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By X. L. Wang

Hydrothermal method was applied in the preparation of calcium sulfate whiskers in airtight re-actor using gypsum as primary materials. The optimum conditions of preparation are as follows: pH value 9.8~10.1, concentration 5%, material size 18.1µm, which were determined by the analysis of the diameter of CaSO4 whiskers through SEM. On these conditions a product of ultrafine CaSO4 whiskers with diameter of 0.19µm and aspect ratio of 98 is obtained. Ultrafine CaSO4 whiskers with different concentrations, modified by titanate NDZ-401, were added into polypropylene as intensifier and composites of Ultrafine CaSO4 whiskers/ polypropylene were prepared by melting-extruding method. Mechanical performance of the composites was tested and surface morphology of the composites was observed by SEM. The results indicated that impact notched izod of the composites was enhanced by 49.5% compared with pure polypropylene when 10.0% Ultrafine CaSO4 whiskers were added into polypropylene and toughening effect was very remarkable. Dispersion behaviour and interface phenomenon of Ultrafine CaSO4 whiskers in polypropylene matrix were investigated by SEM. The results indicated that Dispersion performance of Ultrafine CaSO4 whiskers modified by titanate NDZ-401 in polypropylene matrix is good, which improved mechanical performance of composites to some extent.

Jan 1, 2014

By F. H. Deist, M. P. Roberts

"The Collieries Research Laboratory of the Chamber of Mines of South Africa is developing a coherent system of programs to aid in the full spectrum of activities arising in the planning of new as well as operating mining enterprises. It is the purpose of this paper to describe the design and application of two subsystems in the complex.One of these subsystems is an initial version of a production simulator. This program draws upon a model of a mining enterprise and simulates the operational and financial aspects of a set of alternative mine production plans.These plans are specified in terms of proposed sequences of operations. Details such as reserves, production rates, resource requirements and so on, are taken from the model.Physically, the model takes the form of a cross-referenced data base, maintained by means of a general file maintenance system which is another subsystem described.The paper concludes with a description and analysis of the first practical application of the two programs."

Jan 1, 2014

By N. Acarkan

Slags usually contain some quantity of valuable metals. They are actually a secondary resource of metals, rather than an end-waste and have been utilized as a resource material in many areas. In addition, for some applications, slags have comparable or even better properties than their competitors. Leaching is a method for extraction of metals from copper slags. The extraction of metals such as copper and cobalt from the copper slag of Küre-Turkey, was investigated in the past decades. Fayalitic type of these copper slags containing 0.934 % Cu, 0.353 % Co and 50.91% Fe were subjected to the experimental study. As a result of mineralogical analysis of the slag sample, fayalitic type of slag was found to contain hercynite, magnetite, hematite, pyrite, chalcopyrite, covellite, bornite and metallic copper. Direct acid leaching methods were applied on the sample. Effects of leaching time, temperature and acid concentration on Cu and Co leaching recoveries were investigated in the direct acid leaching. The optimum leaching conditions were found as leaching time of 2 hours, solid/liquid ratio of 1/3, H2SO4 concentration of 125 g/L and temperature of 70 °C. At these conditions, 75.5 % of Cu, 95.6 % of Co and 70.9 % Fe were extracted. In the second stage of the leaching experiments, copper in the pregnant solution was precipitated by cementation to produce a Cu concentrate assaying 95.58 % Cu; cobalt was obtained by precipitation with H2S to produce a concentrate containing 62.10 % Co. As a result of this study a process flow sheet has been developed for recovering Cu and Co from these slags to demonstrate its economic and technological benefits.

Jan 1, 2014

By K. Tsuchihashi, A. Kishimoto, T. Uda, Y. Kado, S. Maruyama

We recently proposed a continuous production process for titanium metal with some experimental results. In the process, titanium tetrachloride is reduced by Mg in the presences of Bi to form a Bi-Ti alloy at 900ºC. At this temperature, the obtained alloy is liquid and allows for the continuous removal of product and heat from the reaction vessel. The obtained Bi-Ti alloy was vacuum-distilled at 1000ºC for 24 hr, and 98 at % (92 wt %) titanium, which was easily crashed to powder, was obtained. Bi solvent was selected because of the highest titanium solubility at 900ºC and the moderate vapor pressure among the candidate metals (Bi, Sn, Pb, Zn, and Sb).

Jan 1, 2014

By Guadalupe Sanchez, Roel Cruz, Sergio Castro, Claudia Beltrán, Isabel Lázaro

The recovery of zinc in refineries is strongly affected by the formation of zinc ferrites during the roasting of zinc concentrates. To achieve the highest zinc recovery most of these plants operate under high acidity and high temperature conditions in their leaching circuits. However, under these conditions high iron dissolution occurs. For iron control the common practice is to precipitate it as jarosite, and calcine is normally used as neutralizing agent. This practice causes a significant loss of metal values associated with the calcine, such as zinc ferrites and silver insoluble phases. These metal values are carried by the jarosite into confined waste in many plants. In order to diminish such losses, it is necessary to use a neutralizing agent that could substitute the use of calcine. An alternative neutralizing could be the basic zinc sulfate (BZnS). This work presents the results of a laboratory analysis on the required conditions for the BZnS production from process streams of a zinc refinery plant. Neutralizing behavior of BZnS was evaluated in iron precipitation as jarosite, in order to establish the feasibility of replacing the calcine and decrease the loss of zinc and other metals values during the iron removing step of the hydrometallurgical circuit of the zinc refinery under study.

Jan 1, 2014

By A. Vilinska

Microorganisms have a tremendous influence on their environment through the transfer of energy, charge, and materials across a complex biotic mineral-solution interface. Recent developments in biotechnology have not only aided hydrometallurgical leaching operations but also shown great promise in mineral beneficiation processes. The adhesion of bacteria on minerals alters the surface properties relevant to flotation and flocculation of minerals. The biomodification of mineral surfaces occurs through the attachment of microbial cells, oxidation reactions and adsorption or chemical reaction with the metabolite products. Several types of heterotrophic and chemolithotrophic bacteria have been successfully applied in flotation and flocculation processes for the last two decades. Al-though the potential of microorganisms in minerals beneficiation has been realised by several re-searchers from their laboratory investigations, the studies were mostly confined to pure mineral systems and there is hardly any sincere effort to apply the methodologies on ores. This paper presents a brief summary of the literature in bioflotation and bioflocculation, and attempts to outline new dimensions of research for a practicable application of this technology in mineral industry.

Jan 1, 2014

By Olli Haavisto, Heikki Häkkänen, Tommi Kauppinen, Navid Khajehzadeh

Raman analysis is a well-established method for finding the abundant minerals in an ore sample. In this study, Raman spectroscopy is tested as a method for rapid and contactless on-line mineral analysis. Rapidness might enable on-site analysis of rock drillcore, which in turn would lead to more cost-efficient solutions in mineral exploration. This paper discusses the use of Raman analysis to identify minerals and to measure their concentration. The sample set under study consists of rock drillcore collected from Agnico-Eagle Kittilä Mine, Finland. Selected parts of the sample set are measured by Raman spectroscopy and the minerals are identified using reference spectra from a public source. Moreover, the direct measurement of concentration of different minerals with the help of Non-negative least squares (NNLS) optimisation algorithm is considered. The optimisation algorithm was constructed to form a linear combination of reference spectra which best represent the measured spectrum, or an average of measured spectra, from an ore sample. The results show that NNLS can identify abundant minerals in a given sample. Also through this method of analysis the results of a traditional point-count method can be expanded: It was observed that, due to grain size, multiple minerals consistently appear in the spectra measured over an area, which means that point-count method is not a proper way to interpret the spectra. This can be seen as a new result, as formerly the discussion has attended to other methods.

Jan 1, 2014

By N. V. Ramana Murthy

Utilisation of Low-Grade Iron Ore Fines after concentration not only helps in conservation of the mineral wealth, but also substantialsly improves the economics of iron ore mining. There has been need to develop suitable beneficiation process for upgradation of low-grade iron ores towards their rational utilisation. Presently the circuit adopted for processing iron ores has limitations in reduction of alumina. The depletion of high-grade reserves, utilisation of low-grade reserves coupled with in-creasing market pressure for improved product quality necessitates re-examination of the process flow sheets and evaluate alternative or supplemental processing routes. The main objective of the Process amenability studies for utilisation of Low-Grade Iron Ore Fines (-10mm) is to get Pellet grade concentrate with +65% Fe (min), SiO2 1.8% (max), Al2O3 1.8% (max) and other proportionate constituents by adopting suitable beneficiation techniques and to collect the relevant data (Quality and Quantity of the Products) for the process development. In an effort to formulate a conceptual process flow sheet, the Process amenability studies for utilisation of Low-Grade Iron Ore Fines (-10mm), which is lying at a mine site in India, samples were collected and taken up for the study. The efforts of R & D of NMDC are discussed in this paper. Low-Grade Iron Ore Fines (-10mm) sample assayed 60.10% Fe with 3.48% SiO2 Aland 4.48% 2O3from 40 microns to 300 microns. The sample consists of hematite as the chief ore mineral followed by minor amounts of maghemite. The gangue minerals include quartz and ferruginous clay in which quartz occurs as medium grained where as ferruginous clay occurs as fine to sub microscopic size mineral. The economical processing route evolved out of the studies finally could yield a final concentrate constituting 58.63% by weight along with Iron unit?s recovery of 63.51% assaying 65.10% Fe with 1.48% SiO2 and 1.85% Al2O3route that adopted comprises the following operations. Making slurry in a sump pump followed by grinding in close circuit with 48mesh size Screen. The -48 mesh size product was subjected o the Cycloning to remove slimes. The Cyclone Underflow product was subjected to Floatex Density Separation (FDS) to separate fine heavy minerals from the gangue minerals. The FDS Underflow was collected as concentrate. The FDS Overflow product was further subjected with Wet High Intensity Magnetic Separation (WHIMS) to recover more Iron units as magnetics. A conceptual process flow sheet was evolved, which may become the prelude to the subsequent finalisation of the process flow sheet for commercialisation.

Jan 1, 2014

By L. Gonzalez-Sardi, W. McCombe, M. Pearson

Pressure oxidation is increasingly being used for processing refractory sulphide ores and concentrates because it offers highly effective base metal and precious metal extraction while minimizing elemental sulphur, arsenic & mercury emissions. Yet pressure oxidation processes introduce new safety concerns and process risks as demonstrated by a number of safety incidents over the last 20 years, including overfilling, oxygen-metal fires, nozzle/sparger failures, and uncontrolled pressure relief events. Chemical Process Safety regulations in the United States and Canada mandate that companies constructing or operating chemical process facilities perform a rigorous hazard and risk analysis based on either ANSI/ISA-84.00.01 or IEC 61511 safety standards to determine the level of protection required for each hazard in the plant. This paper describes the application and implementation of three (3) unique safety instrumented systems developed by Hatch for ensuring the safe operation of three different pressure oxidation processes.

Jan 1, 2014

By Meredith Scaggs, Emily Sarver, Lucas Rojas Mendoza

"Early on Jan. 9, 2014, approximately 37,800 L (10,000 gal) of crude 4-methylcyclohexanemethanol (MCHM) leaked from a storage tank sitting on the bank of the Elk River near Charleston, WV (WVDEP, 2014; CSB, 2014). MCHM is a chemical commonly used in preparation of fine coal and is considered nonhazardous in terms of transportation, storage regulations and also toxicity (CDC, 2014a). Freedom Industries Inc., a producer and vendor of specialty chemical products, had acquired the storage facility from Etowah River Terminal, LLC just a few weeks prior in December 2013 (WVDEP, 2014; Freedom, 2005). The direct cause of the spill was ultimately determined to be two small holes in the base of the 76-year-old tank, which were created due to corrosion damage (Bauerlein and McWhirter, 2014).The spill site was located a little more than 1.6 km (1 mile) upstream from the intake of a municipal water treatment facility operated by West Virginia American Water (WVAW), which serves a population of 300,000 across nine counties in central West Virginia (CDC, 2014a). In a matter of hours, the leaked MCHM made its way through the treatment facility and into the water of nearby homes and businesses, where its strong smell was noticed almost immediately. On the evening of the spill, WVAW concluded that its conventional treatment processes, which include carbon filters to remove a variety of contaminants from water, were not capable of fully removing the MCHM and a "Do Not Use" order was issued for all customers (WVAW, 2014a).With little information readily available regarding the potential human health effects of MCHM, the U.S. Centers for Disease Control and Prevention (CDC) quickly issued an advisory ruling that set a maximum screening level of 1 ppm for safe drinking water (CDC, 2014a). Based on this recommendation, the "Do Not Use" order remained in effect for a total of eight days, until Jan. 17, when the WVAW distribution water was confirmed to have MCHM concentrations below the approved level (WVAW, 2014a). However, due to the pungent odor of the chemical, its presence was still recognizable in the WVAW facility and in consumers’ tap water after the order was lifted (Manuel, 2014). Recent studies have shown that the chemical can be detected in water at sub-ppb concentrations, a fact that undoubtedly added to growing public concern (Rosen et al., 2014; Gallagher et al., 2014). In response to numerous complaints and demands, WVAW continued flushing the treatment facility and pipes until Feb. 25 when MCHM levels were measured below 2 ppb (WVAW, 2014b), and eventually replaced the affected filter media (WVAW, 2014c)."

Jan 1, 2014

By Ghislain Bournival, Seher Ata, Graeme J. Jameson

A common method to prevent bubbles from coalescing in a flotation cell is by the addition of surfactants, called frothers. The gas dispersion properties in a column were tested for solutions of 1-pentanol, tri(propylene glycol) methyl ether, and poly(propylene glycol) in the presence of sodium chloride. The dependency of surfactant on the gas holdup can be divided into regions. It seemed that for a sufficiently low concentration of surfactant, even a stronger surfactant could show a transition in gas holdup from constant/decreasing to increasing with concentration. This region, however, was not marked by a decrease in the average bubble size. In addition, PPG gave higher gas holdup values while averaging larger bubbles. On the other hand, sodium chloride mostly affected the gas holdup when the concentration was high enough to prevent bubble coalescence. Another parameter affecting the gas holdup was the superficial gas velocity. A linear dependency was found between the two under a bubbly flow regime. The current study showed that both surfactants and salt could slightly affect the influence of the superficial gas velocity on the gas holdup.

Jan 1, 2014

By L. S. Gertsch

The production of minerals for human use at locations other than the Earth is expected to ?advance ? human prosperity in ? ways that [do] not compromise the potential prosperity and quality of life of future generations? (Brundtland, 1987); in other words, sustainably. This paper examines the interaction of extra-terrestrial mineral production (ETMP) with the following sustainability imperatives: ? The sustainability of human activities on Earth; ? The sustainability of human activities elsewhere; ? Human survival in general, the ultimate sustainability goal. Some of the consequences of mineral production on Earth are widely considered to decrease the future prosperity and quality of human life. Examples include noxious by-products or wastes and unsettling economic up- and downswings. Moving mineral production activities to extra-terrestrial locations, where appropriate, will decrease many of its deleterious effects. Terrestrial mineral production presently is decreasing in some countries and increasing in others, moving from the cheaper and easier ores to more expensive, difficult materials. When the full costs of maintaining the terrestrial environment in a sustainable manner are included, total mineral pro-duction costs must increase. The cost of extracting mineral products from extra-terrestrial sources will be substantially higher, especially in the initial phases, but as the full costs of terrestrial production increase, at some point in the future (different points for different minerals), the curves will cross (Fig.1). This will occur at different points for different materials, a process whose prediction will be complicated by substitution of cheaper materials for some uses as prices of the original material rise. In summary, mineral products from extra-terrestrial sources will tend to increase the sustainability of human civilization, once steady state has been reached.

Jan 1, 2014

By K. C. Viveros, R. R. Ambriz, C. García, F. De Villèle, A. Talha, D. Jaramillo

Cold hole expansion on base metal, weld metal and heat affected zone of 6061-T6 aluminum alloy welds was simulated by means of finite element method. Three dimensional compact test models with a previous fatigue crack length with a relation of ??= a/W = 0.3, were used to analyze the hole expansion process. Considering the local mechanical properties for each zone of the welded joint, the optimal expansion degree (1.64 to 2.46 %) was determined. The residual stress field, through thickness, after the expansion process in all welding zones, were correlated with the crack opening displacement obtained by finite element analysis. It was observed, that compressive residual stress fields for a post-expansion, in different crack lengths, provided a crack closure mechanism for base metal, weld metal and heat affected zone. Contrary, the crack remained open when residual stresses are positive. The results are given as tangential stresses versus distance from the edge of the cold expansion and crack opening displacement as a function of applied load.

Jan 1, 2014

By T. Shumba

The solvent extraction section of an old Uranium Plant in the Vaal River region produced a sub-stance called Crud (Chalk River Unidentified Deposit) that formed within the aqueous/organic interface of the settler of the solvent extraction circuit. The crud was deposited together with gold tailings to the tailings dam many years ago. Previous research done on the crud confirmed that ex-posed crud leaches Mn and Ni at concentrations that are well above their acceptable risk limits as well as Zn that leaches at concentrations that are slightly lower than its acceptable risk limit. Soil washing and bioremediation technologies were employed to treat the contaminated soil. Various laboratory test work and the pilot scale studies were conducted in parallel with each other and the results of the laboratory studies were used to determine critical parameters. Four lixiviants, i.e. sulphuric acid, acetic acid, oxalic acid and ethylene diamine acetic acid were tested at three concentration levels i.e. 0.001M, 0.0001M and 0.00001M, respectively. Column tests showed that the leaching of the heavy metals increases as the soil porosity increases. Silica sand was added to increase porosity of the contaminated soil. Highest Mn removal was achieved mainly by sulphuric and oxalic acid at 0.001M at all soil levels. EDTA was significantly efficient in the removal of Ni and Zn. The recovery of heavy metals, particularly Mn, decreased as the depth of sampling in-creased. Heterogeneous bacteria and filamentous organism plate counts were conducted to evaluate the growth of the bacteria and filamentous organisms in the soil. Results showed that more organism growth took place in the bioremediated soil with a fertilizer added to it. The leaching of metals from the soil that was bioremediated in the pilot study was generally higher than the extraction of the metals from the soil that was leached with no bioremediation carried out. The results from this study suggest that the leaching of heavy metals from the contaminated soil is to a large extent dependant on the pH of the leaching solution. By increasing the soil?s porosity and bioremediating the soil, higher extractions of metals were achieved.

Jan 1, 2014

ABSTRACT Understanding process histories and worker exposures in nickel production operations is critical in determining the role nickel compounds play in respiratory cancer incidence. As part of a series on Vale Canada’s (previously known as Inco) nickel processing operations, this paper includes descriptions of Ni electrolytic operations at refineries in Port Colborne, Ontario (1922–1984), and Thompson, Manitoba (1961–present). Industrial hygiene measurements, by area and personal sampling, of workplace aerosols at these operations are reported.

Jan 1, 2014

By Jianjun Tian, Changjiu Zhang, Chunmin Wang

Two lines of single stage autogenous milling circuits have been installed and commissioned as the primary grinding process for the Sino Iron project where magnetite ore is treated to produce iron concentrate via magnetic separation. Various challenges were encountered during the commissioning and ramp up stages which are discussed in the paper and include treating a highly competent ore in a closed circuit AG mill, operating the largest mills in the world and dealing with a number of engineering issues related to plant operability. Details of how these challenges were overcome are described as well as the observed operating characteristics of the mills and their optimisation through rigorous study, simulation and successful solution implementation. Further potential improvement opportunities are also discussed as part of the ongoing technical program at site.

Jan 1, 2014

By Avishan Atrafi, Marek Pawlik

"Gas dispersion properties of sodium salts of 6, 12 and 18-carbon fatty acids (hexanoic, lauric and oleic acid) were investigated as a function of pH. A strong effect of pH was observed on gas dispersion properties of fatty acids. At high pH for 12 and 18 carbon fatty acids, at which these surfactants formed a true solution, the gas dispersion properties were similar to those of MIBC. In the case of sodium hexanoate, which has a much higher solubility than the longer chain fatty acids and therefore does not form precipitates, the gas dispersion properties of this surfactant were strongly enhanced in the acidic pH range, where hexanoic acid was fully associated. This result is an indication that undissociated hexanoic acid is much more surface-active than anionic hexanoate. Only a small effect of the surfactant chain length on gas dispersion properties of the tested reagents was observed. The measured critical coalescence concentration (CCC95) values increase slightly by decreasing chain length and range from 5.8 x 10-5 mol/L (17.7 mg/L) for sodium oleate to 7.2 x 10-5 mol/L (16 mg/L) for sodium laurate at pH 10 and 1.9 x 10-4 mol/L (26 mg/L) for sodium hexanoate at pH 3.7. These are compared to CCC95 of MIBC, which is measured to be 8 x 10-5 mol/L (8 mg/L). The soluble molecular species were recognized as the most effective species in preventing bubble coalescence."

Jan 1, 2014

By Silvia Serranti, Giuseppe Bonifazi, Roberta Palmieri

The possibility to develop an efficient recovery and reuse of concrete materials from Demolition Waste (DW) represents one of the main targets applied to end-of-life constructions dismantling/recycling. The need to recycle end-of life concrete materials is strongly increasing in these last years for several reasons: i) the decrease of steady supplies of good quality natural aggregates, ii) the need to secure ample supplies of concrete aggregates to the construction industry and, finally, iii) the environmental constraints limiting the DW wastes disposal. The fulfilment of these goals produces several benefits, that is: i) a reduction of new resources consumption, ii) a strong reduction of the costs linked to transport and energy production, iii) the possibility to utilize materials, otherwise lost (e.g. land filled), iv) land preservation and, finally, v) the reduction of the environmental impact of new exploitation activities. A lot of efforts have been addressed to develop, set-up and apply innovative technologies to maximize DW conversion into useful secondary raw materials. The possibility to utilize efficient, reliable and low cost analytical tools to perform detection/control actions: i) to assess concrete characteristics, before demolition, and ii) to detect the presence of contaminants in coarse aggregates (e.g. bricks, gypsum, steel, glass, plastics, wood, etc.) represent the key issues to fulfil in order to develop innovative process/control actions/procedures inside the DW sector. In this paper a new technology, based on HyperSpectral Imaging (HSI) sensors is investigated to develop suitable and low cost strategies finalised to define and implement innovative smart detection engines for sorting and/or DW flow stream quality control, addressed to perform recovered materials and/or products certification. The proposed sensing architecture is fast, accurate, affordable and it can strongly contribute to bring down the economic threshold above which recycling is cost efficient.

Jan 1, 2014

By J. H. Zietsman, S. Maharajh, J. Muller

In the chlorination process for TiO2 pigment production, blends of titania feedstocks such as ilmenite, synthetic rutile (SR), natural rutile, upgraded slag, and chloride-grade slag are reacted with coke and chlorine at a temperature of around 1000°C to form TiCl4, which is the main product, and other waste metal chlorides. TiCl4 is the main feed material for the TiO2 pigment-making process. Feeding different titania materials to the chlorinator affects the amounts of coke and chlorine required for the process, the amount of waste generated, waste disposal costs, the amount of TiCl4 produced, and bed build-up rates. These factors influence the value of the feedstock. Generally, a higher TiO2 feedstock is more valued since less waste is generated and less reagents are consumed. To quantify the impact of different feedstocks on the chlorinator, a techno-economic model was developed to describe the chlorination process and estimate process variables at steady state. This paper describes the development of the model and studies in which the model has been used to quantify the effects of using different feedstocks.

Jan 1, 2014

By Xiao Jian Li, Dai Xiong Chen, Jian Wen Yang

In one kind of lead and zinc bearing polymetallic ore containing secondary copper, the characteristic of low sulfur, high zinc, and particularly the existing of secondary copper minerals can lead to lead concentrate with high content of zinc because the dissociation of Cu2+ in the grinding process may have an activation influence on sphalerite. Considering its process mineralogy analysis, a new process of seperation of lead and zinc has been put forward. The experiments focused on the analysis of the advantages and disadvantages of the inhibition effect of traditional adjustment reagent + zinc sulfate on activated sphalerite compared with new organic inhibitor, polysaccharide xanthate. According to the numerical calculation and test results, a reagent system of polysaccharide xanthates is developed, which has a good inhibition effect on Cu2+ activated zinc minerals, achieving high-efficiency separation of lead and zinc. A new reagent system and flotation process was developed under optimal conditions. Under the condition of the run-of-mine ore containing 2.37% Pb and 12.48% Zn, lead of 67.69% grade and lead concentrate with the recovery rate of 86.06%, zinc of 60.32% grade and zinc concentrate with the recovery rate of 96.15% were achieved.

Jan 1, 2014