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By R. L. Murray-Smith, M. E. A. Robertson, M. J. Prosser

The AZTEC is an automated instrument, for the non-destructive analysis of gold ore samples, which uses energy dispersive X-ray fluorescence (XRF), This is achieved by X­ray tube excitation of gold K X-rays. The first production instrument was commissioned at Vaal Reefs Chemical Laboratory (VRCL) in November 1987, followed by two second generation instruments in 1989. AZTECs have also been installed at Western Deep Levels and at Anglo American Research Laboratories (AARL). A further unit is being assembled at Ashanti mine, Ghana. At VRCL the AZTECs are used primarily for the evaluation of mine (stope) samples. Each of the production instruments can routinely analyse 650-700 samples per day, with the aid of a robotic sample transfer system. Various techniques have been evaluated for increasing sample throughput. For example, higher value samples can be counted for a shorter time to obtain the necessary relative precision.

Jan 1, 1991

By Martin F. Grier, Nicholas H. Kempton

The Mt. Todd Gold Project in the Northern Territory is a joint venture between Billiton Australia Gold Pty. Limited, a wholly owned subsidiary of Shell Australia Limited, and Zapopan NL. As manager of the project, Billiton is guided by Shell's corporate policy that foremost consideration be given to protection of the environment from unacceptable impact and that sound environmental programmes are to be implemented effectively at all company operations. This policy on Health, Safety and the Environment helps operating companies in addressing environmental matters in a systematic way and gives guidance on the practical implementation of a range of controls to protect the environment. Most importantly, it seeks to do this in a co­ operative rather than adversarial manner. In developing the Mt. Todd Gold mine the joint venturers' environmental objectives have therefore been to plan and operate the project consistent with the highest industry standards and community expectations and in accordance with all Northern Territory government requirements. A development strategy has been designed which minimises environmental effects. Planning priorities have focused on the successful co-existence of the mine with an endangered species of bird, the Gouldian Finch, which breeds in the area; the mitigation of impacts on surface and ground. water qualities; and the protection of significant Aboriginal cultural and archaeological sites.

Jan 1, 1991

By J. W. C. Wong, T. A. Songberg, S. D. Miller, J. J. Jeffery

Natural degradation of cyanide has been widely used by the gold mining industry for removal of CN from cyanidation processing wastes. However, little documented study has addressed the decay and fate of cyanide within residue storage ponds. 'fhis paper describes a study on the cyanide behaviour in a residue storage pond at the Boddington Gold Mine in Western Australia. Depth profile samples were collected from the active residue storage to determine the distribution of CN forms and complexing metals throughout the settled residue.

Jan 1, 1991

By Hans von Michaelis

It is appropriate that this opening session of HAZPAC '91 and Randol Gold Forum CAIRNS '91 should address the question of what the two industries can learn from each other. The panel is made up of members with experience in both industry. Several are experts on managing both hazardous waste and the mine/mineral processing environment. There is a marked difference in the regulatory needs with respect to treating and disposing of mining and mineral processing wastes, and "hazardous" or industrial waste materials. The topic of this paper is on the things that the two industries have in common: Many of the processes and technologies that are being used or are currently being developed for treatment of hazardous waste are the same or similar to the processes that have been used for decades or k,nger in the mineral processing industry. Hazardous waste treatment and remediation of contaminated solid and/or groundwater is a relatively new industry. Many of the practitioners in this new industry are relatively inexperienced in most of the "new" technologies that are being applied or developed.

Jan 1, 1991

By P. Richardson, B. Sceresini

The carbon-in-pulp and the carbon-in leach process for the recovery of gold and silver from cyanide leaching of ores is now widespread in the precious metals mining industry. However the presence of various base metals can have a detrimental effect on the efficiency and the economics of the process due to high cyani,:••? consumption and a reduction in leaching and adsorption rates resulting in poor recovery of the precious metals. Furthermore the presence of fast leaching and adsorbing metals such as copper can significantly reduce carbon loading capacity for the precious metais thereby necessitating a higher carbon inventory, more frequent stripping and poor bullion quality resulting in higher production costs. This paper describes the development and application of a process for the recovery of copper and and the recovery and re-use of the associated cyanide from the leach circuit at the Mt. Gibson Gold Project in the Murchison Goldfield in Western Australia. The process provides a means to counter-act the detrimental effects of the copper which occurs in the ore as various oxide and sulphide minerals including an extremely fine chalcopyrite powder. It has the added benefit of recovering the base metals in this instance copper, in a saleable form. The process is subject to a patent application by Reynolds Australia Metals, Forsayth N.L. and the author.

Jan 1, 1991

By D. K. Gibson, A. I. M. Ritchie

The phenomenon of acid drainage is likely to occur whenever pyritic rock is broken up, permitting access of air and water. The basic chemistry of the oxidation process is described by the equations below:- FeS 2 +1120 + 7 02 ➔FeS04 +112S04 +1440k.J This reaction proceeds rather slowly, although believed to be bacterially catalysed to some extent. Once sufficient ferrous ions and acidity have been established the following two reactions take over, yielding the same net result but at a much greater rate. First, ferrous ions are oxidised to ferric; this is an extremely slow reaction unless bacterially catalysed.

Jan 1, 1991

By J. M. Carter, Rodney H. Sergent, L. E. Kun, J. T. Pressly

Underground mine service water in South Africa is used for dust suppression and cooling the environment as well as the pneumatic rock drills. Although the chilled water is not intended for potable use, it is often used as drinking water by mining personnel. Furthermore, droplets sprayed are liable to be inhaled. The water is recirculated on a continuous basis and is a potential source of infection by intestinal microorganisms or water-borne diseases such as cholera or typhoid. In order to protect the health of the underground workforce it is customary to disinfect the chilled service water, The bacteriological quality of the water is monitored by enumerating total aerobic bacteria (TAB), total coliforms (C C) and Escherichia coli (E Coli). E coli is an indicator of human faeca_l __ - -- contamination, The bacteriological standard specified by the Anglo American Corporation for mine service water is less than 3000 TA B per 100ml, less than 2 CC per ml and the total absence of E Coli. There are several disinfecting agents available for use. Among these are UV irradiation, ozone, chlorine dioxide and compounds that produce hypobromous and hypochlorous acids. Historically, the methods of treatment have been chlorine based and include the use of gaseous chlorine (surface installations only), calcium hypochlorite granules or tablets, chlorinated cyanurate tablets, sodium hypochlorite solutions and hypochlorite produced by electrolysis.

Jan 1, 1991

By Stuart K. Nicol, Malcolm D. Engel, Neville T. Moxon

Ion flotatir,n of gold is a process being developed to selectively float extremely dilute aurocyanide liquors using a novel surface active complexing agent. The principle of ion flotation is also applicable to a wide range of other metal-containing solutions. The market potential of the gold flotation process would be enhanced by the possible combination of the gold recovery capabilities with both cyanide recovery and metal removal. For example, recovery of copper cyanides from a return liquid strean1 would be a useful means of reducing operating costs and satisfying environmental pressures to treat tailings dams. Experimental work is described where samples of tailings solution from a far north Queensland gold mine were subjected to ion flotation to remove copper cyanide species from a clear recycle solution. The form in which these products was removed was of secondary importance compared to the need to produce a clean solution for use in the plant. Recovery of the anionic copper cyanide species was accomplished using a quaternary ammonium surfactant.

Jan 1, 1991

By A. N. Islam, C. Simons, M. N. Hughes, J. Barrett

The effluent from the bio-oxidation of arsenopyrite contains high concentrations of iron(III) and arsenic(V), the pH being in the range 1.0-1.3. The use of lime to increase the pH causes the precipitation of calcium sulfate, calcium arsenate and a mixture of solids containing calcium, iron and arsenic. The presence of calcium is due to slaked lime encapsulated by the iron arsenate precipitates. These iron arsenate solids are related to known minerals. The use of sodium hydroxide to effect the precipitation of iron and arsenic produces solids which are more stable than those produce by using slaked lime. The use of limewater produces an initial precipitate of calcium arsenate.

Jan 1, 1991

By J. W. C. Wong, S. D. Miller, J. J. Jeffery

Pre-mining identification of acid forming mine and waste materials is of concern to the mining industry because of the potential for the generation of acid mine drainage, acid rock drainage, and soil acidity problems. Accurate identification of acid forming material is essential for developing appropriate waste management strategies to reduce environmental problems related to acid generation from sulphide containing wastes. The acid-base accounting procedure, in its various forms , is commonly used for pre-mining screening of mine and mine waste materials. The procedure is generally effective when used and applied correctly but is prone to incorrect interpretation of results which can have significant financial and environmental implications. This paper examines the acid-base accounting Procedure and the possibility of misuse of this method with special emphasis on the sampling method, the sulphide forms, the acid neutralization capacity, and the interpretation of results. Data from numerous coal, base metal, and gold mining operations are used to illustrate the application of the acid-base account. The data base indicates that overall, approximately 1/3 of all waste generated by mining and mineral processing is potentially acid forming indicating the need for correct identification and management. Problems associated with simple application of 'absolute' acid-base criteria for classifying acid forming material are highlighted and the need for developing site specific or 'relative' criteria is discussed and illustrated by case study.

Jan 1, 1991

By Victor F. Hollister

Porphyry-type deposits are characterized by mineralization in, as well as adjacent to, an igneous body, usually a porphyritic stock. One deposit style includes both mineral dissemination and mineralized veinlets, and both porphyry copper and porphyry molybdenum deposits are characterized by dissemination and veinlet control of ore minerals. Those gold deposits that occur in stocks, with gold occur- ring in veinlets and disseminations within the stock, clearly are can- didates for consideration as porphyry gold type. Porphyry copper and porphyry molybdenum deposits are also characterized by potassic, phyllic, argillic, orpropyllitic alteration or some combination of these alteration types. Where two or more alteration zones are present, these are arranged in a sequential outcrop pattern. Gold occurring in dissemination and in veinlets in as well as adjacent to stocks, and which also occur in typical pervasive porphyry alteration suits, constitute a clearly defined class of deposit that fits the definition of a porphyry gold type. Porphyry copper deposits may carry appreciable gold. Porphyry copper-gold deposits are known from all porphyry copper provinces. This chapter is intended to cover porphyry gold occurrences that may have little or no copper or molybdenum as economic concentrations.

Jan 1, 1991

By Danqing Xu, A. W. Khair

This paper presents a laboratory simulation of regrinding and resulting dust generation. An Automated Rotary Coal Cutting Simulator (ARCCS) was modified to conduct regrinding experiment. In order to estimate the effects of coal properties and operating parameters on regrinding and dust generation, an orthogonal fractional factorial experimental design was implemented in regrinding experiment. Marple personal cascade impactors, Series 290, were used to measure dust concentration during experiment. Three types of coal seams, namely, Waynesburg, Pittsburgh, and Lower Kittanning, were used to represent different coal properties. Experimental results and complete parametric analysis were presented.

Jan 1, 1991

By J. C. Zelanko

The U. S. Bureau of Mines conducted a multi-faceted geomechanics research project at a bump-prone longwall coal mine in eastern Kentucky. This mine presented a unique opportunity to study coal mine bumps in that the problem appeared to be confined to areas beneath a sandstone channel of limited areal extent. The Bureau's research plan sought to exploit the uniqueness of the site by monitoring strata behavior and longwall support reactions as the longwall face approached and passed beneath a sandstone channel. The study incorporated static pillar stress and strata deformation measurements, shield support leg pressure measurements, and microseismic monitoring as well as geologic mapping and the collection of observational data. Data collection was underway when a major coal bump occurred on the longwall face at the mine. Pillar behavior (load and deformation), shield loading, and microseismic activity were monitored prior to, during, and after the bump. Observations in the tailgate indicated that these pillars were failing prior to and after the face bump. Shield load data which were evaluated in an effort to identify trends which could be used to forecast coal bumps appear to provide a measure of the effectiveness of destressing operations conducted on the face (e.g. shot firing). Analyses of microseismic data revealed anomalous values associated with microseismic "energy" prior to the face bump. In addition, microseismic source location data and underground observations provided some insight as to the sequence of pillar and face bumps.

Jan 1, 1991

By P. C. van Aswegen

The Bacterial Oxidation (BIOX®) process for the pre-treatment of refractory ores for gold recovery developed by Genmin, the mining division of Gencor, has been operating successfully at the Fairview mine since October 1986. The continuous operation of a pilot plant at Genmin Process Research has resulted in further process developments to improve plant operating efficiencies. These new developments which include a higher solids content of the pulp feed to BIOX®, lower retention times, higher operating temperatures, lower power utilization for oxygen dispersion .and reduced nutrient addition have all been successfully implemented on the Fairview plant.lt has furthermore been confirmed that the arsenic precipitate formed in the neutralization of effluent solutions complies to the United States of America EPA standards. Continuous cyanidation pilot plant work conducted on BIOX® product has indicated that cyanide consumption can be drastically decreased if a continuous flowsheet is implemented in preference to a batch leaching system.

Jan 1, 1991

1. Reviews Extraction metallurgy, by J.D. Gilchrist. 3rd ed. Oxford, Pergamon, 1989. 431 pp. £50.00 (hard cover), £14.95 (soft cover). Reviewer. Prof. M.D. Brayshaw. Reviewer. Prof. M.D. Brayshaw This third edition bears testimony to a work that contains much of value for lecturers, students, and practising metallurgists. Mineral processing in the United Kingdom, edited by P.A. Dowd. London, Institution of Mining and Metallurgy, 1988. 223 pp. £25.00. Reviewer: Prof. M.D. Brayshaw It came as both a pleasure and a challenge for a resident of South Africa (with its volume and diversity of minerals) to review a book focusing on the beneficiation of ores from the sparsely endowed mineral chests of the United Kingdom. 2. Recent issues Rock mechanics. Theory and applications with case histories, by W. Wittke. Translated from German by R. Sykes. Berlin, Springer-Verlag, 1990. 1076pp. DM248. McGregor's quick reference to the JSE. Pretoria, Juta & Co., 1990. R39,95. McGregor's economic alternatives. Pretoria, Juta & Co., 1990. 400 pp. R34,95. 3. New journals Journal of Materials Chemistry, edited by A.R. West and J. Leader, and published two-monthly by The Royal Society of Chemistry (Blackhorse Road, Letchworth, Herts SG6 IHN, OK). £195 per year, starting in 1991. New Materials World, published monthly by Lawrence Cooklin (15 Selvage Lane, Mill Hill, London NW? 3SS, OK). £180 per year. Mendeleev Communications 4. Books from The Institute of Metals The following were published recently, or are to be published soon, by The Institute of Metals, 1 Carlton House Terrace, London SWl Y SOB, OK. Illustrated case histories of marine corrosion. 1990. Modern steelmaking methods, by C. Moore and R.I. Marshall. 2nd ed. 1990. Grain boundary fractures, by S.F. Pugh. 1991. 160 pp.

Jan 1, 1991

Written contribution by J.F. Curtist The paper is an interesting exercise in the application of mathematics to a theoretical situation presumed to oc¬cur underground. However, some of the assumptions on which the calculations are based are unlikely to occur in any actual mining situation. Assumptions made in the paper Objections to these assumptions are noted seriatim. (1) `it is assumed that any loading-rate effect will be small and can be ignored' (p. 3). A loading rate of the order of 50 kN-12 per cent of the maximum load-is customary to prevent the props being dislodged by the blast. (2) `it is unlikely that all the props will be installed with their full stroke available, but for the purpose of this analysis, it is assumed that this is the case' (p. 3). A more reasonable assumption would be that, with the most careful selection of prop length and the most rigid control of stope width, the available stroke length would on average be reduced by the order of 70 mm on installation-20 per cent of full stroke. (3) `each support unit supports a block of 3,3 m2 bound¬ed by vertical fractures with zero cohesion that are parallel and at right-angles to the stope face respec¬tively' (p. 5). Joughin and Jager have shown this to be an unwar¬ranted assumption in respect of the positioning, the direction, and the dip of the fractures present in a stope in rockburst conditions. If, as assumed, there was `zero cohesion' between such blocks, the removal of a hydraulic prop in row 3 supporting such a block would ensure that it fell out before a profile prop could be installed in the same position. (4) `the height of each of these blocks is 3,0 m, the volume of each block is 9,9M3, the mass of each block is 27 225 kg' (p. 5). The concept of individual props being affected by dis¬crete blocks of known and uniform dimensions of relatively low ground velocities (less than or equal to 2,16 m/s) acting in line with the axis of the prop is one that lends itself to neat mathematical calcula¬tions. It does not, however, bear much similarity to the actual conditions that are exposed underground in excavations where rockbursts occur. Ortlepp and co-workers concluded that `the impulse of the shockwave can cause the displacement of the

Jan 1, 1991

Publications of the IMM These two titles have just been published as part of the popular series of Special Reference Lists being issued by the Institution of Mining and Metalurgy, 44 Portland Place, London WIN BR, England.

Jan 1, 1991

By Batric Pesic

The interactions of mineral-pyrite with T. ferrooxidans were studied by using a cyclic voltametry technique. The interactions with bacteria were examined during the entire growth stage of bacteria (fermentation), The pyrite ?surface invariably drastically changed ' its. properties at the second day of fermentation. Beyond two .. days of fermentation, the cyclic voltamograms were insensitive to convective diffusion produced by stirring. The product layer was examined by SEM,. X-ray diffraction and chemical analysis. The SEM study revealed that bacteria populated the pyrite surface at an extremely high density levels. The high density of bacteria, and the solid reaction products formed on the pyrite surface created conditions for pore diffusion which explained why the CVs became .insensitive to convective diffusion in solution (stirring). The x-r:ay diffraction study confirmed jarosite as a product layer. A mechanism of T. ferrooxidans cells serving as nucleation sites for jiarosite formation is proposed.

Jan 1, 1991

1. Books on management The following are available from Knowledge Resources, P.O. Box 3954, Randburg 2125. . Competitive advantage of nations, by Professor Michael Porter from Harvard Business School. This book highlights the importance of industries in contributing towards national competitiveness. It is being regarded as one of the 10 best business books published during 1990. . The borderless world, by Kenichi Ohmae, Managing Director of McKinsey in Japan. This deals with business in the new interlinked economy. . Megatrends 2000, by John Naisbitt and Patricia Aburdene. This book outlines the mega/macro trends that will

Jan 1, 1991

By M. J. Oliver, A. J. Nugent

Hydrogen Peroxide and Caro's Acid (H2so5) were used to treat cyanide containjng effluents. Significant reagent savings were achieved by using Caro's Acid. Weak Acid Dissociable (W.A.D.) cyanides were removed at near stoichiometric levels of Caro's Acid. Hydrogen Peroxide showed poorer efficiency in the presence of W.A.D. cyanide complexes, resulting in higher consumption rates. By using Caro's Acid, reaction catalyst requirements ar(! el.iminatnd, react.ion I.imes significant.I y rnduced and capita] costs for an effluent lreal.ment facility are minimal. The Efflox* Process ut ilisc�s this more efficienl oxidising reagent in a treatment system exhibiting a simple non proprietary control system with minimal peroxygen consumptions.

Jan 1, 1991