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By Leopoldo Cortez, Fernando Durão

The dynamic control of a froth flotation section is simulated through a neural network feedback controller, trained in order to stabilize the concentrate metal grade and recovery by applying random step changes to the feed metal grade. The results of the application example show that this controller seems to be sufficiently robust and a good alternative to handle a non-linear process.

Jan 1, 1995

By I. Nishkov, L. Alexandrova

The kinetics of froth flotation and the three-phase contact (TPC) parameters are studied at temperatures varying from 20°C to 40°C. The material floated consists of glass spheres and a quartz particles with various diameters. Dodecylamine hydrocloride (DDAHCI) is used as a collector. The equilibrium three-phase contact angle is measured with a microscope technique using the modified Mingins-Scheludko method. Using a Wilhelmy method, the temperature effect on the surface tension of the DDAHCI solution is determined. The formation of the thin film on a polished plate of vitreous silica and the expansion of TPC is monitored by means of a metallographic microscope and recorded on a attached camera at different temperatures. The experimental data show an intensification of the flotation kinetics at 30 and 40°C in the case of small particles. Such an intensification is not observed with the larger particles. The cause for intensification of the flotation kinetics is sought for in the dependence of the TPC rate of expansion and induction time on temperature.

Jan 1, 1995

By Jozef S. Stachulak

Inco Limited operates 11 underground mines in the Sudbury District. The mines are located on the rim of the Sudbury Basin, an oval with the axis in the range of 27 and 60 km. The ore dips to at least 3000 m below surface. The ores are mined primarily for nickel and copper. Total ore production from underground is in excess of 55,000 tons per day. Over 40 surface fans have been installed since the late 1960's. All of the fans are adjustable pitch, axial flow units. A major factor influencing ventilation design in the last 30 years has been the introduction of diesel equipment underground. Volumes per fan have ranged from 60 to 330 (cubic metres per second), with motors from 100 to 2500 hp. Fans of the axial flow type have been in common use for main fan installations at Canadian mines for many years. The standard arrangement has been to mount these fans horizontally, i.e. with the fan shaft and the long axis of the housing horizontal. This is a natural arrangement for an underground fan, but for a surface installation, a vertically mounted fan has definite advantages. The surface area taken up by a typical vertical fan installation is generally about one quarter of that with a horizontal fan of the same capacity. (1) This is not a problem with isolated fans and flat surface outcrop sites, but where the installation is to be near existing buildings, or where there are poor surface soil conditions, space and cost considerations greatly favour vertical fans. MAIN FANS INSTALLED There are 43 main surface fans in operation at 11 mines. Twenty-seven of these fans are supply units, and 75% of them are vertical installation. The remaining 16 units are main surface exhaust fans, with predominantly horizontal installation. Within the last five years, some 20 main booster fans have been installed underground at several mines. Axial flow fans, with adjustable pitch blades, are used for both surface and underground installations. Exhaust fans are equipped with stainless steel or cast aluminum blades. Main underground fans are arranged horizontally and the majority of them have a floating shaft between the fan shaft and the motor. (2) The size of the fans in service varies from 1.8 m to 5 m in diameter, with the majority ranging from 1.8 to 2.5 m. The pressure produced by these fans varies from 0.25 kPa to 2.0 kPa. At Inco Limited, two main fans in parallel are preferred, rather than a single fan, so that if one fan fails, the remaining fan can still supply up to 70% of normal air quantities, while the damaged fan is repaired. This requires closure doors on each of the fans so the fan can be isolated in case of failure. It is more expensive than a single fan, but results in less production interruptions. The fan installations are well away from sharp inlet and outlet bends. FAN DESIGN INTEGRITY Both the mine operator and the fan manufacturer must understand that the main fan is critical to the mine operation, and that everything technically possible must be done in design and manufacture to ensure the highest degree of reliability. Some of the design parameters and criteria, based on Inco experience, are outlined and discussed below. RESONANT FREQUENCIES AND HOUSING MODEL ANALYSIS Any fan assembly will have many different resonant frequencies. It is a challenge to the designer to arrive at a design in which forcing frequencies do not coincide with any of these resonant frequencies to produce unacceptable vibration levels in operation. Finite element analysis is a useful tool that can be used to identify the most critical of these, so that housing and blade stiffness can be adjusted to change any resonances that might be close to forcing frequencies. Shaft critical speeds should be at least 25% above the fan operating speed, and there should be sufficient separation between other resonant and forcing frequencies to avoid excitation that might result in high vibration levels. QUALITY ASSURANCE Radiographic Blade Examination Mine fan blades are normally cast in small lots. To ensure that the castings are sound, a full radiographic examination is recommended in the highly stressed lower 1/3 of the blade.

Jan 1, 1995

By Y. A. Attia, D. K. Sengupta, H. A. Hamza

Increased recycling of waste paper has been emphasized in recent years in both the United States and Canada for environmental and economic reasons. Removal of ink particles from waste paper pulp is therefore necessary. One of the most promising methods for ink removal is froth flotation. This study investigated the feasibility of a simplified flotation scheme and found that about 90% to 92% ink removal can be achieved. Also, a 95% to 97% ink removal is achievable if a hydrophobic polymer is used ahead of the flotation stage. Clean paper pulp recovery was over 90%. The effects of pulping pH, flotation pH and concentrations of flotation and polymeric reagents are discussed in the paper.

Jan 1, 1995

The copper concentrate market is becoming increasingly unstable. In the early 1990s large concentrate stocks were built up and the glut was cleared only after treatment charges rose so sharply that 'non-traditional' custom smelter capacity, such as in Kazakhstan, could be employed, By 1994 the market had shifted and Western smelters were unable to secure enough concentrates to operate full out. The reason for these sharp swings in the market balance is that virtllally all the recent mine development has been non-integrated. With different companies developing new mine . and smelter capacity, it is inevitable that the pace of expansion in the two sectors will not be coordinated. For many years the Japanese smelters were the major buyers from the new mm-integrated mines. However, Japanese smelter capacity is unlikely to increase appreciably in the future and this stabilizing influence will be very difficult to replace. This paper will examine the likely concentrate/smelter balance over the next five years and will forecast the likely direction of? treatment charges. It will also touch on the critical variables in assessing the viability of new greenfield custom smelter capacity, such as proximity to concentrate sources, by-product sulfuric acid prices and, most importantly, tariff protection.

Jan 1, 1995

By Igor Rojkovic

The most important uranium mineralization in the Western Carpathians occurs in the Permian rocks. Low grade stratiform uranium mineralization was formed during the Permian due to adsorbtion and reduction by organic matter, titanium oxides, iron hydroxides, pyrite and clay minerals. During the Alpine orogeny uranium (± molybdenum and copper) remobilized stratabound ores were formed. Dominant ore minerals are uraninite, U-Ti oxides, molybdenite, pyrite and chalcopyrite Two generations of ore minerals are reflected by their textures and chemical composition.

Jan 1, 1995

By J. W. Lyman

Nickel-metal hydride (Ni-MH) battery electrodes have been developed as a substitute for cadmium-containing negative electrodes. Use of Ni-MH electrodes offers enhanced electrochemical properties in many instances as well as reduced environmental toxicity. Rechargeable batteries using Ni-MH electrodes are also strong candidates for electric vehicles. During the production and secondary reclamation of these battery types, recycling procedures will be needed to prevent environmental impact caused by these wastes as well as to recover the value inherent in the scrap. The U.S. Bureau of Mines (USBM) is investigating hydrometallurgical technology that separates and recovers purified metallic components from Ni-MH battery scrap of two types, AB, and AB,. An investigation of acid dissolution and metal recovery techniques has determined several processing alternatives that may be used to promote the successful recycling of much of the battery fabrication scrap and eventual secondary scrap. Although recovery techniques have been identified in principal, their applicability to mixed battery waste stream and economic attractiveness remain to be demonstrated.

Jan 1, 1995

By Charles Dr. Li, John Dr. Box

Selective flotation and adsorption behavior of zircon and rutile under hot soap conditions have been examined. Conditioning temperature, pH and washing steps were shown to control the flotation selectivity. The adsorption of the sodium soap of oleic acid at zircon- water and rutile-water interfaces was investigated through micro- electrophoresis and adsorption density measurements. The soap adsorption on the zircon surface increased markedly with increasing temperature due to a strong chemisorption/surface reaction, and was almost independent of pH. In contrast, the soap adsorption on rutile decreased at high pH values. A simple physisorption plus hydrophobic interaction appeared to be the principal mechanism for the soap adsorption on rutile at moderate temperatures (below ~70(C), beyond which it may change to chemisorption through an activation process. Water wash, particularly under acidic conditions (pH 2-3), of the rutile particles treated with soap, will lead to a desorption of the soap from the rutile surface by forming an acid salt precipitate.

Jan 1, 1995

By Dredge K, Becker G

The successful dissolution of the valuable metal components of a solid phase is often a basic requirement for a successful hydrometallurgical treatment process. Sulphide concentrates are often an intermediate product in the production of refined metals. These concentrates need to be further processed to realise the contained metal values in a useful form. Pyrometallurgical techniques have tended to dominate, at least the initial treatment of metal sulphide concentrates. The technology described, Activox«, has been developed specifically for the hydrometallurgical treatment of these sulphide mineral concentrates, in particular those containing copper, nickel or gold. The Activox« dissolution technology coupled with the use of existing, or newly developed, downstream processing techniques, offers alternative processing options for the recovery of full value, saleable metal products. The technology is suitable for application down to relatively small scales opening up the opportunity for on-site production of metals even at modest scale mining Operations.

Jan 1, 1995

Low displacement fault zones often comprise a mesh of interlinked faults, extensional-shear and purely extensional vein fractures. Hydrothermal mineralisation localised around such structures testifies to their importance as conduits for fluid flow. Mesh structures are most commonly developed in situations approximating bulk pure shear but predominantly simple shear meshes also occur. They appear to develop through the infiltration of pressurised fluids into a heterogeneous rock mass with varying material properties. In some circumstances, mesh formation appears to be a precursor to the development of major through going faults. Mesh formation generally involves hydrofracturing (Pf > s3, at least locally) and the condition Pf ~ s3 to be maintained for the mesh to remain a high permeability conduit, requiring fluid over pressuring at other than shallow depths in extensional-transtensional regimes. The volumetric character of earthquake swarm activity appears to result from the passage of hydrothermal fluids through mesh structures, representing a form of distributed fault-valve action along suprahydrostatic hydraulic gradients arising from magmatic intrusion, compaction overpressuring, metamorphic dewatering, etc. Fluid redistribution in the crust is influenced by maximum hydraulic gradient (not necessarily vertical), by existing permeability anisotropy arising from bedding and other forms of crustal layering, and by structural permeability developed under the prevailing stress field. Strong directional permeability develops in the s2 direction, parallel to fault-fracture intersections within the mesh and orthogonal to fault slip vectors. In particular tectonic settings, stress-controlled permeability allows strongly focused flow through fault-fracture meshes with high potential for mineralisation. Favoured localities for mesh development include short-lived link structures along large-displacement fault zones such as dilational jogs, lateral ramps, and transfer faults.

Jan 1, 1995

By Schofield D

The problem of production scheduling is sufficiently complex to negate the use of many conventional optimising techniques as there are numerous and diverse factors that must be considered when trying to produce an optimal schedule. These factors include: grade distribution, orebody geometry, production rate capacity, processing constraints and market price of the minerals amongst a variety of others. In addition it may be observed that many of these factors incorporate a degree of uncertainty and any schedule produced must inevitably consider risk as a primary consideration. The very nature of the problem has limited the use of conventional optimisers. Genetic algorithms use methods based upon evolution and natural selection to produce `optimal' solutions to complex system problems. They are extremely flexible and robust in their nature and it is these characteristics that are important in this particular problem domain. A particular strength of the genetic optimisation approach is the ability to handle the multiple and non-linear constraints that are typically encountered in mine scheduling problems. This paper concentrates on the development of a prototype application of a genetic algorithm to the problem of scheduling the output from multiple production points in an underground mining operation. In particular it.describes a system (GO-SCHED) that can be customised to handle a wide variety of underground scheduling problems. GO-SCHED, a Windows-based system, can interface with a variety of databases and spreadsheets for data input and output and provides a simple intuitive approach to the solution of the scheduling problem.

Jan 1, 1995

South Africa is the world's largest producer of gold. The survival of its gold mining industry is dependent, to a large extent, on the successful implementation of new mining technology which reduces the operating costs. Gold mines of the country have a record of a high operational cost per tonne of rock excavated. The geology of the gold-bearing rock, in addition to the mining depth and the gold recoverable grade, profoundly affect the profitability of the industry. Among the other mining operations, drilling and blasting take a fair share of the mining cost. It is therefore proper to implement a dynamic approach of technological review aimed at combating the escalation of mining costs. Over the years, the industry has moved away from labour intensive activities. Mechanised operations are introduced where possible. Management techniques are oriented more towards better utilisation of human resources and machinery so as to enhance productivity in the stopes. This paper addresses the issue with particular reference to blasting operations in the stopes of deep gold mines. It reviews the conventional drilling and blasting techniques. It outlines some innovative changes brought about in the course of recent years with the aim of optimising productivity and the stope efficiency in particular. It focusses on the peculiarities of the blasting technology in deep mines. It discusses the issue of interaction between the high stress fields underground and the blasting generated stresses on rock fragmentation, as well as their impact on the remaining excavations. It anticipates the concept of the new technology of selective blasting in stoping. Finally it puts forward the crucial role played by management of the human factor underground.

Jan 1, 1995

By Saskia Duyvesteyn

For many applications in hydrometallurgy and water treatment it would be advantageous to use ion-exchange resins in stirred reactors. However, attrition of the resin may lead to significant losses of both resin and metal values and prevent water quality goals from being reached. We have studied the recovery of fine resin particles by froth flotation, using the model copper - Dow XFS4195 chelating resin system. As the functional group on the resin is a bis-picolylamine, the resin should be amenable to flotation by anionic collectors, such as sodium dodecylsulfate and sodium dodecylsulfonate. The kinetics of copper loading from dilute aqueous solutions in an agitated vessel were studied as a function of copper concentration, pH and resin bead size. The flotation of unloaded resin was investigated for different types of collector, collector concentration, conditioning time, and resin bead size. Potential applications are discussed.

Jan 1, 1995

By B. M. Ghadiali, J. B. Putnam, T. P. Smirnoff, M. A. Elioff, P. F. Ryan

Geotechnical investigations for the Mid-City Extension of the Los Angeles Metro revealed high concentrations of toxic hydrogen sulfide (H2S) gas as well as methane. Testing techniques employed to determine the extent of gasses, and to identify potential treatment measures, included gas sampling with cone penetrometers and soil-gas extraction with air injection testing. A gas reservoir model was developed to predict inflows into excavations. Other studies included a hazard evaluation and a general data search for other H2S occurrences and geologic conditions that could facilitate the accumulation of H2S. The paper describes the investigations and proposed design and construction alternatives.

Jan 1, 1995

By Kjell Winther

"Hydralift Scanmec introduced early in the eighties a new and different mill design for very large grinding mills. The design described has actually no size limitation upwards and is so far suggested with motor power up to 40 MW. The mill is furnished with gearless ring motor drive transmission. It is totally fabricated, without heavy castings. The first installation, an 8, 1 MW ball mill dia. 6,5 m x 9,65 m length, has been in continous operation in 13 years without problems. Total grinding costs has been reduced with 3 0% compared to traditional smaller mills. Reductions has been achieved in maintenance cost, power consumption, liner wear and grinding media consumption.So far 3 ball mills of the described design are delivered and in operation, one grinding Iron ore and two grinding Nickel ore.IntroductionThe design of mills for mineral ore dressing has basically been unchanged since grinding in mills started some I 00 years ago, in spite of the fact that mills have grown larger and larger. This has resulted in structural and mechanical problems, causing expensive failures and loss of production.Hydralift Scanmec engineers were designing mills for more than 20 years according to the old «rules». As they experienced interest for an increase in the mill size at the time when reports about failing mills were published, they started analyzing the different mill parts to find new solutions. One goal was to only use elements from proven technology in the new design. Two key items were ring motor (wrap around motor)(Isch et al. 1977, Meintrup and Klein 1982, Ranze 1983) and large diameter pad bearings (wrap around bearings)(Fuller 1984), both acknowledged from other industries."

Jan 1, 1995

By Thomas M. Barczak

Wood cribs have been the dominant form of supplemental support in coal mining for many years. Recently, there has been a renewed interest in prop supports as a replacement for wood cribbing due to the increasing cost of mine timber and engineering advancements in prop design to improve their stability and yield capability. Prop supports generally consume less material, can be installed in less time with less labor, and provide less restriction to mine ventilation than wood crib supports. Several prop supports are now available or under development'. These include: (1) Strata Products Propsetter? Support System; (2) Heintzmann ACS and Super Prop; (3) MBK-Hydraulik MEGA prop; (4) Advanced Mining Technology Inc. (AMTI) BTS Mortar prop; (5) Dywidag Coal Post; (6) Western Support Systems YIPPI support; and (7) "The Can" support by Burrell Mining Products. A comparison of the performance and cost of these support systems to wood cribs is made to provide mine operators with information needed to assess their application potential. Examples of current underground installations are discussed. Included in this assessment are full scale tests of these supports conducted in the U.S. Bureau of Mines' Mine Roof Simulator.

Jan 1, 1995

By J. J. Moore, B. Mishra, D. L. Olson

The production of radioactive and reactive metals, such as plutonium, uses various pyrometallurgical techniques that generate significant quantities of waste salts contaminated with hazardous, reactive or radioactive materials. Health concerns, environmental regulations and economic considerations require proper mitigation processes to recover the valuable components and for recycling or unrestricted release of these salts. The Oxygen Sparging Process converts soluble metal halides, such as chromium-, plutonium-, cerium chlorides, into insoluble oxides and/or oxychlorides which can be consolidated and separated for long-term storage or further processing. The matrix salt phase, viz. calcium and/or alkali chlorides, are clean after oxygen sparging and fit for recycling. This method has been described and its optimized parameters discussed to show that RCRA regulated elements, such as, chromium, lead, cadmium, etc. report to the consolidated phase making the salt recyclable. Salt Scrub Reduction Process for the recovery of radioactive and RCRA metals from the waste salts has been developed. The process uses a Ca-Ga intermetallic alloy which recovers over 98 percent of the reactive metals. The matrix salt phase in this process, viz. calcium or alkali metal chlorides, are clean after salt scrub reduction.

Jan 1, 1995

By Jinrong (Patrick) Mang

Three of the most challenging problems in phosphate beneficiation are discussed: flotation efficiency, resource conservation and environmental impact. Some new flotation machines offer the opportunity of reducing power and reagent consumption significantly, while increasing specific capacity many fold. Efficiency might also be improved dramatically by replacing the "double float" process with a single-collector scheme. Model based software control is a powerful tool for improving overall plant efficiency. Recovery of phosphate values from the phosphatic clays could extend phosphorus reserve life significantly. phosphate recovery from the slimes might be achieved by sizing-flotation, selective flocculation and bioleaching. Reducing the volume of phosphatic clays produced is another key stop to minimizing phoephate logs. Such a reduction may be realized by floating at finer cut size. Although an ideal' dolomite separation process is yet to be developed, a cationic flotation process may prove to 'be economically feasible. Loss of phosphate in the desliming stage is the major problem with most of the flotation schemes for removing dolomite.

Jan 1, 1995

By Dao De Xu, Heechan Cho, Mark S. Klima

A study was conducted to determine the feasibility of using dense-medium centrifugation for separating fine (-150 µm) coal. A centrifuge provides the capability of varying the rotational speed and retention time independently, which offers the potential for a higher degree of control as compared to a dense-medium cyclone. Tests were conducted with a 140-mm diameter by 76-mm long Plexiglas separator, which was fitted with appropriate feed and discharge pipes to allow continuous separations to be made. A suspension of ultrafine (-10 µm) magnetite and water was used as the dense medium. The effects of operating conditions, including the magnitude of the 'g"-force and retention time, on centrifuge performance were investigated.

Jan 1, 1995

By C. K. Nworu, L. O. Asuquo, C. O. Nebo

Selective flocculation studies of Agbaja iron ore with starch-type and nonionic polyacrylamide-type flocculants has been conducted to determine the effect of flocculant type. The results indicate that corn starch was slightly better than cassava starch in selectivity performance. Cassava starch was in turn better than Superfloc 16, while the poorest results were obtained with commercial starch. Sodium humate shows better dispersive capability, and thus enhanced flocculation results, than sodium silicate. Pulp pH affects the zeta potential, polymer chain configuration and hence selective flocculation. Overall results indicate that recovery and separation of this very fine grained iron oxide by selective flocculation is feasible.

Jan 1, 1995