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By Mark K. Larson, Douglas R. Tesarik, Heather E. Lawson

"Load transfer distance (LTD) is simple in concept and usually evident in underground coal mines. Many people in the mining industry recognize LTD as the distance from the panel to where the mine ribs and pillars show evidence of renewed spalling, floor heave, or other effects of increased weight due to longwall mining or pillaring. Barrier pillars, in particular, are designed to shield mains and other relatively permanent facilities from this loading. LTD is also important in determining the extent and degree to which mining increases the load on pillars and ribs in the gate roads. Generally, a long LTD reduces loads in gate roads, but may require larger barrier pillar widths to protect mains or adjacent panels from excessive loads. Therefore, a long LTD may make it easy or difficult to meet various objectives of mine layout design . LTD reflects overburden geology in two ways: First, overburden that is weak and readily caves will limit both the amount and distance of load transfer. Second, stronger, stiffer, sandier, and more massive overburden increases both the amount and distance of load transfer. As such, LTD is central to coal mine layout design and calibration of numerical models that seek to anticipate these transfers of load during mining. However, the term does not have a consistent definition in the literature, and various instruments and observational techniques with varying sensitivities and thresholds have been used to indicate the onset of mining-induced stress increase and, subsequently, to determine an LTD. Consistency is important for meaningful comparison of ground response between mining sites and for accurate calibration of models.This paper adds to the body of observed and reported LTDs by presenting cases with relatively sandy and massive overburden at two western coal mines. These two cases include observation and measurement of LTD with multiple methods and provide insight into how distances reported relative to different criteria and instrumentation could be adjusted for comparison against a common base. This base is the criteria used by Peng and Chiang (1984) to determine their empirical equation. In one of these two cases, LTD was recently measured at a western U.S. coal mine (Mine A) to be approximately four times that calculated using the Peng and Chiang empirical equation. LTD measurements were examined using various instruments at Mine A and at adjacent Mine B. The measurements at Mine B showed that LTD was significantly greater than that calculated by the Peng and Chiang equation. Difficulties with BPC installation and fittings at Mine B permitted only ranges of LTD to be determined from some BPCs. Even so, the LTDs and ranges of LTDs determined were consistent with the LTDs determined at Mine A."

Jan 1, 2015

By R. Woods

"Comments on the paper ""Formation of hydrogen peroxide by chalcopyrite and its influence on flotation,""by A. Javadi Nooshabadi and K. Hanumantha Rao (Minerals & Metallurgical Processing, 2013, Vol. 30,No. 4, pp. 212-219)The formation of hydrogen peroxide from water during the grinding of chalcopyrite in a nitrogen-sparged environment, as reported by Javadi Nooshabadi and Rao (Minerals & Metallurgical Processing, 2013, Vol. 30, No. 4, pp. 212-219), is questioned on the grounds that oxidation of water by the mineral is unlikely to be thermodynamically feasible. It is argued that it is more likely that any peroxide that had been formed would have been generated from residual oxygen in the nitrogen-flushed system than from the oxidation of water.The formation of hydrogen peroxide by finely divided pyrite had been reported by a number of authors (Borda et al., 2001; Borda et al., 2003; Cohn et al., 2006; Schoonen et al., 2006; Schoonen et al., 2010; Jones et al., 2011; Javadi Nooshabadi et al., 2013). That hydrogen peroxide is formed in the presence of oxygen in solution can be comprehended from wellestablished mechanisms. Pyrite in aerated solution is known to oxidize by an anodic process that is coupled with the cathodic reduction of oxygen (Holmes and Crundwell, 2000). The latter process has been shown to occur through the formation of hydrogen peroxide (Biegler et al., 1975; Ahlberg and Broo, 1996). The pH dependence of cathodic oxygen reduction at other sulfide minerals, including chalcopyrite (Biegler et al., 1977; Rand, 1977), implies a similar mechanism at these surfaces."

Jan 1, 2015

By M. Noppé

"Dilution in underground coal operations can be underestimated by up to five times during Feasibility Studies, with disastrous economic consequences. Every 1% of stone waste introduced can reduce an in situ specific energy of 11,000 BTU/lb (25 MJ/kg) by some 110 BTU/lb (0.25 MJ/kg) and increases the abrasiveness of the run-of-mine coal. Where a wash plant is not in place, penalties imposed for not meeting contractual specifications alone can amount to some AU$1 million per year.This paper presents a method for monitoring, reporting and ultimately controlling dilution in an underground coal mining operation. The dilution trends before and after introducing the recommended controls in a continuous miner/longwall mine are presented over an eight year period. The additional information from such a dilution monitoring program can also be used to control mining horizons and plan longwall extraction heights across the face proactively, on a short-term scale with resulting improvements in productivity. INTRODUCTION Grade control, as practiced on any mine, is concerned with predicting routine quality and tonnage values for short- to medium-term mining operations, and the reconciliation of these predictions against “actual” results. For a longwall mine supplying steam coal, such routine parameters may include the proximate analyses, specific energy (SE), abrasiveness and sulphur, as well as float and sink analyses if the coal is beneficiated. In addition, grade control is concerned with identifying the mineable horizon (or horizons) in a selective-mining operation, together with monitoring how well these horizons have been extracted or adhered to. Close-spaced surface drilling can be costly for any mining venture, particularly for longwall mines operating in the deeper seams. For this reason, much of the data for short-term grade control requirements are acquired during actual bord-and-pillar development. The underground data are derived from so-called “channel” samples. These samples are cut or chipped from the coal seam, perpendicular to the mining horizon, with dimensions suitable for obtaining sufficient “representative” sample for analyses. For a 2m thick mining horizon, a channel sample 300 mm wide and 50 mm deep over the thickness of the horizon would provide some 4.5 kg of sample, sufficient for most of the necessary tests. To allow the information to be computer recorded, additional information such as seam thickness, sample co-ordinates, and the elevation of the seam (or horizon) roof or floor, may be required."

Jan 1, 2015

By H. Wen, X. Zhai

"The Jurassic coal fields which lay in west China are the major energy base and contain half of coal resources in China. Due to the gather and degeneration rules, the spontaneous combustion characteristic of Jurassic coal is distinguished with permo-carboniferous coal, which needs to be studied deeply. Programmed heating experiments of five Jurassic coal samples and three permo-carboniferous coal samples from different primal coal fields in West China were conducted to identify the characteristic parameters in the low temperature stage of oxidation and spontaneous combustion. The experiments were carried out under non-isothermal heating conditions up to 180? at the heating rate of 0.33?/min in an air atmosphere. The result showed that oxygen consumption rate, CO gas production rate and heating intensity of all coal samples increased with the rising of the temperature, which of the Jurassic coal was higher than that of Permian-carboniferous coal. The C2H4 gas of Jurassic coal generated earlier, more than that of Permian-carboniferous coal in the process of oxidation and spontaneous combustion. It indicated that the Jurassic coal was easier to be oxidized and spontaneous combustion and the index parameters of spontaneous combustion were different between the Jurassic coal and permo-carboniferous coal.INTRODUCTION Coal was the foundation of industry development, and occupied 70% of primary energy production and consumption structure in China. According to the data of the 3rd coalfield prediction, 39.6% of the total coal resources were located in northwest Jurassic coal field in China [1], where the quality of coal was excellent. The study of northwest Jurassic coal already dated from the 80s of the 20th century, about coal rock composition, coal metamorphism [2], coal-derived hydrocarbons, coal structure [3], etc. The results of these studies showed that the composition and properties of Jurassic coal was obviously different from Permian-carboniferous coal, as well as the characteristic of spontaneous combustion [4]. As a result, the spontaneous combustion characteristic of Jurassic coal particularly needed to be studied. Now more and more methods could be conducted to test the characteristics of coal spontaneous combustion, for example, thermal analysis technology [5-7], programmed heating experiment [8-10] and coal spontaneous combustion experiment [11,12]. In these methods, programmed heating experiment could be conducted to determine the oxygen consumption rate, CO gas production rate and heating intensity quickly."

Jan 1, 2015

By DuPont Magazine

RBH Note: as stated many times in these articles, frozen dynamite was one of the greatest hazards facing the blaster. It wasn’t until the late 1920s that it was solved for good, with the introduction of nitrated ethylene glycol as a partial replacement for nitroglycerin in dynamites. The du Pont low freezing dynamites contained TNT, DNT, or nitro-substitution compounds of various sorts.

Jan 1, 2015

By Z. Abbasloo, A. Masoomi, L. Ebrahimi, A. Mortazavi, A. Keshavarz

"Investigation and 3D analysis of Heap no. 2 of Meydook copper complex was the subject of this study. In this project all geological and geotechnical investigations conducted in the mine were evaluated aiming at determination of Heap no. 2 design parameters. The main objective of the project was to evaluate the potential for construction of Heap. No. 2 on a waste dump built in a valley in the north side of the pit.Considering the space limitation for dump location this was a viable alternative to reduce the costs associated with heap no. 2 construction. Moreover, it allowed for a significant reduction in overall mining costs. Considering the project condition, a 3D analysis of heap major structures including; valley rock foundation, waste dump, and low grade ore was carried out. Five sets of analyses were conducted and the displacement and stress fields were calculated within the heap no. 2 components. In all analyses conducted the subsident profile was determined for the valley base rock and heap foundation (waste dump). Moreover, the shear interaction between heap and waste dump was evaluated at the heap interface. The analyses results showed that the maximum settlement at the heap base is about 4-5 cm and the waste dump provides a safe and reliable base for heap construction. Moreover, the analysis results showed that the selected %5 grade for the heap interface is good and does not pose any risk in terms of heap Interface shear displacements. A sensitivity analysis of heap mechanical parameters was also conducted. The obtained results show that if the friction angle of heap material is reduced below 25 degree due to acid spraying process, the heap walls become unstable and the heap geometry must be redesigned."

Jan 1, 2015

By J. Boisvert, E. Daniels, C. Deutsch

"INTRODUCTION Conventional mine planning is performed on a single resource model at a selective mining unit (SMU) scale deemed appropriate for the deposit and mining method. Estimation methods such as kriging and inverse distance, commonly used to construct a single model, are susceptible to histogram smoothing (Rossi & Deutsch, 2014). This can be mitigated by limiting the number of composites per estimate, therefore correctly reproducing the distribution of estimates (Boisvert & Deutsch, 2012). Search limiting techniques remedy histogram smoothing at the cost of introducing a problematic conditional bias (Isaaks, 1999) and introduces even greater spatial smoothing. Localization is an alternative, offering histogram reproduction through post processing of more robust probabilistic modeling techniques. A single localized model at the SMU scale is desirable. The correct histogram can be reproduced and a single model allows for the use of conventional mine planning and resource evaluation techniques. Despite the advertized benefits of localization, the necessary reliance on a larger panel scale as a middle step in the localization process yields unsightly “edge-effect” artifacts (Boisvert & Deutsch, 2012). Two approaches to artifact reduction are presented here. The first is a straight forward optimization approach designed to minimize an objective function that penalizes artifacts including panel edge discontinuities to generate a model free of panel edge-effects. The second approach redefines a panel in a less conventional fashion as a randomly chosen set of SMUs throughout the domain. This method produces a model void of any regular panel shape resulting in an artifact free model. Artifact reduction minimizes the obvious “edge-effect” issues of localization but local precision issues described by Boisvert & Deutsch (2012) persist. Localization is not a replacement for quantified uncertainty for comprehensive risk analysis and resource evaluation. LOCALIZATION Initially developed with Uniform Conditioning in mind, localization collapses a distribution of local uncertainty at a panel scale to an SMU scale model for mine planning (Abzalov, 2006). This process has been extended to Indicator Kriging (Hardke, 2011), Sequential Gaussian Simulation (Boisvert & Deutsch, 2012) and MultiGaussian Kriging (Daniels and Deutsch, 2014). The localization process is performed in a similar fashion regardless of which technique is chosen to create the prior model of uncertainty. Methodology There are three scales of importance considered in the localization process. The point scale, otherwise known as the data scale, is the smallest and is the scale at which experimental data is collected. The SMU or block scale is the familiar scale at which mine planning and resource evaluation takes place. Lastly, the panel scale is larger and contains a number of SMUs. Each of the three scales is illustrated in Figure 1."

Jan 1, 2015

By J. M. Ekenes, C. A. Caro

"New approaches that increase hydrometallurgical recovery from refractory minerals in below mill cutoff -grade sulfide copper ore can add significant value, improve profitability and increase ore reserves. This paper describes the development and implementation of an engineered heap (EH) approach to leaching low-grade, chalcopyritebearing ore at Freeport-McMoRan’s mine in Morenci, AZ. The technical evolution of the engineered heap concept is described together with the challenges and benefits following implementation. Introduction The Morenci ore deposit, located in eastern Arizona, has been mined for copper for 140 years. Mineralization in the Morenci district consists of sulfides and oxides. To process these ores, Morenci operates concentrator and leaching circuits. Leaching accounts for two-thirds of the copper produced in Morenci. More than one-half of this leaching-derived copper production comes from run-of-mine (ROM) stockpiles. The largest category of material moved in Morenci is destined for ROM stockpiles and waste dumps. Materials that are not economic to mill or leach are designated “waste.” However, this designation can change based on improvements in extraction technology and commodity prices. Chalcopyrite does not leach well due to its refractory nature. For predominant chalcopyrite mineralized ore, copper recovery during a typical leaching cycle may be as low as 5%. For this reason, chalcopyritedominant ores below mill cutoff grade have historically been classified as waste. By incorporating advanced leaching technology to improve metal recovery from previously leach-resistant ore types such as chalcopyrite, the Morenci Mine has been able to reclassify substantial amounts of this “waste” to “ore.” Process chemistry Chalcopyrite copper extraction is temperature, oxygen and ferric dependent. The temperature is achieved primarily by pyrite oxidation (Eq. (1)) and secondarily by oxidation of chalcopyrite itself (Eq. (2)). The regeneration of ferric in solution can be enhanced by providing the appropriate acid and oxygen levels according to Eq. (3). In the absence of microorganisms, this reaction is very slow."

Jan 1, 2015

By J. Finch, Wei Zhang

In this paper we describe the synthesis of a new homologous series of linear Polyglycol-based frothers that consist of Ethylene Oxide (EO) and hydroxyl as hydrophilic groups and Propylene Oxide (PO) and alkyl chains as hydrophobic groups. The synthesized frothers were of two types: Alkyl-Ethoxy-Propoxylate (abbrev. CnEOlPOm) and Alkyl-Propoxy-Ethoxylate (CnPOmEOl) giving: (a) different number of groups and chain length, and (b) different locations of the groups. The identities were confirmed by proton nuclear magnetic resonance (NMR) spectroscopy and total organic carbon (TOC) analysis. The characterization of the products was carried out in a bubble column. At steady state, bubble size, gas holdup and water overflow rate were measured as a function of frother concentration. The results indicate that increasing number of PO groups led to significant decrease in bubble size, and increase in gas holdup and water overflow rate. Increasing the alkyl chain length, gave similar but less pronounced trends. There was no impact of increasing the number of EO groups on bubble size but there was an in increase in gas holdup and water overflow rate. Changing the location of the PO and EO group had a significant effect on all three parameters.

Jan 1, 2015

By Nicolas Gatelier, Sophie Laurent, Thierry You

Hard-rock caverns for hydrocarbon storage are a very particular type of underground facility controlled not only by local administrative and regulatory constraints that can be very specific, but also by the possible risks of geotechnical or geomechanical failure. Each such facility throughout the world is a prototype that needs to be adapted to very different site conditions. The straight forward application of design methodologies from relatively similar fields (mines, tunnels) can be very useful, but risks holding back the scientific and technical improvements needed by an engineering industry in full development. Here we look at various case histories and at problems that have been raised where recent attempts at standardization would appear to have been ill adapted, and where storage designers, through experience and judgment, may still provide innovative engineering solutions.

Jan 1, 2015

By Paul Worsey, Matthew K. Coy

New blasting mat designs are currently tested in the field on actual blasting jobs and only undergo qualitative rather than quantitative assessment. The majority of matted blasting occurs in trenching in which the blast designs and field conditions vary considerably. In order to assess a new blasting mat material and design, a new standard test was devised.

Jan 1, 2015

By M. Muinonen, R. Pandher

Royal Nickel Corporation is developing the Dumont Nickel Project, a large nickel sulphide deposit located near the town of Amos, Québec. The nickel occurs as pentlandite, heazlewoodite, and awaruite. The relatively low grade ore can be processed to a very high grade nickel concentrate, containing 29% Ni. The absence of copper and precious metals in the ore renders this concentrate amenable to processing by dead roasting in a fluid-bed roaster and smelting in an electric furnace to produce ferronickel for sale to stainless steel producers. Laboratory test work and conceptual engineering design was completed to demonstrate the amenability of Dumont concentrate to produce ferro-nickel.

Jan 1, 2015

By Alan A. Campoli

"Pumpable crib support for longwall gates and ventilation bleeder entries is becoming more prevalent in United States coal mines (Figure 1). The pumpable crib selection and spacing design has been greatly refined by the full-scale testing conducted at the National Institute for Occupational Safety and Health (NIOSH) Mine Roof Simulator. The peak load on 24-, 27-, 30-, and 36- inch diameter J-Cribs is, on average, 300, 400, 450, and 650 kips, respectively. Standard J-Cribs have useful deformation of approximately 8 inches. The maximum useful deformation can be extended to 18–20 inches with an exterior reinforcement layer or an interior double wall, for all four J-Crib diameters. J-Crib diameter is primarily limited by a maximum 4.5:1 height-to-diameter aspect ratio. Spacing is controlled by immediate roof stability, anticipated pillar deformation, and roof bolting practice. Approximately 500,000 J-Cribs have been successfully placed in 18 different United States longwall coal mines. The selection and spacing of the J-Crib utilized to date is summarized for each mine.IntroductionLongwall productivity and safety depend on ground stability in gate and ventilation bleeder entries. Numerous support technologies have been developed and employed in United States longwall mines since the 1990s to replace traditional wooden cribbing. Many, if not all, of these technologies have been evaluated at the NIOSH Pittsburgh Research Laboratory since the mid-1990s (Mucho, et al., 1999). The NIOSH Mine Roof Simulator has a 3,000-kip vertical load and 24-inch displacement capacity, which has facilitated in-depth analysis of complex multimaterial support technologies like the pumpable crib. The extreme cost and human exposure risk associated with modern longwall mining prevent the trial and error development that would have been required absent the Mine Roof Simulator research. As a direct result of this research, pumpable cribs are becoming a major component of the standing support industry, providing the peak capacity and extended deformation characteristics necessary for successful gate and bleeder support. Recent research by Zhang, et al. (2012) and others have defined the required performance characteristics."

Jan 1, 2015

By J. Pereyra, M. DeMarco

"INTRODUCTION It can be vital that bolted joints holding subassemblies together remain secure. Bolts should resist the loosening effects of vibrations and dynamic loads yet need to be easily removable during maintenance. When a threaded fastener is subjected to vibration, the rapid movement causes a lowering of friction against the threads and a subsequent loss of preload. The loss of preload allows the fastener to vibrate loose and possibly fall out. As the diameter of fasteners increase desired preload becomes increasingly more difficult to achieve. Input torque requirements for achieving proper bolt preload is exponentially related to any given fasteners diameter. This means that specialized tooling or bolting practices are usually required to attempt the tightening of fasteners to reach their required preload. Traditional methods can cause problems with joint integrity and do not provide consistent bolt load across the bolted surface. BOLTED CONNECTIONS A failed critical bolted joint can lead to high maintenance costs, machine downtime, and risk to worker safety. Control of the clamp load in a bolted joint is vital. However, when faced with a problem joint, it is not surprising that the design engineer will not have an answer if asked about the clamp load. Torque calculations must always be based on the existing conditions that often are vague. Unless all parameters are correct, the calculation will be unreliable. Examples of parameters are: • Thread condition of the fasteners • Hardness of contact surface • Material (steel, aluminium, copper, etc.) • Extra friction from a locking fastener • Extra friction from an adhesive • Lubricant on the thread • Type of bolt head (flanged, regular or serrated) • Surface coating of the bolt • New or reused fastener During tightening, bolts are subjected to both tensile and torsional stress. The total stress in a bolt can be calculated using the formula: Total stress = vsx2 + 3txy2 In order to maximize the desired tensile stress (sx) it is vital to minimize the torsional stress (txy). Tensile stress (clamp load) is achieved when the bolt is axially elongated. Unwanted torsional stress (twisting) in bolts arises during tightening due to thread friction. High thread friction increases torsional stress and causes yielding at lower clamp load levels than normal. A lubricant is necessary to minimize the malign torsional stress. However, many commonly used bolt-locking systems are based on increased thread friction (deformed nuts, adhesives, etc). To minimize thread friction and concurrently safely secure the joint has often incorrectly been considered impossible. The use of locking systems that increase thread friction is the single most common reason why the full capacity of bolted joints is not utilized. The following example illustrates the problem."

Jan 1, 2015

By D. Y. Li, C. D. Ma, T. Zhou, T. J. Cheng

In this paper, a number of experimental tests are carried out to study the strength difference on rectangular prismatic marble specimens with different height-to-width (H/W) rations. The specimens have a nominal size of 45×15 mm in the compressive cross-section (W×T) and different heights (H = 22.5 mm, 45 mm, 60 mm and 90 mm). It is to say that the height-to-width ratios are equal to 0.5, 1.0, 1.33 and 2.0, respectively. The quasi-static uniaxial compressive tests are finished by a servo-controlled INSTRON machine (the strain rate at about 10-5/s), and the dynamic compressive tests are finished by a diameter of 50 mm cylindrical SHPB apparatus (the strain rate reaching about 101/s). The rock failure process of marble specimens is captured by a high speed camera in order to distinguish the fracture propagation behaviour. It is found that the compressive strengths increase when the H/W ratio of marble specimen changes from 2.0 to 1.0 due to the end clamping effect both for quasi-static and dynamic loads. However, when the H/W ratio changes from 1.0 to 0.5, the apparent compressive strengths decrease both for the two loading conditions. The strength decrease of short marble specimens may be attributed to the change of failure mode from shear to slabbing, which can be identified by the fracture patterns of the specimens. Based on the uniaxial compressive tests, the slabbing strength of the marble was found to be about 40% of its UCS for the specimens with a nominal height-to-width ratio of 2.0. In addition, it is found that the dynamic increase factors (DIF) are affected by the specimen’s aspect ratios. It implies that the same aspect ratios should be used to compare the dynamic and static compressive strength of rocks. Meanwhile, both the static and dynamic tensile strengths of the marble are obtained by the Brazilian disc tests. The ratio of the dynamic tensile strength to the static tensile strength of the marble is about 2.68.

Jan 1, 2015

By H. Wen

"Taking the long flame coal, gas-fat coal and anthracite as samples, we tested the adsorption quantity to single component gas of N2, CO2 and CH4 under atmospheric pressure phase at different temperatures. Then we analyzed the adsorption characteristics and models of different metamorphic coals. The results show that metamorphic grade, temperature and gases species are main factors to adsorption quantity of coal. The higher and lower metamorphic grade of coal have greatly influence on adsorption capacity while moderate grade of coal has opposite result. The coal adsorption amount to three single component gases under the same experimental condition is CO2> CH4> N2.The simulation precision order of four adsorption models is quadratic curve model > Freundlich isotherm model> Langmuir model >logarithmic curve model. Quadratic curve model and Freundlich isotherm model both can accurately describe the adsorption behaviors of N2 and CH4, different isothermal adsorption curve of CO2 needs two kinds or more models to describe. This has a reference value to the study of adsorption characteristics and models to single component gases.INTRODUCTION Adsorption is the interfacial phenomena that concentration of single or multiple components in the interface layer is different from the bulk phase (1964). Adsorption model is mathematical models to describe the adsorption characteristics of the adsorbent, mainly reflected to fitting effect of gas adsorption isotherm, which contribute to deeply understand the adsorption characteristics of adsorbent. Many scholars have carried out extensively experimental studies of the coal adsorption process from different angles. Zhao (2010) studied the influence of coal metamorphism to pore development of coal seam through a variety of experimental methods. Zhang (2006) analyzed the adsorption capacity and the controlling factors from three aspects of the coal rank, maceral and coal mass deformation. Cheng et al., (2002) studied the influence of pore size distribution of different rank coals to adsorption constants. Zhong (2002) carried out varieties of isothermal assay and established the prediction method of coal seam adsorption affected by a variety of conditions. R. M. Bustin (1998) proposed that we could not simply describe the change law of coal adsorption capacity and maceral content by a fixed parameter, and the adsorption capacity of the same coal rank also has great change. C. R. Clarkson et al., (1997) used four different adsorption models to describe the coal methane adsorption process, and the fitting precision of adsorption models is D-A equation >D-R equation > BET equation> Langmuir equation. Gasem, K et al., (2003) found that the fitted isothermal adsorption curve of D-A equation and BET equation are better than Langmuir equation under high pressure condition, while D-R equation and BET model are better to CO2 adsorption. In recent years, scholars’ at home and abroad research achievements of coal adsorption focused on high-pressure stage (about 0~15 MPa), mainly for coalbed methane exploitation, carbon dioxide trapping and sealing technology development, but the study of coal adsorption under atmospheric pressure phase is little. In this paper, we analyzed the adsorption characteristics and models under atmospheric pressure phase, it has a reference value to the study of characteristics and models to single component gas."

Jan 1, 2015

By S. K. Jena, S. Singh, B. Das, N. Dhawan, P. K. Misra, D. S. Rao

"Iron as an impurity in pyrophyllite ore affects pottery, ceramics and tile quality. We carried out the characterization of a pyrophyllite ore sample using optical microscopy, scanning electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA) and wet chemical analysis. The study revealed the presence of 2.15% iron oxide (Fe2O3 ) along with silica and alumina as the major components, which constituted around 90% of the total sample. We carried out the removal of iron from the pyrophyllite using magnetic separation and acid leaching and found that wet high-intensity magnetic separation (WHIMS) could remove 28% of iron values while oxalic acid leaching could remove up to 99.3%. The leaching kinetics of iron removal and the effects of pulp density, acid concentration, leaching time and temperature were also investigated. The optimum conditions for leaching were found to be leaching time of 60 minutes, temperature of 90°C, pulp density of 5%, oxalic acid concentration of 0.3 M, and particle size below 100 microns. Iron dissolution from the pyrophyllite sample can be best described by the diffusion of ions through the product layer of constant-size spherical particles. The breakdown of the pyrophyllite structure was evident from the FTIR and TGA studies. The activation energy of the leaching process over the temperature range was calculated to be 43.47 kJ/mol. IntroductionPyrophyllite is a naturally occurring phyllosilicate mineral composed of aluminum silicate hydroxide [Al2Si4O10(OH)2] as the major component and often associated with other minerals such as kaolinite, mica, quartz, rutile and epidote. It occurs in fine-grained sericite schist that is quarried as pyrophyllite (Pandit et al., 2008). In India, pyrophyllite occurs mainly in Madhya Pradesh state, Uttar Pradesh state and the Keonjhar district of Odisha state (Harpavat, 1995). Pure pyrophyllite is a highly desirable material for various applications due to its unique properties. It exhibits high refractive behavior, low thermalelectrical conductivity, low expansion coefficient, low hot-load deformation, low bulk density and high corrosion resistance to molten metal and basic slag (Rieger, 1997). It is used in the ceramics, refractory, foundry, electrical-insulation, sanitary-ware, glassmaking, pesticide and rubber fields. Compared with clay, it has lower thermal conductivity and coefficient of expansion, making it more suitable for refractory applications (Harben, 2002; The Minerals Yearbook, 2011)."

Jan 1, 2015

By D. J. A. Chambers, J. M. Wempen, K. D. Koper, M. K. McCarter, K. L. Pankow

"The EarthScope Transportable Array (TA) of broadband seismometers (www.usarray.org) was deployed across southwest Wyoming from November 2007 through May 2009. During this time period the Array Network Facility (ANF, anf.ucsd.edu) detected and located a total of six seismic events near the trona-mining district. This lack of seismicity is atypical compared to coal mines employing similar mining methods. In this study, eighteen months of continuous seismic data from several nearby TA stations are reexamined using conventional and correlation-based methods to detect seismic events. Waveform cluster analysis and epicentral locations are used to discriminate between mining induced seismicity (MIS) and seismic energy generated from surface blasts at nearby coal mines. The locations and magnitudes of the 143 newly detected MIS events are compared to regional subsidence as measured by Differential Interferometric Synthetic Aperture Radar (DInSAR). INTRODUCTION An abundance of natural resources and a favorable political climate have made southwest Wyoming home to multiple large mining operations. Among these operations are five underground trona mines located approximately 50 km west of Rock Springs, Wyoming. The trona mines employ room and pillar, longwall, and solution mining methods over an area roughly 900 km2, and produce a sizable portion of the world’s soda ash (Brown 1995). Historically, in the Rock Springs mining district, several relatively large magnitude seismic events have occurred. These events are thought to have been related to mining activity and have caused notable subsidence (Case 1997). The largest event in the region recorded by seismometers, ML 5.1, has been confirmed as the 1995 Solvay Trona Mine collapse (Pechmann et al. 1995). In addition, blasting at surface coal mines near Rock Springs produces significant amounts of seismicity; approximately 50% of all daytime seismic events in the Mountain time zone from 2007 to 2009 locate near an active surface mine in this region (Astiz et al. 2014). Much of the current research related to surface subsidence and induced seismicity focuses on wastewater impoundment (Ellsworth 2013) and hydraulic fracturing. The observable seismicity in geological injection environments is widely variable and McGarr (2014) has argued that, in such environments, the maximum amount of seismic energy that can be released is proportional to the injected volumes. Like injection environments, in extraction (mining) environments seismicity is highly variable depending on many geological and operational variables (Boltz et al. 2012; Carnec and Delacourt 2000; Fritschen 2010; Iannacchione et al. 2005; Sen 2013) and does not always correlate well spatially with subsidence, a surface expression of extraction at depth."

Jan 1, 2015

By P. R. Brito-Parada, A. Norori-McCormac

Positron emission particle tracking (PEPT) has become an important tool for flotation research, as it is able to resolve directly the behaviour of particles in laboratory scale flotation vessels. The first applications of PEPT to flotation showed only the motion of an individual particle in the pulp and the froth, but nonetheless allowed interpretations of behaviour not previously possible. Since then, PEPT measurement and data analysis techniques have improved significantly and now ensure a high level of confidence in the particle behaviour obtained. In particular, statistical analysis of long-duration experiments allows time-averaged data to be collated, ensuring spatial accuracy and allowing rigorous comparison of different conditions. It will be shown that these PEPT techniques can be used to compare directly the effect of operating conditions and particle properties in a laboratory flotation system. Particle tracks will be illustrated, as well as analyses of particle speeds, average flow streamlines and occupancy that show marked differences in behaviour near the interface and impeller.

Jan 1, 2015

By Marco Quirion

The Daniel-Johnson dam, formerly named Manicouagan-5 (Manic-5), is located 800 km northeast of Montreal (Quebec) in Canada. This is the largest multiple-arch concrete dam in the world consisting in 13 arches and 14 buttresses. Since its construction in 1969, various type of cracks have appeared on both downstream and upstream faces of almost all the arches of this concrete dam. As a part of the Daniel- Johnson’s dam safety assessment program, Hydro-Québec is currently performing structural analysis of the dam with advanced numerical models to better understand and predict the dam behaviour. Because the buttresses transmit all the arch loads to the rock mass, determination of the properties of the dam foundation should not be neglected in dam global safety analysis and also to insure that reliable input parameters are used in the dam numerical simulations. This paper summarizes the past and the more recent investigations of this foundation used to assess its safety and stability. Moreover, the use of rock mass classification to estimate the deformation modulus, based on empirical equations, gives values in the range of 30 to 40 GPa that are higher than expected values. Using those values in the numerical simulations for dam structural analysis gives an excellent correlation with displacements monitoring of the buttresses.

Jan 1, 2015