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By Xiong Dahe

In recent years many creative technologies are applied to SLon vertical ring and pulsating high gradient magnetic separators. SLon-2500 and SLon-3000 vertical ring and pulsating high gradient magnetic separators are created towards larger scale. Through optimizing the magnetic system and lowering the electric current density, their energy consumption is obviously dropped. New magnetic matrixes are developed to raise the beneficial efficiency of valuable minerals. Special SLon vertical ring and pulsating high gradient magnetic separators are developed which can treat coarser particles of 0-5 mm. Through these technology creations, the mineral processing efficiency of SLon magnetic separators is further raised and their processing cost dropped. Therefore, they have been found wider applications. SLon-2500 applied in Essar Steel of India. In 2007, Essar Steel did a test on its Kirandul hematite ore with SLon magnetic separator and got very good results. The feed grade is 59.77%Fe, after SLon one roughing and one scavenging, the total iron concentrate grade is 65.00%Fe and iron recovery 93.86%. In 2008-2010, the company bought 10 SLon-2500 magnetic separators to treat such iron ores. In 2010 the first SLon-3000 was applied to processing ilmenite. The magnetite-ilmenite deposit is located in Pan Zhi Hua, Si Chuan Province of China. The ore processing flow sheet is: Drum low intensity magnetic separator is used to take out magnetite, and then the SLon-3000 is used to recover ilmenite for roughing. The mags of the SLon-3000 are further cleaned by flotation. The SLon-3000 average operational results are: feed grade 9.52%TiO2, mags grade 17.43%TiO2, mags mass ratio 41.01%, TiO2 recovery 75.09%, non-mags grade 4.02% TiO2, non-mags mass ratio 58.99%. SLon magnetic separators Applied to treat 0-5mm limonite: The feed of SLon magnetic separator is usually 0-2 mm which needs to be ground by ball mill. As many Chinese iron ores are poor grades, if we can throw part of tails before grinding, the grinding cost will be greatly reduced. In 2010, a SLon-1500 and a SLon-2000 were specially built to treat 0-5 mm limonite. The feed grade is 26.51%Fe, mags grade 53.20%Fe, iron recovery 64.26, and tails grade 13.66% Fe. SLon-2500 applied to purify quartz. In 2009, a SLon-2500 magnetic separator was applied to purify quartz in Shan Xi province. Its feed is 0-1mm quartz which contains 0.15%-0.25%Fe2O3, the designed non-mags grade need to be less 0.08% Fe2O3. The production results of SLon-2500 non-mags are 0.05-0.06% Fe2O3, much better than the designed data. SLon applied in Si Jia Ying Iron Mine to recover hematite. Si Jia Ying is a big oxidized iron mine located in He Bei Province of China. In 2005-2010, a plant annually treating 10 million tons of oxidized iron ore was built in which 39 SLon magnetic separators are applied. The total flow sheet results are: Feed grade 30.44%Fe, iron concentrate grade 66%Fe, iron recovery 80%Fe, tails grade 9.65Fe%. SLon applied to recover specularite. Li Lou Iron Mine in An Hui Province of China built a plant annually processing 5 million tons of iron ore in 2010-2011. 25 SLon-2000 magnetic separators are applied to recover specularite. The total flow sheet results are: Feed grade 31.65%Fe, iron concentrate grade 65%Fe, iron recovery 80%Fe, tails grade 10.37%Fe. SLon applied in Da Hong Shan Iron Mine. Da Hong Shan Iron Mine is located in Yun Nan province of China. It treats 4.5 million tons of oxidized iron ore annually. 15 SLon-2000 magnetic separators are applied to recover hematite. The total flow sheet results are: Feed grade 35.61%Fe, iron concentrate grade 64.95%Fe, iron recovery 74.08%Fe, tails grade 15.55%. Keywords: SLon magnetic separator, iron ore, ilmenite, quartz, beneficiation

Sep 1, 2012

Spent automobile catalyst is an important secondary resource of PGMs (platinum group metals) and the recovery is significant. Various methods of recovery technology have been reported and applied in practical production, including pyro- and hydrometallurgical processes. Since the grade of PGMs in the catalysts is so low, approximately 0.5 wt. %, the present recycling technologies require high energy-consumption, it is of great significance to enrich the PGMs with some energy saving physical separation methods as a pretreatment. Automobile catalyst is usually composed of cordierite phase as a substrate and alumina phase, with PGMs, which covers the cordierite phase. We adopted the quenching pretreatment, one method of thermal shock, to generate micro-cracks between the two phases and separate the alumina phase from cordierite. Quenching was carried out by heating the catalysts in an electric furnace of different temperatures followed by rapid soaking into cold water. It was found that the phase boundary between alumina and cordierite was broken in the quenching and selective separation (detachment) of alumina from the cordierite could be achieved in the following surface grinding. The effect of quenching was checked by microscopic observation, hardness measurement, and chemical analysis. This paper figures out the stress formula of the quenching process, which is largely connected with layer thickness and temperature gradient by using an FEM (Finite Element Method) simulation and clarifies the mechanism of crack generation in the quenching process. Keywords: automobile catalyst, PGM, quenching process, FEM

Sep 1, 2012

By Özcan Y. Gülsoy

Coal beneficiation with optical sorting has not yet been studied in detail. Optical separation of coal from gangue particles as a dry method can be used as an alternative to the other enrichment methods. Developments in optical and pneumatic technology put the optical sorting one step forward by means of applicability of the mechanical sorting to the mineral industry. Because of the inefficient separation performance, dry separation of coal is very limited in industrial applications. Therefore, optical sorting depending on color differences between two minerals can be introduced to coal beneficiation systems. In this study, coal samples obtained from Konya-Ilgin region (Central Anatolia-Turkey) were separated by optical sorter and the results were evaluated. The conventional floatability tests for Ilgin coal are conducted by collecting most of the feed material at 1.3-1.4 g/cm3 density range. Separation of Ilgin coals with heavy medium methods will not be possible because of poor density difference between coal and its impurities. There are important color differences among the floated particles at 1.3-1.4 g/cm3 density range. Therefore, Ilgin coal is subjected to optical sorting in a pilot scale optical sorter. Different size fractions were fed to the optical sorter and then rejected and accepted particles by equipment were analyzed. Ash content of the accepted particles was reduced to 25-35 % and ash in tail increases up to 55-60 % after sorting. Although most of the material floated at low densities, optical sorter separated the feed into two different quality products. This study has the potential to clarify applicability of optical sorting even to non-floatable coals and to provide an important contribution to both industrial applications and literature.

Sep 1, 2012

By Fengnian Shi

In the current energy-sensitive world, sustainable development in the mineral industry will require new, better and more efficient processes. Novel comminution methods, which offer the prospect of achieving the required outcomes of size reduction and mineral liberation at lower energy consumption, are continually being sought. In the past five years, extensive research using high voltage pulse electrical comminution technology has been carried out at the Julius Kruttschnitt Mineral Research Centre (JKMRC), in collaboration with selFrag AG. The major outcome of this research is the development of the concept of pre-weakening ore particles by electrical comminution procedures to reduce the energy consumption in the downstream grinding circuit. The research has also verified the preferential liberation of valuable minerals by electrical comminution. Given the advantages, several potential applications of electrical comminution in the mineral industry are proposed, including AG/SAG mill feed pre-weakening, pebble treatment, ball mill feed pre-weakening, early recovery of the liberated valuable minerals, crack/micro crack generation for improved leaching, and smelter slag treatment. For the mineral industry to utilize electrical comminution, two emerging issues identified from the research need to be address. They are the energy consumption by electrical comminution in the locked cycle treatment and the facilities scale up necessary to move this technology from the laboratory to the plant. Keywords: high voltage pulses, electrical comminution, energy efficiency, mineral liberation

Sep 1, 2012

By Mohan Ram

Structural impurities in the crystal lattice of rock phosphate of Indian origin is a great challenge for beneficiation and practically possesses remote scope of upgradation to the desired level for industrial utilization. There is a wide occurrence of rock phosphate in different parts of India with different characteristics viz. siliceous, carbonaceous and ferruginous. The structural cationic replacement in the composition of apatite is due to the exchangeable cations present in the external impurities associated with the rock phosphate ore. The Indian rock phosphate ore from Purulia district, West Bengal is characterized as unusual structural composition due to the exchangeable cation in its composition. The elemental distribution of ore exhibits the disproportionate ratio of P2O5 and CaO which is 5.88: 3.31 in reference to the theoretical composition of P2O5: CaO in apatite which is 4.23: 5.55. The substitution by trivalent Al+++ cations within the structure of apatite in place of divalent Ca++ is found upto 18% and substitution of exchangeable cation in place of PO4 and F ion by CO3/SO4 is found upto 0.1% and OH ions upto 0.2% respectively in a lattice of apatite thereby diluting the grade of rock phosphate and restricting its industrial use even after beneficiation. This paper reveals the unusual compositional features of rock phosphate under study and is a guideline to the mineral industries using such rock phosphate. Keywords: external impurities, exchangeable cation substitution, structural compositional features, electron probe micro analyzer

Sep 1, 2012

By Ashish Agarwal

For a correct evaluation of the performance of any process, it is important to reconcile the data gathered in the plant from the material balance point of view for all the streams flowing in and flowing out of the process unit. There are two main approaches to reconciliation of data, which involve minimization of the sum of the squares of: (i) the closure residuals and (ii) the component adjustments; both weighed with the estimated variances of the components. Though, these approaches have served us well, it has not been possible to ascertain if the reconciled values for various components and the split factors obtained using these approaches are truly the best estimates. In this paper, this aspect has been investigated by analyzing pseudo-experimental data of known error structure on size classification of particles in a hydrocyclone. Three types of basic error structures were considered for the measured component values: absolute error, relative error and chi-square error. The error structure was modified by adding a random component of error using normally distributed random numbers corresponding to zero mean and different levels of variance. By carrying out a large number of simulation experiments, it has been shown that in the presence of random errors, irrespective of the basic error structure of data, which is usually unknown, the chi-square error minimization criterion can be used to obtain most reliable results. Keywords: data reconciliation methods, chi-square error minimization

Sep 1, 2012

By A. Luszczkiewicz

An innovative hybrid technology for beneficiation of difficult-to-process sedimentary copper ores comprising acidic leaching stage of the feed combined with subsequent flotation has been presented. Acidic leaching, preceding the flotation process, plays a beneficial role of efficient chemical grinding for liberation of copper sulphide minerals finely disseminated in the copper-bearing carbonate-shale rocks. The process was applied on a fully industrial scale. Flotation results were analysed for both chemically modified and unmodified flotation feeds. After several months of industrial scale operation, it was found that both metals recovery and concentrate grade remarkably increased as a result of application of chemical modification of the flotation feed. Beneficial effects of chemical pre-treatment of flotation middlings on selectivity at a comparable concentrate yield in industrial flotation scale, revealed a considerable increase of the total copper recovery by 3.5percent. Based on the industrial and laboratory investigations we consider a further development of the process and introduction of hydrometallurgy for better recovering of metals from low-grade copper concentrates

Sep 1, 2012

By V. K. Chandaliya

N-Methyl-2-pyrollidone (NMP) has already been proven a good solvent for extraction of coal. It is believed that organic components of coal are likely to be dissolved with the solvolytic power of NMP. During dissolution process, original coal also gets disintegrated and thus helps in further extraction. Coal extraction highly depends on temperature, coal to solvent ratio, N-Methyl-2-pyrollidone (NMP) to Ethylenediamine (EDA) ratio and the size of coal particles. The process has been established in the laboratory. There is no reference available beyond lab scale. In present study, we are running a bench scale plant with 40 kg/batch capacity. Design of experiment was done in such a way that the optimum zone of the process gets evaluated for clean coal having low ash with high yield. Bench scale plant trial was conducted based on optimum zone developed during design of experiments (DOE). From the DOE analysis it was observed that feed size and coal to solvent ratio are important parameters for this process. Total 27 experiments (four factors with 3 level of variation) were designed through Box-Behnken model. It was observed that -0.5 mm feed size of coal, 150 °C extraction temperature, 17:1 NMP to EDA ratio, 1:9 coal to solvent ratio was optimum conditions. The results obtained at optimum conditions are 50% clean coal yield with 5% ash.

Sep 1, 2012

By Matveyeva Tamara

The main deposits of gold-sulfide ores of Russia are characterized as refractory raw material with the non-uniform finely-interspersed sulfide mineralization, submicron gold, the low gold content (3-5 ppm) and non-uniform distribution of the gold associated with pyrite and arsenopyrite. These ores show low indicators of extraction of gold and silver at cyanidation. Flotation is one of the basic technological procedures of processing of gold sulfide ores however simultaneous presence of pyrite and arsenopyrite and lack of effective methods of their selection constrains application possibility of flotation schemes because of rigid requirements to flotation concentrates under the arsenic content and practically excludes smelting of pyrite concentrate. The main losses of precious metals at flotation technologically are concentrated in thin classes (up to 15 %) demonstrating an inefficiency of standard reagent modes. For an estimation of expediency and possibility of application of selective flotation of pyrite and arsenopyrite a scientific substantiation of the mechanism and criteria of selection of gold-bearing ferrous sulfides of various material structure is developed and for difficultly divided pairs of sulfides with close technological properties the new selective reagents providing effective extraction of gold from hard-to-beneficiate ores are designed. The original technique for modifying surface composition of natural sulfides by nano-sized Au is worked out and the mechanism of selective adsorption of new reagents ? oxypropyl ester of diethyl-dithiocarbamatic acid (OPDTC) and oak bark extract (OBE) on Au-bearing sulfide minerals is revealed. Formation of almost insoluble OPDTC-Au compounds is defined by methods of scanning electronic microscopy (SEM) and UV-spectroscopy. Application of developed reagent modes using new reagents have been tested in laboratory conditions at flotation gold-sulfide ores samples and collective concentrate probes providing high extraction of gold and improved quality of the concentrate (less than 2 % As). Keywords: pyrite, arsenopyrite, selective flotation, flotation reagents adsorption, complex-forming, gold recovery.

Sep 1, 2012

By D. Moradkhani

The objective of this research was, to evaluate the hazard of heavy metals in the soil around the National Iranian Lead & Zinc (NILZ) Company. In this study, 38 samples of soil around the NILZ factory were collected using standard sampling method, so that, the heavy metals Pb, Zn, Cd and Cr have been evaluated. The concentration of heavy metals were measured and compared with standard limits. The results show that the hazard of heavy metals in soil is not so serious and the content of Pb in just 5 percent of samples, and the content of Zn in just 3 percent of samples were above standard limits and the concentration of Cd and Cr were under the standard limits. Average, variance and standard deviation of the elements are calculated and with due attention to the standard deviation, Pb and Zn are seen to be more distributed than Cd and Cr. Also the isograde curve of heavy metals was drawn using software called Surfer. These curves showed that the heavy metals are concentrated at particular distances from the factory. Keywords: heavy metals, remote sensing, sampling method, isograde curve, Surfer software

Sep 1, 2012

By Mike Hollitt

The first decade of the 21st century was one of fundamentally changed dynamics for the minerals industry. Following intense globalization commencing in the late 20th century production is now concentrated into large businesses that can compete across geography in diverse commodities. Asian industrialization and urbanization is now the main driver of growth in demand for energy and materials. Demand for the output of these industries has risen sharply, reversing decade long trends to reduced real commodity prices. Supply responded with expansions of existing mining and processing operations, and large investment in new resource development. Development of new, lower grade or more remote resources was stimulated. Resource development by global entities in frontier environments reinforced the importance of effective forms of social contract, and of stronger environmental performance. The worst economic shock in decades provoked no significant pause despite large impacts on corporate ownership. State owned enterprises commenced unprecedented foreign direct investment in minerals and energy resources. A thrust towards resource nationalism re-emerged as governments sought to ensure that the export of state owned resources contributes more strongly to government revenue, reducing the burden of trade in scarce resources on other trade-exposed sectors. The unprecedented combination of forces at work has made future predictions difficult, with day-by-day volatility in anticipated corporate fortunes, and investment plans. The challenge for process innovation (and for exploration) has been to keep up, maintaining a lid on costs as lower grade and more challenging ore bodies are brought on quickly in a context of competition for land use, community expectations and continued care for natural and living environments. While new projects have provided the necessary platforms for implementation of innovative approaches, there is evidence that a gap may have emerged between the pace of growth and the pace of innovation. The history of a century of process innovation in the context of growth of output, declining resource grades and commodity prices is presented. The necessary conditions for accelerated process innovation are considered, and future needs and approaches are discussed. Keywords: process innovation, resource development

Sep 1, 2012

By M. Roy

Coke combustion during sintering process is significantly governed by coke breeze size distribution, which in turn affect sinter quality i.e. sinter granulometry, Tumbler index, Reduction Degradation Index and Reducibility Index of sinter. To know the effect of microfines of coke breeze on sintering process parameters, pot sintering tests were conducted and it was found that when microfines are eliminated and optimum coke size (1-3mm) is used yield of sinter increased by more than 7%. Similarly productivity increased by 9%, the strength of sinter i.e. ISO Tumbler Index increased by 2.3% and +10mm sinter size increased by 5.5%. Controlling of microfines during crushing and by improving crushing index will result in improved quality and productivity of sinter with lesser amount of coke breeze. This paper describes that how to optimize solid fuel i.e. coke breeze consumption in sintering process through granulometry control. Keywords: iron ore sintering, coke breeze granulometry, productivity of sinter, quality of sinter

Sep 1, 2012

By B. P. Baruah

A good deposit of high sulphur coals of tertiary origin is existent in North eastern region of India. These coals are known to have indifferent characteristics in comparison to other Indian coals. The general Physico-chemical characteristics are low ash and high volatile matter, calorific value and sulphur content. Sulphur in these coals (70-95% of organic) is mostly affixed to the structure of the coal. Owing to the stringent environmental regulations, the utilization of these coals has severe limitations due to high sulphur content. In the present investigation, sulphur incorporation in to these coals has been discussed along with possible organic sulphur functionalities. The various desulphurization techniques carried out for removing sulphur from these coals have been discussed. Two step oxidative desulphurization processes has been found to be most efficient for organic sulphur removal along with mineral matter and potential toxic elements. Keywords: oxidative desulfurization, potential toxic elements, sulfur incorporation

Sep 1, 2012

By A. Koizhanova

Kumistinskoye gold- and silver bearing ores (Republic of Kazakhstan) as well as standardized test solutions containing gold, silver, copper, zinc and iron were studied. The best results in silver and gold recovery from Kumistinskoye gold- and silver bearing ores were achieved through use of complex cyanide-thiosulfate solutions as compared to individual cyanide solutions and thiosulfate solutions. It was found that such complex solutions substantially step up leaching process herewith increasing precious metals recovery rates. Thermodynamics of studied chemical processes was calculated. Reaction order, kinetic constant and activation energy of gold leaching process through use of cyanide-thiosulfate solutions were identified. We managed to prove that the sorption rates and holding capacity in process of gold anions recovery with anionite AM-2B are comparable to sorption characteristics for cyanide solutions. Keywords: gold, silver, copper, zinc, iron, cyanide-thiosulfate solutions, anionite AM-2B

Sep 1, 2012

By A. Oberrauner

Electrostatic separation is a dry separation technique usable for many applications in the mining- and recycling industries. At the Chair of Mineral Processing intensified research has been done on this topic during the last years. One challenge was to measure the triboelectric charging of fine mineral particles in a triboelectric charging device consisting of an electrically insulated polyethylene rotor/stator assembly. These tests, performed on monomineralic samples, were accomplished in a climate chamber. It was shown that charging of minerals not only depends on rotor speed, feed rate and atmospheric circumstances but also on the properties of the applied electrostatic field. Tests on pure calcite in contact with the polyethylene rotor/stator system resulted in specific triboelectric charges up to +10 nC/g at low relative humidity. With more water present in the surrounding atmosphere, these charging values decreased significantly. However, at higher relative humidity, triboelectric charge values could be maintained after an electrostatic field of positive polarity was applied. Similarly, charging behavior was found with other hydrophilic minerals. The idea behind all these tests was to find the largest charging difference between minerals occurring together in a deposit and to be able to charge them oppositely, assuming that this means good sort ability in an electrostatic separator. The results gained from these investigations are shown. After having obtained many results on charging pure minerals, it became interesting to test the applicability of the charging tendencies on electrostatic separation of fines <100 µm. In order to do so, a separator for fine polymineralic powders was developed, constructed and combined with the triboelectric charging device, all being set up in a climate chamber. This new so-called coax-separator is presented along with first test-results.

Sep 1, 2012

By Sanjay Agarwal

Polymetallic sea nodule is a good source of manganese having 22.3% Mn, 5.4% Fe, 6.14% Si, 1.1% Cu, 1.15% Ni, 0.076% Co & others. These nodules are available in plenty on the sea beds, generated over thousands of years. Nodules mainly consist of manganese dioxide and iron oxide phases and other metals are entrapped in the complex cage of these Mn-Fe oxides phases.World-wide research is going on sea nodules as an alternative future source of many metals, which has led to intensified efforts to develop practical and economical processes for recovery of these metals. Very little attempt has been made world over on manganese extraction from sea nodules. We at CSIR-NML, India have developed a direct reduction smelting process of nodules to recover manganese as Fe-Si-Mn alloy. This alloy is extensively used in the steel industry as deoxidizer and as an alloying element to make different grades of steel. Lab scale experiments were conducted to study the manganese distribution between Fe-Si-Mn alloy and FeO-SiO2-MnO-CaO-Al2O3-MgO slag at different temperatures by varying the basicity of the slag. The direct reduction smelting of nodules is carried out on 1 kg scale in 50 kVA electric arc furnaces to have Cu, Ni and Co alloy and Mn rich slag. This manganese rich slag is further treated in 50 kVA arc furnace to produce Fe-Si-Mn alloy. The composition of Fe-Si-Mn alloy obtained is in the range of Mn: 60-65%, Si: 14-17%, C: 1- 2%, S: 0.03% and the balance iron which is acceptable grade for industrial use. The equilibrium amount of MnO in the final slag is controlled by the temperature of the final melt and the silica, lime, alumina content of the final slag. Increasing the basicity of the slag plays a major role in minimizing the loss of MnO to slag, increasing the amount of SiO2 of the slag, increases the manganese loss in the slag. Increasing the CaO/ Al2O3 ratio of the slag decreases the manganese loss in the slag. Increasing the MgO/CaO ratio of the slag increases the manganese loss in the slag. Thus by adjusting

Sep 1, 2012

By M. Saba

In cyanide leaching procedure, achieving an acceptable efficiency for silver and gold is very time-consuming, thus, enough studies have not been performed for optimization and modeling of this process. The kinetics of cyanide leaching includes two steps: first step comprises a sharp slope while the other has a slight increasing trend. In the present study, in order to reduce the time and cost, the cyanide leaching process of a sulfide silver/gold ore was optimized in the first period. The applied parameters and their ranges are: temperature 20-40 (°C); time 1-8 (hrs); cyanide concentration 1-2 (mole cyanide / mole Cu); the percentage of solid to liquid 1-2 (%) and pH 10-12. For design of experiments fractional factorial 2(5-1) was used. Also four center points were applied to increase the accuracy of the model. In addition, by analysis of variance (ANOVA) the most effective parameters were identified and the optimized condition was determined. A regression model was proposed to describe the effects of independent variables and their interacting role on silver recovery. Results showed that the model was linear for silver and nonlinear for gold. In the gold recovery process, the two important parameters are time and pH with the former being more effective. Due to the existence of cyanide ions in the medium, temperature and cyanide concentration have less influence in the gold recovery process. Solid to liquid ratio, in addition, comprises a slight negative impact on the procedure. This emphasizes the different kinetics of silver/ gold cyanide leaching. Finally, using the optimum condition the amount of silver and gold obtained were 61% and 67% in 8 hours, respectively. While in general conditions, the results were 37% and 54% in 24 hours, respectively. Keywords: cyanide leaching, refractory gold/silver ore, modeling, optimization

Sep 1, 2012

By H. R. Manouchehri

Large variations in flotation characteristics of minerals have been observed in winter and summer in plant practices as a result of changes in pulp temperature. Variations in temperature may affect the quality for pulp and related process water through changes in dissociation of different chemical species within the pulp, as well as changing in gas and metal hydroxide solubility, reagent adsorption and its stability on mineral surfaces, water/pulp viscosity, etc. All of these affect the flotation characteristics of specific mineral to some degree or another. It has been observed in Cu-Pb-Zn and/or Pb-Zn sulfides flotation that sphalerite (ZnS) flotation is strongly affected by changes in pulp temperature. Plant practices have shown that at the both low, e.g., T <10-12°C, and high, e.g., T > 60°C, the recovery for copper activated sphalerite is dramatically dropped. Within this paper the effect of pulp temperature on flotation characteristics of sphalerite is brought into considerations and laboratory flotation tests were conducted in conjunction with surface and solution chemistry analysis to understand the effect of temperature on sphalerite recovery. The effect of temperature seems to be complex since the temperature affects both the physical (hydrodynamics) and chemical phenomena in the flotation cell. In fact all sub-processes in flotation, i.e., collision, attachment and detachment, are affected by changing in temperature. Experimental results indicating that at alkaline pH values, e.g., 8.5 to 10.5, the recovery for copper-activated sphalerite is dramatically reduced when temperature is below 10-12°C, which is in agreement with plant practice at Boliden?s Garpenberg plant in Sweden. However, results from other studies indicated that the zinc recovery is also considerably decreased at high pulp temperatures, i.e., 62°C and above.

Sep 1, 2012

By Tasuma Suzuki

Electrokinetic/permeable reactive barrier system is a promising in situ soil and ground water remediation technique to reduce toxic NO3- into less toxic NH4+. Using granular zero-valent iron (Fe0) as a reductant, the first objective of this study was to investigate the influence of the solid-liquid ratio and aqueouspHon NO3- reduction. The results obtained from a series of batch experiments showed that NO3- reduction was enhanced by either increasing solid-liquid ratio or decreasing aqueous pH. Based on insights obtained from batch experiments, the second objective of this study was set to design the remediation conditions of the electrokinetic/Fe0permeable reactive barrier system to maximize the NO3- reduction efficiency. Experimental results showed that the effectiveness of the system strongly depended on the Fe0 percentage in the reactive barrier, the pH in the anode reservoir, and the applied voltage, which were consistent with the results obtained from batch experiments. Under optimized treatment conditions, nearly 100 % NO3-was reduced into NH4+ in the permeable reactive barrier and collected in the cathode reservoir. Insights obtained from this study provided fundamental information on roles each of remediation design parameters plays, and will be useful to optimize the remediation conditions. Keywords: electrokinetic remediation, permeable reactive barrier, zero-valent iron, nitrate

Sep 1, 2012

By N. P. Haran

A detailed study was undertaken to beneficiate sub-grade iron ore sample from Kenojhar District, Orissa, India containing 57% Fe (T), 7.7% SiO2, 4.8% Al2O3, 4 % L.O.I. 0.4% TiO2,1.3 % Mn and traces of S(T) to make it suitable for the user industry. The mineralogical study indicated that it predominantly consists of haematite with subordinate amounts of goethite and clay. Quartz, Cryptomelane / Psilomelane, Pyrolusite, Gibbsite, Feldspar and Muscovite mica were present in very minor to trace amounts. The Denver grind ability tests indicated, that the sample could be categorized as ?medium soft to medium.? The Bond ball mill work index was determined to be 14.19 kwh per short ton. The beneficiation process involved classification followed by tabling of the classified sand, ground to minus 48 mesh size. The table slimes were subjected to Wet High Intensity Magnetic Separator (WHIMS). The developed process yielded a composite concentrate from tabling and WHIMS operations assaying 65% Fe(T), 2% SiO2, 1.8% Al2O3, 2% Mn and 0.9% LOI with a recovery of 60.1% Fe (T), amounting to 52.5 wt.% yield. To meet the size specifications for pellet making, it was further ground. Dewatering studies were also carried out on the ground combined concentrate and rejects. The thickener area of ground combined concentrate using 0.02 kg/t of Sufloc A 1115 flocculant was 0.02 m2/tonne of dry solids per 24 h. And for the combined rejects using 0.12 kg/t of flocculant, it was 0.035 m2/tonne of dry solids per 24 h. The moisture content, in the pressure filtration cake, in the ground combined concentrate product was 10.0%, and productivity was 506.7 kg/m2h. Thus, by thickening and filtration of process products, 90% of water used in the process could be recovered. The study highlights the development of a simple and cost effective flowsheet with almost complete water recovery for a subgrade iron ore sample. Keywords: tabling, WHIMS, thickener, filtration

Sep 1, 2012