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By L. B. Rothfeld

This paper presents preliminary results of a Bureau of Mines study of potential costs of compliance with the federal Resource Conservation and Recovery Act for copper heap and dump leaching. Specifically, estimates are given for the cost of compliance with possible technology standards that would require the use of liners and closure caps regardless of terrain and underlying geology and hydrology. This cost is compared to the co lit of compliance with present state requirements for terrain a typical of those found at existing copper leach sites in the Southwestern U.S.A. Incremental compliance costs are found to widely exceed screening criteria used by the Environmental Protection Agency to denote significant economic impact.

Jan 1, 1993

By G. S. Victorovich

Technical progress in primary smelting has changed the face of the copper industry in the years since the Second World War. Much of this change has resulted from a wide acceptance of flash smelting technology. In addition, research has been directed toward devising converting processes to replace conventional Peirce-Smith converting technology. One major thrust has involved a revival of the old " ", idea of oxygen flash converting of comminuted mattes. This paper reviews the 60-year history of flash converting. Particular attention is paid to Inco's investigations into the processing of white metal containing significant amounts of nickel and, in some cases, iron. Thermodynamic analysis and laboratory experimental results are presented which throw light on the behaviour of nickel and other salient features of flash converting. The possible role of oxygen flash converting in the copper pyrometallurgy of the future is briefly discussed vis-a-vis direct production of copper.

Jan 1, 1993

By M. A. Chandler, G. T. Adel, J. N. Richardson, E. C. Gutierrez

A rapid, bench-top analyzer has been developed to determine P2O5 content and CaO/P2O5 ratio in phosphate ores. The analyzer utilizes a portable computer equipped with a frame grabber to measure the reflective intensity (gray level) of phosphate samples placed in front of a television camera. P2O5 content is related to the average gray level of the sample, while CaO/P2O5 ratio is determined from the amount of bright material present. The sensor is currently being used to analyze flotation concentrate samples at Texasgulf's phosphate operation near Aurora, North Carolina. Sensor development along with results from laboratory and in-plant testing are discussed.

Jan 1, 1993

By Mohamad H. Hussein

A minipile system was employed in underpinning a historical structure in Florida. The existing structure is founded on shallow foundations. Subsurface conditions at the project site consist of deep organic deposits interbedded with loose sand and silty sand. A minipile foundation system was deemed the most appropriate underpinning corrective measure for the already badly cracked structure. A total of 68 minipiles, 3.5 inch OD and 0.25 inch wall thickness closed-ended concrete-filled steel pipes, were installed to depths varying from 55 to 175 feet. Installation was accomplished with a pile driving hammer having a rated energy of 1 kip-ft. Highest required pile design load was 15 kips. Conventional static and wave equation analyses were performed to establish preliminary pile lengths, to assess pile drivability and establish driving resistance criteria. Dynamic pile testing using the Pile Driving Analyzer was conducted on six of the production piles. This paper describes geotechnical design considerations, installation procedures, and dynamic field monitoring. This case represents unique applications of pile dynamic testing and such slender, very long minipiles in compressible soils.

Jan 1, 1993

By M. R. Smith

Barrick Goldstrike Inc.'s Betze/Post Open Pit is located at the north end of the Carlin Trend, in Eureka County, Nevada, U.S.A. (see location Map, Figure 1). About ten open pit gold mines exist on the trend, which strikes northwesterly, through the north end of Eureka County and into Elko County. The final Betze/Post Pit configuration is shown in Figure 2, Pit Configuration. The final pit will be about 2450m long by 1550m wide, elongate in a west-northwesterly direction. The pit straddles the Barrick/Newmont property boundary. The highest elevation of the pit perimeter is 1800m at the south wall, with the east end pit bottom elevation at 1200m.

Jan 1, 1993

By Denisov GA

Conventional processes for disintegration of ores are characterised by low selectivity and cause damage to the components of their structure. It affects their liberation and recovery which are connected also with the inevitable formation of extreme fines. In the world practice recently came into view 4 trend to grinding of materials within a thick layer (in a bed layer), which provides a substantial selectivity of liberation, for example, of kimberlite. The degree of diamond preservation in the final product is highly increased. However, this method causes a considerable overgrinding of material. A new method of intralayer vibro-impulse breaking of materials providing an easily adjusted force acting at the layer and timely removal of product size grains from the grinding chamber has been developed in Russia.

Jan 1, 1993

By Thomas M. Barczak

Wood cribs are used extensively by the mining industry to stabilize mine openings. While the cost per crib is relatively low, their extensive use can result in annual mine costs of over $1 million. In an effort to improve the utilization of these supports and to reduce ground control hazards, the U.S. Bureau of Mines has developed engineering methods to assist mine operators in wood-crib design and employment. Design and employment criteria are established based on the strength, stiffness, and stability of the crib structure in relation to the load conditions imposed by the mine environment. Models have been developed based on full-scale tests in the USBM's Mine Roof Simulator that compute the capacity of wood cribs of various configurations and material constructions as a function of displacement of the crib structure due to roof-and-floor convergence. These models permit the comparison of the loading characteristics and costs of employment of different crib designs, and in conjunction with roof behavior models, provide a means to determine the optimum design and employment strategy.

Jan 1, 1993

By K. N. Han, P. B. Queneau, Bruce W. Cavender

Measures of metallurgical performance, such as recovery rates or mass balances, are frequently based on point estimates of operating conditions in the system of interest. Because the processes being measured are dynamic, a range of uncertainty accompanies each measurement; this uncertainty is reflected in the accuracy with which the calculated result describes the true metallurgical performance. In stochastic modeling, a range of probable values is used in place of a point estimate to describe each variable. The calculated result takes the form of a distribution, delineating both the magnitude and probability of potential outcomes.

Jan 1, 1993

By Deepak Malhotra

The first step in the development of a gold deposit is the detailed mineralogical examination of the ore types, major and minor mineral constituents and their association. It is extremely difficult and expensive mineralogically to characterize the occurrence and association of gold with other minerals for low-grade refractory ores (less than 0.1 troy oz/t Au). Even if a mineralogist can identify a gold-associated particle or two, one wonders how representative they are of the deposit. What alterative does a metallurgist have for characterization of gold-bearing ores? Diagnostic leach procedures, consisting of a series of sequential leaches, can provide the metallurgist/mineralogist with reasonably good Indication of the deportation of gold in the various mineral matrices. This information con help the metallurgist concentrate on the most promising process options In the Initial stages of the project development process.

Jan 1, 1993

By Lorenzen L

In South Africa, as in many other countries, the young engineering graduate is promoted quite soon to a management position where he uses less technical skills and more people-oriented skills. In the standard undergraduate curriculum for engineering, little attention is paid to the non-technical issues of the profession. An undergraduate course in management techniques cannot be a substitute for a MBA or Masters degree in engineering management, but can at least create an awareness of the practical problems facing the engineering manager. The aim of this paper is to provide an outline of such a course structure at the University of Stellenbosch. A survey is also presented on management training in the South African and Australian mineral industries. Feedback from students and graduates indicates that the fresh graduate does not fully appreciate the value of such a course until he/she achieves a position of responsibility after two or three years. Nevertheless, the management course appears to be successful in widening the perspectives of the engineer. As explained frequently in management journals, the technically oriented person (the engineer) has a convergent thought pattern, which could be in conflict with the more divergent thought pattern of the top, personnel or marketing manager. It becomes increasingly imperative for the young minerals engineer to be externally oriented instead of the traditional internal focus of engineering. The engineer should not only be aware of environmental issues in the technical design and operation of plants, but should also understand the inter-relationship between public relations, political pressures and environmental perceptions vis-d-vis technical facts.

Jan 1, 1993

Surface contamination of minerals during fine grinding may occur due to coating of one material on the other. This can alter the surface chemical properties and adversely affect the separation of minerals by physico-chemical processes. In dolomite-silica system, selectivity was completely lost (compared to a synthetic mixture) after wet grinding of the minerals in spite of using a dispersant. Adsorption and surface characterization studies were conducted on silica particles separated after grinding with dolomite. SEM-EDAX analysis indicated the presence of dolomite on silica particles, which could cause the loss of selectivity.

Jan 1, 1993

The Ross Goldfield is a unique gold resource. From its discovery in 1865 there was a growing understanding of the geology of the deposit as mining moved from the surface at Jones Flat in the south to underground extraction at Ross Flat further north. Multiple layers of gold-bearing gravels were penetrated in deep shafts and six rich gold-bearing bottoms were worked. The ultimate bottom on the Old Man Group gravel surface has never been reached either at Jones Flat or at Ross Flat. Mining at Ross Flat was ultimately halted by uncontrollable flooding, by escalating costs and by a shortage of labour during the First World War. Mining at Jones Flat recommenced in the late 1980s and attention has once again been drawn to the potential magnitude of the resource at Ross Flat. Research of historic literature shows that there is potential for a bulk gold grade of 400 mg/m3 in a volume of 82 million cubic metres of gravels which lie in a basin between Jones Flat and north Ross.

Jan 1, 1993

By Amanatidis A

In this paper, the kinetics of iron precipitation as sodium jarosite from aqueous solution is investigated. The determination of the reaction mechanism is attempted based on the experimental data of iron removal as a function of time, without using the characteristics of the precipitate.Experiments at the temperature range from 50° to 95°C were carried out with initial conditions of iron concentration IQ g/L, sodium sulphate concentration 25.44 g/L, sulphuric acid concentration 3.68 g/L, pH = 1.5 and agitation rate 600 rpm. Temperature greatly and positively influences iron precipitation from the solution and this is accompanied by pH decrease. The activation energy was determined using the maximum values of the precipitation rate, which were evaluated by polynomial fitting of the sigmoidal shape experimental curves, and it was found to be 44.37 kcallmole. The determination of the rate-controll ing mechanism was based on some criteria used for the discrimination among the three probable mechanisms of precipitation (diffusion, mononuclear nucleation, polynuclear nucleation). These criteria utilise various funetions of the recovery 'a' of iron precipitated versus time, the most important of which are the chronomals. The results of the kinetic analysis procedure showed that the polynuclear nucleation growth mechanism controls the precipitation of iron as sodium jarosite. This was confirmed by the high value of activation energy, excluding diffusion as the controlling mechanism.

Jan 1, 1993

By Balint F

The Izok massive sulphide deposits are located in the Northwest Territories of the remote western Canadian Arctic. Together they represent one of the highest grade undeveloped zinc-copper resources in North America. Metall Mining Corporation is presently engaged in a feasibility study on developing the Izok property as well as actively exploring for additional reserves. The Izok deposits are Archean-aged, volcanogenic massive sulphide (VMS) bodies hosted within and near the top of a thick sequence of predominantly felsic pyroclastic rocks. The hangingwall package includes additional felsic volcanoclastics, dacitic and basaltic flows, thin sulphide-rich iron formations, and turbiditic sediments. The felsic volcanics are intruded by syn- to late-hydrothermal dacitic dykes and sills and post-hydrothermal gabbroic dykes and sills. Both intrusives are interpreted to be volcanic feeders to overlying flows. All lithologies are cut by much later irregular granitic pegmatite dykes and regionally metamorphosed to pyroxene homfels grade. The deposits occur within a large kilometre-scale soda-depleted alteration zone. The immediate footwall and hangingwall rocks to the deposits are characterised by zones of muscovite-biotite (with or without sillimanite), lesser chlorite-biotite-cordierite (with or without anthophyllite), and locally intense silicificified and albitised zones. All lithologies have been affected by a later calcic metasomatic alteration. As currently defined, the Izok Zn-Cu-Pb-Ag deposits comprise a cluster of four complexly-zoned composite lenses: the Northwest, North, Central, and newly discovered Inukshuk deposits. The first three deposits are amenable to open pit mining while development of the Inukshuk deposit will require underground methods. The combined mineral inventory of the Northwest, North, Central and Inukshuk deposits at present totals 15.6 million tonnes with a grade of 2.4 per cent Cu, 13.8 per cent Zn, 1.4 per cent Pb, and 74.6 g/t Ag.

Jan 1, 1993

By Paul E. Queneau

The QS (Queneau-Schuhmann) copper converter is a gently sloped, stepped, horizontal kiln-type tilting reactor in which desired bath oxygen activity, compositional and temperature gradients are created by countercurrent flow of matte and slag phases through a series of controlled bubble plume, mixer-settler configurations. Flow of gas and slag is normally concurrent. Copper sulfide concentrates are top-fed, employing oxygen flash burners. Oxygen and oxygen-carbonaceous fuel mixtures are bottom-blown into the smelting bath through judiciously located, independently regulated submerged injectors. Composition and mass flow rates of injector inputs are controlled to produce bubble plumes of desired character, without jetting through and out of the bath. The mixer-settler pattern can be reinforced if desired by employment of suspended shallow baffles. State-of-the-art instrumentation provides timely information required to govern key process variables. The outstanding capabilities of the QS converter for coppermaking have now been indicated by the current success of industrial QSL (Queneau-Schuhmann-Lurgi) leadmaking reactors. Modified converter designs are employed for leadmaking, nickelmaking and steelmaking.

Jan 1, 1993

By Masanobu Morita, Koichi Kurokana, Kenji Hashimoto, Yoji Tasaki, Yukio Iida

"It has been the long desire of blasting engineer to realize the automatization of tunnelblasting to improve the safety and efficiency. As for bore hole drilling, the automatizationhas been achieved by the improvement of drilling machine. However, the firing process isstill depending on the hand-operation. We developed the wireless initiating system using amacrowave power as a step for automatization of tunnel blasting operation. In this paper,we present the outline of the wireless initiating system and the results of experimentalstudy of the wireless detonator which is key component of the system."

Jan 1, 1993

By Donelson A. Robertson

Proper coupling between the seismograph transducer and the surface is the most important aspect of seismograph monitoring but probably receives the least attention in many blasting situations. Without good coupling, particle velocity measurements may be higher than actual and frequencies may be lower. If the field data are inaccurate, sophisticated instrumentation and computer programs cannot correct the readings.

Jan 1, 1993

By T. Y. Yan

O2, NaCl03, H202, NaOCI and Ce+4 have been examined as oxidants in an alkaline carbonate system for uranium in situ leaching. The South Texas and New Mexico ores contained up to 2.6 meq/g of reducing compounds that consume oxidants in the leaching operation. Leaching rates did not increase linearly with the oxidation potential of the oxidants. A mild oxidant can be used to maximize uranium oxidation selectivity and oxidant efficiency. 02 can oxidize most of the uranium mineral with an adequate rate and high oxidant efficiency.

Jan 1, 1993

By B. E. Davis

A problem that has continued to plague the Florida phosphate industry is the loss of coarse phosphate in the flotation circuit. Attempts to remedy this problem such as floating the coarse material (plus 425 µ m) in a separate circuit have resulted in limited success, but recovery is still not optimum. The Bureau of Mines is investigating ways to improve the recovery of coarse phosphate through improvements in the conditioning step. Studies to optimize conditioning parameters such as agitation energy, conditioning time, conditioner solids, and residual clay content have resulted in improved P2O5 recovery. Optimizing these and other conditioning parameters resulted in a rougher concentrate grading 30 pct P2O5 with a P2O5 recovery of 97 pct.

Jan 1, 1993

By Oboso A, Nakahiro Y, Takenaka Y, Wakamatsu T

As part of the fundamental studies on the recovery of Au by solvent extraction, the synergism of combined extractants on the extraction of An from the sulphuric acid solution containing thiourea was investigated. Extractants tested were di-(2-ethylhexyl)phosphoric acid (D2EHPA), tri-n-octylamine (TOA), tri-n-butyl phosphate (TBP), and trioctyl phosphine oxide (TOPO). Four kinds of extractant combinations, D2EHPA/TBP, D2EHPA/TOPO, TOA/I'BP, and TOAITOPO, were tested to clarify the synergism on the extraction of Au in terms of various concentration ratios, diluents, the concentration of sulphuric acid, and the concentration of thiourea.

Jan 1, 1993