Search Documents

By Lei Wang, Jianjun Wang, Lingen Luo, Zhengbang Li

Dearsenication in molten steel was studied by adding Ca-Fe Alloy-based arsenic removal agent. In order to improve the utilization rate of Calcium Iron Alloy and improve arsenic removal ratio, [O] is less than 0.0005% and [S] is less than 0.0035%, Al is added into the molten steel. In the processes of adding CaO-Al2O3 based alkalinity slag for arsenic removing in molten steel (initial arsenic content is 0.0080%), arsenic removal ratio reaches 50% when Ca-Fe Alloy addition amount is 18%. During the arsenic removal experiment, adding Rare Earth promotes the arsenic removal reaction and makes the arsenic removal more effectively.

Jan 1, 2015

By Mingming Zhang, Mallikharjuna R. Bogala, Ramana G. Reddy

Steelmaking desulfurization slag samples were characterized using chemical, X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectrometry (EDS) methods. The objective of this work is to investigate the occurrence of sulfur and phosphorus components in the slag samples and to identify their origin and associations with the iron phases. Thermodynamic calculations results confirm the presence of phosphorus and sulfur components in the slag sample at high temperatures (1400 to 1800oC). The main constituents of slag include Ca3SiO5 (28.1%), MgO (9.31%), Ca3(PO4)2 (9.18%), CaS (8.39%) and CaO (5.68%). The major phosphorus and sulfur components of the slag are Ca3PO4 (99.2%) and CaS (79.3%) respectively. Characterization studies indicate the presence of microparticles of different sizes and shapes in the slag sample. Elemental analysis of these particles confirm the presence of major elements (O, Mg, Al, Si, S, Ca and Fe) in the slag sample.

Jan 1, 2015

By Qiang Zhong, Bin Xu, Qian Li, Yongbin Yang, Tao Jiang

Viscosity of slag determines the production efficiency, energy consumption and distribution of elements between metal and slag, which is very important for pyrometallurgy. Slag of goldantimony ore blast furnace smelting has seldom been studied. In this paper, the viscosities of gold-antimony ore smelting slags of different composition have been studied by the rotating cylinder method. The results showed that, for a slag of 38.95% SiO2, 16.17% CaO, 25.97% FeO, 10.25% Al2O3, 5.17% MgO, the viscosity can be decreased by reducing 3.24%-8.5% SiO2 or increasing 3.31%-9.56% CaO content. Complex SixOy z- from SiO2 acts as the main cause for the high viscosity in a slag of high SiO2. The increasing of CaO causes the decreasing of the amount of SixOy z- and the O2- dissociated from CaO breaks the complex SixOy z-, which can decrease the viscosity. Viscosity of different composition slag in the appropriate range temperature can be calculated from the Arrhenius equation.

Jan 1, 2015

By Bhagyadhar Bhoi, Chitta Ranjan Mishra, Pravas Ranjan Behera

Red mud of Indian origin contains around 55% plus of Fe2O3 and is considered as a hazardous waste for the alumina industry. For production of one tone of alumina employing the Bayer’s Process, around two tones of red mud is generated from three tones of Bauxite. Conventional process of steel making is not devoid of environmental pollution. In the present investigation, efforts have been made to produce steel from red mud by adopting reduction roasting, magnetic separation and hydrogen plasma smelting route. Magnetic fraction, containing enriched iron oxide and minimal content of alumina, is produced following the first two stages which is then subjected to hydrogen plasma smelting process for production of steel. This novel concept follows a green path way for production of steel free from pollution and is termed as green steel. Further, the only by-product that is produced in the process, is water, which is eco-friendly and recyclable.

Jan 1, 2015

By Joe E. Bryan, John P. McDonnell

"Underground mine rib stability is an ongoing safety issue in all mining applications. Rib-related accidents present at least as many problems as roof-related ground control. Underground coal mine rib safety is continually emphasized as a primary safety concern at every mining operation. The application of rib support materials is increasing as more difficult mining conditions are experienced due to deeper cover, more variable depositional environments, thicker seam heights, and multi-seam mining effects. As the coal seams become thicker, the need for rib control increases. A variety of rib control methodologies has been documented and research continues on mine design methods and support techniques to reduce or eliminate rib-related accidents.This paper presents an alternative rib bolting technology using proven conventional rib support systems that allows mine personnel to more efficiently install rib support during development operations. This alternative rib bolting method allows for additional rib support with a single support installation.INTRODUCTIONRib control continues to garner the watchful eye of both concerned operators and government officials due to many factors: inherent safety within entries and crosscuts, actual rib stability history, safety improvement, cost control, improved mining methods, and maintaining production goals. As demonstrated through many years of actual practice, desired outcomes can be achieved by scrutiny, innovation, and combining improved practice methodologies.Rib surface control continues to be a necessary part of the production process. However, production and safety issues persist at the point of installation using current control apparatuses and methods to install rib controls. Among others, current issues of rib control are quantity of bolts required, overall time required for installation, ease of apparatus installation, flexibility of the system for appendage installation and operator exposure. A need exists to decrease the time miners spend installing rib control apparatuses, while increasing the safety of such installation processes. At present, installing rib control devices (primary rib bolts, plates, mesh, and, in most cases, secondary rib bolts and plates) is performed in a very congested area and is time-consuming process at the primary coal-winning area: the face. The MatLok system addresses these problems."

Jan 1, 2015

By J. M. Ríos

"Without conscious effort and understanding, a number of factors unique to mineral exploration often hinder building sustainability in host communities. These include the episodic and transitory presence of an exploration team in the community and the inherent uncertainty of outcomes— most projects fail from an exploration perspective. Experience in rural communities across Mesoamerica, however, has shown that it is possible to go beyond pragmatic philanthropy and infrastructure improvements to promote positive, sustainable outcomes in communities. Examples are provided of lessons learned and proven practices that improve quality of life and support a strong social license to operate.RÉSUMÉ Sans une compréhension et un effort réfléchis, de nombreux facteurs uniques à l’exploration minérale nuisent souvent à l’établissement d’un développement durable dans les communautés d’accueil. Ces facteurs comprennent la présence épisodique et transitoire d’une équipe d’exploration dans la communauté et l’incertitude inhérente des résultats – la plupart des projets échouent après l’étape de l’exploration. L’expérience dans les communautés rurales à travers la Méso-Amérique a toutefois démontré qu’il est possible de dépasser la philanthropie pragmatique et les améliorations des infrastructures pour promouvoir des résultats positifs et durables dans les communautés. Des exemples qui améliorent la qualité de vie et soutiennent un solide permis social d’exploitation sont présentés; ils sont tirés de leçons apprises et de pratiques éprouvées."

Jan 1, 2015

By Akshay Sakhuja, M. S. Karthika, R. Vignesh

"The bridge across River Mandovi in Goa is a cable stay bridge structure proposed parallel, along existing bridges for regulation and reduction of vehicular traffic; the entire bridge structure is supported on pile foundation socketed in rock. This paper describes drilling related issue encountered during execution of pile where bed rock varies considerably from factual geotechnical investigation, which in turn affected the productivity of bored piles socketed in rock then chiseling is advocated for rock socketing with limited number of blows based on penetration resistance of rock encountered or equivalent energy principle to increase the productivity and also to avoid excess chiseling which otherwise would have fractured the rock mass below and around the pile tip resulting in increased settlement of pile subjected to design load. Contractor decision on socket length have been taken without compromising either quality or productivity; the paper presents various procedures and the equipment involved for installation of pile in rock along with the conclusion related to termination of pile in rock and also the lessons learned in process.INTRODUCTIONPile foundations are generally used to transfer heavy loads in deeper bearing stratum if the soil immediately beneath the base of the foundation does not have sufficient capacity. The bridge across River Mandovi, Goa is in its construction phase as a part of the development plan of Goa State Infrastructure Development Corporation Ltd (GSIDC). The project was awarded to M/s. L&T Construction, Heavy Civil Infrastructure; subsequently the geotechnical investigation was awarded to M/s L&T Geostructures.The client has specified the foundation of the bridge as rock-socketed. Rock socketing is generally done to achieve higher bearing pressure through concrete-rock shear interface which many building codes permit. The design and construction of rock socketed pile foundation entails a detailed analysis and judgement on the superstructure loads, predominant geological conditions as well as ground water levels. The termination of pile is normally based on thumb rule of half to three times the pile diameter into the rock. Quite often the criteria is based on chisel penetration rate (Gandhi,1990) In fact, this is the key factor to consider appropriate and economical depth of embedment of pile into rock stratum which necessitates enormous understanding on the type and quality of rock strata encountered which may significantly influence the selection of suitable rotary rig for pile installation. Such criteria are site specific and also applicable for the set of equipment used for the particular project."

Jan 1, 2015

By Seth H. Hamblin, John E. Regan, Dimitrios Palantzas

"Through reliability-based calibration of larger pile load test databases, recent developments of the Load Resistance Factor Design (LRFD) methods, which include geotechnical load and resistance factors for deep foundations design, have advanced the state of practice for geotechnical engineering. These load test databases upon which the current geotechnical load and resistance factors have been developed are limited, however, and do not provide sufficient data to support the development of resistance factors for uplift (tension) pile capacity. As such, some recommended resistance factors for uplift capacity estimation methods are simply derived by reducing the recommended resistance factors for piles in compression by a factor of 0.10.The results of three (3) tension loading tests performed to failure on 508 mm (20- in) square precast, prestressed concrete piles, driven though granular soil in southeastern Massachusetts, are presented and compared to static pile capacity calculations and dynamic analyses performed using the Pile Driving Analyzer (PDA) during installation. These results are presented along with current recommended LRFD resistance factors for driven piles under uplift (tension) loading conditions. These comparisons offer an assessment of the applicability and limitations of current resistance factors methods for piles under uplift loading and may be useful additions to the existing database for future calibrations of LRFD resistance factors for driven prestressed concrete piles in sand.IntroductionIn 2010, two (2) natural draft cooling towers were constructed by Kiewit (Kiewit) Construction Company of Woodcliff Lake, New Jersey at the Brayton Point Power Station in Somerset, Massachusetts. These massive 500 foot tall, 400 foot diameter cooling towers were designed to convert the existing “open loop” system into a “closed loop system” thereby dramatically reducing the thermal impact to Mt. Hope Bay.Based on design guidance from the German VBG Design Code and the Massachusetts State Building Code (MSBC), tension (i.e. uplift) and lateral loads due to wind loads and design seismic events represented the critical loading conditions.Weighing approximately 190,000 kips upon completion, the cooling tower loads are transferred to 44 foundation nodes (i.e. pile caps) evenly spaced along ring beams which run the circular perimeter of each tower base. Each pile cap node was designed to resist a 2,000 ton compression load, 200 tons in tension (i.e. uplift), and 600 tons in the lateral direction."

Jan 1, 2015

By Deepak Pappusetty, Miguel A. Pando

This study is motivated from the increased interest in recent years to explore use of Ocean Energy Converters (OEC’s).OEC’s can be tidal or generate electricity from wave or current action. Design of foundation systems for these OEC’s is a key consideration as it can represent about 35% of the initial installation cost. The primary focus of this paper is related to foundation systems involving monopiles where a key design consideration includes gradual accumulation of pile head deformations beyond serviceability limits of the OEC. This design consideration is important since these foundation systems are often subjected to more than 108 low amplitude repetitive dynamic load cycles during a normal 30 year design life. Research on single model piles installed in sand and subjected to over 104 low amplitude lateral load cycles have shown that pile head displacements and rotations tend to increase gradually with increasing load cycles. This gradual development of pile head deformation is related to plastic strain accumulation in the soil in the vicinity of the monopile. Analytical methodologies based on conventional p-y curves typically cannot predict these accumulated pile head rotations and displacements. Even 3D dynamic Finite Element Analyses may not capture this response for several conventionally used soil constitutive models. This manuscript presents predictions using p-y based methods as well as 3D dynamic finite element analyses. The different numerical predictions are compared to available experimental data. Results from this study show that conventional p-y methods do not predict the gradual pile head displacements observed experimentally. Modified p-y curves, developed for cyclic loading, do a better job than conventional p-y curves but tend to greatly under predict deformation. This is believed to be related to the cyclic load test data used to develop these cyclic p-y curves which involved at most up to 500 cycles and did not include high frequency contents or partial unloading cycles. The 3D FEA captured reasonably well the general observed trends of gradual accumulation of pile head rotation and lateral deformation with increasing constant amplitude lateral load cycles.

Jan 1, 2015

By R. Radhakrishnan, C. Gunasekaran

"Calicut Bypass Phase-II project included construction of 7 m high embankment over soft compressible clays up to 18 m in thickness. Approx 1.5 km length of road out of a total 5 km length consisted of abandoned paddy fields which were low lying, waterlogged and marshy in nature. On the basis of excellent results achieved in earlier phases of the by-pass construction, ground improvement work by installing pre-fabricated vertical drains (PVD) was undertaken to stabilize the embankment foundation along the weak clay areas prior to road pavement construction to avoid large post construction settlement as well as to improve the lateral stability during and after embankment construction. This project perhaps stands out as one of the highway projects completed within a very short time period of total 18 months including four month long heavy monsoon period, when embankment construction was not possible and construction of two bridges across rivers. All activities including the ground improvement had to be programmed and completed within the shortest time period possible. The paper discusses details of the extensive ground improvement and soil instrumentation carried out for the project and will illustrate how careful planning and execution can reduce the period required for highway projects involving ground improvement.INTRODUCTIONPhase-II construction of Calicut by-pass was undertaken on a priority basis by the State of Kerala in 2014. The main contract was awarded to M/S ULCCS Ltd, Kozhikode, Kerala and the ground improvement work was awarded to M/S Geo-Enviro Engineers P Ltd, as specialist agency to design and execute the work.Soil investigation carried out confirmed thick soft clay deposits below GL in three areas along the road alignment totaling approx 1.5 km in length. These areas were low lying, waterlogged and marshy in nature. Highway embankment had to be constructed up to 7 m in height above existing GL to form the proposed road alignment along these areas. On the basis of excellent results achieved in earlier phases of the by-pass construction using pre-fabricated vertical drains or PVD (R. Radhakrishnan, 2006), ground improvement using PVD had been included in the contract to stabilize the embankment foundation along the weak clay areas prior to highway embankment construction to avoid large post construction settlement as well as to improve lateral stability during its construction."

Jan 1, 2015

By Pathik Deb Mallik, Shyamal K. Mitra, Rajiv Kishore, Shuvranshu Rout, Manos De

"This paper presents a case study on the design and construction of a deep underground pit structure constructed inside almost a century old existing plant building. The complexity and challenge for the design and construction lay in executing the work in a difficult subsoil condition especially the presence of deep mica schist. The limited space availability in the existing plant for construction work without hampering regular production in other adjoining areas of the plant made the execution more challenging. Experience with difficult subsoil and proximity to old foundations entailed a non-conventional engineering approach while ensuring complete safety in spite of maintaining the normal operation.INTRODUCTIONTata Steel Processing and Distribution Limited (TSPDL) is a subsidiary unit of Tata Steel Limited (TSL) having a CR processing facility inside the premises of Tata Steel Limited. TSPDL intended to install equipment for a new slitting line inside the existing shed including construction of very deep structure called “loop pit” where the strips from cut CR sheets collect in the form of loops and are recovered as scrap. The entire plant is located within the shed of existing plant. The construction of all foundations including the loop pit is to be executed in the limited area without disturbance to normal production work in balance areas of the plant and also maintain safety and integrity of existing structures.The existing shed is an old structure constructed approximately 80 years ago. The building column foundations are gravity type design of brick masonry supporting only the vertical load from the columns. This type of foundation designed with no eccentricity of loading provides no allowance for implementing any foundation stabilizing design. The present project required civil construction for the new equipment foundations safely within this area."

Jan 1, 2015

By Brian Isherwood, Tara Brown, Paul Kreycir, Jenny Earle

"The Shangri-La hotel and luxury condominium tower, recently opened on University Avenue in downtown Toronto, required eight levels of underground structure, four extending into the shale bedrock.Isherwood Geostructural Engineers was retained in 2007 by Anchor Shoring Limited to provide an alternative design-build solution to better address serious foundation risks. The site, bounded on three sides by City streets, abuts an existing 1957 14-storey building with five underground levels to the north. Sitting on the rock surface along the east perimeter under University Avenue runs the existing Toronto Transit Commission’s University Subway Line built by cut-and-cover in the 1950’s and which was believed to lie very near the property boundary at the southeast corner of the site.The bedrock under Toronto is known to contain very high locked-in horizontal stresses, much higher than can be resisted by shoring techniques, which result in inevitable wall movement when excavating deep into the rock. The strategy adopted to control the risk to the Subway, adjacent building, and major utilities is described in the paper, along with the comprehensive monitoring of movements, and their comparison to predictions.The ProjectThe 66-storey Shangri-La hotel and luxury condominium tower, recently constructed on University Avenue in downtown Toronto, houses 222 hotel rooms in floors 1-17; 287 residences on floors 18-49; and private estates including two 2-storey penthouses on floors 50-66. These comprise 873,000 square feet of development. Eight levels of underground basement are required to provide parking and other amenities, the lower four extending into the shale bedrock."

Jan 1, 2015

By Mihir B. Roy

"Coal transported by rail for Thermal Power Plant in Haldia, West Bengal, India, was to be received and stored in Coal Complex comprising of Wagon Tippler, Track Hopper, Junction Houses and network of horizontal and inclined tunnels. The site was very soft with high ground water level. Deep excavation and dewatering posed great difficulty. Original plan was to drive about 1000 m of steel sheet pile and well sinking which had major impact on cost and time. High ground water was identified as the main problem. Controlling water level and maintaining it would allow open excavation over major areas. Scheme for lowering aquifer with one and two-stage well-point dewatering system was developed following basic principles of groundwater and seepage. Arrangements of wells, installation and pumping were worked out in detail. Water levels could be lowered below bottom levels of excavation. Design of sheet pile was modified under lowered ground water condition. Overall length and depth of sheet pile were reduced drastically. Open excavation was possible in segments over major areas. The scheme was highly successful in smooth and fast progress of underground works. The works were completed safely months ahead of schedule time and with significant saving in cost.INTRODUCTIONThe Coal Receiving Complex of thermal power plant comprised of 250 m long 8 m deep Track Hopper (TH), 12 m deep Wagon Tippler (WT) with provision for addition of another Wagon Tippler. Track center lines of TH and WT were very close. Coal unloading facilities were connected with a network of underground tunnels and Transfer Points (TP) upto Pent House (PH). The facilities were optimized in a compact layout within about 400 m x 120 m area. Initially excavation for TH was started adopting side slope of (1 V : 1.5 H) with 2 m wide berm and dewatering by in-pit sump and pump. When depth of excavation reached about 5-6 m, failure occurred over a long stretch as shown in Figs. 1a - 1b photos. Further work was stopped to develop scheme for carrying out deep excavation and civil works safely."

Jan 1, 2015

By Mark Spence, Tom Lardner, Matthew Janes

"IntroductionThe design-build method streamlines project delivery through a single contract between the Contract manager and the design-build team. The design-build method places emphasis on collaborative project management between design and construction disciplines to minimize project schedule, reduce costs, encourage balance risk amongst the design-build team. Since 1985, the percentage of nonresidential design and construction projects has increased from 5% to 45%.1A project carried out in Edmonton, Alberta, Canada will be used as an example to illustrate the challenges of the design-build project delivery method and the merits of establishing a GBR. The project involved a complex slope stabilization as part of an extensive freeway widening. At the project location the roadway was being widened within the base of a historic stream valley into a steep slope with a history of a previous slope failure. The slope was to be steepened through the installation of a series of 14 interlocking arc structures constructed half way up the slope. Access and schedule proved critical to the successful completion of the project.Geotechnique and Site HistoryThe geotechnical investigation undertaken for the site included six boreholes drilled at the crest of the slope to depths ranging from 14.5 m to 30.2 m. Laboratory testing of the soil samples included direct shear tests, Atterberg limits and grain size analysis. The geotechnical report also referenced a previous geotechnical investigation that was carried out in response to a failure of the slope in 1971."

Jan 1, 2015

By Sumantra Sengupta

"Northeast Frontier Railway (NF Railway) intends to connect Imphal, the capital of Manipur (bordering Myanmar) with Assam by railway link. They have planned a 125km long railway line that passes through steep rolling hills of Patkai region, eastern trail of Himalaya, and as a result large number of tunnels and bridges need to be designed. While the high mountains are penetrated by tunnel, the deep gorges between the mountain ridges are connected by tall bridges. The tallest of such bridges connects a gorge at about 140m above its bed level with an overall length about 700m at rail level. In all, five such bridges with tall piers are now under construction. With extensive study on possible alternate arrangement of the bridges considering the effect of high seismicity of the area, moderately to highly weathered siltstone/ sandstone as ground bed material, slope of the hills etc it was decided that bridge will be founded on 1.5m diameter bored cast in situ piles with length varying from 20m to 30m depending on the location. The substructures are RCC hollow pier and superstructures are steel open web through type girder of 103.5m span. Considering absence of any major construction work in the vicinity, it was decided that prior to design work, Site-specific spectrum study will be carried out and design will be carried out considering the varying stiffness of the tall piers, each of different height. Interesting results were obtained regarding behavior of piles under lateral loads generated by high seismic conditions. The paper discusses in detail the design of Pile foundations and the effect of bed material along the steep slope on which the piles are being constructed.INTRODUCTIONIndian Railway has undertaken the construction work of connecting the North-Eastern states of India through railway line. The major stretches of the area passes through hilly terrain and as a result the line passes through tunnels and bridges in succession. The tall mountains are being penetrated with tunnels and immediate after deep gorges are crossed with high level bridges. The entire area is under high seismically active zone. The bed material below the ground level of the sloped hill is 4 to 10 meter of mixed soil of sand, gravel, pebbles etc underlain by moderately to highly weathered sandstone, siltstone at the higher level and moderately weathered sandstone, siltstone at lower level. Considering all the aspects like constructability, maintainability, geological and geotechnical aspect, seismicity, stability, safety, functional aspect and cost it was finally decided that the bridges will be simply supported structure with open web through type steel superstructure of maximum span 103.5m and hollow cylindrical discretely varying RCC substructure with 1.5m diameter group of piles as foundation. The paper discusses on the design aspect of the pile foundation in the rocky strata in the hill slope. The codes and standards that have been followed for design are IRS (Indian Railway Standard), IS (Indian Standard), IRC (Indian Road Congress), AREMA (American Railway Engineering and Maintenance-of-way Association), UIC (International Union of Railway) provisions."

Jan 1, 2015

By Jogeshwar P. Singh, Mohamed Ashour

The Soil-Foundation-Structure-Interaction (SFSI) problem involves Kinematic Soil- Foundation Interaction occurring during large (cyclic and permanent) ground deformations as well as Inertial Foundation-Structure Interaction occurring during shaking all of which take place while the soil and possibly structural properties degrade with time. The design of the deep foundations for liquefaction induced lateral spread loads include estimation of passive pressure applied by the liquefied material as well as the amount of anticipated displacement. Coupled analyses for SFSI problems that account for liquefaction induced lateral spread and their interaction with the deep foundation system can be performed using sophisticated numerical modeling techniques based on finite element and/or finite difference methods using computer programs such as FLAC or OPENSEES. Such complete SFSI analyses are very tedious and expensive and not feasible for most projects. In 2011, California Department of Transportation (Caltrans) released guidelines for foundation loading and deformation due to liquefaction induced lateral spreading. This simpler prescriptive approach combines empirical and analytical methods through decoupled analyses using computer programs such as LPILE and SLOPE-W together with liquefaction induced lateral spread estimates based on published empirical equations. Pile group effects and pile caps are accounted for using a concept of super-pile. In this paper, we discuss the solution of the same lateral spreading related SFSI problem using computer program CGI-DFSAP (CGI-Deep Foundation System Analysis Program) based on the strain wedge theory that can account for liquefaction, lateral spreading, pile groups, pile caps and nonlinear behavior of piles in a more coupled manner to analyze the foundation system under the lateral spread loadings. CGI-DFSAP can be used to analyze piles in sloping ground conditions as well as piles beneath the abutments near a free-face slope. We have included Strain Wedge Model (SWM) solutions using CGI-DFSAP of several field and laboratory case studies of lateral spreading related to pile foundations. Finally, we have also included the SWM solution of one of the Caltrans (2011) example problems.

Jan 1, 2015

By Y. Nara, N. Aramaki, M. Maruyama

Evaluation of three dimensionally non-uniform strain distribution in rocks under various conditions such as in water or under freeze-thaw cycles is of significant importance to understand their complex deformations and fracturing mechanisms. For this purpose, we developed an image analysis method which can evaluate or “measure” the three dimensional (3-D) strain distribution in rocks. The proposed method utilizes the 3-D images of rock under initial and deformed configurations, which are obtained by some imaging techniques such as X-ray computed tomography (X-rayCT). In the proposed method, the obtained 3-D images are divided into multiple sub-regions of interest. For each sub-region, the strain is evaluated utilizing 3-D affine transform with unknown coefficients to be determined. In the first step, 3-D voxel level displacements at multiple representative points in each sub-region are computed by 3- D digital volume correlation technique between the comparison images and the initial-guess of the transform coefficients are obtained. In the second step, referring to the initial-guess of unknown transform coefficient, they were optimized in sub-voxel level by finding optimum digital volume correlation between the comparison images, which can evaluate the transform coefficients with higher precision. From the calculated transform coefficients, the strain was directly obtained through the spatial derivative of displacement based on affine transform. In this paper, along with the description of the proposed method, the evaluation of deformation in a lignite specimen due to immersion in water was presented as an application example. As the 3-D imaging technique, micro-focus X-rayCT was applied. The result showed that the induced dilatational strain field due to the initiation and extension of cracks in the specimen was clearly captured. Therefore, authors believe that the proposed method can be applicable to various problems in rock mechanics.

Jan 1, 2015

By R. Koen, H. Visser, A. Roodt

"SynopsisThe tetraethylammonium salt of the mono-anionic coordination compound mer-oxidotrichlorido(thenoyltrifluoroacetylacetonato- K2O,O’)niobate(V) (NEt4)[NbOCl3](ttfa)], has been prepared under aerobic conditions and characterized by single-crystal X-ray diffraction. (NEt4)[NbOCl3](ttfa)] crystallized in the monoclinic P21/c space group, with a = 11.483 (5), b = 12.563 (5), c = 17.110(5) Å, and ß = 100.838 (5)o. The complex structure exists in a 50.0% (NbA) : 50.0% (NbB) positional disorder ratio.IntroductionComplexes containing organometallic type ß- diketone ligands with O,O and O,N donor atoms are used widely in coordination chemistry and have applications in catalysis, radiopharmaceuticals, etc. (Schutte et al., 2011; Roodt, Visser and Brink, 2011; Brink et al., 2010; Otto et al., 1998). These ligand systems are very useful because of their highly coordinative nature, high solubility, and also due to their ability to be functionalized with various substituents on the carbonyl carbon atoms (Schutte et al., 2011).Only a small number of ß-diketonate ligands have successfully been coordinated to a Nb(V) metal centre, with only a select few being characterized by X-ray crystallography (Viljoen, 2009; Bullen, Mason and Pauling, 1965; Preuss, Lamding and Mueller-Becker, 1994; Funk, 1934; Davies, Leedlam and Jones, 1999; Allen, 2002. The synthesis and crystal structure determination at room temperature of mer-oxidotrichlorido (thenoyltrifluoroacetylacetonato- k2O,O’)niobate(V) {(NEt4)[NbOCl3(ttfa)]} was first reported by Daran et al. in 1979. Accordingly, for this current investigation, (NEt4)[NbOCl3(ttfa)] was re-evaluated at 100 K to determine if the structural features might change with temperature."

Jan 1, 2015

By H. Utsunomiya, J. Su, K. S. Tamimi, S. Yue, M. Sanjari, L. Kestens, A. S. Kabir, R. Petrov

The recrystallization and texture evolution of AZ31 sheets obtained through two stages was investigated at different stages of post-rolling annealing. The specimens were rolled at the temperature of 100? and at a fast speed of 1000m/min and low speed of 15m/min with a reduction of 30% in one pass. The results show thatAZ31B sheets rolled at 15 m/min and 100 °C has fractured for reductions of more than 30% per pass. However, by increasing the rolling speed to 1000 m/min the rollability was improved significantly and the material can be rolled to reductions of more than 70% per pass. The high speed and heavily deformed materials are fully recrystallized even at 100 °C.

Jan 1, 2015

By D. Virely, M. Gasc-Barbier, J. Guittard

"The valleys of the Dordogne and the Vézère (France) have been inhabited since prehistoric times, as evidenced by the famous site of Lascaux. A few miles away, the village of La Roque-Gageac is also a very popular tourist destination (about 1.5 million tourists per year): The village is sandwiched between a massive limestone cliff and the Dordogne river. The collapse of a cave roof high above the village in January 2010 led us to characterize instability together for the cave and the whole cliff and propose a adapted instrumentation to monitor the fracture openings in the rock mass that are linked to climatic variations. Measurements have been going on and been recorded for nearly 4 years. They point out the role of thermal stress fatigue in the breakdown of the rock mass. In this paper we describe the site under study, the instrumentation and its main results. INTRODUCTIONThe phenomenon of thermal fatigue has been very little studied as far as rocks are concerned, whereas it is rather well characterized for other types of materials: Elsevier published a journal dedicated to fatigue (International Journal of fatigue). In the case of rocks, thermal phenomena and their impacts on mechanical behavior have been analyzed from a micro-structural point of view, and it is now well-known that an increase in temperature causes a dilatation of crystals (Arnould et al., 2004; Berest & Weber, 1998). This dilatation may lead to the development of inter-granular traction and compression stresses, and if those stresses are greater than fracture strength, inter-granular and intra-granular cracks may take place. On the other hand, the fatigue phenomenon (cyclic repetition of a temperature variation which is less extreme than the one that may lead to this inter-granular or intra-granular fracture) is a phenomenon which has not been much studied.The principal studies on thermal fatigue on rocks come mainly from the field of geomorphology, particularly in connection with the analysis of the evolutions of past climate that can explain the present shapes of those landforms: those studies remained essentially qualitative and not quantitative. Le Ber & Oter Duthoit (1987) proposed a thermal and thermodynamic approach to analyse the disaggregation of rock masses. This analysis is dedicated to the study of paleoclimates and was implemented to better understand the formation of slope deposits in order to propose transfer models permitting the reconstruction of the climactic conditions contemporary to their appearance. Since deterioration in the cliff only appears after several cycles, it means that it is a gradual and irreversible deterioration which leads to an increase of the « disorder ». Seen from a macroscopic system point of view, this irreversible evolution is quantified by the internal creation of entropy."

Jan 1, 2015