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By F. W. DeVries

The subject article is an excellent comparison between two potential oxidants, molecular oxygen and hydrogen peroxide, as used in the Palangana field at the time of the trials. The tests showed no advantage to using hydrogen peroxide; however, it would be unwise to generalize that the experience in these trials was universally true. During the time of the work cited, extremely high levels of an unusual impurity were recycling in the lixiviant, which substance was a catastrophically destructive catalyst for peroxide. Since this material was not removed before recycle, it was not surprising that much of the peroxide fed was decomposing in the feed piping and never made contact with the uranium mineralization. Under these conditions, indeed, peroxide showed no improvement over oxygen. This is, however, perhaps the most adverse environment encountered to date in US in-situ uranium leaching. In other operations, peroxide has proved advantageous where two factors have been exploited: 1.Despite the tendency for Hz02 to decompose to water and oxygen in the in-situ leach environment, its higher redox potential before decomposition has provided higher leach rates. In some formulations, overloading beyond the O2 saturation equivalent with peroxide has allowed higher oxidant levels, and higher leaching rates, when overloading with molecular O2, led to vapor-locking.

Jan 1, 1983

By Ronald F. Balazik

This Bureau of Mines study identifies and examines the costs of Federal, State, and local environmental protection controls on domestic phosphate rock mining, The costs include the expenditures needed to comply with government regulations and the effects that these expenditures and regulations have on supply. The study analyzes costs of environmental impact assessments, air and water quality standards, reclamation laws, potential solid waste controls, and local government restrictions. In addition, an industry survey and the Bureau's Minerals Availability System (MAS) are used to evaluate land management policies that restrict access to phosphate resources, Conclusions drawn from these analyses confirm that (1) domestic phosphate mining has incurred substantial control costs and may be subject to significant new regulatory costs in the next several years, (2) certain environmental controls can discourage mining investment, (3) environmental policies governing land-use controls affect the disposition of sizable phosphate resources, and are key determinants in the development of those resources on the Federal do- main, and (4) environmental costs could diminish the competitiveness of domestic producers.

Jan 1, 1983

By Gordon B. French, Donald E. Garrett

INTRODUCTION Crude oil reserves in the United States are still very large, even though for many years they have not been sufficient to supply our entire domestic requirements. They are continuously being depleted as oil is pumped from the ground, but new discoveries and improved secondary and tertiary recovery methods are helping to reduce the rate of depletion. It is thus a slowly diminishing resource, but even as it is being consumed, immense reserves of oil are left behind as the so called "un-recoverable" portion of petroleum formations. Most oil fields can only obtain a 15 to 40% recovery of the original reservoir, and it is widely quoted that there are still about 300 billion barrels of this un-recoverable oil still in place (Mauch, 1980, etc.). With the present comparatively high oil prices, and the possibility of even higher future prices and short supply, this oil becomes an interesting potential reserve. Mining the petroleum formation would be one means of recovering at least a portion of this oil. The concept of oil mining is neither new nor limited to conventional oil fields, since the procedure could be equally employed with the otherwise difficult to produce heavy oil deposits, and the solid or semi-solid tar sands and diatomaceous hydrocarbon formations. Estimates place the U.S. tar sand resource at about 30 billion barrels, and heavy oil at 5-10 billion barrels (Unitar, 1982). Figure 1 graphically summarizes the heavy oil reserves based upon formation depth and characteristics, while Figure 2 shows their location. It is apparent that the preponderance of reserves are in California and Texas, but that they also occur in many other states. The major companies engaged in oil recovery from the heavy

Jan 1, 1983

By J. M. Riley

The Bureau of Mines investigated a promising new technology for recovering A1203 from alunite to support the Bureau's alumina miniplant project. Results are presented for a study of the technical feasibility of treating alunite crushing and grinding reject fines for recovery of A1203. Alunite pellets having sufficient strength and resistance to degradation were produced by combining fines and coarse alunite with a KOH binder. The best pellets were prepared, in a laboratory pelletizer, by adding 1 pct KOH as a 5-pct solution to a mixture of 40 pct alunite dust (98 pct minus 65 mesh) and 60 pct coarse alunite (minus 20 plus 65 mesh). Calcines suitable for K2SO4 and A1203 recovery were produced by reducing dehydrated alunite pellets with sulfur in a laboratory shaft furnace for 4 h at 600° C, followed by air oxidation of the reduced calcine for 1 h at 600° C. This report presents design calculations, schematic diagrams, and discussions of the essential features of a proposed process research unit (PRU)--a continuous, 6-lb/h alunite shaft furnace--for studying the process.

Jan 1, 1983

By R. K. Conrad

The Bureau of Mines conducted corrosion research to determine suitable construction materials for geothermal resource recovery plants. Weight loss, pitting and crevice corrosion, U-bend stress corrosion, and electrochemical polarization measurements were made on selected metals in brine and steam process environments produced from high-enthalpy hypersaline brine from geothermal well Magmamax No. 1 at the Salton Sea Known Geothermal Resources Area, Imperial Valley, Calif. Cadmium (and by extension cadmium coatings) and a 6061-T6 aluminum alloy were unsatisfactory because of high general corrosion rates and, in the case of aluminum, severe pitting Molybdenum and niobium (columbium) were resistant to general corrosion, pitting, and crevice corrosion, Copper alloys corroded at rates that may preclude their use in wellhead brine, The presence of iron accelerated the corrosion of the copper alloys Titanium alloys were resistant to general corrosion and stress corrosion cracking in all of the environments. They exhibited crevice corrosion in some of the brine and steam environments and Ti6A14V pitted in the brine environments. They exhibited passive behavior over a broad range of potentials. Exposure tests were conducted on a high-temperature polyphenylene sulfide thermoplastic (Ryton) in the same environments. A 40-pct-graphite fiber-reinforced Ryton composite deteriorated readily in wellhead brine and failed in all of the brine and steam process environments; Ryton coatings on 316L stainless steel were adherent and performed well.

Jan 1, 1983

By E. L. Mooney, D. F. Gibson, T. E. Lehman

This paper outlines the features of a computerized planning system, which was developed to aid surface mining and reclamation evaluation. Essential features of the system include three main modules: production, reclamation, and impact analysis. In addition, the system incorporates a large number of computerized data analyses and display features, which are described and illustrated in this paper.

Jan 1, 1983

By S. V. Krishnan

Stability of fine quartz suspensions in process water is of concern in several mineral processing applications. In alkaline solutions, the presence of magnesium ions, arising from such sources as water hardness and magnesium-bearing minerals, leads to the precipitation of Mg(OH)2 which coats the surfaces of quartz. The conditions under which heterocoagulation or surface precipitation of Mg(OH)2 on quartz occur and the manner in which they influence the settling behavior of ground quartz was studied by means of settling tests, coating density determinations, zeta potential measurements and electron microscope observations. Coating density was greater when Mg(OH)2 nucleated on the surface of quartz than when the precipitates heterocoagulated on the quartz surface. The settling curves of quartz suspensions in the presence of different concentrations of MgCl2 exhibited a maximum of maxima which occurred at 10-3M MgC12 and pH 11. Interactions between quartz and Mg(OH)2, and flocculation-dispersion characteristics of quartz suspensions in this system are discussed.

Jan 1, 1983

By Jon C. Volkwein

The Bureau of Mines conducted a series of tests to evaluate the effectiveness of mixing a compressed-air-generated foam with dried whole-grain silica sand to suppress dust in minerals processing plants. Dust at downstream transfer points was monitored with personal gravimetric samplers and with Real-Time Aerosol Monitors (RAM's) that were connected to strip' chart recorders. Results showed dust reductions of 80 to 90 pct on three separate occasions at two different plants. The mechanism by which foam suppresses dust is discussed, as are the constraints on the use of foam, which may include incompatibility of the foam with the mineral product, difficulty in controlling the foam generator, and cost.

Jan 1, 1983

By Stanley M. Miller

For rock or soil materials assumed to be generally isotropic and homogeneous, seepage theory and analytic geometry can be used to develop a mathematical technique for estimating the steady state, pie-zometric drawdown to a slope face. The resulting parabolic drawdown curve is a function of slope angle and the height of the original water table above the slope toe. When the slope is cut at a rate faster than that which allows a steady state to be attained, a non- steady state analysis approximates the transient drawdown. Monte Carlo simulation provides realizations of possible drawdown curves that can be included in slope stability risk analyses.

Jan 1, 1983

By J. G. Goodey, G. J. van der Linde

This paper describes pilot-plant tests on the recovery of apatite from a hitherto untapped material. This materialhydro- separator overflow-is very fine (80 per cent smaller than 45 µm and 32 per cent smaller than 10 µm). . The pilot-plant tests proved that the recovery of apatite from this material is economically and technically viable. This was confirmed by plant trials, which, in the early stages, produced concentrate assaying 36,6 per cent P2O5 at a recovery of 65,5 per cent.

Jan 1, 1983

In the estimation of reserves the known values of the variables of interest from surrounding drill holes are used to compute or estimate the unknown value of the orebody over a given region or at a given point of interest. The classical means of doing this are: 1. The Polygonal Method û where the region is divided into polygons centred on bore holes, each variable is then assumed to have constant value over each polygon. 2. Inverse distance methods, where the variable is assumed to vary linearly with the distance between the known values of the drill holes. 3. Inverse distance squared method û a quadratic variation is assumed for the variables between the bore holes.

Jan 1, 1983

By George S. Austin

Adobe, dried mud bricks, have been used since before historic time in the construction of dwellings. Building materials are normally evaluated for thermal performance based on measurements known as R- and U-values. The R-value is an indicator of the ability of a wall to insulate effectively and the higher the R-value, the better it is as an insulating material. The U-value, or value of conductance, is the reciprocal of the R-value and reflects the rate at which heat is conducted through a material. But the "heat capacity of the wall" must also be considered. This measures the length of time that passes before a steady state of heat flow is achieved. The effective U-value measures both the resistance to the transfer of heat and the capacity to hold heat. These latter value make adobe a far more interesting as a modern building material that was formerly recognized.

Jan 1, 1983

By Isiah M. Warner, Philip Oldham, John Kennedy, Bennett D. Lass

A new method for determination of residual flotation oils on beneficiated kaolin clays has been developed The method, which yields qualitative information, is based on fluorescence measurements employing a spatially resolved, polychromatic illumination source for excitation, and a two-dimensional detection scheme using a silicon-intensified, video imaging device The method was used to identify residual oils on a beneficiated, Washington County, Georgia, crude clay The results were compared to a similar qualitative analysis performed via capillary column gas chromatography using a flame ionization detector The video fluorometry was the preferred method of analysis

Jan 1, 1983

By J. S. Falcone

Soluble sodium silicate materials have well known applications in flotation for desliming, selective depression and corrosion control. Recent advances in the understanding of the complex polymeric nature of silicate solutions using NMR spectroscopy, combined with our studies of the effects of polymeric silicate anions on metal ion activities in solution, oxide mineral surface charges and surfactant adsorption on clays are related to beneficiation processes. The results of these studies indicate the sodium silicates can be used to cause a solution chemistry and particle surface charge characteristics favorable to enhanced effectiveness in typical ore beneficiation systems.

Jan 1, 1983

By George L. Atwood

The western phosphate field, one of the United States' great mineral resources, lies within the western states of Idaho, Utah, Wyoming and Montana. This Permian sedimentary deposit has been known since the turn of the century and since the 1920's has been mined for its phosphate content. Isolation from markets and relatively high mining costs have restricted development as compared to eastern United States deposits, but nevertheless a significant western phosphate industry has developed. Geographically the deposit covers an enormous area of about 337 000 km2 (130 000 sq miles). It covers Idaho from Pocatello east- ward, western Wyoming to the eastern flank of the Wind River mountains, and extends well into southwestern Montana and into a large area of northeastern Utah north of the Uinta Basin and east of the Salt Lake valley.

Jan 1, 1983

By Clement K. Chase, Manuel Lastra, George M. Potter

Heap leaching for gold-silver recovery in the western United States has been widely applied. Advantages, disadvantages, and requirements of the method are discussed, as well as heap building, recovery systems, agglomeration applications, and safeguards against freezing. A list and review of current heap leach operations world-wide are presented, together with obvious opportunities for application of this innovative technique in new areas.

Jan 1, 1983

By Juhani Pulkkinen, Pekka Lappalainen

Preplaced cable bolts - fully grouted old hoisting cables or stress relieved steel strands - have been used succesfully to pre- reinforce ore contact zones and pillars in sublevel stoping at Outo- kumpu Oy mines for ten years. The purpose is to make open stoping methods possible even in "poor'' conditions and to decrease waste rock dilution. Since 1971 more than 120 km cable bolting has been done, and plans for this year in five mines amount to 33 km. In order to understand the function of cable bolt, pull-out tests have been done both in the laboratory and in situ. Bond strength between cable and cement is highly dependent on cable structure and cable surface dirtiness. Steel cables with steel core and rough surface structure have highest bond strength ( 6 MP~). A cable bolt is a friction bolt. After losing its peak bond strength - after starting to move - a cable bolt still has a high loading capacity due to the friction caused by the uneven surface of the cable. Cable bolting is done before actual stoping from existing drifts, sublevel drifts, e.g. or from special bolting drifts. In general stress relieved steel strands are used; 2 x 15.2 mm dia per hole. FEM or BEM calculation is utilized in cable bolting design. Bolts 2 are in fan shape, 10 m ... 50 m long and are spaced 1/20 m ... 1/50 m2 at stope walls. Pretensioning of cable is not needed, when bolting is done before rock deformations. Bolting costs vary between 0.3 USD ... 1.0 USD/ore ton. In the beginning only manual cable installing technique bras used. Now bolting can be done as fully mechanized with the developed cable bolting machine; i.e. drilling of the hole, installing and cutting of cables and grouting of hole.

Jan 1, 1983

By Alexander May

In its role of providing technology to promote the efficient use of minerals and mineral process waste, the U.S. Bureau of Mines has conducted research at: its Tuscaloosa Research Center to identify and develop high volume uses for phosphogypsum. Mixtures containing a maximum of 50 percent phosphogypsum, 6 to 10 percent lime, and the remainder fly ash had compressive strengths as high as 4,800 psi. The effects of the mounts of phosphogypsum, lime, and fly ash were investigated. Also, the effects of fly ash to lime ratios were studied.

Jan 1, 1983

By W. J. Turbeville

The subject of this discussion is timely. The U.S. phosphate industry is suffering the throes of depression. It's plight is a matter of widespread concern. The future role of the U.S. industry in world markets is of particular interest. If we should prognosticate phosphate supply-demand on the basis of recent history, we would face a puzzling choice of scenario. In 1980, perhaps the best year ever for U.S. phosphate, 54.6 million metric tons of phosphate rock entered the market place. Of this, more than half was exported -- divided almost equally - as rock or phosphate fertilizer. During the last half of 1981 the situation had begun to change.

Jan 1, 1983

By R. R. Klimpel

In this first report, we present a preliminary model based on the simple binary sys¬tem of component B occluded in a matrix of compo¬nent A, for the case where fracture planes can pass with equal ease through A or B. By assuming that the volume fraction of B in AB in the overall matrix is small, which is realistic for many prac¬tical systems, the problem is reduced to a one-¬dimensional treatment which is conceptually easy to understand. The model was programmed for Monte Carlo simulation, and an analytical solution also developed based on the assumption of zero or one mineral fragment per particle. Preliminary ex¬perimental confirmation using a synthetic "mineral¬-host matrix" of known amount and size of B in AB is presented.

Jan 1, 1983