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By S. Gajardo, E. Valdés Guerra

Together with Sociedad Punta del Cobre S.A. (Pucobre) and Orica, we are carrying out a study of alternatives for methodology of excavation in Slot Up Raises from actually built with Blind Hole (BH) to drilling and blasting (DB) methodology. The study is part of the permanent search for innovation, the use of technology and the reduction of mine operation costs. This application aims to optimize the Sub Level Stoping method, which has historically been exploited at Pucobre. Using a new variant of the method “Open Stoping”, through the initial development of ascending blind raises using a pilot drilling of a bore hole, with the objective of eliminating the upper level in order to excavate the free face opening. This industrial test aims to replace the mechanized BH Up Raise of 1.5m (4.9 ft.) in diameter and 30m (98.4 ft.) high, with a Up Slot Raise considering two separate blasting events, using different technological enablers, as detailed below: accuracy drilling with relief holes of 254mm (10 in.) diameter, high viscosity bulk emulsion, wireless initiation system and high-strength injectable bulk resin. Considering the importance of the success of this application, a DB diagram was defined to allow the opening of the up raise in two blasting events, separated by intermediate stemming deck located at the same level at a height of 15m (49.2 ft.) from the collar, using high-strength injectable resin. The first blasting event considers the first section from the collar to the first 15m (49.2 ft.), using wired electronic initiation that is detonated on the first day. A second event blasts the section from 16.5 to 30m (54.1 to 98.4 ft.), using a wireless initiation system, as, it has no physical connection, is blasted on the second day after the extraction of the material resulting from the first event. For greater precision, the design of the explosive charge configuration and initiation sequence is made, adjusted to the measurements of trajectory deviations of the actual ground drilling and is also considered for the control of the explosive charge configuration with high viscosity bulk emulsion. This application improves the profitability of the mining business by generating savings through the change of Blind Hole methodology, estimating a savings of more than 75% per Up Slot Raise

Jan 1, 2024

By G. Adderley, Rob. Farnfield, L. Bermingham

The benefits of using electronic detonators within the drilling and blasting process in both surface and underground mining operations are well established and the use of this technology is widespread in the minerals industry. However, many users of such devices will also have experienced misfires where an electronic detonator has malfunctioned and shows evidence of damage from either transient shock or gas pressure. This is typically exhibited as a detonator shell that has collapsed causing damage to the internal electronic components before the detonator has initiated. Users often describe such detonators as being “shrink-wrapped”. The excavation of a misfire is always a hazardous operation, and it is better to minimize the risk of one happening in the first place. As part of a programme to improve understanding of this phenomenon and to allow a comparison between differing designs of detonators, a simple practical test was developed. This process involves the firing of a booster near electronic detonators in water. This paper describes this test work and draws some tentative conclusions on pressures for onset of damage with detonator shells made from different materials. The investigation has also yielded data showing that for some designs there is little difference between the pressure resulting in complete malfunction and sympathetic detonation

Jan 1, 2024

By J. Schoonover, A. Moore

In the explosives industry, individuals face a multitude of hazards while working in mines, quarries, and construction sites. Safety becomes an ever-present driver as companies attempt to control costs, promote quality service and products, and grow business all while ensuring employees return home safely every day. One of the most challenging hazards that threatens the goal of absolute safety is flyrock. Ensuring that a blast does not result in rock leaving the blast area, thereby creating a danger for personnel in the vicinity, can be complicated due to the multitude of factors. Shot design, geology, operational procedures/techniques, explosive products, security plans, communication methods, and drilling practices can all adversely affect the safety of individuals helping execute a blast through an increased risk of flyrock. Flyrock can also pose a major threat to the public and other non-blasting personnel in proximity. Like many other industries encountering various challenging hazards, the explosives industry has recently adopted innovative technologies to help mitigate the risk of complex hazards such as flyrock. Specific applications of Unmanned Aerial Vehicles (UAVs), commonly referred to as drones, employed in the explosives industry can help reduce the likelihood and severity of a flyrock incident. This paper explores a case study and theories of how the integration of drone technology within blast security plans, mine planning, blast design, design auditing, and blast area clearance procedures can help to decrease the risk of a flyrock event through the provision of data and information previously unavailable. Multiple opportunities exist during a blasting operation to gather data using drone technology. It is these data-gathering opportunities that can be leveraged to be maximally equipped for the mitigation of flyrock. Better data from drones can be sourced and used in security plans and clearance measures as well as utilized during mine planning and blast design. Increases in the quality and quantity of information during these crucial steps of blasting has proven to be an effective way to increase the peace of mind for explosive end users. This peace of mind, along with design flexibility and adherence to performance, is why the integration and utilization of drone technology is key for effective flyrock risk reduction

Jan 1, 2024

By D. Fry, S. Hunsaker

Ammonium nitrate in explosives and sulfides in reactive ground have the potential to react at ambient and elevated temperatures resulting in premature detonations. The Australasian Explosives Industry Safety Group (AEISG) published, in 2006, a Code of Practice1 for elevated temperature and reactive ground. This paper reviews the chemistry, general reactivity of various ground types, elevated temperature hazards, and testing protocols contained in the code, that are industry best practices for managing ammonium nitrate-based explosives in elevated temperature and reactive ground conditions. In addition to reviewing the 5th edition AEISG Code of Practice, data is presented validating the recommended sampling guidelines within the code. Dyno Nobel has been screening reactive ground samples and performing sleep time testing since the code of practice was first released. Test results demonstrate the effects of samples that are allowed to oxidize before testing and are shown to be subsequently less reactive and not representative of the actual hazards facing mining blasting operations. Results also show that for a given reactive ground sample, reaction times decrease with increasing temperature. Data also quantify the delay in reaction time given by inhibited products. These results emphasize the importance of proper sampling and preparation of samples to accurately characterize elevated temperature and reactive ground hazards. They also demonstrate the efficacy of inhibited products in managing these hazards

Jan 1, 2024

By A. Vishwakarma, V. Himanshu, K. Dey

Underground mining is the most feasible method after extinction of shallow depth ore deposits. Longhole stoping method is the most technically advanced method for the faster excavation. In this method, the holes are drilled in the form of ring pattern and explosives are used for the rock breakage. During blasting, the explosive energy sometimes also breaks the non-ore material. The non-ore material gets included in the extracted ore and enhances the ore dilution. Few uncontrollable factors which affects the ore dilution are ore body characteristics, rock quality, insitu stress condition etc. Apart from uncontrollable factors, explosive energy and blast design also plays an immense role in ore dilution. In the blasting practice, the purpose is to effectively utilise the explosive energy for rock breakage. The optimum delay is required so that the blast holes attain adequate free face before the blasting. This paper deals with the optimisation of blast design parameters to reduce ore dilution in underground hard rock mining having narrow vein. The study was carried out using numerical simulation. The explicit dynamics based modeller of Ansys was used for this purpose. The parametric variations in the models were done to optimise the parameters. The burden has been optimised first by varying the width of the narrow vein. The blasts of a ring consisting of single hole were conducted in the model by varying the width of the narrow vein. The damage contour under different parametric variations were analysed. The experimental trial has been also carried out at Zawar Group of Mine, Rajasthan, India. The optimum parameter was decided based on the result of experimental trial and numerical simulation model. The output of the model shows that optimum burden for 3.5 m narrow vein width is 1.12 m and for 1.0 m, it is 1.54 m. This shows that the optimised burden is higher in the vein having lesser width as compared to the greater width. The presence of joints/changed media/interface (between the sidewall and narrow vein) is the major reason behind this. The wave gets reflected back very fast on coming in contact with joints in a 1.0 m narrow vein as compared to a 4.0 m narrow vein. This will quickly convert the compressive wave into tensile wave giving rise to tensile slabbing. Hence proper utilisation of explosive energy will take place for the breakage of rock mass when the width of the narrow vein is smaller. The burden obtained from the experimental trial and numerical simulation models is less than 2.0 %. Hence the numerical simulation based approach can be used for the assessment of the optimum burden for ring blasting in narrow vein under different geomining conditions. This helped in reducing ore dilution and maximization of ore recovery. In the future, empirical relationships may be developed by considering different geological discontinuity, the strength of the rock mass and explosive parameters.

Jan 1, 2024

By K. Taylor

In surface coal mining, the performance of a shovel through blasted muck is one of the key performance indicators of the blast. Historically, performance has been measured qualitatively based on operator feedback or visuals of the muckpile. More complete shovel data, such as loading times and GPS location, is available from most fleet dispatch systems that are already in place at most truck and shovel operations. With some database and analysis skill, the drill and blast team can take advantage of this data to make targeted improvements to drill and blast designs. An area typically known to cause trouble for shovel operators at this operation are blast boundaries. Blast patterns with and without design changes along the boundaries were studied in this case study. The instantaneous loading times for each shovel pass were analyzed for 75 blasts across two subsequent benches with similar firing direction and shovel paths. The benches were split into three categories: Main body of pattern, boundary with design change, and boundary with no design change. The loading times from the main body of the patterns and where the design change was utilized in the boundary had similar prevalence of good loading times. However, boundary areas without the deign change had approximately 2% more prevalence of poor loading times compared to the main boundary of the pattern. Improving the dig rates through the boundaries up to the average loading time would result in approximately 280 hours taken off the total loading time for one bench. By quantifying the shovel’s performance by GPS location, the drill and blast team can decide how much of a design change is needed, can target precisely only the areas that require it and measure the impact of any changes made

Jan 1, 2024

By W. Boas, R. Silva, D. Yumi, L. Steffen

The continuity of the flow and stages within the mining process is essential to achieve success in its operation and results, especially when it comes to a gold mine. During the first seven months of 2022, crushing at the Morro do Ouro Mine had 19 stops in the primary crusher due to equipment blockage/obstruction, this could be due to the size of the material that was blasted with explosives and fed. The feeding of coarse material to the crushing plant impacts the operation in several ways, for example, premature wear of the equipment, reduction in the supply of the remainder of the beneficiation, reduction of the buffer pile and damage to the conveyed belt. In a mine located far from the community, the fragmentation improvement is mainly related to load increments or some other relatively simple change. However, when it comes to a mine located close to communities, alterations of this type must be analyzed in detail, as it can have an impact mainly in relation to vibration and flyrock. Aiming to improve the efficiency of the blasting, mainly in relation to the result of fragmentation, a project was created to improve the efficiency of the blasting with a focus on reducing the crushing stoppage and reducing the amount of material discarded due to inadequate granulometry. During the evolution of the project, several improvement solutions were proposed, for example adjustment of the power factor in relation to the geological characteristics of the rock mass, drainage, blasting geometry, vibration reduction techniques and several operational improvements. By using the techniques and methods identified as improvements during the project, it was possible to observe and quantify improvements in relation to the fragmentation of the blast. During the months of January to July 2022 there were 19 events. It was estimated that at this rate there would be 14 more blockage events, but there were only 3 events and that meant a 79% reduction in blockage. In addition to the reduction in crushing shutdown events, there was also a 53% reduction in the amount of ore that is discarded due to inadequate granulometry and, with that, the feed rate of the grinding system was able to reach the maximum feed limit due to the material being fed to the mill well fragmented, contributing to increase the production and productivity of the beneficiation process at the Morro do Ouro Mine in Paracatu-Minas Gerais-Brazil.

Jan 1, 2024

By S. Behera, K. Dey

This paper presents a methodology for finite element (FE) modelling to analyse the total deformation of rockmass under blast-load, with a focus on predicting backbreak that may occur during surface blasting operations. Backbreak can result from improper use of explosive energy, leading to damage beyond the excavation zone and jeopardizing operational safety and productivity. The paper highlights the impacts of backbreak on bench stability, excavator operation, drilling operation, flyrock generation, and improper fragmentation and boulder formation in surface blasting. However, prior estimation of extent of rock breakage zone can provide an idea to formulate the blast design to control the backbreak. While vibration-based prediction models are commonly used to estimate backbreak, they require physical blasting experimentation. To overcome this limitation, the paper describes the development of a FE model using ANSYS Explicit dynamics, which simulates rock blasting and calculates the total deformation of the rockmass. The rockmass deformation is modelled using Drucker-Prager (D-P) strength model with the Jones-Wilkins-Lee (JWL) equation of state for the explosives. The accuracy of the FE model is evaluated through physical experiments, and the results are compared with the vibration models. The FE model demonstrates close proximity to physical observations as well as vibration model result in predicting backbreak, thereby offering a promising alternative to vibration-based prediction models. The primary objective of the study is to predict the response of the insitu rockmass to explosive blast loading and determine the effective rock breakage zone.

Jan 1, 2024

By E. Lentilucci, A. Dey, X. Liu, A. Datta, S. Ghosh

The segmentation of quarry blast smoke plumes is a crucial research area that has the potential to enhance safety, environmental monitoring, object detection, and regulatory compliance in the mining industry. Smoke plume segmentation can be used to identify the spatial extent and temporal evolution of smoke plumes generated by the blast. This information can be used to improve the understanding of blast dynamics and optimize blast designs. Furthermore, smoke plume segmentation can assist in identifying potential environmental and health hazards associated with the release of smoke and dust particles into the atmosphere during quarry blasts. However, many current smoke plume segmentation algorithms are designed for segmentation of smoke plumes from fires and are not suitable for segmentation of plumes from quarry blasts. The proposed method in this paper leverages the video frame captured before the blast as a stationary background image, which helps to reduce other confuser objects present in the image along with a selfadaptive clustering method. The color channels of the image are utilized based on the different contrast properties of the smoke, with a self-adaptive gradient compensation applied for edge detection of the smoke plume. This approach offers a novel and effective way to segment smoke in quarry blast analysis, with potential applications in the calculation of noxious gas volume and concentration within the plume. Compared to other algorithms, our method improves accuracy, decreases the false alarm rates, and reduces the overall miss rate. Overall, this paper contributes to the research on smoke plume image segmentation, particularly for quarry blast smoke plumes, which possess unique characteristics that require specialized algorithms for accurate segmentation.

Jan 1, 2024

By D. Swanson

Cold Detonation Physics (CDP) is a patented new field of explosives and the name for the explosive that is produced when non-toxic dry ice (frozen carbon dioxide) is combined with powdered metals such as magnesium and aluminum, which are non-toxic and nitrogen-free. The explosive is detonator-sensitive and detonates according to the rapid reduction of carbon dioxide back to carbon, which produces solids comprised mainly of metal oxides and about 5% carbon. CDP was determined to produce a maximum of 300 liters of carbon dioxide per kilogram (4.81 ft3 /lb) and about 1.5 liters of carbon monoxide per kilogram (0.024 ft3 /lb). Both these figures shift according to metal content where higher metal produces less gases. According to theoretical modelling, the relationship between static pressure and metal content was determined to be an inverse parabolic curve with optimum pressure at 25% to 31% metal, depending on the type/s of metal/s used. Velocity of Detonation (VOD) was determined by measuring light at the wavefront with fiber-optic cable inserted into a series of holes drilled into the side of a 3-inch diameter (76 mm) schedule 40 steel pipe containing the mixture. The highest VOD was observed at 25% magnesium and measured between 2,500 to 4,500 m/s (8202 to 14,764 ft/s) when initiated by a 454-gram (1-pound) booster and an electric detonator. A 25% 50:50 alloy of magnesium and aluminum sample shot at a higher velocity than magnesium, according to how the alloy generated smaller pieces of shrapnel when compared with shrapnel from a magnesium test. CDP, using 25% alloy, was tested for blasting limestone by drilling 3.5-inch holes (89 mm) and inserting a 3-inch x 4-foot cardboard tube (76 mm x 1.22 m) with the mixture, packed to a density of 0.62 g/cm3 . The blast was initiated with an electric detonator, behaved like ANFO with more energy and fractured rock sufficiently across the entire length of the borehole. Seismic analysis determined that CDP produces lower ground vibrations than traditional explosives.

Jan 1, 2024

By K. Best, D. Conn

The US Army Corps of Engineers KY Lock Project in western Kentucky presented the blasters and vibration consultants with a set of unique challenges. The blasters on this project were faced with difficult geology and joint set orientation and sequencing of blasts opposite from what the explosive engineer/blasting specialist had recommended. Combining these issues with strict vibration and air overpressure specifications, blasting as close as 7 feet (2.1 meters) from a new lock wall, site topography that influenced the air overpressure, limitations on seismograph geophone placement that led to anomalies in seismograph recordings; surprising lessons were learned by everyone involved in the project and it is the authors’ goal to share this valuable information with everyone in the blasting industry.

Jan 1, 2024

By M. Szumny, P. Mertuszka, K. Fuławka

Multi-face destress blasting is the basic method of reducing rock bursts hazard in Polish copper mines. Blasting operations of this type are carried out regularly, twice a day in order to minimize the geomechanical threat while maintaining high extraction efficiency. Unfortunately, the assessment of the effectiveness of this type of work until recently was based solely on determining whether a given destress blasting triggered a seismic tremor or not. Information on the characteristics of seismic waves generated by blasting has so far been omitted in analyzes of this type. The lack of reliable knowledge about the generated seismic effect makes the introduction of constructive corrective actions impossible, which in turn significantly reduces the triggering potential of conducted destress blasting. This study presents the results of comprehensive work aimed at increasing the effectiveness of active rock burst prevention in Lubin underground copper mine. For this purpose, an innovative system for continuous monitoring of seismic waves induced by multi-face blasting was developed, and a new method for seismic assessment of the effectiveness of the destress activities was developed. Based on the monitoring data and the comprehensive analysis of waveforms, the effectiveness of individual blasting operations was determined, and on this basis, modifications to the drilling and blasting patterns aimed at increasing the generated seismic effect were proposed. The use of innovative methods of monitoring and data analysis made it possible to increase the effectiveness of the conducted activities, in terms of the magnitude of seismic vibrations, up to 250%. It should be emphasized that the introduced modifications were aimed at increasing the effectiveness of blasting operations while maintaining the current level of costs. As a result, the proposed solution turned out to be highly effective, significantly affecting the safety of the work carried out in Polish copper mines. Thus the proposed approach is planned to be implemented in other Polish copper mines belonging to KGHM in the near future

Jan 1, 2024

By Mustafa Kumral, Yuksel Asli Sari

Economic evaluations of underground mining operations are made based on the estimated or simulated grades of the block model as the actual values are not known. Depending on how the planning decisions are made, the risk of the operation can be managed and decreased. This research introduces a mixed-integer linear programming (MILP) model for stope sequencing optimization that considers the uncertainty associated with net present value (NPV) using chance-constrained programming (CCP). The introduced method permits achieving a balance between maximizing NPV and reducing the associated operational risk through transforming the problem into a multiobjective problem, where the objectives are maximizing the NPV and minimizing the risk. This risk is expressed in terms of the standard deviation of project outcomes, taking into account multiple possible scenarios. In a case study, the efficiency of the method was demonstrated as a decision-making tool capable of translating a specified risk or reliability level into a stope sequencing plan.

Jan 1, 2024

By Shangyong Lin, Wei Sun, Weiping Liu, Muhammad Azam, Junfeng Cheng, Yujie Zhao, David Asubonteng, Michael Ngoie

Copper concentrates have wide application in global smelting operations, comprising primarily of chalcopyrite (CuFeS2) as the principal mineral, accompanied by chalcocite (Cu2S) and bornite (Cu5FeS4) as secondary copper-bearing minerals. However, these concentrates frequently harbor detrimental impurities, notably fluorine ions, which can cause various complications during the smelting process. Moreover, an elevated fluorine content in copper concentrates may entail financial penalties and sales constraints. This review conducts a comprehensive analysis of existing methods for the removal of fluorine, presenting a nuanced assessment of their merits and demerits. It also provides valuable insights into the current landscape of fluorine elimination from copper concentrates and pinpoints pivotal areas warranting future investigation. This review endeavors to serve as a pragmatic resource for researchers and industry professionals operating within this domain.

Jan 1, 2024

By Liming Yuan, Wei Tang, RICHARD THOMAS, JOHN SOLES

Lithium-ion (Li-ion) battery pack fires pose great hazards to the safety and health of miners. A detailed experimental study has been conducted at the National Institute for Occupational Safety and Health’s (NIOSH) Pittsburgh Mining Research Division (PMRD) to investigate the effectiveness of different fire suppression systems on Li-ion battery pack fire extinguishment. Tests were conducted in a well-ventilated container. Two sizes of battery packs (12 V and 24 V) were heated by heater strips to trigger thermal runaway and fire. Water mist with different flow rates, ABC powder, type D dry chemical, and water mist with F500 additives were used as the fire suppression agents. Multiple thermocouples were installed on the battery packs to measure the temperature evolution during the tests. The results indicate that the water mist with F500 additives is the most effective suppressant among the agents tested. Dry chemicals, however, do quench the fire for a moment, but cannot prevent re-ignition of the battery since they do not provide enough cooling. The findings of this paper can be used to develop safer battery fire suppression techniques in mining environments.

Jan 1, 2024

By Andrea Brickey, RICHARD AMOAKO, Akshay Chowdu

Production forecasts derived from the medium-term schedule represent the best path forward for underground mining operations to achieve corporate and operational goals. Unforeseen circumstances, such as equipment breakdown, can cause significant deviations from established production forecasts in the short term. Such situations require timely mitigation of the effects of the deviations in order to stay as close as possible to the medium-term plan. This paper presents a deterministic mathematical formulation for short-term scheduling that addresses this challenge. The formulation is able to make up for deficits resulting from operational disruptions by minimizing deviations from medium-term production goals and medium-term activity start dates. We demonstrate this in a case study by simulating disruptions involving reduction in ore extraction capacity and development advance rate. Aside from the rescheduling capability, this formulation can help mine planners conduct analysis on the impact of various disruptions on the schedule. The formulation can help identify those conditions or disruptions that are more detrimental to the achievement of forecast targets, or otherwise. The formulation also affords mine planners the flexibility to prioritize one production goal over the other, depending on operational conditions at the mine. In the future, we seek to incorporate in the formulation respirable dust, diesel particulate matter and ventilation constraints in order to create more realistic schedules, and enhance miners’ health and safety.

Jan 1, 2024

By Arif Emre Dursun

The aim of this study is to present hazard classifications of location, type, and causes of accidents in Turkish coal-extracting industries using Analytic Hierarchy Process (AHP). In this study, fatal mine accidents were analyzed by pairwise comparison and weighting, and the most important hazards were identified by determining the effective main and sub-criteria among location, type, and causes of accidents. For this purpose, 1st, 2nd, and 3rd level hazards consisting of location, type, and causes of accident were determined by using the data of fatal mine accidents in underground and open-pit coal mining in Turkey between the years of 2010 and 2020. And then the data were categorized, and each category was prioritized using the AHP technique. According to the weights calculated by AHP, the most dangerous main criteria at 1st level hazards in underground coal mining is ventilation operations (0.363), while the most dangerous sub-criterion at 2nd level hazards is firedamp explosions and other gas accidents (0.409). On the other hand, in open-pit coal mining, the most dangerous main criteria at 1st level hazards are slopes and benches (0.575), while the most dangerous sub-criterion at 2nd level hazards are landslides (0.429).

Dec 30, 2023

By Adabala Raja Venkata Sai Naresh, Radhakanta Koner

Particle size distribution (PSD) is an essential parameter in assessing the overall efficiency of blasting operations in mines and the subsequent mine-to-mill process in the mining industry. Despite some drawbacks of 2D image analysis techniques in accurately estimating particle sizes in PSD, the mining industry has relied on them for the last three decades. This study proposes the 3D rock fragmentation measurement (3DFM) technique for deducting the accurate dimensions of 3D rock particles for the PSD. 3DFM has utilized different processing algorithms. Images of different views of the non-touching rock particles of varying sizes have been acquired as a data acquisition step of structure from motion technology for generating sparse point cloud. Dense point cloud reconstruction is used to avail finer details of the point cloud using clustering views for the multi-view stereo algorithm. Random sample consensus (RANSAC) algorithm coupled with an unsupervised classification using the density-based spatial clustering of applications with noise (DBSCAN) classifier is employed to extract the rock clusters from the 3D point cloud. Finally, the accurate rock sizes are derived using the hybrid bounding box rotation identification (HYBBRID) algorithm with a root mean square error (RMSE) of 0.10 cm for length, 0.10 cm for breadth, and 0.32 cm for depth. The PSD of rock fragments obtained from the proposed 3DFM technique is found to be matching with the results of mechanical sieving and manual gauging with an R2 values of 0.98 and 0.99, respectively. The 3DFM method can be considered cheaper, more accurate, and computationally faster in determining the rock dimensions for the PSD determination method to enhance the productivity of the mining industry.

Dec 29, 2023

By Jorge Alberto Soares Tenório, Denise Crocce Romano Espinosa, Morgana Rosset, Bárbara da Rocha Pereira

High-purity alumina finds application in various electronic industry sectors, with approximately 100 million tons of this compound being produced worldwide. Alumina is acquired through the mining process of bauxite, a rock composed of a mixture of minerals such as gibbsite, kaolinite, hematite, and either anatase or rutile. In 2020, both bauxite and alumina were included in the list of critical raw materials. Due to the demand for high-purity alumina production, the development of a methodology to remove impurities present in the leach liquor from bauxite processing by solvent extraction (SX) followed by precipitation has been widely studied. This work aims to obtain high-purity alumina from bauxite by a solvent extraction process followed by a precipitation step from the sulfur leach liquor obtained by the thorough dissolution of Al and Fe from bauxite. Different parameters were evaluated in the SX step, such as extractant type, pH, temperature, and volume-to-volume ratio. The results indicated that using Alamine 336 as an extractant at pH 0 and room temperature led to an extraction of 90% of Fe and 15% of Al. Aluminum sulfate was completely precipitated as aluminum hydroxide and 55% of Fe using NH4OH. After the calcination procedure, obtaining a 99.9% pure alumina was possible without generating a red mud-similar residue.

Dec 28, 2023

By Chamila Jinendra Nanayakkara, Nimila Dushyantha, Amila Sandaruwan Ratnayake, Gayithri Niluka Kuruppu

Rare earth elements (REEs) are key ingredients in many advanced materials used in energy, military, transportation, and communication applications. However, the prevailing geopolitical dynamics and the rising demand for REEs have rendered the reliance on primary REE resources susceptible to future supply disruptions, posing a substantial risk to the availability of these elements for numerous applications. Therefore, it is imperative to undertake substantial initiatives in the extraction of REEs from secondary sources on a large scale to ensure the resilience of the supply chain. Permanent magnets, lighting phosphors, and nickel-metal hydride (NiMH) batteries are among the secondary sources with high potential for sustainable REE extraction. This review assesses the extraction potential of REEs from the aforementioned three secondary sources and their leaching kinetics and thermodynamics aspects. More importantly, state-of-the-art different existing kinetic models employed in rare earth (RE) leaching were well discussed for a better understanding of the REE leaching reactions. Furthermore, the optimized leaching parameters related to this kinetics were described, and various RE recovery methods were comprehensively summarized. These processes facilitate to managing one of the fastest-growing solid waste streams by minimizing environmental impacts and producing critical metals, including REEs via circular economy approaches. The recovery of REEs from secondary sources aligns with numerous United Nations Sustainable Development Goals (SDGs), particularly in the renewable energy sector for climate change mitigation. Consequently, this trash-to-treasure urban mining concept to transforming e-waste into a valuable resource for REE recovery emerges as a pivotal element within the REE industry.

Dec 28, 2023