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By Hayes P. C

The reduction of small, dense zinc oxide (ZnO) samples in CO/CO2, and CO/N2 gas mixtures has been investigated at temperatures between 900 and 1100¦C. The microstructural characterisation of the reacted and partially reduced samples was complemented with measurements of the rates of the reactions. The mechanisms and kinetics of reduction of zinc oxide were found to be dependent upon the CO partial pressure, the oxygen potential of the gas mixtures, temperature and degree of reduction.

Jan 1, 1991

By N. P. Reddy, L. Adler

The valuable Maximum Utilization Factor (MUF) concept has been extended to other rotating excavators beyond Stripping Shovels and Draglines. In this concept the boom reach and bucket capacity are multiplied to get an MUF, then normalized by dividing by the equipment weight. Statistical analyses were applied to the remaining shovels (hydraulic and cable), draglines, and backhoes. Positive correlations were found. Stripping Shovels and Draglines were also re-examined. The results provide an estimate of equipment diggability and encourages versatility by the interchange of the boom and the bucket. The concept further clarifies the existing equipment classification by delineating General Excavating, Loading, and Stripping kinds. The results also forecast trends, and noted innovative advances and possible retrogression. Extension to other boom excavators, such as front-end loaders, is recommended. The MUF concept provides one of the few indices of gross external characteristics available to the engineer-user of equipment.

Jan 1, 1991

By J. G. Groppo, B. K. Parekh

A series of performance studies were conducted using countercurrent column flotation to recover a marketable clean coal product from existing preparation plant fine waste streams. The test work was conducted at several preparation plant sites in Kentucky and Virginia using a 150-mm (6-in.) inside diameter column that was 5.8 m (19 ft) high. Both thickener feed and classifying cyclone overflow with a typical size distribution of 150 µm (100 mesh) X 0 were tested. The percent solids of the column flotation feed varied from 1.5% to 15% while the ash content ranged from about 30% to 60%. The concentrates produced contained 2% to 10% ash with Btu recoveries of nearly 90% using 0.12 to 1.25 kg/t (0.25 to 2.5 lbs per st) fuel oil and 0.12 kg/t (0.25 lbs per st) MIBC. These results were consistent with or better than results obtained in preliminary laboratory scale column flotation evaluation. Test results from seven different seams are discussed as well as scale-up relationships used to design a full-scale installation presently in operation.

Jan 1, 1991

The patterns of flow of reaction gases through the flash furnace at the Kalgoorlie Nickel Smelter were simulated in a 1:20 scale model using a flow of water. Particular features of the flow down the reaction shaft, through the settling chamber and into the uptake leading to the waste-heat boiler were examined. Inferences were made concerning the effects of the patterns of flow on the efficiency of the smelting reaction, on the entrainment of dust by the gas stream and on the erosion of the refractory lining of the furnace. In addition, the effects of geometrical modifications to the arrangement of the concentrate burners and to the profile of the settling chamber were explored by making these changes to the model and observing the resulting variations in the patterns of flow.

Jan 1, 1991

By V. Rajagopal

Corrosion and abrasion properties of a series of chromium-containing cast iron balls with Cr contents ranging from 0 to 29% was evaluated and compared with austenitic stainless steel and mild steel balls. Marked ball wear tests were performed on artificial ore samples consisting of 95% quartzite with either 5% pyrrhotite or 5% chalcopyrite under a nitrogen or oxygen atmosphere. The electrochemical mechanism was investigated by correlating the corrosive wear with the corrosion currents obtained from potentiodynamic polarization curves under abrasion. An offset in their electrochemical activities was observed somewhere between 16 and 26% Cr. In fact, 26 and 29% Cr cast irons showed an excellent corrosion resistance approaching that of austenitic stainless steel. Flotation recoveries were estimated on a 95% quartzite + 5% pyrrhotite sample ground with various cast iron ball materials under an oxygen or nitrogen atmosphere. Electrochemical results are found to be in good agreement with corrosive wear obtained from marked ball wear test and with flotation results.

Jan 1, 1991

By K. M. Kinealy, A. R. Ramsden, D. H. French

A negative correlation exists between sphalerite composition and gold content when gold is transported as Au(HS)2(-); however, there are spatial and temporal differences within a single deposit. A previous model for the formation of volcanogenic massive-sulphide deposits within thermally intensifying and waning hydrothermal sytems in much the same way as is observed around modern sea-floor vents is supported. The results also emphasise that recognition of the mechanisms of gold transport in ancient deposits depends critically on an understanding of their mineralogy and stratigraphy

Jan 1, 1991

By C. -S. Jiang

In most copper refineries, addition agents are added at predetermined rates with no further monitoring of their activity or concentration in the electrolyte. Increasingly stringent cathode quality requirements, and a desire for better process control in tankhouse operations, have recently directed a number of refineries to search for a better addition agent control strategy. Extensive development work has been carried out at the Noranda Technology Centre for the monitor in of glue and thiourea in copper refinery electrolyte using cyclic voltammetry (cv~. Data from both synthetrc and commercial electrolytes are presented, showing the ability of CV to produce reliable and easily identifiable fingerprints of addition agent concentrations in copper refinery electrolyte.

Jan 1, 1991

By M. L. Apel

A conceptual approach to the bioremediation of uranium mill tailings (UMT) is presented., This approach focuses on, biosorption to remediate the. effluent solution and bioleaching remediate the. solid fraction. Comparative biosorption studies were performed with synthetic single metal solutions using a commercially available biopolymer. The maximum rate of metal sorption by calcium alginate was found to be 5.43, 6,39, 6.48, and 9.74 mg dm-3 min-1 for U022*, Ba2+, Cd2+ and Zn2+, respectively. Activation energy (AEa) for barium uptake by calcium alginate beads was determined to be 11.5 kJ, indicating a diffusion controlled reaction mechanism. Thermodynamic values (AG+ AH+ and ASt) of the metal-alginate activated complex, as reported in the literature, were found to be in agreement with those calculated from this research. Results show that this biopolymer can be effectively applied in the removal of select metals prevalent in uranium mill tailing effluents and associated waste streams.

Jan 1, 1991

By M. F. Gleason, S. Burns, J. R. Arnold

In 1986, Gold Fields began negotiations with a large Nevada electrical power utility to supply power for its Chimney Creek mine in northern Nevada. After the long negotiations reached an impasse over various costs associated with the power line, a decision was made by Gold Fields to generate its own power. Self-generation is not uncommon overseas, but it is rare for any but very large or very small operations in the United States. Surprisingly, under certain conditions a mine can generate its own power profitably, and Gold Fields has found that the associated operating and maintenance problems are minimal. The following report details what factors went into this decision and how it works. Hopefully, it can serve as a guideline for those who may find themselves in a similar position. History In the spring of 1986, Davy McKee Corp. was contracted by Gold Fields Mining Corp. to provide design engineering and construction management for the chimney Creek Mine. Chimney Creek is located about 50 mi northeast of Winnemucca, NV in a remote part of Humboldt County. The nearest industry using utility power was the Pinson Mine, about 13 mi from the proposed plant site. The existing electric line was not capable of carrying another mine the size of Chimney Creek, which required 29 million kwh per year. There were three options available to Gold Fields for the power supply: 1 )Power could be supplied by the public utility from a coal-fired plant about 30 mi away by constructing a new line to the mine,

Jan 1, 1991

The Bureau of Mines, with a history of mining research since 1910, still seeks improvement in safety and health along with improvement and competitiveness in the mining industry. Much promise of such improvements lies in new technology, and this is particularly the case in the still growing coal mine sector, although much Bureau research is long term, high risk, aimed at new concepts.The miner's environment is a primary concern, involving technologies of contaminant monitoring and control in high production scenarios. Contaminants arising from diesel use, alternatives to high speed rotary cutting and more efficient dust removal are being addressed, and drilling efficiencies, better monitoring through unitising operations and insitu rock dust monitoring are particular features.

Jan 1, 1991

The Jurassic Walloon Coal Measures crop out over much of the Moreton Basin and contain numerous thin, banded coal seams which have been mined at various locations since the 1870s. Historically most mining has been by underground methods. Increased exploration during the 1970s and 1980s has led to the delineation of significant open cut coal resources and to the development of the Oakleigh, Jeebropillly and Ebenezer open cut coal mines in the Rosewood-Walloon area. Over 2 170 million tonnes in-situ of shallow, high volatile bituminous coal with a mean maximum vitrinite reflectance of between 0.5 and 0.6 have been proven in the Basin.

Jan 1, 1991

By W. Swisterski, G. Romaniszyn, S. A. Lukasiewicz

The present paper analyzes the motion of a particle of material in a horizontaly rotating tumbling mill. The sliding of the particle under action of dynamic and friction forces and its free flight fall are analyzed. It was found that mechanism of free-fall occurs at supercritical rotations of the mill.

Jan 1, 1991

By Joni M. Barnes

A strain of Pseudomonas stutzeri isohted from selenium contaminated surface waters, was found to be effective . in reducing selenate (Se04 2) stoichiometrically to selenite (Se03 2 '), which was further reduced to elementaJ selenium (Se0 ). These reactions were concurrent with the microbial oxidation of lactate. In order to assess quantitatively the amounts of seilenate and selenitein solution, improvements to existing analytical methods (ion exchange chromatography and inductively coupled plasma atomic emission spectrophotometry technique) .were made.

Jan 1, 1991

By W. H. Pailes, V. Castranova, K. Van Dyke, J. H. Kang

Recruitment and activation of phagocytic cells after inhalation of occupational dusts has been implicated in the development of pulmonary inflammation, fibrosis, or emphysema. Plateletactivating factor has been described recently as a potent inflammatory agent. The objective of the present study was to investigate if platelet-activating factor might play a role in the inflammatory response of the lung to occupational dusts. In vitro exposure of alveolar macrophages to cotton dust (4 mg/ml), silica (10 mg/ml), or coal dust (10 mg/ml) results in the release of picomole levels of platelet-activating factor with a potency of cotton dust > silica > coal dust. Time course studies indicate that platelet-activating factor release from alveolar macrophages is maximal approximately 10 minutes after in vitro exposure to silica. In vitro, platelet-activating factor is a direct stimulant of polymorphonuclear leukocytes increasing chemiluminescence 2.3 ± 0.3 fold above control. The maximal response occurs in the dose range of 10-10 to 10-7M platelet activating factor. In addition, plateletactivating factor potentiates the response of polymorphonuclear leukocytes to a second stimulant; i.e., chemiluminescence generated from polymorphonuclear leukocytes exposed to plateletactivating factor (10-9M) plus chemotactic peptide (FMLP, 10-9M) is 88 ± 22% greater than the sum of the separate effects of these stimulants. In contrast, platelet-activating factor is not a direct stimulant of alveolar macrophages in vitro, having no stimulatory effect on chemiluminescence or superoxide anion release even at levels of 10-6 to 10-5M platelet-activating factor. However, platelet-activating factor (10-5M) does potentiate zymosan-stimulated activation of chemiluminescence and superoxide release from alveolar macrophages by 117 ± 56% and 30 ± 4%, respectively. In conclusion, these data indicate that exposure of the lung to occupational dusts results in the release of platelet-activating factor which may activate polymorphonuclear leukocytes and potentiate the responsiveness of alveolar macrophages to dust. The net result would be pulmonary inflammation and hypersecretion of reactive species by pulmonary phagocytes which could lead to tissue damage and pulmonary disease.

Jan 1, 1991

By John T. Cantwell

INTRODUCTION The process engineer usually is responsible for the design operating philosophy and/or day-to-day operations of a process. Since instrumentation is an integral part of the operation, it is essential that engineers understand the general capabilities of the different types of control equipment available. Many "noncontrol" engineers have become involved with instrumentation for machinery monitoring and control as well as other plant applications. The advent of the microprocessor has led to significant changes in control, both in systems configurations and man-machine interfaces. Today's concept is called simply "distributed control." What is distributed control? Distributed control is exactly what the name implies; the control system is divided into several functional segments and spread out to cover a process. The systems are distributed for physical, functional, and risk reasons. Before delving further into the specifics of distributed control, let's look at the evolution of control systems to see how we got here. Instruments initially were located near measurement and control points in the field. Operators physically had to go to the instrument to change setpoints or take measurements. As processes became more complex, it became evident that a central control area was required. This allowed an operator to monitor and control many variables. The operator's effectiveness was increased dramatically, which resulted in greater efficiency, better quality control, and lower personnel requirements. At the same time, plants became much larger, control applications became more complex, energy became expensive, and the industry became more competitive. All of these factors placed pressure on process and production engineers to get the most for the money. The result was a continuing push to put more instrumentation into a central control room to maximize efficiency and productivity and minimize manpower. This chapter deals in some detail with devices for measuring physical and chemical properties of coal; devices for measuring the weight and weight-rate of flow of coal; devices for the monitoring and control of conveyor systems, solids inventory, fluid flow, liquid level, density, and specific gravity. These instruments have a multitude of uses throughout a coal preparation plant. The discussions cover advancements in "on-line analysis," nuclear control devices, and distributed control using microprocessors, mainframes, and soft-

Jan 1, 1991

By R. E. Moore

The lining systems currently in use in BOF furnaces, certain steel ladles, and the slag line of electric are furnaces were developed during the late seventies through the mid-eighties using a trial and error method of combining aggregate, carbon sources, additives and binders. They are currently based on magnesia, graphite, metal additives and resin binders, the selections of each being tied to the anticipated intensity of the use conditions. The general functions of the respective constituents are well appreciated, however, there is still a great deal that is not known about how the socalled antioxidants protect the graphite nor how impurities from the graphite and the aggregate enter into the wear processes. In a simplified assessment of wear processes, it appears that if the deoxidized layer can be kept very thin, less than 810 mm in depth, and if the viscosity and quantity of the matrix glassy phases can be controlled to resist erosion of the deoxidized layer, lining life can be maximized for the various applications. This paper will discuss the characteristics of the starting materials systems currently being employed for applications requiring a deoxidation function to realize extended wear. It will not attempt to explain all the complex interrelationships between the respective constituents but will point to the potential for improvements through the use of improved constituents.

Jan 1, 1991

By C. W. Schultz

Introduction The Mineral Resources Institute, The University of Alabama, has for the past three years been engaged in a program to develop a beneficiation system for eastern (Devonian) oil shales. One objective of that program was to evaluate advanced technologies for effecting a kerogen-mineral matter separation. Column flotation was among the advanced technologies selected for evaluation. Early in the program it was shown that column flotation was superior to conventional (mechanical) flotation and to the other advanced technologies being evaluated. The investigation then proceeded toward the further objective of defining the optimum operating conditions for column flotation. One observation made in the course of optimization testing was that introducing the feed into the froth (above the pulp-froth interface) resulted in an improved combination of concentrate grade and kerogen recovery. This observation was reported in a previous paper (Schultz and Bates, 1989). Because the practice of maintaining the pulp froth interface below the feed point is contrary to "conventional" practice, it was decided to subject the observation to a systematic series of tests. This paper describes a recent series of tests and the results that were obtained.

Jan 1, 1991

"Polycom, a new approach to ore processing based on pressure comminution, is obviously a very attractive alternative to conventional processing methods.Since a full-scale pilot plant was commissioned in 1986, more than 125 commercial installations, with capacities up to 1000 t/hr, have gone ahead.Already successfully used in processing cement clinker, limestone, coal, and other minerals, Polycom high pressure grinding results in:o Significantly reduced capital costs, because smaller units can be used m new installations;o Capacity increases of up to 100% in existing facilities; and o Operating economies that include energy savings of 20% or more, and reduced wear parts consumption.1. IntroductionAutogenous or semi-autogenous mills in conjunction with rod or ball mills are used with preference for ore processing. Most ball mills are of closed-circuit design and operate with mechanical classifiers (spiral or rake classifiers) or hydrocyclones. In other words, the ores undergo wet primary grinding, since slurries are required for the downstream separation stages anyway. This paper presents a new grinding system based on high pressure comminution of ores. This grinding process allows:- Energy savings of up to 20 % or more- Capacity increases of up to 100 % and more- Reduction of wear costs- Smaller units for new installation and thus- Reduced investment costsThese advantages are highly interesting for both new installations and conversion projects, particulary in cases where an increasing hardeness of the ore, i.e. rising Bond Work Index, reduces the output of the plants or where the metal assay of the ore decreases and the capacity of the existing systems has to be increased. POLYCOM high-pressure grinding rolls have established themselves with great success already for grinding cement clinker, granulated blast furnace slag, limestone, cement raw materials, coal and other materials.Meanwhile more than 250 high pressure grinding rolls have been installed worldwide. Capacities up to 1.000 t/h with roller diameter up to 2.8 m and drive units up to 2.400 kW are installed."

Jan 1, 1991

By Clark IH

Numerical modelling is an effective aid for the planning and design of underground coal mines. With funding from the National Energy Research Development and Demonstration Program, CSIRO Division of Geomechanics has produced a workstation environment which will allow the Australian Coal Mining Industry access to a wide range of numerical design models. The emphasis is on usability and simplicity and the long-term aim is that the techniques should be used routinely at the mine site, so that, in the future, design of a new underground mine will routinely involve modelling of each proposed layout.Each of the five numerical analysis programs, FESOFt, FLAC, MNLAY, FEBLK and UDEC has both strengths and weaknesses. Some analyses with each program demonstrate areas when; observed in situ behaviour in underground coal mines has been successfully modelled, and the results of site monitoring provide a basis for comparison with the predictions of numerical models.

Jan 1, 1991

By Jay Hilary Kelley

A ventilation system is described using dual aircourses: one zone occupied by working personnel, the other at the active working face. The two zones are separated by a partition or Shroud. The occupied zone to the rear of the face zone is ventilated adequately but with considerably less air because little gas, dust, or fumes are present. The face excavating zone is sealed and maintained at slightly more negative pressure preventing dust and gas generating from within to escape. Explosive mixtures within the face zone is rendered non-explosive by the introduction of inert gas therein. Each zone is vented separately to the outside of the mine. Because less total quantity of air is required for human breathing, etc, the total ventilation system can be drastically reduced in tan capacity, development entries, and air shafts, -- a great savings in costs.

Jan 1, 1991