fracture, fragmentation of the medium and dissipation of energy due to damage.INTRODUCTIONDamage prediction of rock mass and its mean fragmentation size are of important to design blast parameters for a given explosive. Current blasting practice solely depends on empirical relationships between fragmentation sizes to those blast design parameters while mathematical descriptions of the physical laws governing the process of rock blasting are limited. A constitutive relationship based on properties of explosives and rock mass is of special interest because of its capabilities in describing the key features of rock fracture and fragmentation, resulting in understanding of the physical process involved in rock blasting. It is well known that blast-induced damage and fragmentation of rock mass occur due to detonation induced stress wave and product gas driven fracture propagation. Nevertheless, the fundamental mechanism of the failure process and the behavior of rock characteristics under these two different loading are not well understood in many cases, which are closely related to growth of fractures and interaction of cracks under different loading conditions.Continuum damage mechanics is considered to be appropriate to describe the failure process under such high-amplitude stress wave. Based on this approach, several theoretical models have been developed to analyze the dynamic damage of brittle material such as rock and concrete with microstructure (Chen, 1999; Taylor et al., 1986; Wu et al., 2004; Yazdchi et al., 1996). These models are mostly based on the theory of damage mechanics or fracture mechanics with some statistical treatment to incorporate random distribution of microcracks. In the application of fracture mechanics theory, sometimes it is difficult to estimate the micromechanical parameters such as crack density and fracture toughness in different modes. In this study, damage in rock material is evaluated according to the earlier model developed by Grady and Kipp (1980), which is a fracture model coupled with a material description for stress wave propagation to predict quantitatively fracture and fragmentation under explosive loading conditions."

Jan 1, 2015

By Xueyuan Nie, Xuezhi Zhang, Henry Hu, Shen Xinwei, Jimi Tjong, Li Fang

With the demand for weight reduction in vehicles and airplanes, researchers have shown great interested in casting wrought aluminum alloy 7075 because of its potential advantages such as high strength-to-density ratio and stress-reduction capabilities. It is therefore essential to conduct a fundamental investigation on solidification behavior and grain microstructure of alloy 7075. In this study, a commercially-available wrought aluminum alloy 7075 was used to study the solidification behavior of alloy 7075. A thermal analysis was performed based on the cooling curve and its corresponding first and second derivative curves. The nucleation of the primary a-Al phase and eutectic phases were analyzed. The comparison between the microstructures of the wrought and cast 7075 alloys shows that coarse microstructure and porosity are present in the cast alloy. The techniques for grain refinement in casting, such as the addition of the nucleating particles and applied pressure, should be employed to reduce the dendrite arm spacing and the porosity.

Jan 1, 2015

By Jay P. Tobin

This paper will address the legal standards applicable to construction blasting lawsuits and offer best practices suggestions for pre-blast inspections, documenting the construction blasting work, recordkeeping, and effectively participating and partnering in the defense of a construction blasting lawsuit.

Jan 1, 2015

By P. James

"INTRODUCTION Dissolved salts build up in leach solutions over time as leach solutions mature. Iron can be particularly problematic for hydrometallurgical copper production as it can compete with copper for separation during solvent extraction (SX), leading to iron bleed through and reduced electrowinning (EW) efficiency. In its ferric form (Fe+3) it precipitates as a hydroxide at fairly low pH and can promote clogging and disrupted flow within leach pads as a result of localized pH deviations – such as might result from weather events. The solids formed can cause relatively irreversible degradation to pad productivity. The precipitation pH point for solids formation falls as the ferric (Fe+3) concentration increases, making the issue more prevalent as leach circuits for ore bodies containing appreciable iron get older. It can also be more of a concern when leaching lower grade ore like tailings where lower copper content may increase iron/copper ratios which may increase iron accumulation rates. The precipitation pH point for solids formation falls as the ferric (Fe+3) concentration increases, making the issue more prevalent as leach circuits for ore bodies containing appreciable iron get older. It can also be more of a concern when leaching lower grade ore like tailings where lower copper content may increase iron/copper ratios which may increase iron accumulation rates. Control of ferric (Fe+3) levels could be used to lower ferric (Fe+3) levels and keep the ferric hydroxide [Fe(OH)3] precipitation pH sufficiently high to avoid the associated solids formation and potential leach pad occlusion. Control of ferric (Fe+3) and ferrous (Fe+2) tenors and ratios may also provide benefit for improving sulfide ore leaching or bioleaching performance and effectiveness. Traditionally options for such control were rather limited with bleeding contaminants off or chemical dosing treatments being prominent methods. Now Blue Planet Strategies introduces a new option. Blue Planet Strategies (BPS) focuses on improved resource utilization targeting electrolytic treatment and waste conversion into resources and has now demonstrated that its proprietary DeMet™ (Dynamic Electrolytic Metal Effluent Treatment) platform is highly effective at efficient low-cost conversion and control of iron content in leach streams in addition to targeted dilute metal recovery.[1-6] This powerful new capability provides a new treatment opportunity to control leach solution ferric (Fe+3) and ferrous (Fe+2) tenors to enhance leach operation production."

Jan 1, 2015