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By G. Thorsen

An alternative way to the normal practice of precipitation of jarosite, goethite, or hematite for removal of iron from zinc sulphate process liquors/ is to employ the techniques of solvent extraction. The process presented avoids the addition of any external alkali for the extraction of iron by integrating the leaching and solvent extraction steps in a hydrometallurgical zinc plant. By starting the leaching of zinc from the solid zinc calcine material with an organic solution of an acid liquid cation exchanger, the organic phase is loaded with the organic zinc salt from the direct reaction with zinc oxide. The residue from the organic leaching is transferred to a hot acid leach circuit where the remaining zinc oxide and the zinc ferrites will dissolve form¬ing an aqueous sulphate solution of zinc and iron. In the subsequent solvent extraction of iron from this aqueous leach solution, iron is exchanged with zinc from the organic phase. The commercial carboxylic acid Versatic 10 (Shell) is highly efficient for this integrated process of leaching and solvent extraction. The resulting iron-loaded organic phase is heated to 150-200 C in the presence of water whereby the iron will be directly precipitated from the organic phase as iron oxide of high purity and the regenerated organic acid is recycled to the organic leaching step for reloading with zinc.

Jan 1, 1980

By A. B. Barlow, D. H. Pitcher

"The Geophysics/Geochemistry Section of the Ontario Geological Survey initiated an aerial geophysical survey in the James Bay Lowlands, Cretaceous Basin area, District of Cochrane, Ontario. The survey was contracted to Scintrex Limited and was carried out in 1978. Approximately 8000 line kilometres of airborne electromagnetic and magnetic data were recorded. The Tridem airborne electromagnetic system was employed, mounted in a twin-engined PB Y Canso aircraft. This specific Tridem system uses a vertical coaxial coil configuration and measures in-phase and quadrature components of the secondary field at 500, 2000 and 8000 Hz.The primary purpose of this survey was to map subsurface conductivities and, in particular, to search for lignite deposits. Physical property measurements show that electrical methods should detect differen ces in conductivity between the moderately conducting clay-lignite horizons and the less conducting clay, soil, muskeg and gravel horizons. A preliminary Tridem test survey, as well as surface DC resistivity soundings, confirmed this approach. The interpretation of the present survey data indicates that Tridem is a suitable electrical method to aid lignite exploration in the James Bay Lowlands."

Jan 1, 1980

By V. E. Suter

Anyone with geothermal experience can readily attest that geothermal operations are a natural extension of oil and gas operations. A geothermal company and an oil company need the same type of people to do the same kind of work. In the geothermal industry, geologists and geophysicists define prospects through surface geology, analysis of surface seeps, magnetics, gravity, and resistivity surveys - techniques similar to those used in the petroleum industry. In addition, shallow (250-ft) temperature gradient holes often are used in geothermal operations. Landmen take geothermal leases that are patterned after oil and gas leases. Exploratory drilling is done with the same drilling contractors and same drilling rigs, with minor modification. Drilling foremen and drilling engineers share the same objective of making the most hole, in the shortest time, at the least cost, with a proper completion. Petroleum engineers test the wells, design the completions, determine the reserves, make economic calculations, work with the tax assessor, and manage the reservoirs. Production engineers build roads, locations and pipelines, install gas/liquid separators and meters, and operate production and injection facilities. A contract to sell steam to a public utility is required. Various governmental regulations, permits, environmental concerns, and public affairs pose similar problems in both industries. Also required of both are top management people who are acquainted with geologic risk, prepared to accept million dollar dry holes, willing to bid competitively at lease sales, and able to invest large sums based on a technology not yet fully proven. Successful geothermal development requires in-depth financial ability similar to that required for petroleum development. A high capital investment is required early for leases, geological and geophysical work, and exploratory and confirmation drilling. After

Jan 1, 1980

By Colin MacDonald

The choices of an uranium mill flowsheet are pri- marily determined by economic feasibility with plant location and regulatory bodies playing a lesser but still important role in this determination. The host ore bodies will determine the leach pro- cess to be used for basic uranium extraction. Im- mediately following this decision, the method of leaching has to be determined. These can be: - Atmospheric leaching - Pressure leaching - In-situ leaching - Heap leaching The three previously stated criteria lay important parts in this decision. In the case of atmospheric or pressure leach and once the soluabilized uranium has been liberated from the host gang material, liquid solids separation becomes the major criteria. Three process flowsheets are available; they being: -Countercurrent decantation - Countercurrent or co-current filtration - Resin in pulp Following liquid solids separation, concentration and precipitation become the next variable choice. They being: -Solvent extraction - Fixed bed ion exchange - Fluid bed ion exchange Lastly, washing and drying of the precipitated product to remove impurities can be carried out by either filtration or centrifugation. With the exclusion of milling circuits, grinding circuits, flotation circuits, and calcining processes, we have 240 variations of the flowsheet between leaching and a dry washed precipitate. Of this total, filtration in one form or another and in single or multiple applied forms has application in 144 streams. This paper intends to discuss four (4) facets of the total flowsheet in which filtration is applied, following grinding and prior to calcining. They are: - Leached pulp liquid solid separation - Tailings dewatering - Pregnant solution clarification - Yellow cake washing and dewatering

Jan 1, 1980

By Rodolfo V. de la Cruz

Abstract. The Hoskold mineral valuation method was critically examined. The original derivation was presented and found to contain a number cf erroneous assumptions as follows: the sinking fund must be available for reinvestment in another property; the series of reinvestment of the sinking fund results in a perpetual annuity to the investor, and; evaluation of the present value of the net cash flows at the speculative rate of interest. The proper procedure of deriving the Hoskhold mineral valuation formula was discussed and illustrated with a cumulative cash position diagram, a useful tool in economic evaluation and investment decision methods.

Jan 1, 1980

By J. B. Goddard

Abstract. Leaching of, uranium in situ from sandstone deposits with ammonium carbonate solution containing: dissolved oxygen occurs rapidly compared with the leaching of the bulk of the sulfur present as FeS2. However because of their high reducing, capacity and their relative abundance, the FeS2 minerals consume; the bulk of the oxidants A pressure leach apparatus was-construtted which permitted the measurement of oxygen consumtion by FeS2. Oxygen consumption by FeS2 is best described by a first-order reaction. The experimental rate constants for various cores are roughly proportional to their FeS2 contents.

Jan 1, 1980

By Kuwasaki N, Mitsune Y

Many activity measurements of components in liquid oxides have been reported in the field of slag chemistry. However, very little is known about the thermodynamic behavior of compo- nents in oxide solid solutions. In the present paper, e.m.fs. of the follow- ing galvanic cells employing solid electrolyte Zr02(CaO) were measured on the entire range of composition of the solid solutions. Pt/Ni-(Mgl-x ix)O/ZrO2(CaO)/Ni-NiO/Pt Pt/Ni-(Mgl-xNix)2SiO./ZrO2(CaO)/Ni-NiO/Pt Pt/Ni-(Mg l-xNix)Si03/ZrO2(CaO)/Ni-NiO/Pt. Activities of NiO in these solid solutions of (Mgl_ Nix)O and (Mgl_ Nix) 2Si0a(where 0

Jan 1, 1980

By Haydn H. Murray

The area from Ohio on the east, Tennessee on the south, and Minnesota on the west: contains some very unique and useful clay deposits. Included are fireclays and plastic clays in Ohio, Kentucky, Indiana, Illinois, and Missouri; flint clays in Kentucky and Missouri; ball clays in Kentuckv and Tennessee; adsorbent clays (fuller's earth) in Missouri, southern Illinois, and Tennessee; and alluvial clays and shales for structural clay products from every state. Unique kaolin clays are known in Minnesota, Missouri, and southern Illinois and halloy-site localities are known in southern Indiana. The geology, physical properties, and uses or potential uses of these midwestern clays are described.

Jan 1, 1980

By J. Slivnik, A. Stergarsek

[The site] [Z]irovski vrh uranium ore deposit is located in the extreme north-western part of Yugoslavia, some fourthy kilometers from the capital of Socialist Republic of Slovenia, Ljubljana, not far from the Italian and Austrian border. The sandstone type deposit of uranium ore with medium grade is located in a foothill of Julian Alps. The site shows some typical conditions for this region, which demand special attention in respect to the incorporation of an uranium treatment facility into environment. Among these specific conditions the following site characteristics should be mentioned: - populated area of agricultural and recreational value, - unconvenient climatic conditions with excessive rainfall and long lasting temperature inversions in the winter time, - very pure surface and underground waters which supply the drinking water reservate for large area including the capital of Slovenia, - sharp relief, - unconvenient geological structure. The choise of technology The intention to produce uranium and at the same time respecting the natural characteristics and existing uses of the site made the design of the ore treatment facility relatively difficult one. In general, there were two basic alternatives available perform the task. First alternative was to adopt the usual technological flowsheet with wet tailings disposal and with discharge of used water i.e. liquid effluents into the river. In order to prevent the negative impact of such technology on the sourrounding area sophisticated water purification installation and costly measures in wet tailings disposal e.g. impermeabilisation of large areas by concrete injections, large dam constructions, uncertain capturing of the water sources should be employed. Second alternative was to modify the usual flowsheet by employing the maximal recycling of liquid effluents to the process and to dispose the solid

Jan 1, 1980

By E. A. Lowe, A. F. Bellamy, J. W. Smith

"In the autumn of 1977 Bethlehem management initiated feasibility studies on recovery of by-product molybdenum from concentrate produced at the existing Highland Valley mining operation. Over the fall and winter months test work was carried forward concurrent with design, flowsheet, equipment specification and cost studies. The decision was made to go ahead with a 200 ton-per-day treatment plant. Construction started in early 1978 and progressed to an initial start-up stage in mid-June. Full operational status was reached in August 1978. Operational results through August 1979 are presented. INTRODUCTIONBethlehem Copper Corporation operates a 20,000 ton-per-day Open Pit Mine and Flotation Plant located in the Highland Valley, some 30 air miles Southwest of Kamloops and 20 miles Southeast of Ashcroft, B.C.Two open pits are worked; the Iona Pit with limited reserves of higher Mo content, and the lower grade, more extensive Jersey Pit. Upwards of 150 tons per day of bornite-chalcopyrite bulk concentrate is produced, ranging 0.25% to 1.5% in molybdenum grade depending on the area mined."

Jan 1, 1980

By Robert H. Poppe

The Regional Copper-Nickel Study examined the potential impacts of copper-nickel sulfide mining, concentrating and smelting operations in northeastern Minnesota and gathered extensive monitoring data on the ecological characteristics of the region's aquatic and terrestrial biota. Because of the many development options possible, the diversity of the region's ecology, and the uncertainty of future environmental regulatory requirements, the Study did not attempt to measure the magnitude of environmental impacts on specific biological communities from a specific development proposal. The Study provides a broad base of environmental resource and impact information that hopefully will assist mining developers and environmental regulators when assessing specific proposals in the future. The following discussion is not a description of what will happen if copper-nickel development occurs in northeastern Minnesota but an exploration of why certain potential aspects of such development should be carefully considered and adequately understood before unnecessary or irreversible decisions are made.

Jan 1, 1980

By Hanes J

More than 200 bursts in coal occurred at Leichhardt Colliery prior to December 1978 during mine development in the 6 m thick Gemini seam at depths approximating 400 m. Three large bursts each displaced more than 300 tonnes of coal and stone. Two of these which occurred in continuous miner developments, are described and compared. Geological settings, mining strains including induced cleavage and roof failures associated with bursts are described. A shotfiring technique replaced mechanised mining following a major incident at the colliery. Present mining procedures, the apparent improvement in stability of workings and ongoing geotechnical monitoring programme are discussed.

Jan 1, 1980

By C. E. Jordan

Abstract. The U.S. Department of the Interior, Bureau of Mines, as part of its effort to maintain an adequate supply of minerals and metals to meet national economic and strategic needs, is conducting research on the pneumatic recovery of coarse mica. A system of crushers, screens, and zigzag air classifiers is used to concentrate coarse liberated mica particles from mica ore and from the waste tailings of abandoned mica operations. The plus 0.21-millimeter-size mica is effectively recovered by this method. The mica concentrates produced contain over 90 percent mica. The method recovered up to 78 percent of the mica in the samples. As a dry concentration method, the pneumatic-beneficiation technique may be advantageous in areas of limited water resource.

Jan 1, 1980

By David L. Veith

As the basis for the State of Minnesota's Regional Copper-Nickel Study environmental evaluation, hypothetical mine models were developed ranging in ore capacity from 5.35 to 20.00 x 106 mtpy. Open pit and underground mining operations were defined utilizing conventional methods of ore extraction. Processing of the copper-nickel sulfide material involved conventional bulk flotation of the valuable minerals, with maximum water recycle And tailing disposal. Flash smelting and electrolytic refining of the concentrate resulted in 0.10 x 106 mtpy copper plus nickel metal, plus associated cobalt and precious metals. Variations in model parameters allowed environmental trade-offs to be identified.

Jan 1, 1980

By Gregg W. Morrison

"The Craigmont copper-iron skarn deposit is adjacent to the southern margin of the late Triassic Guichon Creek batholith in south-central British Columbia. Host to the ore are sedimentary and volcanic rocks of the western calc-alkaline belt of the Upper TriassicNicola Group. In the mine area, the Nicola Group rocks are a stratigraphically complex sequence, at least 1800 feet thick, which have been subdivided into Basalt, Rhyolite, Carbonate and Clastic Sediment units. All the units strike and dip parallel to the margin of the Guichon Creek batholith and are within the batholith contact aureole. However, only the Clastic Sediment unit is in contact with the batholith.Most of the skarn and ore is within the Carbonate unit and more specifically within an Interbedded facies that consists of lime sandstone, lime siltstone, quartzo-feldspathic siltstone and argillite. The Interbedded facies and the adjacent barren Massive Limestonefacies are interpreted aspart ofa carbonate reef complex. The distribution of skarn and ore within the Interbedded facies suggests that the facies boundary was a physical and chemical barrier that resulted in concentration of metals adjacent to the Massive Limestone facies.Two stages of skarn formation have been recognized at Craigmont. In Stage I, ore-bearing magnetite-rich and actinolite-epidote-magnetite skarns developed both in basaltic rocks and in Fe-bearing siltstone and argillite of the Interbedded facies, while barren grossular garnet-epidote-calcite-pyrite skarns developed in Fe-poor rhyolitic bands within the Interbedded and Massive Limestone facies . In Stage ll, massive, barren grandite garnet skarn replaced mineralized Stage I skarns in the vicinity of diorite plugs. and specularite ore formed in brecciated Stage I skarn and clastic rocks away from the plugs. Theformation of Stage I skarns required no addition of material, only redistribution and concentration of elements already present within the Interbedded facies. However, the concentration of Cu in Stage lore requires a mechanism for more efficient leaching of Cu from the host rocks, an anomalous concentration of Cu at the site of the Stage I orebody or an additional input of Cu from an external source. The formation of Stage II skarn and ore requires only remobilization and recrystallization of Stage I skarn and ore.Copper and iron are the only elements in economic concentrations in the ore and chalcopyrite is the only significant copper-bearing mineral. Chalcopyrite is disseminated and interstitial to magnetite in Stage I mineralized skarns and is interstitial to specularite in the matrix of Stage II breccia ores. Chalcopyrite also occurs with pyrite as stringer ore in bleached • sediments and rhyolite tuffs in the stratigraphic footwall of the main orebodies.The Craigmont deposit has more features in common with Cu-Fe deposits hosted in metavolcanic and metasedimentary rocks than it has with typical skarn deposits associated with porphyry copper deposits. The orebody is more likely a product of concentration of metal contained within the Nicola Group rocks than of the mineralizing event that produced the . Highland Valley Cu-Mo porphyry deposits in the central part of the Guichon Creek batholith ."

Jan 1, 1980

By S. K. Nicol, A. R. Swanson, J. C. Day

Addition of oil to a suspension of hydrophobic coal particles can influence its dewatering characteristics. An agglomeration process occurs in which coal particles are held together by negative capillary pressure at particle/oil/water contacts. Consequently, the units round which flow can occur are enlarged and this improves dewatering parameters such as drainage rate, solids recovery, and equilibrium moisture content. This paper discusses processes which attempt to use this principle, in terms of metallurgical and economic efficiency. The discussion is augmented by results of recent experiments on the effect of oil addition to centrifuges and vacuum filters.

Jan 1, 1980

By P. W. Jeran, S. J. Pepperney, M. C. Irani, F. F. Kopsch

The Bureau of Mines has designed and put into operation a fail-safe control system for use in underground coal mines equipped with methane drainage pipelines. This control system can detect certain unsafe conditions and respond by automatically shutting off the flow of methane from the degasification borehole to the drainage pipeline. Methane flow is shut off when the methane content in the return airways reaches a predetermined level (typically 1.5 pct), when the methane drainage pipeline is ruptured by roof fall, or when there is an electric power failure. The fail-safe control system was designed using commercially available components and a methane analyzer system previously developed by the Bureau. The fail-safe system consists of a unit that combines a shutoff valve and pneumatic valve actuator, and electronic and mechanical equipment designed to detect hazards and effect shutdown. The fail-safe control system was designed to meet regulatory requirements issued by the Mine Safety and Health Administration (MSHA), U.S. Department of Labor, and State regulatory bodies for the safe operation of underground methane pipelines used for mine degasification. MSHA has inspected and tested this system and permitted its use in two mines. The Bureau installed the fail-safe system in two working coal mines, where successful performance has been demonstrated.

Jan 1, 1980

Mineral deposits in New Zealand whose origin can be ascribed to primary magmatic segregations are associated with mafic-ultra- mafic complexes related to two orogenic episodes which took place during Paleozoic and Mesozoic times. These mafic-ultramafic complexes are essentially of two types. One is ophiolitic and has podiform chromite mineralisation presumably formed below a spreading ridge. The other type occurs as intraplate layered intrusions in which Fe-Cu-Ni sulphides and Fe- Ti-V oxides have formed as a result of liquid immiscibility with the host magma, and have subsequently accumulated by gravity means. Generalised descriptions are given for some deposits in NW Nelson, Fiordland and Marlborough districts.

Jan 1, 1980

By R. R. Klimpel

The use of chemical reagents in flotation has been studied in great detail, e.g. (1, 2, 3, 4). Important progress has been made on the understanding of surface chemistry concepts involved in flotation. However, such scientific studies are often very complex even for rather simple idealized systems. Therefore, the deve- lopment of predictive or quantitative tools for plant engineering evaluation is still in the evolutionary stages. Until further progress in fundamental work is achieved, the operating engineer is faced with semi-empirical physical testing of reagent changes on several sizes of the actual equipment under study to be confident of the economic viability of any change.

Jan 1, 1980

By Narasimhan K. S, Sastri S. R

A typical high silica low grade magnesite from the Salem area of Southern India, was used in studies to develop a suitable flotation system involving commercially inexpensive sodium oleate as the collector together with other reagents which can give a product of the required grade with an acceptable recovery. It was found that the presence of metallic ions such as Cu+, Fe+++ or Ca++ introduced by the addition of their salts, or by their formation with the addition of hydrochloric acid to react with magnesium and calcium carbonate in the me, can act as effective depressants for silica. The addition of 'hydrochloric acid' was found to give best results.

Jan 1, 1980