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By Jake Gibson

"As one of the most pressing and important political debates of this century, climate change has captured global attention and is forcing governments to take action toward decreasing greenhouse gas (GHG) and carbon emission levels below what was previously thought to be necessary. With the ever-increasing price of diesel fuel, accompanied by the popular topic of carbon taxes and greenhouse gas emissions, the mining industry is looking to industry specialists for assistance. The benefits of a no-idle policy reach far beyond carbon reduction and fuel savings, ranging from decreased maintenance to increased engine life. With products like battery-powered ac systems and diesel-fired heaters, going noidle is easier today than ever before. With both systems being manufactured to withstand the harsh environments of the mining industry, the end user will see a seamless change from conventional, inefficient belt-driven systems to future, standalone mobile equipment HVAC.The history of GHGs and climate changeIn 1896, Svante Arrhenius first claimed that the combustion of fossil fuels may eventually result in enhanced global warming, but not until 1955 did Gilbert Plass draw global attention to global warming by summarizing that adding carbon dioxide to the atmosphere would intercept infrared radiation and thus warm the earth. Then in the early 1960s, Charles Keeling developed modern technology to produce concentration curves for atmospheric CO2 (Fig.1).In 1988, the Intergovernmental Panel on Climate Change (IPCC) was founded by the United Nations after acknowledgment of a rising global annual temperature. The IPCC consists of more than 2,500 scientific and technical experts from more than 60 countries. Because climate change could not be solved by a single country, the Kyoto Protocol was negotiated in 1998, requiring all participating countries to reduce their GHG emissions by at least 5 percent from the 1990 levels. The Protocol was signed by 186 countries in 2001 (since then several countries have retreated from the agreement, including the United States). In 2002, the Bush administration announced a policy for climate change relying on domestic, voluntary actions to reduce the "greenhouse gas intensity" of the United States economy by 18 percent by 2012. The U.S. still attends the Kyoto conference of parties (COPs) but does not participate in negotiations, as it is not bound by its terms."

Jan 1, 2014

By D. J. Zhao

The reduction of ilmenite pellets was investigated at 950°C and 1000°C under a CO-N2 gas mixture with 10 L/min gas flow rate. All the reducing reactions were conducted in a furnace with a thermogravimetric analysis system. The reduction rate is higher at 1000°C than that at 950°C. At the early stage of the reactions, with the CO concentration increasing in the gas mixture, the reduction rate increased at 1000°C. In addition, at the early stage of the reactions, a rapid temperature increment and a rapid conversion of oxygen were observed on the curves of temperature versus time and conversion of oxygen versus time under different experimental conditions. The solid reaction products obtained in these experiments were analyzed by Scanning Electron Microscopy (SEM) and Energy Dispersive Spectrometers (EDS). Metallic Fe with small amount of Ti dissolved in it and oxides of Ti were found in the solid reaction products, but the formation of any nitride phases was not found under the prevailing conditions.

Jan 1, 2014

By B. Q. Xiao

In surfactant flooding, surfactants added are often a mixture of the same type of molecules with different lengths of carbon chains. The relationship between a single, pure surfactant solution and crude oil is seldom studied. Additionally, up to now, alkylbenzene sulfonates are applied widely in surfactant flooding, such as Daqing oilfield, China. A factory producing alkylbenzene sulfonates will enlarge its yield to 20 000 tons per year over there. For the purposes of widening the alkylben-zene sulfonates? application, 16 kinds of pure alkylbenzene sulfonates were synthesized through Friedel-Crafts acylation and Wolff-Kishner reduction reactions, and the compounds? molecular structures were confirmed by 1HNMR and 13CNMR spectra. The factors affecting interfacial tension (IFT), such as, surfactant type, oil composition, electrolyte concentration, and alkali concentration were considered. The synthesized pure surfactants? critical micelle concentration (CMC) and optimal salinity were measured through interfacial tension technique. According to lab experiments results, heavy alkylbenzene sulfonate (2SY) was synthesized in magnifying scale in Jinzhou Wash Chemical Plant and the coretests were conducted using it. The results showed that the homemade heavy alkylbenzene sulfonate (2SY) flooding can improve oil displacement efficiency 20% more than water flooding at surfactant?s concentration from 0.05%(wt) to 0.2 %(wt).

Jan 1, 2014

By Johannes Käppeler, Alexander Weh, Harald Giese, Klaas van der Wielen

"High voltage breakage is a novel comminution technology that shows considerable potential for various applications in mineral processing and recycling. It relies on highly energetic electrical pulses to induce electrical explosions in rocks, causing the formation of plasma channels and powerful shockwaves that result in fracturing and fragmentation of particles. There has been considerable interest in this technology for its ability to weaken rocks and preferentially liberate target minerals, as previously demonstrated by other authors. Weakening has the potential to significantly reduce energy consumption during comminution, or alternatively, increase throughput of a circuit. Better liberation may yield an improved concentrate grade and/or recovery, reduce fines losses to tailings or increase the grind size required for liberation, thereby also reducing energy requirements. This review aims to increase general awareness of this technology, and promote further research into it by providing a general summary of the theory underlying high voltage breakage, as well as the envisaged applications of this novel technology. A brief history of the technology is presented before progressing onto the physics underlying the electrical and geomechanical aspects of high voltage breakage. Key results regarding weakening and liberation are discussed, and some mention is made of current challenges and planned developments to increase the throughput of high voltage breakage units to the level where it can be integrated into new and existing processing circuits."

Jan 1, 2014

By H. Zhu, Q. Jiang

The leaching kinetics of iron during the atmospheric direct leaching (ADL) of marmatite concentrate was studied under the following conditions: reaction temperature of 343-383 K, slurry pressure of 0.3-0.7 MPa, particle size of (-74 ?m, +63 ?m), (-63 ?m, +44 ?m), (100%-44 ?m). The statistical effects of reaction temperature, total pressure and particle size of concentrate on the extraction and the leaching rate of iron were analyzed. The results show that reaction temperature is a significant factor while slurry pressure and particle size are not statistically meaningful with respect to the extraction or the leaching rate. The extraction of iron fits better to the mixed-controlled shrinking core model and the apparent activation energy was calculated to be 37.66 kJ/mol. The leaching of iron is mixed controlled by the interfacial chemical reaction and diffusion across the product layer.

Jan 1, 2014

By Peter Ay, Harry Pempel, Satya Narra, Mike Müller, Jens Markowski

"Within the next few years major changes in mobility are expected. Increasing numbers of electric powered cars, electrobikes and E-Scooters define the transport sector. Recently lithium based traction batteries as storage medium have led into matrurity of series production combining high electrical efficiencies with low weights and compact dimensions. Due to the relatively young development with lithium batteries utilization, only few investigation were conducted regarding their recycling. Conventional battery recycling processes can not be applied due to differences in design and chemistry. So an automated disassembly and processing procedure for lithium traction batteries has been developed in the R/D-project ""Li-WERT"". Instead of complete smelting of the batteries without pretreatment, an automated disassembly and specific treatment of the material streams was realised, adjusted to the needs of the subsequent recovery technologies. A higher quality, with reduced expenses for the separation of fine-grained or fused material mixes, can be obtained for the individual components. The automated disassembly using an industrial robot significantly reduces dangers for the operating crew. The selective disassembly and beneficiation allows full recovery of the fractions. The batteries will be disassembled to cell level by the industrial robot. Anodes, cathodes, and separation layers are isolated and processed. The technology is designed, that no waste is generated for disposal. The pelletised cathode coating and the other separated metals (stainless steel, copper, aluminum) can be used in respective metallurgical plants. Circuit boards and plug contacts are also coveted secondary raw materials for reuse. The process is modular and offers high flexibility, e. g. for new battery types/ sizes by quick adjustment of the robot and tool change. Adaptation to other cathode materials (e. g. Li[FePO]) is possible. After finishing the R/D-project, a pilot plant for demontage was realised in 2013."

Jan 1, 2014

By P. A. Bepswa

A numerical study done to test the efficacy of heuristics developed for the design of measurement networks for high precision metallurgical accounting is presented in this paper. The heuristics considered were designed to maximise variance reduction of terminal stream measurements through data reconciliation for observable linear flow systems. A complex metallurgical process flow sheet from the mineral sands industry was used as a case study. Monte Carlo type simulations coupled with a non-linear programming based steady state data reconciliation algorithm were used as tools to investigate the heuristics. The results obtained suggested a close correlation between magnitudes of measured variances and the respective levels of variance reduction obtained through data reconciliation for both internal and terminal streams. It was observed that variance reduction through data reconciliation was maximised for terminal stream measurements in networks characterised by high precision measurement of internal streams and/or in flow sheets characterised by high ?stream to node ratios?. Terminal streams attached to highly interconnected parent nodes were observed to experience higher reductions in variance compared to terminal streams attached to less interconnected parent nodes. The results generally highlight the additional benefits of highly interconnected flow sheets and high precision internal stream measurement regimes on the maximisation of variance reduction of terminal stream measurements through data reconciliation. These findings are significant to metallurgical accounting and to process accounting applications in general in that they provide a conceptual basis for design decision making regarding the construction of measurement networks aimed at maximising variance reduction of targeted streams through data reconciliation.

Jan 1, 2014

By Jesús L. Valenzuela, José R. Parga, Salvador Aguayo, Héctor Moreno

The Merrill Crowe zinc-precipitation process has been applied worldwide on a large number of operations for the recovery of gold and silver resulting in a higher consumption of zinc dust from cyanide solutions. However, in some of plants this precipitate is of low quality, because lead, cadmium and especially copper are precipitated along with gold and silver. The low quality precipitate also requires more fluxes in smelting and shortens crucible life. In this study, a process is introduced to remove copper, silver, lead and cadmium from barren solutions following the Merrill-Crowe process. Copper and silver are removed by precipitation in a serpentine reactor, using sodium sulfide as the precipitator, and sulfuric acid for pH control. The recovery of lead and cadmium ions with natural hydroxyapatite using cow bone powder (CBP) as a new adsorbent material, is introduced. CBP is capable of removing lead and cadmium ions from aqueous cyanide solutions with 99% efficiency. It has the ability to compete with other existing commercial adsorbents for the removal of lead and cadmium. Results show that pH value has a significant effect on copper cyanide removal efficiency, and it was determined the optimal pH range to be 2 - 3. At this pH value, the copper cyanide removal efficiency achieved was up to 99 %; and for the cyanide associated with copper cyanide complexes, the recovery was 90%. Finally, the precipitate quality was improved 400% .This procedure was successfully run at three mines in México.

Jan 1, 2014

By J. Langwaldt

Ammonium-nitrate is a main component in blasting agents and dissolved ammonium residues may be discharged with mine water. The European Union aims to reach a good state of the water quality and recommends ammonium content below 0.5 mg/L for drinking water. Natural zeolites adsorb ammonium from water. In this work, the removal of low-concentration ammonium by commercial natural zeolites was studied in continuous tests. Natural zeolites made up between 83% and 95% of the mineral composition. The major zeolite minerals were chabazite and clinoptiolites and minor amounts of erionite and mordenite were as well present. The five natural zeolite samples, 500~710 µm, were conditioned to obtain zeolites in the Na-form. Ammonium adsorption onto natural zeolites depends mainly on the zeolite mineral type. The chabazite containing zeolite was superior over the four clinoptiolite samples for the removal of low concentrations of ammonium from water (pH of 7.5, flow 5 mL/min, room temperature). The adsorption capacity of chabazite was 48.3 mg NH4+/g zeolites, i.e. 73% of the theoretical exchange capacity 69 mg NH4+/g, during duration over 107 days and almost 6700 bed volumes exchanged. The four tested clinoptiolites had an ad-sorption capacity of 15.7mg to 25.0 mg NH4+/g zeolites. The natural zeolites were rapidly regenerated by an alkaline sodium chloride solution fed to the columns.

Jan 1, 2014

The energy dispersion X-ray fluorescence (EDXRF) analysis technique is a rapid and accurate method for describing sample?s element component and percentage composition. On the base of profound research for the national and international development and research condition, the author researched the EDXRF analyze technique and the EDXRF analyzer?s principle in depth, the difficulties and the key points for research and development of EDXRF analyzer; gave a scheme for re-search of bench EDXRF analyzer; researched some algorithms used in energy spectrum analysis; developed the energy spectrum analysis software based on the Visual C++ 6.0; together with the energy spectrum analysis software, the author designed and processed the structural of the bench XRF analyzer and integrated the import X-ray tube, thermoelectrically cooled Si-PIN photodiode X-ray detector and pulse amplitude analyzer as a model machine. The result shows: The model machine can be used in multi-element analysis at the same time for different types of dry mineral samples, with fast analysis speed, accurate model and high stability.

Jan 1, 2014

By Sravya Kosaraju, Christian Ekberg, Stefan Allard

Li-ion batteries are now used in electric vehicles (EVs), plug-in hybrid vehicles (PHEVs) and, hybrid electric vehicles (HEVs). Nanostructured Li(NiyMnzCo1-y-z)O2 is one of the more popular cathode chemistries for automotive Li-ion battery, due to its enhanced properties such as large surface area, short diffusion length, enhanced ionic and electronic conductivity, improved mechanical strength and structural integrity [Pan et al, 2013]. Recycling of Li-ion batteries helps to mitigate environmental effects of virgin metal extractions along with improper disposal of end of life batteries. To fulfill these objectives of the recycling, recovery of pure streams of the involved metals should be considered. In this study, the batteries were first discharged and dismantled in an inert atmosphere (Ar). The electrodes were then heat treated in a box furnace. This was done in order to break the chains of the adhesive (PVDF) and consequently separate the metallic substrates Cu and Al from the electrochemically active compound. This heat-treatment also helped to simplify the dissolution of the metal constituents in the electrochemically active compound from the cathode in the acid leaching process. Solvent extraction was chosen to achieve separation and recovery of metals with higher purity from these leachates. In the scope of the present work, a complete process from the point of dismantling to separation of constituent metals using solvent extraction was studied.

Jan 1, 2014

By S. Hunt, S. Jayasekera, J. Kyle, N. Perera, K. Stone

A preliminary investigation has been conducted to determine the conditions for the precipitation of phosphate from the liquor produced after a hydrochloric acid pre-leach and rare-earth recovery from a rare earth containing fluorapatite concentrate from the Nolans rare earth deposit in the Northern Territory of Australia. The results show that at 50oC the phosphate can be precipitated in two stages using limestone to produce a Stage 1 precipitate containing most of the impurities including iron (94%), aluminium (92%), fluoride (98%), uranium (84%) and thorium (94%), followed by a relatively pure Stage 2 dicalcium phosphate precipitate (DCP) containing only 0.05% Fe, 0.05% Al, 0.1% F, 0.01% U, and <0.01% Th. The initial Stage 1 precipitate contained about 25% of the phosphate while the remaining 75% reported to the Stage 2 phosphate precipitate. Depending on the required radioactivity specifications, the amount of phosphate in the Stage 1 precipitate could be reduced. Reagent requirements were 11.4 kg limestone (as pure CaCO3) per cubic metre of solution for the Stage 1 precipitate and 39.7 kg limestone (as pure CaCO3) per cubic metre for Stage 2. The analysis of radionuclide balance indicated that radionuclides deported mainly to the final filtrate (86.4%) compared to Stage 1 precipitate (5.4%) and Stage 2 precipitate (8.2%). Settling and pressure filtration tests indicated the precipitates were both readily settled and filtered. The final moisture contents of the Stage 1 and Stage 2 precipitates were 62.5% and 49.3%, respectively.

Jan 1, 2014

By Ayumu Tokumaru, Shuji Owada, Gangfeng Liu

"Several million spent catalytic converters are disposed annually worldwideandeach containing about 0.5-1g ofplatinum and 1-2g of all the platinum group metals (PGMs), then,it is fairly significant to recover PGMs from the spent automobile catalyst. The PGMs’ recovery is a proven technology, including pyro-and hydrometallurgicalmethods, and the highestrecovery can achieve approx. 98 wt.% by acid-leaching method, but theserecyclingtechnology seems to be too highlyenergy-consuming. SincePGMs aredistributed only in coat layer in spent catalyst, it is of great significance to enrich the coat layerwith some physical methods as a pretreatment.In this paper, according to the double-deck structureof the catalyst andthe different properties of the two main compositions, alumina-ceria phase of coat layer and cordieritephase of substrate, the concentration of the coat layer was investigated by combiningthree kinds of physical separation technologies, heating-quenching, crushing and surface grinding. In the first stage, thermal stresscouldgeneratebetween the two phasesby thermal expansion difference,to producefracturesin the thinnest part of coat layerand micro-cracksin coat layerand at the interface of coat layerand cordierite substrate. The second stage of crushing, by jaw and roll crushers, could break dominantly the coat layer and the third stage of surface grinding, carried out by attritor, promoted further separation and concentration of coat layer fromthe substrate.We also improved the attritor grinding by adding a new lift-arm to the cell for achieving better mobility of sample particles in the selective surface grinding."

Jan 1, 2014

By G. Önal

Recovery of nickel and chromite from the tailings has been studied on the samples with 0.214 % Ni and 5.10 % Cr2O3 content and taken from Orhaneli Chromite Concentration Plant. Mineralogical examinations of the samples showed the existence of chromite, olivine, pyroxene, chrysotile, anti-gorite, chlorite, idingite, tremolite and calcite together with trace amounts of millerite, pentlandite, pyrite, pyrrhotite, hematite and limonite type iron oxide minerals in partially serpantinized dunite type particles. In order to recover chromite from Chromite Concentration Plant tailings Mozley Table and Knelson Separator are used and concentrates containing approximately 42% and 46% Cr2O3 are produced respectively with 40% recovery. Most of the nickel remained in the tailings. Therefore, acidic leaching tests are performed in order to dissolve nickel from these tailings. Effects of particle size, acid concentration, temperature, leaching time and solid/liquid ratio on the nickel leaching efficiency are investigated. The optimum leaching conditions are found as 250 g/L acid concentration, 1/5 solid/liquid ratio, 2 hours of leaching time and 60°C temperature, almost all nickel is dissolved at the optimum conditions and acid consumption is about 841 kg/t. Repeated leaching tests are carried out in order to have enough Ni content in the leach liquor for the further treatment of solutions. After repeated leaching tests, leach liquor contains 3 kg/m3 Ni, 48 kg/m3 Fe, 2.2 kg/m3 Si, 23 g/m3 Cr and 590 kg/m3 H2SO4. Ni is recovered from that solution by precipitating with H2S followed by HNO3 dissolution and precipitating Ni as hydroxide with 63% Ni content. Leach cakes are subjected to the gravity separation (Mozley table) to recover the remained chromite and a chromite concentrate with 47% Cr2O 3 content is produced with 53% recovery. As a result of the abovementioned tests, a conceptual process flow sheet is proposed for the treatment of these chromite concentration plant tailings.

Jan 1, 2014

By B. D. Pandey, M. S. Kim, B. S. Kim

The recovery of Sn from used Pb-free solder (Sn, 3~4 % Ag, < 0.9 % Cu, < 1.2 % Pb) has been investigated by electrorefining in sulfuric acid solutions containing small amount of hydrochloric acid. This involved preparation of the anode material by melting and casting the used solder followed by refining. During electrorefining, dendritic tin was deposited on stainless steel cathode. Increasing the amount of hydrochloric acid up to 0.3 mol /L in the electrolyte enhanced the current efficiency to 92.2 % and the enrichment ratio of silver to 94.3 % in the anode slime which was otherwise 84.7% and 81.6 % in absence of HCl, respectively. The electrolyte containing hydrochloric acid has also prevented the precipitation of tin oxide in the bath. In the scale-up experiment using 1.6 kg anodes, 84.3 % current efficiency and close to 100 % Ag enrichment ratio were obtained, while the purity of electro-refined tin was over 99.9 %. The energy consumption of the winning process was found to be 0.151 kWh /kg-Sn which is competitive as compared to commercial tin electrorefining processes.

Jan 1, 2014

By Ben Murphy, Alejandro Yanez, Tatu Miettinen

"Flotation using large volume cells has grown in importance during recent years, particularly given the increasing demand for minerals whilst ore grades are decreasing. Outotec introduced the TankCell® e300 in 2007 to enable concentrator plants to process these higher tonnages. From the beginning, TankCell® e300s with FloatForce® mixing mechanisms have demonstrated good metallurgical performance with decreased operating costs and high availability. This paper deals with specific engineering challenges that need to be considered when installing these units rather than giving examples of performance. Today there are over 100 TankCell® e300s operational worldwide. As more of these units are installed new technical challenges are encountered and solutions developed to maximize their productivity. Lessons have been learnt by operators, engineering companies and the cell manufacturers on how best to design and layout these cells in modern concentrators to ensure smooth transition from design to installation to operation. This paper presents information on important design considerations and learning that has been obtained through the design, installation and commissioning of the TankCell e300 around the world. Areas pertaining to cells layout such as feed and discharge arrangements along with items of metallurgical concern such as sampling, reagent addition and the potential benefits of installing a variable speed drive on the motor will be covered in depth."

Jan 1, 2014

By O. J. Restrepo-Baena, L. Rojas-Mendoza

Gold losses must be controlled during extracting processes, especially during cyanidation. Otherwise recovery decreases and therefore the profitability of projects too. One of the phenomena that generate such losses is known as preg-robbing which occurs when some mineral constituent adsorbs aurocyanide complex from a cyanide solution. There are some laboratory methods to identify potential preg-robbing in gold ores, highlighting the PRP method, the BGMI test, and cyanidation tests by conventional agitation without activated carbon (BRP) and with activated carbon (CIL). For this study we performed an initial characterization of a sample from Antioquia - Colombia and then we carried out the methods described above in order to identify the presence of carbonaceous matter. We obtained a percentage of preg-robbing of 78.7% by applying the BGMI test; the preg-robbing potential by the PRP method was 97.9% with an extraction of 0.77% and an inferred recovery of 36.6% if preg-robbing did not occur. Finally we obtained under the BRT test a recovery of 0%, while for CIL test an extraction of 33.6% what confirmed the presence of preg-robbers agents in the gold ore. We conducted all tests in the Institute of Minerals - CIMEX at Universidad Nacional de Colombia - Medellin.

Jan 1, 2014

By P. E. Hand

Coal is a complex heterogeneous commodity that can be mined in a number of ways and needs to be processed to a homogeneous quality that satisfies the customer?s requirements, while attempting to maximize revenues. Only a small proportion of coal is suitable for metallurgical use. Export coals cover a wide range of qualities and some coals can be used optimally in the raw state for energy production. Critical quality parameters vary and can be a combination of heat value, ash, volatiles, sulphur, phosphorus, sizing, amongst others. The level of beneficiation is generally dictated by the washability of the coal, mining contamination, and the target product quality. The steps in the coal chain covered in this paper comprise exploration, mining selections, production, the washing process, and product delivery. Many points of sampling are needed to maximize yield at the correct quality, and some of these will be described in the paper. Keywords coal chain, coal beneficiation, sampling.

Jan 1, 2014

By J. -C. Sztuke, M. Cao

ABSTRACT Wash water and polyethylene oxide (PEO) were used in the flotation of quartz and coal. Wash water decreased entrainment of –15 µm quartz. The optimum superficial wash water rate was 0.05 cm/s. PEO also lowered entrainment. The combination of wash water and PEO led to a slight further reduction in entrainment. For 1:1 mixtures of –15 µm quartz and –300 µm oxidized coal, the combined use of wash water (0.05 cm/s) and PEO increased the separation efficiency from approximately 30% to > 70%, whereas wash water alone at 0.05 cm/s did not lead to a discernible increase.

Jan 1, 2014

By J. M. Mwase

The platinum group metal (PGM) industry is currently reliant on the crush-mill-float-smelt-refine route to process PGM ores. However, there are many instances where this route would not be feasible. An alternative process route has been developed which involves heap bioleaching to extract base metals followed by heap reclamation and a water wash step, leading into heap cyanide leaching to extract precious metals. This process was evaluated through test work on samples of Platreef ore using laboratory scale columns. After 304 days 75% Ni and 93% Cu were extracted in the bioleach experiment at 65°C, and after 60 days 58% Pt, 99% Pd and 90% Au in the follow-up cyanide leach experiment at 50°C. A preliminary process flow sheet has been developed around this. Analysis via a mineral liberation analyser showed that the remaining Pt was in the form of the mineral sperrylite, which appeared to be slow leaching in cyanide in comparison to the other mineral types. Analysis of cyanide effluent solution showed high levels of thiocyanate, which present an environmental risk for disposal and high consumption of cyanide. Further studies to develop the process for commercial application in the South African PGM industry are outlined.

Jan 1, 2014