Search Documents

By B. Ball, C. H. Cox, S. N. Yap

Electrokinetic measurements on cassiterite were made in the presence of sodium di-hydrogen phosphate, mono-hydrogen arsenate, bisulfite, and sulfate. Flotation studies were also conducted using sodium dodecyl sulfonate in the presence of these salts. It was found that the anions specifically adsorb on cassiterite in the order H2AsO-4 H2PO4 HSO3 SO4 and consequently cause flotation depression. The adsorption mechanisms of the various inorganic anions are discussed in detail.

Jan 1, 1980

The ownership, policies, organisation, structure, market, financial considerations and communications of a large resource project vary significantly through its discovery, feasibility, development and production phases. The extent of these changes, from discovery in 1957 through to 1979, is examined for the Mt. Newman iron ore project in the Pilbara region of Western Australia and some of the factors that influenced it are detailed. This shows that only some of the influences are under the control of the mine owner/operator, despite their significant impact on the returns for the massive capital invested. The effect of the general business climate on the various phases is also examined.

Jan 1, 1980

By Dolf W. Fieldman

Most recently the geologic setting of the mineral deposits in the Silver Cliff district is described by William M. Sharp in ?Geologic Map of the Silver Cliff and Rosita Volcanic Centers, Custer County, Colorado?, (U. S. G. S. Map I- 1081). The discussion will relate only to the southern half of the Silver Cliff volcanic center and differences in geologic interpretation, which are largely structural, will be pointed out as they arise. Only the manganese/silver zone of the Kate Area will be discussed in detail.

Jan 1, 1980

Duties on Lead Imports from Mexico. - On September 15, the President signed Proclamation 4792 suspending concessions formerly granted as of January 1 on red lead imported from Mexico. The Proclamation also increased the duty payable on litharge imported from Mexico from 3% ad valorem to 3.5% ad valorem, effective September 15. Appeal of Lead Standards. - The U.S. Court of Appeals for Washington, D.C., rejected petitions by the Lead Industries Assoc. and St. Joe Minerals Corp. for a review of standards promulgated by EPA and OSHA. The Lead Industries Assoc. reportedly will appeal to the U.S. Supreme Court on the basis of the "benzene" and "cotton dust" decisions. Scheduled implementation of standards will continue during the appeal.

Jan 1, 1980

By H. M. Friede

Discussion of the above paper by A. SIFF The steely nature of the Iron Age objects mentioned in Dr Friede's paper point to two hypotheses. (1) The African iron workers were conversant with the art of direct steel manufacture. (2) They were less knowledgeable of the art of the production of carbonless iron. In this context I cannot but quote T. A. Wertime.

Jan 1, 1980

By Donald H. Matthews

The Society of Explosives Engineers is an international organization of over four hundred members involved in the explosives industry, with most members being active in the United States. The regulations imposed by regulatory agencies on the explosives industry have drastic effects far beyond the industry. Since explosives are used in mining, manufacturing, construction, entertainment, and art, all phases of man's activities, including fundamental needs for survival, are affected by how efficient the industry uses explosives. We, as members of SEE, must be sincerely concerned with both the quantity and quality of government regulation, and this paper spells out some of the problems caused by regulations and offers a solution.

Jan 1, 1980

By F. X. McCawley

The Bureau of Mines, in pursuing its goal of extending the life span of strategic materials, conducted field corrosion studies at the East Mesa Known Geothermal Resources Area (KGRA) in the Imperial Valley, Calif., to determine the optimum materials of construction for use in geothermal mineral energy resource recovery plants. These studies included characterization of geothermal environments and in situ corrosion testing. The corrosion resistance of 10 alloys exposed to 5 brine and steam process environments was evaluated using the low-salinity, high-temperature brine from geothermal well Mesa 6-1. Of these alloys, Hastelloy C-276, Hastelloy S, Incone1 625, titanium-2nickel, and 316 L stainless steel had excellent resistance to corrosion in all of the process environments; E-Brite 26-1 and 430 stainless steel had fair resistance. Although general corrosion rates for 4130 steel and 1020 carbon steel were substantially higher than those of the other iron-base alloys, these two alloys could prove useful in low-salinity process environments because of their low cost. Aluminum alloy 5005 was the least corrosion resistant alloy and pitted severely. Scales formed on all of the alloys in every process environment. Calcite, aragonite, and an amorphous silicate were the major components of the scales.

Jan 1, 1980

By E. K. C. Williams, Nathaniel Arbiter

INTRODUCTION The surface processes involved in preparing ores for flotation and for operations depending on their flocculation/dispersion characteristics * vary widely in agitation dependence. Most of the reagents used for these purposes are added to grinding circuits, pump sumps, launders, or directly to flotation cells with the turbulent flow conditions usually adequate both for mixing reagents and for surface reactions without special conditioners. However, some reagent systems do require specific control of agitation intensities and reaction times, the more important of these being the following: 1. Activation of ZnS with CuSO4. With the usual conditions pH about 10, with collector added with the CuSO4, Cu 2+ is almost completely precipitated as basic compounds and as collector salt. As a result the levels of reagent in solution are extremely low which probably accounts for the need for separate conditioning. The agitation intensities are at about the 0.01 HP/ton level.** 2. Flocculation with natural or synthetic polymers. In this case the agitation problem is two-fold; first, to insure adequate initial mixing of the viscous stock solution of the

Jan 1, 1980

By R. B. Schluter

The Bureau of Mines investigated the flotation responses of two copper-nickel ore samples from the Duluth Complex with the objective of recovering bulk sulfide concentrates. One of the ores studied was taken from a test pit; the other was taken from a test shaft. The samples were quite similar except that the pit sample analyzed 0.35 pct Cu and 0.11 pct Ni and the shaft sample analyzed 0.69 pct Cu and 0.14 pct Ni. Flotation responses were studied in both laboratory and pilot plant tests. Pilot plant flotation responses were similar for both samples resulting in grades of 12.2 pct Cu and 2.5 pct Ni for the pit sample and 12.2 pct Cu and 2.1 pct Ni for the shaft sample. Weight recoveries were 2.5 pct for the pit sample and 5.2 pct for the shaft sample. Copper and nickel recoveries for the pit sample were 87 and 62 pct, respectively, and 92 and 73 pct for the shaft sample. Both concentrates contained small but significant values of cobalt and precious metals. Cobalt recoveries were low--less than 40 pct for both concentrates. Precious metals contents of the concentrates were 1.59 oz/ton for the pit sample and 0.99 oz/ton for the shaft sample. Silver was the predominant precious metal by weight, but platinum and palladium represented the highest values.

Jan 1, 1980

By Henryk Bystron

The underground fire areas are formed as a result of failure of an active fire extinguishing in mines. Such areas bring about a fire hazard for the work safety and for the mining operations. For liquidation of fire areas it is necessary to create conditions under which a possibly small amount of air is flowing to the fire. To achieve this end, isolation methods are used which consist in erection of full stoppings of various types, sealing practically the fire areas. These methods usually fail in oases when the coal seam is thick and the fire area is situated between the intake shaft and the outtake shaft in which a high-pressure fan is in operation. In such oases ventilation methods based on the balance of aerodynamic potentials in fire areas are to be used. For a very long time the isolation and ventilation methods have been developed in the world mining, No sooner than since 1980 the aerodynamic potential has been used in ventilation methods [1,2,6]. So far, the aerodynamic potential was called in different ways and was determined by different formulae which gave its numerical values more or less approximative. Nevertheless, even in situations featuring by a lack of sufficient theoretical bases of the aerodynamic potential the ventilation methods brought considerable profits in the field of safety in mines and of economics in mine ventilation [1-6,9,10]. The increase in the depth of underground mines and their equipment with expensive machines (apparatus) brought about that the Central Mining Institute at Katowice undertook research works which are crowned by the theory of the aerodynamic potential in mine ventilation networks [7]. The use of this theory in the mentioned ventilation methods will increase their effectiveness. Since the theory will be published in the III rd quarter of this year, we cite in the present paper the formulae and relations associated with this theory which are indispensable to present the balance of aerodynamic potentials in the fire areas in their control by ventilation methods.

Jan 1, 1980

By V. R. Spironello

The Bureau of Mines is involved in research directed toward the conserva¬tion of important raw materials and the utilization of solid waste. Two of the objectives are to conserve high-quality coking coals used for foundry coke and to utilize waste materials of marginal quality but of high calorific value. These objectives are consistent with Bureau goals. Pilot plant cupola trials were made to evaluate the adequacy of various alternative fuels, and to determine to what extent they could replace the foundry coke in cupola charges. Information was obtained on furnace performance, metal and slag chemistry, environmental questions, and the properties of castings. It was shown that anthracite or bituminous coals can partially replace charge coke up to the 40 pet level. Briquetted materials prepared from fuel fines, and waste prod¬ucts or byproducts of high calorific value, all tend to break down on heating in a cupola so that their use must be restricted to below 20 pet replacement. In cases where pitch-bonded coal fines or petroleum coke were used, carbon pickup by the iron was inadequate for gray iron specifications. Although emphasis during this work was placed on basic slag practice, some acid practice results are included.

Jan 1, 1980

By C. P. Patel

"The Sturgeon Lake Joint Venture volcanic massive sulpide deposit was discovered in 1970. Milling was started by Falconbridge Copper Ltd. at Sturgeon Lake in September 1974. The Sturgeon Lake pit and mill are located 88 kilometers by road northeast of Ignace, Ontario. IgnE1ce is a town of some 2800 people located on the Trans-Canada Highway, 241 kilometers west-northwest of Thunder Bay. The mill is treating an average of 1100 TPD producing separate concentrates of copper, lead and zinc. Initially, difficulties were experienced in achieving accept-able concentrate grades and recoveries but these were eventually overcome. This presentation describes current metallurgical strategy as practiced at the Sturgeon Lake mill.But first, a few words about the type of ore being treated. In geological terms the ore is classified into two main categories. They are the massive sulphides with underlying zones of stringer sulphides as illustrated in Fig. 1. The plan view is shown in Fig. 2. The areas of East-limb and North-limb are as shown. These last two ores have suffered enough alteration to cause problems during treatment. The massive sulphides consist of chalcopyrite, sphalerite, galena, tetrahedrite and small amounts of pyrrhotite among other gangue materials. The stringer ore is comprised of predominantly chalcopyrite intrusions into rhyolite and has lesser amounts of sphalerite and tetrahedrite. At present we are treating a predetermined blend of massive and stringer ores from zones that have been metallurgically tested to ensure compatibility with current treatment procedure in the plant. Ore responding to this treatment is classified as normal ore while the ore proving incompatible is classified as north-limb ore or east-limb ore."

Jan 1, 1980

By A. McIntyre, L. R. Plitt

Both the Bond and the Hardgrove grindability tests are widely used in the mineral industry to measure the ease of the comminution displayed by a material. The Hardgrove test is mainly used for coals, whereas the Bond grindabifity test is mainly applied to hardrock minerals. The Bond grindability has the advantage that it can be empirically related to the energy required for comminution (work index), whereas the Hardgrove grindabifity test has the advantage of being easier to perform. In an effort to establish a valid correlation between work index and Hardgrove grindability, a series of parallel grindability tests were carried out on a wide variety of rocks and minerals. The standard Hardgrove test was modified to allow for materials with a higher density than coal. A new, satisfactory relationship was established which permits rapid estimation of work index from Hardgrove test data.

Jan 1, 1980

By B. W. Jong

As part of the Bureau of Mines program to develop substitute or improved performance refractory materials for metallurgical applications, the Tuscaloosa Research Center has evaluated the effect of additives on sintering and strength properties of aialon (silicon aluminum oxynitride) compositions fabricated by a conventional powder metallurgy technique. Additions of Y203, Gd203, CeO2, MgO, ZrO2, ZrSiO4, and MgA12O4 to a sialon composition containing 70 pct ß-Si3N4 + 30 pct a-A1203 increased sintered densities by as much as 50 pct over densities of undoped material. The studies also indicated that sintered densities reached a maximum between 20 and 30 mole-pct a-A1203 when a series of sialon compositions of a-Si3N4, having 6.7 to 57.9 pet a-Al203, were doped with Y203, Gd2O3, and MgO. In studies to establish the effect of the crystalline phase of the silicon nitride and alumina used, tests were made using a- and ß-Si3N4 and a- and ?-A12 03 as starting materials. The tests indicated that when using an addition of 5 wt-pct Y203, best results were obtained with a sialon composed of 74.4 mole-pct a-Si304 and 25.6 mole-pct ?-A1203. In other tests made with this sialon composition MOR values of 28,120 and 29,500 psi at 25° C, and 23,520 and 16,850 psi at 1,400° C, were obtained when doping with 5 wt-pct ZrSiO4 and ZrO2, respectively.

Jan 1, 1980

In North-West Nelson the Riwaka Complex, a linear basic intrusive complex, is exposed for approximately 45 kilometres. Some 500 kilometres south, across the Alpine Fault, a linear zone of similar but less well known basic intrusives that may be correlatives of the Riwaka Complex is exposed discontinuously for about 80 kilometres. The Complex was emplaced at several centers along a major tensional fracture zone that developed in upper Carboniferous to Lower Permian time. This fracture zone probably formed in response to the development of a west dipping subduction zone that gave rise to the Permian volcanic arcs in east Nelson and western Southland. The Riwaka Complex contains three rock suites. The Fractionation Suite, characterized by cyclic mineral layering and small scale cumulus banding is the largest and is divided into the Ultramafic, Hornblende and Plagioclase Series, each of which is subdivided into several units. The Cumulus Gabbros represent a restricted but important suite of unusual composition, while the third suite is the late phase Diorite Suite.

Jan 1, 1980

By William Y. Mo

This Information Circular provides a detailed background documentation of how the Bureau of Mines projects U.S. mineral demand to the year 2000. These statistical projections serve as a quantitative basis for contingency forecasting of the low, high, and probable U.S. demand for nonfuel minerals by end-use categories and are published in the Bureau of Mines Mineral Commodity Profiles and Mineral Farts and Problems series. Aluminum is used as an example in this study.

Jan 1, 1980

By Parker A. J, Muir D. M

Solutions of acetonitrile in water dissolve water soluble copper(I) chloride. Removal of volatile acetonitrile from the resulting solutions, by distillation with low grade steam, precipitates pure copper(I) chloride. This is used to purify a crude copper chloride sublimate from the chlorination of nickel matte but is applicable to other sources of copper(I) chloride. The pure product can be converted to pure copper(I) oxide, copper(II) oxychloride or pure copper metal directly.

Jan 1, 1980

By R. L. Wiegel

The National Science Foundation, Erie Mining Co., and University of Minnesota Mineral Resources Research Center jointly sponsored a project to demonstrate the use of a small computer in the control of cyclone overflow size on one line in the Erie Mining Co. concentrator. The Erie circuit, similar to most taconite circuits, uses magnetic separators to reject tailings following each stage of grinding, resulting in additional variations in the demands made on the grinding circuit because of weight rejection fluctuation. Mathematical models were developed for rod milling, ball milling, hydrocycloning, fine screening, and five stages of magnetic separation. These models were used in concert to simulate the operation of Erie's circuit from rod milling through finisher magnetic separation.

Jan 1, 1980

By Shoobridge PH, Firkin GR

The Imperial Smelting Process blast furnace (ISF) of the Sulphide Corporation Pty Limited zinc/lead smelter at Cockle Creek, New South wales, has in recent years greatly increased its consumption of low grade feed materials, and as a consequence has experienced periods of unstable furnace operation. Routine examination of production sinter, including softening characteristics and micro- examination, showed that the problems had been caused by an increasing silica content in sinter. The silica entered a low melting point glass phase containing calcium and lead oxides. The relative volume of this phase increased until it formed a continuous matrix in the sinter structure and this made the sinter more likely to soften at lower temperatures. Premature softening caused loss of operating stability in both the shaft and hearth of the ISr. The required sinter structure for ISF smelting was found to consist of a network of intermeshing, refractory crystals which provided skeletal strength for sinter lumps even after the glass phases had begun to soften and melt. With an understanding of the importance of microstructure and softening temperature of zinc/lead sinter and the progressive identification of those factors in sinter production which affect the microstructure, a significant improvement in stability of operations has been possible.

Jan 1, 1980

By R E. Langston, S M. Gazioglu

A preconstruction inventory program was conducted to determine the existing conditions of residential, non-residential and all other structures within 2,000 feet of the blasting limits for a highway excavation site in Asheville, North Carolina. Prior to major production blasting, eleven test blasts were detonated to establish site specific propagation parameters in order to develop contours of maximum allowable explosive charge weights per delay. The method of scaling distance by the square root of charge weight per delay was utilized in developing the contours of allowable charge weights. The charge weight contours were revised during blasting operations as additional vibration data became available. The effects of blast induced vibrations on a nearby water storage reservoir, a nearby vehicular tunnel and other adjacent residential and non-residential structures were observed and monitored over a period of two years of blasting operations.

Jan 1, 1980