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By P. D. Rao

The combination of high moisture and low heating value has restricted most low-rank coal (LRC) usage worldwide to mine-mouth power generation. Coals from Usibelli Coal Mine and the Beluga coal field have a heating value of approximately 8,000 Btu/lb and 28% moisture. Hydrothermal treatment (at 275 to 352'C) of lump coal from Usibelli Coal Mine and Beluga coal field enhanced the heating value of the coal, on an equilibrium moisture basis, from 8,000 Btu/lb to nearly 12,000 Btu/lb. The product coal with high heating value and 0.2 % S is an environmentally acceptable premium fuel. The Hardgrove grindability index of the coal is greatly improved, further enhancing its value. Increase in hydrothermal drying temperature promotes vesiculation of resinite. Vitrinite reflectance increased to 0.72 and vitrinite was subjected to widespread visiculation resulting in a coke like structure indicative that the material went through the fluid stage.

Jan 1, 1991

Crushing and grinding activity in 1989 followed the rapid pace of the mineral industry. Use of existing installations, demand for expanded capacity, and implementation of entirely new operations contributed to a high level of activity. At the 1989 SME-AIME Annual Meeting in Las Vegas, NV, the crushing and grinding session focused on wear materials in crushers and mills. Another session joined the process control group in its simulation-modeling and control of crushing and grinding circuits. Both sessions addressed the optimization in operating effectiveness. Specific subjects covered grinding media wear of forged and cast grinding balls and rubber lined mill liner wear. Also, the Semi Autogenous Grinding (SAG) Mill Conference in Vancouver in September 1989 provided a valuable update on the progress of SAG operations in recent years. Operationally, gold grinding and roasting circuits were implemented in 1989. Freeport McMoRan Gold started up two operations in Nevada. Two other circuits, both using SAG mills, are scheduled to start in 1990. These will be in Nevada and British Columbia. Elsewhere in gold, additional capacity continues to be brought onstream, both domestically and worldwide. In copper, expansions continue to call on additional crushing and grinding units. The unrest at Bougainville in Papua New Guinea has fueled a continued, strong demand for comminution in the copper sector. Specific equipment installed or started in 1989 included the ac variable frequency drive SAG mills in Australia, Alaska, and Papua New Guinea. Also, the gearless drive SAG mill in Chile provides tremendous flexibility in terms of mill speed. The trend toward moveable in-pit crushers continues -even at established operations.

Jan 1, 1990

A new classification of subduction related (epithermal- / mesother-mal) gold mineralisation styles based on the tectonic framework they occur in, has been found helpful in practice. It offers a ratio-nalisation of exploration efforts during all stages of work.Methodology on the ground during first pass- and follow up explo-ration which has been found effective for the various mineralisa-tion styles is being briefly outlined.

Jan 1, 1990

By J. P. Bunch

As the number of environmental laws continues to steadily increase and the economic penalties for contamination problems become more severe, environmental management represents an important management function within today's U. S. mining industry. The economic impact to a mining company for contamination is not only realized in legal fees and fines but also in the cost of doing normal business. For example, a mining company with contaminated property applying for a loan may be refused because of a lending institution's reluctance to finance due to liability concerns. Or, an insurance company may decide to greatly increase its annual premiums because of existing or potential contamination problems. One of the main duties of the environmental manager is to seek ways to reduce these types of problems by eliminating contamination or by knowing what problems exist and designing corrective measures to prevent the situation from worsening.

Jan 1, 1990

By N. S. Dalal, B. Jafari, F. H. Y. Green, V. Vallyathan

"INTRODUCTIONThe mechanistic details of the biological events leading to coal workers pneumoconiosis (CWP) are not yet fully understood, despite several decades of extensive epidemiologic1.2 and laboratory studies.2-6 Epidemiologic studies1.2 have shown, for example, that the incidence and severity of CWP differ markedly in the different regions and mines at comparable exposures, but laboratory investigations2-6 have demonstrated only partial correlation of the epidemiologic data with the differences in the mineral composition and the rank of coal mined. In particular, while epidemiologic data indicate1.2 direct correlation of the· prevalence and severity of CWP with the rank (i.e., % carbon content) of coal, this correlation has not been established by laboratory4'6 and animal exposure3 studies. In order to explain these results, in 1980 Artemov and Reznik' suggested that perhaps they arise from the fundamental differences in the surface properties of the coal. dusts inhaled by the coal miners and those used in the laboratory studies: while the miners inhale freshly fractured coal particles, henceforth called the 'fresh' coal dust, the laboratory studies generally utilize 'aged' coal dusts (i.e., dusts that have been stored for many days or even longer). Reznik and Artemov' used electron spin resonance (ESR) spectroscopy to show that the mechanical crushing of some Soviet Union coals generated organic free radicals and that the concentration and the decay times (hence the reactivity) of these radicals were higher for the coals of higher ranks. Since some of the radicals decayed within a few minutes in air, the authors surmised that while these radical species could lead to certain specific pathogenic reactions at the sites of mining operations, this might not be the case in the laboratory studies, due to the conventional use of 'stored' dusts which would be expected to contain significantly smaller free radical concentrations. This is consistent with the recent findings that, standardized, aged coal dusts exhibit minimal cytotoxicity. 8While the above mentioned work of Artemov and Reznik7 did suggest a possible new clue to the pathogenesis of CWP (i.e., the role of the coal based free radical species), no direct biological/cytotoxicity data were provided to show that 'fresh' coal dusts were, indeed, more pathogenic than the 'stale' ones. Because of the rather significant implications of the Artcmov-Reznik hypothesis to the understanding of 1hc biochemical mechanism and, hence, the strategies for the eventual containment of CWP, we have initiated a comparative study of the free radical formation and cytotoxicity properties of freshly crushed coal ·particles. As done by Artemov and Reznik, 7 we have used the ESR technique as the direct method of measuring the concentration and decay kinetics of the coal based free radicals. Our preliminary ESR studies on two Pennsylvania coals, a bituminous (carbon content 72 % ) and an anthracite (95 % carbon) coal, have confirmed the Artemov-Reznik finding that the crushing-induced free radical sites are higher on the coals with higher carbon content (i.e., higher rank).9-11 In the present work we describe our more recent results of a parallel study of the time dependence of the decrease in the free radical content of a freshly made anthracite dust (as measured via ESR) and that of the dust's cytotoxicity potential as measured by the extent of hemolysis of (sheep) erythrocytes. We have also investigated the effects of free radical scavengers on the cytotoxicity potential of the dust and deduce that indeed the free radicals could play a significant role in the initial events in the mechanism of the cytotoxic effects due to the inhalation of coal dust inhalation."

Jan 1, 1990

By R. W. Adams

A new process has been developed for leaching zinc sulphide concentrates at atmospheric pressure using air or oxygen plus nitrogen dioxide in dissolved or gaseous form as? an oxygen carrier. The process is flexible and can cope with variations in the degrees of retention and regeneration of dissolved nitrogen dioxide in the leaching phase. By controlled addition of concentrate a leach solution with low residual nitrate concentration can be produced. Following separation by filtration of unleached solids and elementa1 sulphur and conventional oxidation/precipitation of dissolved iron, the leach liquor can be treated with metallic zinc to remove the remaining nitrate and other meta111c impurities such as copper, cadmium and cobalt to provide a solution suitable for electrolytic recovery of zinc. Pilot scale testing of the process .has given zinc recoveries in the high nlnet1es, production of a hi.gh grade jarosite-free Pb/Ag residue (50% Pb.) and a saleable high grade of elemental sulphur. .A wide range of concentrates can be treated containing substantial levels of lead and copper as well as zinc. Indicative cost estimates suggest that the new process is competitive with alternative procedures such as pressure leaching.

Jan 1, 1990

By Donna L. Anderson

This U.S. Bureau of Mines report discusses the status of a laser-based guidance system to provide position and heading feedback and closed-loop control of tramming maneuvers for a continuous mining machine. The system has been developed and tested at the Bureau, and is now being prepared for underground experiments. The system hardware includes laser scanners, a sensor communication network, and host computer hardware. The system software includes a position and heading computation module and a tram control module. The description of the software includes discussions of laser data acquisition, error compensation methods, position and heading determination, safety checking for continuous miner tramming, and closed-loop tram control. The accuracy of the laser scanner's data, the reliability of the lasers in a dusty environment, and the system's accuracy on tracking the position and heading of the continuous mining machine are shown in the results of experiments performed at the Bureau. Conclusions are stated based on these experimental results, and further work to improve the system performance and prepare for underground testing is discussed.

Jan 1, 1990

By M. B. Cortie, J. H. Potgieter

An account is given of the production of three types of experimental high-chromium duplex stainless steel. The alloys had chromium contents of 22, 29, and 35 per cent. The partitioning of the main alloying elements between the austenite and ferite phases was determined, and the effect of the alloying elements chromium, nickel, and molybdenum on the mechanical properties and corrosion resistance of the duplex stainless steels is summarized. The phase compositions of the different duplex stainless steels were measured by different techniques, and the values obtained were correlated. The cracking occasionally observed during the thermo mechanical processing of these alloys was studied, and is explained as being the result of known embritlement processes.

Jan 1, 1990

By P. A. Mingione

"AEROPHINE@ 3418A is a unique sulfide mineral promoter produced by Cyanamid, based on phosphine (PH3) chemistry. It has proven effective as a collector for the sulfide minerals of copper and particularly lead (galena), as well as for secondary gold and silver values. AEROPHINE 3418A has widest application as a Cu and/or Pb collector for complex ores of Cu-Zn and Pb-Zn, which frequently have significant quantities of associated precious metal values. Advantages shown in the use of AEROPHINE 3418A are improved selectivities against Zn- and Fe-sulfides, increased precious metals recoveries, reduced total collector consumptions for Cu and/or Pb flotation, and increased flotation kinetics leading to higher recoveries of these values. Operating plant, pilot plant and laboratory test data from treating different ores are presented, demonstrating the advantages in use and preferred application of AEROPHINE 3418A.INTRODUCTIONCyanamid operates the only phosphine and phosphine derivatives plant in North America, located in Niagara Falls, Ontario. Specialty chemicals manufactured at this facility are used in many diverse applications, including solvent extraction reagents and textile flame retardants. A unique phosphine-based sulfide mineral promoter, AEROPHINE 3418A, is also produced. The origins of AEROPHINE 3418A promoter date back to the 1960's, when it was established that sulfide mineral collectors based on phosphine chemistry demonstrated efficacy. This new collector chemistry was found to provide flotation performance differing significantly from those of more traditional thiol collector chemistries such as xanthates, dithiophosphates, mercaptobenzothiazoles, thionocarbamates and those with xanthogen groups. Some of the advantages ultimately demonstrated by AEROPHINE 3418A promoter compared to these traditional collectors include:"

Jan 1, 1990

By J. F. Peterman, M. C. Roberts

The success of any industrial mineral project requires an accurate forecast of the demand fir the material as well as accurate projections of costs and prices. This paper develops a general method of predicting mineral requirements and applies it to the case of graphite. The basic method is to explain graphite consumption in each of its major uses by the output and manufacturing technology of the using industry. Once these underlying factors are determined, they can he projected to establish future requirements. This forecast is critical to the evaluation of a new source of supply, such as the graphite resources of Upper Michigan.

Jan 1, 1990

Mineral resource and ore reserve estimation is a challenging and demanding field, requiring application of professional knowledge, skill and experience of the highest order. If the many potential hazards and pitfalls are to be avoided however, there are two other requirements which are of equal, if not greater importance:

Jan 1, 1990

By Draper J. J, Lang S. C

Regional geological mapping and facies analysis of the Late Devonian to Early Carboniferous Keelbottom Group of the Burdekin Basin have resulted in a depositional model representing six siliciclastic-carbonate facies. The six facies represent alluvial fan, braidplain delta, siliciclastic shoreline, siliciclastic shallow marine, restricted siliciclastic/carbonate shelf, and carbonate shoal depositional environments. These facies are identified in the Star beds which are equated with and included in the Keelbottom Group in this paper. Facies are repeated throughout the Group, as a result of two transgressive-regressive cycles.The first transgression recognised in the Keelbottom Group began in the mid-Famennian, and followed deposition of the Late Devonian Dotswood Group. It was marked by the deposition of Siliciclastic Shoreline facies in the basal Myrtlevale Formation, which was succeeded by Siliciclastic Shallow Marine facies at the peak of the transgression. The return of Siliciclastic Shoreline facies in the upper part of the Myrtlevale Formation marked the onset of the first regression, which resulted in the progradation of Braidplain Delta facies from the northwest of the basin. During the peak of this regression, deposition in the western part of the basin was dominated by Alluvial Fan facies.

Jan 1, 1990

By Orid A

A fast, non-contact technique for measuring sizes of rock fragments on a conveyor belt is presented. An image processing technique called active stereopsis is used which makes use of a light stripe projected on to the surface of the fragments on the conveyor belt. A CCD TV camera is used to capture the shape of the distorted light stripe. the video image of this shape is then processed by a computer program so that the 3D profile of the surface can be obtained by triangulation. The sizes of the rock fragments are then calculated from this profile. The speed of the technique is improved by calibrating the light stripe system before measurement begins so that the profile of the fragment surface can then be measured using simple geometry. The technique is fast and highly parallel so that it is able to operate in real time.

Jan 1, 1990

By Daniel B. Conn, John L. Floyd

PhotoSeis™ is a blast analysis method that combines the advanced technologies of high speed motion picture photography and digital seismology. When fracturing rock with the use of explosive energy, the human eye cannot detect the details of the process due to its short duration. An extended time base is required to accurately quantify the response of the rock mass to the detonation process. This time base is provided by the use of high speed motion picture cameras. The control of ground vibrations and airblast is an important consideration when developing efficient blast designs. High vibration and airblast levels can be an indication of improper design, inaccurate detonators, or adverse geology. Since many factors can elevate airblast and ground vibration, a greater understanding of the site specific response to the blast design is needed that is beyond the scope of simple seismographic recordings. By synchronizing the photographic record provided by the high speed motion picture cameras with the airblast and vibration information from digital seismological monitoring, the Photoseis™ technique can be of great assistance in controlling airblast and vibration and optimizing the use of explosive energy for rock fragmentation.

Jan 1, 1990

Gold mineralization like other low concentration high value commodities has gained the notoriety of being difficult to sample. This adversely affects the confidence that can be placed in resource estimates and ore reserves. As an example, it is not uncommon to find differences of the order of 30% between duplicates of a single sample sent to two different commercial laborartories. Two halves of drill core generally show marked differences in grade. Again differences of 50% are not uncommon in halved core. In the context of this type of "error" within the base data used for the resource estimate, many of the subtleties of computation methods and expert judgement of resource categories, are almost a case of shutting the gate after the horse has bolted. Managers, financiers and consultants must question the quality of the base data upon which resource estimates are made. They must insist that standard and duplicate samples are used to measure the accuracy and precision of commercial analytical laboratories, that sampling practices have been checked for possible bias and give tolerable repeatability. Further they must ensure there can be a realistic confidence in the estimates by correctly using these measures of data quality to quantify risk.

Jan 1, 1990

By Tim Q. Haldane

The ability to efficiently process low grade gold ores has allowed the Gold Fields Mesquite Mine in Imperial County, California to expand from a 2.1 million tonne per year rate in 1986 to its present 7.3 million tonne per year processing rate. Increased tonnage demands led to the 1989 construction and start-up of a dump leach pad to supplement the existing heap leach operation, resulting in an excellent opportunity to compare the two processes at the same operation. Additional operating costs associated with the crushed ore heaps are justified through enhanced recoveries, even at very low ore grades. An overview of current operating practices at Mesquite is presented along with metallurgical and economic comparisons between the crushed and run-of-mine ore heaps.

Jan 1, 1990

By Richard C. Repsher

The U.S. Bureau of Mines has developed a method and device designed to detect lose rock material in underground mines. The technology is designed to be an aid to mine workers in detecting hazardous roof conditions in underground mines which can complement or replace the traditional roof sounding techniques where the miner relies on experience to determine whether rock conditions are sound. The leading cause of accidents and fatalities in underground mines is falls of lose rock pieces or rock slabs from the mine roof. The device is an electronic roof sounding device that acoustically determines the integrity of mine rock. In previous research the Bureau of Mines found that loose rock, when impacted, vibrates at a much lower frequency than intact rock material. A major problem in determining rock stability using this technique has been the repeatability of the matt signal. This difficulty baa been greatly reduced in the current design by measuring the power spectra contained in two separate frequency bands of the signal produced by striking the rock in question. The ratio of the energy contained in each band is computed. This process minimizes any striking force differences, producing accurate, repeatable results for solid rock as well as loose, drummy material. The prototype has been successfully- tested in a variety of underground environments including coal, uranium, molybdenum, silver and salt. The technology has been investigated by the U.S. Mine Health and Safety Administration and the Department of Energy for use in detecting detached tunnel lining areas in nuclear repositories. The paper will discuss the technique, applicable results, and future applications.

Jan 1, 1990

By C. Tan, A. Putz, P. Lacombe, R. Kemp, M. Kaya, B. J. Huls, A. R. Laplante

"This paper concentrates on the four recent plant trials/ applications of froth washing. Results showed that improved metallurgical performance can be achieved with wash water. Increased froth cleaning yielded better upgrading, and some cases slightly improved recovery. Froth sampling and salt tracer tests supported the findings of froth washing tests.At Falconbridge, Ni grade increased from l.47% to 2.15% and recovery from 85% to 87%. At Eastmaque, final Au grade increased from 2.3 to 2.7 oz/st at a slightly higher recovery. At Les Mines Selbaie, Cu grade increased from 24.5% to 25.S% and Zn grade from 54.5% to 56.l%. At Zinc Corp. of America, average Zn grade increased from 55% to 56. 8% at the same recovery for a 45-day period. A number of plants in Canada and the United States have evaluated and/or now practicing froth washing. Wash water has now proved itself in some plants over several months of operation.INTRODUCTIONFroth washing in mechanical flotation cells offers a number of metallurgical (i. e. increased grades and/or recoveries) and economical (i.e. decreased transportation and smelting & refining costs) benefits. Fundamental development work in laboratory and pilot scales performed at McGill yielded encouraging results. (Kaya and Laplante, 1988a and 1989a). Since laboratory and pilot flotation performance can differ from full-scale due to differences in hydrodynamics, kinetics, and froth characteristics (e.g. stability, loading etc.), plant trials were essential to prove the viability of this technology."

Jan 1, 1990

Disastrous earthquakes are a reality on the Australiancontinent. Unfortunately it has taken the fatal 1989 New-castle earthquake to demonstrate to all Australians that we do not reside on a "stable continent". While the world accepts the potential of plate tectonics and its associated plate margin earthquakes, particularly around the active Pacific Rim, the realisation of devastating intra-plate, or continental, earthquakes is only now beginning to take effect. The 1989 Newcastle earthquake provides many lessons on which to further fundamental earthquake research and the applications to the future welfare of human civilisation. To mitigate the earthquake hazard in relation to the devastation to life, property and industry, research must be undertaken with the resulting informa-tion to be included in the nation's disaster management programs. The earthquake hazard is everpresent in east-ern Australia and the major step in its quantification is a more realistic determination of earthquake risk estimates through an integrated study of seismology, engineering, insurance and sociology.

Jan 1, 1990

By C. Richard Tinsley

Investment activity in the Pacific Rim of Fire has seen a phenomenal surge from epithermal gold exploration. Individual countries are attractive because of lower up-front minerals lease costs (United States, Canada), better geological prospects (Chile, Indonesia), or cheaper equities (Australia). Since the October 1987 stock market crash, large companies are shedding minority joint venture interests to focus on core businesses. Some vertical integration is evident in Japanese coal investments in the Pacific Rim. This article does not cover the aluminum industry oligopoly, which is multinational in character. Nor does it cover the many Canada to US minerals investments. It will be interesting to see if the new US-Canadian free trade treaty will reverse that investment flow. Cross-border investments The following examples should dispel any doubts about the significance of cross-border investment in the Pacific Rim. BHP, Australia's largest public company, has invested $US 4.5 billion in the JS for the following transactions 1984 $2 billion Utah Minerals 1984 $500 million Energy Resources 1985 $745 million Monsanto Oil 1987 $400 million 50.7% Hamilton Oil 1989 $378 million Pacific Resources Placer Dome, mainly through 76% owned Placer Pacific, has the following gold mine developments in hand including the date the project began, Placer Dome's ownership, project name, its location, and capital expenditures: • 1985, 53.1 %, Kidston, Queensland, $A 139 million; • 1989, 37.9%, Big Bell, Western Australia, $A135 million; • 1989, 60.6%, Misima, Papua New Guinea, $C252 million; • 1990,45.5%, Granny Smith, Western Australia, $A95 million; • 1991, 50%, La Coipa, Chile, $US276 million; and • 1991, 25.3%, Porgera, Papua New Guinea, $C1.1 billion. Australia's Western Mining Corp. (WMC), through a foray of off-market acquisitions in late 1987, acquired con¬trol of five Canadian gold companies for a $A488-million outlay ($C452 million) as follows:

Jan 1, 1990