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By M. J. Ferrante

Relative enthalpies of cuprous iodide (CuI) were measured at the Bureau of Mines to provide thermodynamic data for the advancement of min-eral technology. Enthalpy measurements between 298.15 and 1,396.3 K were made with a copper-block drop calorimeter. The temperatures of transition were measured by differential scanning calorimetry (DSC). Reversible transitions were determined at 643 K with a standard enthalpy of transition [(6Htr)] = 0.74 kca1/mol, at 679 K with a [6Htr = 0.65 kca1/mo1, and at 868 K] with a standard enthalpy of fusion [(6H~) = 1.895 kca1/mol.] Tabulated values are listed at selected temperature increments from 298.15 to 1,600 K for the standard relative enthalpy (HO -H298), heat capacity (CpO), entropy (SO), and Gibbs energy function [-(Go -H298)!T]. The enthalpy data are also given in the form of equations and combined with thermodynamic data from other investigations to derive values of standard entha1pies of formation [(~HfO)], Gibbs energies of formation [(6GfO)], and logarithms of the equilibrium constants of formation (log Kf).

Jan 1, 1987

By Stone. Jon P.

INTRODUCTION Countries that are currently developing their mineral potential have unique information systems requirements to support these activities. The mining laws usually grant the State considerable authority over the process. In many instances, the mining laws give a government agency the responsibility for granting and controlling exploration permits and development concessions. This is the case in Costa Rica. The Direcion of Geologia, Minas, y Hidrocarburos (DGMH) of the Ministerio de Industria, Energia y Minas (MIEM) is responsible for the management and operation of the National Mining Register. This paper describes the results of two studies of the information system requirements to support the National Mining Registry as well as those supporting some of the other function of the DGMH. The first of the studies reviewed the situation before the installation of computer equipment. The second study evaluated the installed systems. BACKGROUND Historical Perspective Mining in Costa Rica is at present a relatively minor part of the economy. It consists primarily of industrial minerals and gold production. Gold production is largely by small-scale miners and may be more substantial than reported. There is considerable interest on the part of the Government in both having a better understanding of the existing mining industry and promoting future development. Mining law was first provided by the Ordinanza de Mineral (of 1830). This was replaced by the first Mining Code of 1953. Apparently, one of the first problems caused by the 1953 law was the granting of concessions which were not worked. A 1968 agreement with ALCOA also resulted in political conflict. The Government worked on a new Mining Code for many years and in 1982 the current Mining Code was enacted. Draft implementing regulations were prepared in April 1984. Mining Code of 1982 The Mining Code of 1982 addresses most aspects of mining in Costa Rica including the declaration that all mineral resources are to be the property of the State. The State may grant exploration permits and exploitation permits. The exploitation of hydrocarbons, radioactive minerals and certain water resources was reserved to the state. The DGMH was given authority to settle placer claim disputes, maintain a registry of exploration permits, and exploitation concessions. and generally supervise mining activity. Towards this, the Mining Code of 1982 includes rather detailed requirements for the processing of application for permits and concessions. Mining Code Application Requirements The following briefly describes the requirements to give the reader a feeling for the complexity of the process. Currently, over 1,000 active applications, exploration permits and exploitation concessions are being monitored under the process. The number remains relatively consistent in that the number of new applications is usually about the same as the applications that are put aside. The time and date of the filing must be certified by the DGMH. The application must include all the information specified in the Mining Code. If incomplete, DGMH must notify the applicant of the deficiencies or omissions and direct that the applicant correct the deficiencies or omissions within 8 business days (a single 30 business-day extension is allowable). If the applicant does not respond as directed, the application is deemed as not having been filed and the pertinent information is placed in the files. The DGMH must reject the application outright and direct it be placed in the files in the following cases: (a). If the new application covers the area of a previous permit or concession, either being processed or already granted.

Jan 1, 1987

By Jean-Marc Simard, Vincent Jourdain, Denis W. Roy

"Seven lithologic units, informally characterized, were recognized in the vicinity of the Montauban orebody. The first five lie in stratigraphic order. From structural bottom to structural top these are: (1) grey composite gneiss; (2) dark grey quartz-biotite gneiss; (3) quartz-biotite-garnet gneiss hosting several calcareous, aluminous and magnesian members and gold mineralization; (4) light grey quartz-muscovite-(sericite)-biotite gneiss; and (5) metabasafts. The last two intrude the sequence: (6) amphibolite dykes and (7) pegmatite veins. The orebody lies on the inverted limb of an overturned synform verging to the west with the metabasafts marking the core of the fold. As the foliation is folded, this fold is attributed to deformation ""D2""; deformation ""DI"" being responsible for the formation of the foliation. A late brittle deformation developed shear zones with probable strike-slip motions. The refined stratigraphy and the identification of the structural position of the orebody provide new tools for regional interpretation and prospecting.RESUMESept unités lithologiques ont été définies informeffement à proximité du gisement de Montauban. Les cinq premieres reposent en ordre stratigraphique; ce sont de la base au sommet structural: (1) le ""gneiss mixte gris""; (2) le gneiss gris forcé à quartz biotite; (3) le gneiss a quartz-biotite-grenat comprenant plusieurs membres calcareux, alumineux et magnésiens ainsi que la minéralisation aurifère; (4) le gneiss gris clair à quartz muscovite- Isericitel-biotite; et (5) les métabasaltes. Les deux autres unites sont intrusives dans la sequence: (6) les dykes d ‘amphibolite et (7) les veines de pegmatite. Le gisement se sitlie sur le flanc inverse d'un synforme déverse vers I' ouest dont les métabasaltes occuperaient le cœur. Comm e la foliation est plissée, ce pli est considère appartenir d la deformation ""D2""; la deformat ion ""DI"" etant responsable de la formation de lafoliation. Une deformation cassante tardive se traduit par des zones de cisaillement, d rejet apparemment directionnel. Cette stratigraphie plus précisé et l'indentification de la position structurale du gisement fournissent de nouveaux omits de prospection et d'interprétation regionalé."

Jan 1, 1987

By P. M. Lin

The problem of abandoned mine land (AML) subsidence is getting more severe because abandoned mine lands which used to be located in the remote areas have been gradually developed into suburbs or even urban areas. Abandoned mine subsidence is also becoming more common than before because the time-dependent effect of exposed underground materials. These materials will deteriorate gradually and cause subsidence as time passes. Subsurface conditions of abandoned mines are seldom known to the public. Mine maps are not always available. If the mine mans are available, their accuracy are very - often questionable. In addition, the most common damages to surface structure and ground surface due to mine subsidence can also be created by other non-mining related geological hazards. These factors make the study of abandoned mine subsidence significantly complicated, tedious, and inconclusive. For instance, the cause, time, and amount of surface subsidence can be predicted with relative accuracy during active mining. However, it will be a considerable challenge to do so on abandoned mine subsidence. If abandoned mine subsidence can be predicted in advance, then the damages can be held to a minimum. However, this prediction technique is not yet well developed. Therefore, remedial measures require more attention. In order to have effective remedial measures, the real cause of the damage should be determined first. This paper describes the approach which was employed for the determination of abandoned mine subsidence. A site investigation was made first. According to the information obtained from the site investigation, a hypothesis was set up. Then the instrumentation was used to prove the hypothesis. By going through the procedures for several cases, a guideline which can be used by the inspectors to inspect abandoned mine subsidence will be established.

Jan 1, 1987

By R. S. Das, A. K. Sinha

Modern mine ventilation systems have grown rapidly in recent years both in terms of complexity and value for human health and safety. Although computer models are now available to help the design and operation of mine ventilation systems, considerable differences often exist between the computer-based predictions and practical results. Research conducted to compare computer results with practical measurements made in ventilation circuits simulated in a physical model seems to confirm such differences. It is concluded that although a mine ventilation computer model is a very powerful tool, it can be utilized to its full potential only if reliable input data are provided.

Jan 1, 1987

Use water-jet-assisted cut-ting technology to reduce the exposure of mi ne workers' to respirable dust. Approach Install water-jet-assist on mining machines and evaluate its impact on respirable dust. How It Works Water-jet-assisted cutting involves a mechanical cutting bit working in combination with a moderate pressure (generally up to 10,000 psi) water jet directed just in front of, or through, the bit tip. One of its advantages is reduced dust generation because the jet wets the face of the material being cut more efficiently than a conventional low-pressure water spray, thus capturing much of the dust before it ever becomes airborne. It also removes loose cuttings ahead of the bit before they are pulverized by the bit into respirable dust. Total water consumption is about the same as for conventional low pressure dust control water spray systems. However, there is some increase in power consumption because of the energy needed to provide the high pressure water.

Jan 1, 1987

By I. J. Jansen, C. L. Hooks

Successful soil construction involves prepa¬ration of an adequate base, selection of high quality soil ma¬terials, and placement of those materials by means which will establish a continuous macropore network and modest to low soil strength. Where such has been accomplished, experi¬ments reveal row crop productivity on reclaimed land which is very competitive with that on undisturbed land. Inferior productivity and sensitivity to drought stress are experienced where the soils are excessively compacted during construc¬tion. Some deep tillage practices have been quite successful in improving the compacted soils, but it is preferable to avoid compaction as the soil materials are handled.

Jan 1, 1987

By W. Z. Choi

In our previous work, a population balance model describing the simultaneous processes of size reduction and mineral liberation has been developed. The experimental verification of this model, however, has been limited to a binary mineral system containing only one composite particle class. When considering multiple classes of composite particles, the estimation of model parameters becomes much more difficult. In the present work, a procedure for estimating model parameters for a multiple composite class model has been developed. Emphasis is placed on the direct experimental determination of these parameters. The physical significance of the breakage rate function and the liberation function in characterizing the liberation process is also discussed.

Jan 1, 1987

Faced with low prices and weak demand in an oversupplied market, the Australian coal industry must seek to further reduce its costs. The paper examines minesite competitiveness of the open cut coal industry in Australia with some references to the coal operations of M.I.M. Holdings Limited. The make-up of F.O.R. mine costs is analysed in order to identify where efforts should be directed to maintain competitiveness. The scope for mine site improvements through changes to working practices, the application of new technology and cost management is examined.

Jan 1, 1987

By Dan G. Wasyluk, Meryl J. Klassen, Tony J. Morris, Clive H. MacKay

The Rogers Pass Project in British Columbia has involved the construction of two railway tunnels totalling 16.6 km and a 345 m deep shaft. Systematic geological mapping was carried out at four headings during construction. The paper discusses the procedures used to record the geology, structure, rock mass characteristics and excavation performance. Coded data from the geological mapping and shift inspector reports was entered into a computer data base. The rock mass quality was evaluated for both the Geomechanics and Q classification systems. Continuous computer generated graphic logs were produced showing the excavated perimeter map, geological parameters, installed support and construction activities. The tunnel logs were updated on daily basis and used during construction by project staff for evaluating support requirements and monitoring excavation progress. The specific requirements, difficulties and advantages in mapping tunnels using a computer based system are compared to those of a conventionally mapped tunnel excavation with hand drafted tunnel logs.

Jan 1, 1987

By Malcolm J. McPherson, Daniel J. Brunner

This paper describes an experiment conducted to investigate the law of airflow on a mechanized longwall coal face. Background to the Square Law relating frictional pressure drop and airflow is presented and deviations from this Law are discussed. The procedures used to investigate the Law of Airflow for the longwall are described and the results are presented. The results verify the Square Law relationship for airflow along a mechanized longwall face.

Jan 1, 1987

By Hayes P. C

The kinetics of reduction of PbO-silicate melts in CO-N gas mixtures at 900¦C have been studied. Rea~tion rates were measured by moni- toring the CO2 content of the product gas. A wide range of gas and melt compositions and gas flowrates have been investigated. The overall reaction rates in heterogen- eous systems are typically characterised by a steady increase as the gas flowrate is in- creased. At low flowrates the processes are limited by gas film mass transfer. At high flowrates it is expected that the rates will tend to maximum values determined by either the rate limiting chemical reaction or diffusion in the condensed phase. In the present series of experiments it has been found that for any given gas composition the overall reduction rate goes through a maximum with increasing gas flow. The maxima, which occur at relatively low gas flows, are more than an order of magni- tude greater than those observed at high gas flowrates. The results of these and other experiments are presented and analysed. Possible rate limiting mechanisms in the reaction system and their implications regarding commercial reactors are discussed.

Jan 1, 1987

The height of permanent slopes at the Panguna mine of Bougainville Copper Limited will vary from 350 to 950 metres. A few degrees difference in slope angle has a large effect on the ore/waste stripping ratio. Optimum slopes can be achieved if longer batter slopes (exceeding 45m height) are excavated using bulldozers to trim parallel to controlling fracture surfaces. Unnecessary slope flattening by incorporating benches can cost millions of dollars in lost ore. Faults and other major weaknesses, which can result in wedge failure or erodible zones have been treated successfully with shotcrete, rockbolts and cable dowels. To minimize support effort and interference with mine production, early identification and treatment of unstable areas is important.

Jan 1, 1987

By Wilton Johnson

Native asphalt was produced by four companies in two States, Texas and Utah. Bituminous limestone, used primarily as a paving material for street and road repair, was produced by one firm. R. L. White Co., Dabney Quarry, Uvalde County, TX. Gilsonite, a solidified hydrocarbon found only in Utah and Colorado, was mined by three firms: American Gilsonite Co., a division of Chevron Resources Co. (a subsidiary of Standard Oil Co. of California); Ziegler Chemical and Mineral Corp.; and Hydrocarbon Mining Co. (a subsidiary of Oberon Oil Inc., a Utah corporation), from properties in Uintah County, UT. Gilsonite is used for a variety of purposes including automobile bodysealer, light-weight aggregate for cement used in oil well drilling, asphaltic building board, protective coverings, anticorrosive paints, and roofing compounds. Gilsonite production in 1985 declined 57% owing primarily to reduced oil well drilling activity. The value per ton was essentially unchanged.

Jan 1, 1987

By C. M. Suhr

n order to validate the borehole analysis valuation procedure commonly used in the South African gold mining industry, a simulated orebody was used to create borehole values which would serve as data for the procedure. After confirming the distribution, calculating the variance size of area relationship, estimating the block variance, and calculating a profit measurement for each set, comparisons were made to the known population parameters. Results show only one overall bias (in the estimation of the lognormal third parameter), which is carried throughout the analysis. The remainder of the analysis is unbiased, validating the procedure.

Jan 1, 1987

By Richard D. Miller

The helium resources base of the United States was estimated by the Bureau of Mines to be 1,070 Bcf as of January 1, 1985. These resources are divided into four categories in decreasing degree of assurance of their existence: (1) helium in storage and in proved natural gas reserves, 280 Bcf, (2) helium in probable natural gas resources, estimated at 243 Bcf, (3) helium in possible natural gas resources, estimated to be 287 Bcf, and (4) helium in speculative natural gas resources, which makes up the remaining 260 Bcf. These helium resources are further divided into depleting, non-depleting, and stored classifications. The depleting resources are those associated with natural gasfields that are, or will be, produced for the natural gas they contain. Almost all of the helium in potential (probable, possible, and speculative) natural gas resources is included in this classification. These depleting resources are estimated to contain 900 Bcf of the total helium resource base. Helium resources contained in nondepleting natural gas resources, those in shut-in, abandoned, or otherwise nonproducing natural gasfields, are estimated to total 133 Bcf. There is 37 Bcf of helium in storage in the Federal Government-owned Cliffside Gas Field near Amarillo, TX.

Jan 1, 1987

The Quioma Mine is located along the axis of the Cordillera Oriental, 130 km southeast of Cochabamba, South Central Bolivia. Silver, lead, zinc, antimony, and gold have been intermittently produced from veins in the Quioma area since Colonial times. Mineralization occurs within steeply dipping fissure veins transecting moderately folded Lower Ordovician sediments. Tectonic activity is early to mid-Tertiary and the vein system parallels the fold axis of a major northwest-southeast striking, doubly plunging anticline. Vein sets occur within a 2 km wide band over a strike distance of 13 km along the northeast limb of the anticline. Economic mineralization occupies syntectonic pre-mineral fault zones developed in more competent stratigraphis units of Lower Ordovician clastic sediments. Veins average 55 cm in width, although mineralized structures up to 3 m wide with a known strike length of several hundred meters have been mined. Mineralization consists of siderite, argentifferous galena, sphalerite, and quartz, with minor amounts of chalcopyrite, barite, and bournonite. Pyrite is rare except at the Boston vein where it occurs with stibnite that contains trace amounts of gold. A marked characteristic of veins in the district is evidence of repeated stages of movement during mineralization. Intrusive rocks are rare in the Quioma area. Narrow porphyritic dikes of Andesitic composition averaging 1 m in thickness have been observed. These dikes occasionally show a close spatial relationship to the veins and are often kaolinized and carbonitized. Vein and dike contacts are sharp and alteration does not appear to extend into the wall rock. Mineral zoning is suggested by antimony mineralization observed in peripheral areas of the anticline.

Jan 1, 1987

By Wright J. K

A description is presented of the results of reduction experiments using a laboratory reduction apparatus in which simulation of the gas and temperature profiles which occur in direct reduction shaft furnaces is achieved using microcomputer control. The apparatus allows continously changing reduction conditions to be impressed on lump or pellet samples to simulate the environment that is experienced by iron ore burdens during their transit down the shaft of a direct reduction furnace. Three pellet samples and three lump ore samples were reduced in the apparatus. Comparative reduction curves and strengths after reduction for the materials were obtained over a range of reduction temp- eratures using Midrex-type gas compositions. The resulting reduction and strength curves show considerable variation in behaviour and reflect the physical and chemical variations in the individual ore and pellet types. A comparison is made of the reduction rates and modes of reduction of the samples reduced under "conventional" test conditions using a single unchanging gas composition and the simulated shaft furnace reduction conditions. It was observed that the course of reduction is very different in the two procedures and the major influence of temperature on the strength of the reduced product is noted.

Jan 1, 1987

By Smith DM Jr

Silver deposits, in which silver forms at least fifty percent of the value of the ore, are abundant and large on the east side of the Pacific and are absent in the western Pacific. To determine if this uneven distribution is related to features of consuming plate tectonic boundaries which dominate the metallogeny of the Pacific Rim, the variation of Ag/Au in porphyry copper deposits was used to estimate the relative silver content of magma generated in subduction zones. Porphyry copper provinces with high Ag/Au occur in regions of the eastern Pacific where silver deposits are abundant, suggesting that the distribution of silver deposits is controlled by the relative abun- dance of silver in subducted ocean crust. Ocean crust being subducted in the eastern Pacific is mostly less than 50 million years old in contrast to most ocean crust in the western Pacific which is much older. Enrich- ment of silver in young ocean crust at spread- ing centers may reflect metallogenetic evolution over geologic time. Silver may be transported to the surface in volcanic rocks, and deposits are common where felsic varieties are abundant. The high ,solubility of silver in natural waters provides a natural storage mechanism for silver weath- ered from these rocks and ultimately circulated in near-surface hydrothermal systems where many silver deposits form. The regional distribution of silver deposits is not influenced by discoverability, vertical metal zoning, or regional tectonic style. The effect of igneous differentiation is unclear.

Jan 1, 1987

By Ito H, Noguchi F, Ueda Y

DTA curves of synthesis lead sulfide and commercial. lead concentrates during oxidation were measured to clarify the mechanism of ox- idation of lead sulfide. The oxidation reac tions could be divided to elementary reactions with production of basic lead sulfates such as 2PbO PbSO4. An existance of iron sulfide played an important role of the oxidation of lead concentrates. The oxidation rates of lead sulfide were measured in the wide range of oxygen potenti- als using IR type SO2 gas-meter. The oxidation rates under low Po 2 which corresponds to the direct oxidation smelting were much lower than those obtained under high Pot. The combustion temperatures of lead sulfide were also measured by hot thermocouple method. Those values were extremly low compar- ing the oxidation temperatures obtained by DTA.

Jan 1, 1987