Search Documents

By Batric Pesic

A hydrometallurgical process for recovery of Zn and Mn from Bunker Hill Water Treatment Plant sludge was developed. The process is unique because it treats an unusual combination of metals, Zn and Mn. Another non-standard feature of the process is that leaching takes place with ~S04 in the presence of a reductant (SO2). Zn and Mn are recovered simultaneously by electrowinning, Zn on a cathode and Mn on an anode, as MnO2 The major purpose of the process is to detoxify the sludge by removing toxic heavy metals. The recovered metal values could be marketed to offset the overall costs of water and sludge processing. This work is presented in two separate parts, 1. Leaching and Solution Purification, and II. Electrowinning. This paper covers only the first part of the hydrometallurgical process: Leaching and Solution Purification. Initially, the paper briefly discusses the history of the pollution problem at the Bunker Hill Superfund Site, the origin of heavy metals in the mine waters, and the development and use of the water treatment plant. The leaching of sludge was examined as a function of the following parameters: constant vs. initial pH, initial vs. delayed addition of SO2, temperature, and pulp density. It was found that leaching with H2SO4 at pH 2.0 for 15 minutes (at 60°C), followed by S02 addition for another 15 minutes, could completely dissolve Zn and Mn. Solution purifIcation was done in three stages. In the first stage iron was removed by adjustment of pH (to pH 5.0) and oxidation offerrous to ferric iron (with H2O2). In the second stage, Cu and Cd were removed by Zn dust cementation. Finally, Co and Ni were precipitated with the organic reagents 1-2 nitroso-naphthol and nitroso, respectively. Electrowinning of Zn and Mn is discussed separately in Part II of this paper.

Jan 1, 1996

By Cheng Xiangzhou

The China Ocean Mineral Resources Research and Development Association (COMRA) conducted a topographic survey in its deep seabed claim area with the SeaBeam system in 19475. After analyzing the data, it was determined that there is a group of living things several hundreds of meters in depth that significantly affect the sound waves in the frequency range of interest. We will attempt to investigate more about such influences. Physical model testing is an important means for studying the theory, and for development of the technology for geophysical prospecting. Because the manganese nodules are distributed over the sea floor in irregular patterns, it is hoped that study of the acoustic properties of manganese nodules by means of physical model testing can improve interpretation of the data of the multi-beam system and the SeaBeam system. This will provide a more reliable basis for delimiting the mineral site and evaluating the reserves in the Pioneer area of China.

Jan 1, 1996

By H. Sevim

In long-term open pit production planning, a series of nested and maximum-value pits is usually generated first. These pits are then considered as possible pushbacks over a number of planning periods. To determine the best pushback in each planning period, the pits are evaluated for their technical and economical feasibilities under certain production constraints. Parameterization is a commonly used technique to generate a series of pits. In almost all cases, however, some of the consecutive pits generated by this technique are too far apart from each other. This is called the "gap" problem. It may make the entire pit series useless for production planning purposes. A new pit gener¬ating algorithm has been developed to overcome the gap problem. Through this algorithm, a series of nested maxi¬mum-value pits can be generated with a controllable size increment. The logic of the algorithm is illustrated through a small hypothetical case. Its capability of generating maximum-value pits that are as optimal as those generated by parameterization and its advantages over parameteriza¬tion are presented through an actual gold deposit case.

Jan 1, 1996

By Amir Rehmat

The Institute of Gas Technology has developed a fluidized-bed process for recovering direct reduced iron from blast furnace flue dust a material currently considered to be a waste from the iron and steel industry. In the process, a portion of the carbon in the flue dust is combusted to supply energy for the endothermic reaction between carbon and steam. The reaction produces reducing gases comprised of carbon monoxide and hydrogen both of which react with iron oxides to produce reduced iron. Up to 95 percent of the iron oxides contained in the waste stream can be reduced to elemental iron. The vitiated reducing gases emanating from the process can be used as fuel in the plant. The yield of iron depends upon the quantity of iron oxide present in the flue dust and generally ranges from 20 to 30 percent of the waste stream. The investment cost estimated for a single processing train dedicated to one steel plant can be recovered in less than one year.

Jan 1, 1996

By F. J. J. van Loo, J. K. Kivilahti, M. Paulasto

"Activation mechanism and interfacial reactions in brazing of ShN4 with different AgCuTi filler alloys has been investigated thermodynamically and experimentally. During brazing the AgCuTi filler alloy is divided into two liquids Ll and L2, where the (Cu,Ti)-rich liquid L2 gathers at the ShN4 interface and reacts with it. The concentration of Ti in L2 is high, but due to the strong attractive interaction between Cu and Ti, the activity of Ti in L2 is considerably low. In reaction between ShN4 and Cu-containing brazes a Ti-Cu-Si-N compound is typically formed at the interface. In absence of Cu, in joints brazed with AgTi based filler alloys, extremely Ti-rich solution reacts with ShN4 and as reaction products TiN and TisSh[N] are formed. IntroductionAdvanced ceramics like silicon nitride are increasingly used as structural components in demanding applications as well as in electronics industry. Complex, multicomponent structures for engineering applications generally require interconnections and therefore joinability of ceramics largely determines the possibilities of metal-ceramic structures to enable demanding functions. Brazing with active filler metals, most of which are based on the Ag-Cu-Ti system, has been commonly employed for joining of ShN4 to other ceramics and metals. The interfacial microstructures formed when ShN4 is brazed with Ag-Cu-Ti braze alloys have been discussed in several recent studies [1-7]. However, some inconsistencies exist in the reported results. The formation of layers of TiN and titanium silicides, possibly TisSh, next to the ShN4 has been reported in several studies [1-5], while in another investigation, a layer of an orthorhombic TiSi- Cu-N phase was found beyond the TiN layer [6]. In few investigations the thermodynamics of the ShN4-Ti system has been considered, but no detailed thermodynamic analysis of the chemical interactions between the braze and ShN4 has been provided. In order to resolve which chemical reactions are possible under various joining conditions and thereby to be able to control the brazing of ShN4 the reactions in brazing has to be studied using both microstructural and thermodynamic analysis."

Jan 1, 1996

By Jan M. Mutmansky, David R. Kalasky

Computer simulation continues to be one of the most successful analytical applications of computers in the mining and mineral processing industries throughout the world. Through simulation, managers and engineers can explore the impact of new technologies, equipment designs, plans and operating strategies to improve their operations. It is not uncommon for a single simulation application to provide a quick payback of analysis expenses (within weeks or months) yielding long-term financial and operational dividends. The paper will present a summary of the types of software systems that are available for use on PCs and other computer systems. Support software for curve fitting, statistical analysis, and optimization of simulation models will also be presented. Methods of leveraging simulation efforts through networking and coupling of software systems will be discussed. Finally, the trends in simulation in the mineral industries will be analyzed. Areas of strength and weakness of simulation will be discussed along with the usefulness of commercial general-purpose and custom-writ- ten simulation packages. The future possibilities for simulation in the mineral industries will be outlined and predictions on trends for the future will be presented.

Jan 1, 1996

Australians have always been great travellers but, traditionally Australian companies have been very conservative in contrast to more daring individual Australians. During the 1960s, '1970s and 1980s, the Australian companies spent much of their time exploring in Australia. It was only some of the major companies like CRA and BHP that had explored in places like Bougainville and Chile. However, during the mid-1980s some of the smaller companies started looking beyond their shore towards other opportunities in other countries. Why did they do this? Were they pushed or did they jump? And where did they go?

Jan 1, 1996

By J. C. Adams

Although explosives constitute only a small portion of a mine's total cost, the relative success of each blast has a tremendous effect on subsequent activities such as excavation, crushing, and equipment maintenance. Beginning in January of 1993, tests were carried out to determine whether productivity could be improved by replacing standard ammonium nitrate fuel oil mixtures (ANFO) with a high density, high performance blasting agent. The study was carried out at gold mines, coal mines, and cement quarries in Nevada, California, Colorado, and New Mexico. A wide variety of rock types and blasting conditions were encountered. Results showed that at most operations productivity was sufficiently improved to more than offset the increase in explosives cost. This resulted in a net reduction in mining cost. This paper presents a summary of these results.

Jan 1, 1996

By M. J. Beus

This paper will describe the research approach being initiated by the Spokane Research Center to assess hazards and design criteria to prevent ground and muck falls in and around ore passes in hard-rock mines. The major goal of this research is to compile detailed information about ore pass processes and hazards, identification and testing of prevention strategies, and development of computer-based measurement and design methods. Recent ore pass failures have underlined the lack of OE pass design capabilities and standards available to both mine engineers and MSHA personnel. Design criteria and ore pass hang-up prevention and remediation strategies will include the effects of internal ore pass loads, blasting to relieve hang-ups, and rock mass stress redistribution and structural interaction from nearby mining. New visualization and three- dimensional analysis methods will be presented as an extension of existing ore pass design and analysis techniques. A sophisticated particle-flow analysis program will be used to simulate the response of various ore pass designs to a wide range of loading conditions driven by rock mass deformation, muck flow, ore pass blockage, and blasting in both nearby stopes and the ore pass. Analysis techniques will be calibrated and design criteria validated at the Spokane ore pass test facility. These tools will serve to reduce research costs by limiting the number of experimental field tests required.

Jan 1, 1996

By R. W. Bartlett

I first met Milton Wadsworth in 1951 as an eighteen year old junior taking his mineral processing course at the University of Utah. He guided my senior thesis, evaluating the then new polymer flocculants on settling uranium leached ore pulps. This was before ion exchange and solvent extraction. After my military service and a brief working stint at Kennecott he supervised my PhD work. He encouraged me to be active in AIME and its constituent societies, where both of us have been directors of AIME and presidents of TMS. He has been a consultant for research groups that I have managed. Above all, he has been my mentor and friend for nearly 45 years. Thus, I am honored and particularly pleased to receive 5MB's Wadsworth Award.

Jan 1, 1996

By Barbara Maren Winkler

For mine production problems in mines with varying qualities, both open pit and underground, the linear programming method (LP) has been used successfully. By this method it is possible to keep the total production blend for each period within a required range of qualities while optimizing objectives like production costs, net return, ore grades, other qualities, or a combination of these. Technical restrictions like constrained capacities can be added to the model. This makes LP a flexible and powerful tool for mine production planning. Practical experiences have shown the major influence fix costs have on the actual economic result of a planning decision. It can be proven that fix costs cannot be included in LP models. We describe a way to address this fix cost problem by using mixed integer linear programming (MILP) as an extension to LP in the optimization of a mine planning problem. This raises the issue of complexity. We discuss the computational complexity of the resulting models and the enhancement of model flexibility for the user of a planning system. We demonstrate the method embedded in a practicable everyday planning system for a complex underground coal mine. By computational examples we show how the method improves the economical results of the planning.

Jan 1, 1996

By J. C. Yingling, J. W. Leonard

Introduction The absence of coal-face particle management heavily penalizes the transportation of coal from initial loading to final consumption. The penalties include dust problems, significantly reduced mine-loading-cycle productivity, mine-belt spillage, excessively high coal-preparation costs, chute blockages and dangerous pulverizer blockages at the final point of utilization. Fine particles commonly cause environmental and economic problems. It is well known that these fines can cause safety and environmental dust problems. But it is not well understood that these fines can also swell broken coal to a point where 5% to 15% more time and capacity must be used to deliver the same tonnage. In this paper, methods and rewards for reducing and/or managing fines at the mine face are discussed. Computer-based loading-cycle model productivity estimates, viewed from a new perspective, are made on the basis of material volume rather than on the long-established, and frequently misleading, basis of tonnage. It is typically the volume of broken material being transported that defines the capacity of a given transportation system, while the corresponding tonnages are merely a reflection of the specific material densities. Published evidence suggests that the swelling of broken coal can be decreased very significantly using small quantities of certain nonfrothing chemicals, which are added to mine-face spray water, and by employing improved mine-face breakage practices. In a future paper, the effects on transportation productivity beyond the coal mine will be discussed. The precursor to the work presented in this paper, involving the bulk density improvement for broken coal and the subsequent production gains for underground coal mines, was earlier presented in Leonard and Newman (1989). In the past, this topic has been studied and practiced only in byproduct coking in the steel industry. However, a potential exists for an increase in coal-industry productivity by improving the bulk density of coal to yield a subsequent reduction in delivered cost. This can occur with breakage, handling and treatment methods resulting in the loading of greater quantities of coal in fixed volumetric capacity haulage units such as mine cars, shuttle cars and scoops. Laboratory-based experiments to achieve an increase in productivity by increasing coal bulk density were discussed in Leonard, Paradkar and Groppo (1992). Chemical techniques using small quantities of commercially available reagents (surfactants) resulted in about a 13% to 15 % increase in bulk density, which was thought to produce a proportional increase in the productivity of a mine, together with a subsequent reduction in cost. The idea is to mix the reagents with the water that is used to spray coal during mining. In this paper, the impact of bulk density improvements on production rates is presented. Increases in production ranging from 60% to 88% of the bulk density increases are projected. This analysis was performed for atypical continuous-miner section. In the following sections, discussion and results of the analysis are presented. Discussion An analysis was performed to ascertain the impact of bulk density improvements on face-production rates for a typical continuous-miner section. Figure 1 illustrates the section layout and cut sequence. This layout and sequence is identical to the case described in King and Suboleski (1991). As can be seen, the section uses five entries and 12.2-m cuts that are taken by a remotely controlled continuous miner. The seam height is 1.5 m and two shuttle cars (5.7 t nominal capacity) are employed for haulage from the miner to the section feeder, which, throughout the cut sequence, is positioned as illustrated in Fig. 1. The simulation model was coded in the SIMAN simulation language. The major impacts of increased bulk density improvements on such a production system are as follows: •Shuttle-car payloads, in terms of the mass of coal transported per haul cycle, are increased proportionally to the increase in bulk density that results from the application of surfactant. •Shuttle-car discharge times should remain largely unchanged, because they are determined by the volume of material that is discharged, rather than the mass, and this volume does not change.

Jan 1, 1996

By D. C. Panigrahi

The paper presents the application of Object Oriented Programming approach for the development of a network simulation model based on nodal pressure method using linearised flow equations. The convergence and computational efficiency of the algorithm have been investigated. Finally the paper re- ports the validation of this algorithm in actual field conditions.

Jan 1, 1996

By Fathi Habashi

Solid gas reactions of metallurgical importance can be classified into three groups: Physical processes, e.g., drying and sublimation Chemical processes which may be an addition or a thermal decomposition reaction Electrochemical processes which may be addition, oxidation-reduction, or displacement reactions. Examples are given and the role of the boundary layer is emphasized.

Jan 1, 1996

By P. Tapp, T. Evans, N. A. Molloy, J. Lucas

"Consideration of the protoype tuyere geometry for injection of inert gas through the bottom in a basic oxygen steel furnace and a requirement to specify an optimal flow for bottom wear and metal penetration led to experimental investigations[l,2] to apply the results of previous workers to this specific case, Flow velocity profile development within the tuyere was proposed as significant and the experimental scheme was designed to test this. It is proposed that the design criterion for the conditions of optimal flow of the prototype geometry be based on the non-dimensional mass velocity.INTRODUCTIONSharma[3] tested small diameter tuyeres in a laboratory hot model using molten iron to define a flow criterion for prevention of penetration of the bath liquid into the tuyere. Using argon, nitrogen and helium through a range of tuyeres (1 to 3 mm ill ) he proposed the jet Froude number C Fr' ) with the critical value being 2400 - 2500 or higher. Sonic or supersonic velocity was not a sufficient criterion. The tuyere design was a parallel tubular duct of moderate aspect ratio CAR) i.e. the ratio of length to diameter ranging from about 22 to 36 in the experimental furnace.Farmer et al[4] stated their their aim ""to develop a unifying explanation and procedure for the proper design of tuyeres"" but disagreed with Sharma's jet Froude number criterion. Recalculating Sharma's data they proposed instead a fully expanded Mach number of 1.75 with an initial expansion angle of ten degrees as the lower bounds of flow to meet the design requirement. They experimented with tuyeres in a water model using tubular, annular and convergent-divergent nozzles. The aspect ratio of the parallel duct tuyeres was from 533 to 762 using diameters of 1.4, 1.7 and 2.0 mm C the diameters being of tubes to be used full scale). Subsequently these results were applied to a prototype tuyere using a diameter of 1.7 mm with beneficial results in practice. This tuyere had an aspect ratio of 1067."

Jan 1, 1996

By Brian Wingfield, Rick Givens, Greg Williams

Many technological advancements have been made in explosive products and applications over the last 15 years resulting in productivity and cost gains. However, the applications of total energy (engine horsepower) in the majority of rotary drilling technology, has remained virtually unchanged over that period. While advancements have been made in components, efficiency, and types of hydraulic systems used on drills, the application of current hydraulic technology to improve drilling productivity has not been interactive with end users. This paper will investigate how traditional design assumptions, regarding typical application of horsepower in current rotary drill systems, can actually limit productivity.

Jan 1, 1996

By Clive-Workman Davies, K K. Kabongo, Mensah Frimpong

Given the capital intensity of the dragline operation coupled with rising cost of explosives, the onus is on mine operators to make maximum use of explosives in blasting to assist dragline diggability. At a surface coal mine in South Africa large boulders necessitating secondary breakage and in some cases completely unfragmented sections of a blast resulting in low dragline diggability were encountered in the interburden blast. Twelve blasts were therefore closely monitored and dragline productivity evaluated. The ultimate aim was to improve the overall blasting performance and hence increase dragline productivity. Three areas were in focus; fragmentation assessment, dragline productivity assessment and cost analysis. The studies indicated unsatisfactory explosive and initiation performance, problematic blast design and questionable operators performance. It is established that dragline cost account for 60% of the total mining cost whereas the drilling and blasting cost account for the remaining 40% and that improvement in dragline productivity results in automatic cost saving.

Jan 1, 1996

The structural design of a pavement relates to the ability of the road to carry the imposed loads without the need for excessive maintenance or rehabilitation. Current techniques for the structural design of haulage roads are empirical and based primarily on the previous experience of personnel assigned to pavement design, both in terms of the strength of the structure and the quality of the wearing course material. This has the potential for unwarranted expenditure on too thick a structure or, conversely, premature deformation leading to the need for excessive expenditure on maintenance. Furthermore, the effect of larger haulage vehicles on the structural performance of a pavement cannot be predicted. Thus, there is a need to develop a portable and practical method of structural design. This paper presents an overview of structural design methods for mine haulage roads and, through an analysis and quantification of the structural performance of existing pavements, recommends the mechanistic design procedure, together with a revised structural design and associated limiting design criteria. It is concluded that the application of the mechanistic method to a design project can reduce the costs of haulage roads construction and accrue additional benefit in terms of reduced operating and maintenance costs.

Jan 1, 1996

By M. D. Bishop

Early solvent extraction circuits in the uranium industry utilized bona fide kerosenes as diluents for extractant chemicals. These kerosenes were used successfully in the uranium industry; however, at least one plant was destroyed by fire resulting from the use of a low flash point kerosene. Although the term "kerosene" is used throughout the solvent extraction industry, the authors have been unable to find any use of kerosene in copper solvent extraction circuits. A term that is occasionally used with reference to diluents is "metallurgical kerosene." Such a term is unrecognizable in the petroleum industry. Kerosene [or kerosine] is a flammable hydrocarbon mixture that is less volatile than gasoline. It is produced for combustion purposes and may have variable compositions of organic compounds including alkanes, alkenes, alkines, and aromatics. Diluents are constant composition hydrocarbon mixtures developed specifically for use in solvent extraction processes. These products usually have much lower vapor pressures and higher flash points than kerosene. In solvent extraction systems, they typically comprise 70 to 95 v/o percent of the circuit organic. The primary purpose of the diluent is to adjust the extractant concentration to the working range of the operation. The diluent and extractant must be completely soluble or miscible with each other. Secondary diluent effects are to promote transfer kinetics, optimize phase disengagement, and minimize both organic in aqueous and aqueous in organic entrainment.

Jan 1, 1996

By D. H. Rubisov

The neural networks modelling approach is one of the most elegant black-box type methods to model industrial processes. In this paper, this approach is applied to model the performance of the CEZ zinc electrowinning plant. The model that was built was found to exhibit an excellent predictive ability for voltage and current density. The model was also used to investigate the sensitivity of the process to various key variables such as temperature, current density, zinc and sulphuric acid concentration, etc. Optimal regimes for zinc production were identified from the power consumption standpoint.

Jan 1, 1996