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By C. Nikolic

A process utilizing ozone for the precipitation of cobalt from nickel sulphate liquors containing ammonium sulphate has been developed. Best results were obtained using nickel carbonate to maintain solution pH at 5.0 to 5.5. Work was performed both in column and stirred-tank reactors. Variables studied included neutralizer type and concentration, NH4+ concentration, temperature, Ni++ and Co++ concentration, per cent O3 in the O2 carrier gas, O3 input rate and agitation. The over-all rate of cobalt rejection increased sharply with increasing agitation and ozone concentration in the gas phase, reflecting relatively slow transfer of ozone from the gas to the liquid phase.

Jan 1, 1978

By Roshan B. Bhappu, Thomas J. Lien

The DYNA WHIRLPOOL Processor (DWP) is a cylindrical dynamic heavy media vessel. It is used to beneficiate fine ore sizes from one and one-half inches in diameter down to 65-mesh. Process units available treat up to 80 tons per hour. Units can be manifolded for higher capacity plants. Finely ground magnetite and ferrosilicon are used for media. , Installed capital costs are from $4,000 to $6,000 per ton hour of feed. Operating costs are from $0.30 to $0.50 per ton of feed. The DWP is used to beneficiate metallic and non-metallic ores and coal. The OCC Vessel is a static heavy media separator used to beneficiate coarse ore up to six inches in diameter and auto scrap. Process units available treat up to 300 tons per hour.

Jan 1, 1978

By Tomek Ulatowski

This article discusses four principal areas relevant to financing direct reduction facilities: (1) Lenders' differing requirements with respect to projected cash flows; (2) The impact of leveraging on project viability; (3) The importance of appropriate debt structure; (4) The significance of accurate and complete capital cost estimates. The overall findings emphasize the inseparable connection between the project economics and its financeability, and particularly how direcly intertwined they both are in the project planning.

Jan 1, 1978

By O. P. Garg

Based on improved methods of collection and analysis of geotechnical data, slope angles have been steepened in some mines of the Iron Ore Company of Canada at Schefferville, Quebec. This paper describes the slope design case history for Fleming NO.3 mine and illustrates the application of modern techniques. The new design has resulted in significant financial savings due to a reduction in required waste stripping.

Jan 1, 1978

By Tom Retka

This three volume final report summarizes the activities and conclusions of this contract. The objective of the contract was to develop noise control modifications on a retrofit basis, for auger miner coal-cutting systems. Manuals were prepared to assist mine shop personnel in retrofitting the auger miner with these noise controls. Final Report Volume I - Details all vibration and acoustical tests conducted in development of the noise controls. Final Report Volume II - Noise Control Modification Manual for the Jeffrey 100-L Auger Miner describes the various noise control modifications to the auger miner, along with fabrication procedures, cost and vendor information. Final Report Volume III - Noise Control Modification Manual for the Jeffrey 94-L Bridge Conveyor describes the various noise control modifications to the bridge conveyor, along with fabrication procedures, cost and vendor information.

Jan 1, 1978

By Larry Urbanoski

"This paper describes the application of a radioisotopic energy dispersive X-ray aY1alyser to complete on-stream analysis in a base metal concentrator.The major components of the system are outlined and some description of the application, operating experiences and benefits are provided.IntroductionThe ma1n intent of this paper is to describe the on-stream analysis system in operation at the Geco concentrator. X-ray analysis systems installed in Canadian concentrators to-date may be broadly classified as wavelength dispersive analysers whereas the installation described herein is an energy dispersive x-ray analysis system. Energy dispersive x-ray analysis techniques may utilize radioactive sources to provide primary x-rays for excitation of elements and separate the secondary x-rays on the basis of energy levels. In contrast wavelength dispersive analysers apply high voltage x-ray tubes to provide primary x-rays and utilize crystals to disperse and thereby separate x-rays generated by bombardment of the sample."

Jan 1, 1978

The breakage mechnism of a spherical charge greatly differs from that of the cylindrical charge used in underground mining. The advantages of the spherical charge could not be utilized until INCO Metals Company, Ontario Division, introduced large diameter holes to their operation.

Jan 1, 1978

By Selby DW, Hamill J, Cauley ID, Thomas I, Thornton AJ

The main objective of sulphide flotation in a cassiterite concentrator is to remove sulphide minerals (pyrite, pyrrhotite and sometimes chalcopyrite) from the ore prior to gravity concentration. Tin losses in the sulphide flotation stage account for a significant proportion of the total tin loss. separate studies of the sulphide flotation circuits of Renison Ltd and Cleveland Tin Ltd were conducted to investigate reasons for the tin losses. Sampling surveys were conducted in the rougher-scavenger and also the regrind-cleaner sections of both plants. In both plants, the rougher circuits recover excessive quantities of liberated cassiterite, while recovery of the desired composite cassiterite-sulphide fraction is low. The regrind mills are successful in liberating the composite cassiterite in the rougher concentrate, but at the expense of increasing the proportion of very fine tin mineral. The cleaner circuits recover between 40 and 60% of the cassiterite received, and this is all lost.

Jan 1, 1978

By Howard E. Parkinson, John N. Murphy

The past five years have seen communications techniques and hardware developed by the Bureau of Mines and its contractors increasingly brought into use in U.S. mines. The Bureau philosophy has been to help develop and introduce new hardware that goes as far as possible toward meeting the mining industry's needs. The Bureau programs are also designed to provide continuous fallout of new communications capabilities which are introduced to the mine operators as they occur. As more progress is made in meeting mine communications needs, it is hoped that the mining industry will readily adopt the equipment and techniques that it finds most useful in meeting its individual needs. This paper reports on recent advances achieved in the development of improved mine communications systems. In May 1975 the U.S. Bureau of Mines (USBM) conducted a mine communications technology meeting to provide a brief overview of the USBM communications technology developments in the past 5 yr. This meeting lasted for 1 1/2 days. Therefore, I have elected to narrow this paper to a brief review of recent underground mine communication developments. The following will be discussed: 1) Ultra-high frequency (UHF) radio for fan hole drill operators;

Jan 1, 1978

By A. Bentzen, S. S. Wong, W. K. Fletcher, B. J. Price, A. J. Sinclair

One hundred eleven pyrite samples from three porphyry-type deposits in the Canadian Cordillera were analyzed (many in duplicate) by AA spectrophotometry for Co, Ni, Cu, Pb, Zn and Mn. All elements have density distributions that are lognormal or combinations of lognormal populations. Co and Ni in pyrites show zonal patterns that relate generally to mineralogical zones in the porphyry systems, particularly if contoured as the Co/Ni ratio. High Cu and Mn values in pyrites also correlate with Cu-rich mineralogical zones. Other elements studied appear less regular in their distribution patterns, although Pb and Zn highs in pyrite seem to occur sporadically near the margins of porphyry systems. These data considered with two other studies permit construction of an empirical model for the distribution of certain minor elements of pyrites from porphyry systems of the calc-alkalic suite. In particular cases pyrite geochemistry shows potential as an exploration tool to aid in target definition for detailed exploration.

Jan 1, 1978

A system for rapid on-line determination of weight percentage coal in slurry and weight percentage ash in coal has been developed at the Julius Kruttschnitt Mineral Research Centre, University of Queensland. The gauging system is suitable for use with coal flotation slurries or slurries having a maximum particle size of about 1 millimeter. The system is based upon measurement of gamma ray transmission; radioisotope sources emitting photons of two widely different energies are employed. The inaccuracies of measurement that would normally result from variable amounts of air entrained in the slurry are substantially reduced by pressurising the slurry to approximately 2MPa (300 psi) using a Mono pump. The equipment can be used to make measurements on more than one slurry stream by pumping streams sequent- ially. The system is being tested at the Peak Downs Mine of the Utah Development Company in Central Queensland. This paper describes the theoretical principles of the gauge design, the experience gained to date in the commissioning of the equipment, including the installation of a PDP 11/03 computer, and the progress made in developing satisfactory interpretations of the gauge count-rate output.

Jan 1, 1978

By Peter L. Langsjoen, Kenneth L. Maloney

Ten small and intermediate-sized (4.5 Mg/hr to 113 Mg/hr steam--10,000 to 250,000 lb per hr) coal-fired boilers in the upper Midwest have each been tested on both a bituminous eastern coal and a subbituminous western coal. The purpose of this study was to determine the feasibility of substituting western subbituminous coal for eastern bituminous coal as a means of reducing the SO, emissions from this class of boiler and to demonstrate the feasibility of greatly expanded western coal utilization as a means of reducing the use of oil and gas. The scope of this study was such that the representative boiler types were tested on both eastern and western coal for a period of time sufficient to completely characterize their individual emission and operational characteristics.

Jan 1, 1978

By Paul C. McWilliams

This Bureau of Mines report analyzes data on the physical properties of quartzite rock from the Crescent mine, Coeur d?Alene mining district, Kellogg, Idaho, to demonstrate the use of multivariate techniques. After regression, factor, component, cluster, and discriminant analyses are discussed, these techniques are applied to the Crescent mine data. Three appendixes contain some of the required mathematical and statistical detail plus heuristic examples of three multivariate techniques --component, cluster, and discriminant analysis.

Jan 1, 1978

By W. M. Tupper

Municipal governments recognize the importance of aggregates in the local economy and the need to manage this resource in the interest of the public good. They have encountered problems with regulating the industry and the dichotomy between the urban need and the rural source. They have suffered from a lack of financial benefit, an adequate aggregate inventory, provincial strategy, economic information and public understanding. A provincial strategy for ensuring the availability of aggregate supplies to developing areas of the Province is essential. The Province should also be responsible for licensing, research, technical expertise on rehabilitation, public education and financial assistance. Upper-tier municipalities (regions or counties) should assume responsibility for resource management, including resource availability, demand characteristics, truck routing, phasing of resource development and sequential land-use planning. Area municipalities (towns and townships) can best determine the social and environmental impact of a specific aggregate development proposal and should therefore have the primary responsibility for the location of new pits and quarries. They should also have the authority to supplement provincial regulations concerning operating standards and the phasing and standards of site rehabilitation.

Jan 1, 1978

This paper describes the mechanical and electrical maintenance activities as practised at Isa Mine. The principles of preventative maintenance adopted are described as well as the basis of maintenance cost control.

Jan 1, 1978

By Adrian C. Dorenfeld

The lesser developed countries (LDC's) may be classified into two categories: 1) oil producers, and 2) non-oil producers. The non-oil producing LDC's, as a class, are at present in very difficult financial straits. (1) Since the quadrupling of world market crude oil prices in 1972, an ever greater share of the LDC's export earnings have gone to pay for oil imports, in-stead of national reinvestment. The LDC's inter-national debts--much of it to pay for oil--have soared to record levels, with consequent limits for future credits. (1) Again, this inhibits future national investments, and there does not seem to be an end to the future increase of Organization of Petroleum Exporting Countries (OPEC) prices. Indeed, some of the economic difficulties in some metal markets--particularly the imbalance of production vs. markets for copper, can be traced indirectly to the OPEC cartels' heavy-handed impact on copper producing LDC's which must produce copper at any price to meet their oil bills. (2) Among the major oil importing LDC's are the Philippines and South Korea. 50th nations have substantial cement industries. The South Korean industry is geared for major export markets in the Far East. Both nations have ambitious plans for economic growth in order to accommodate burgeoning populations with ever increasing expectations for high standards of living. These plans had some success, more or less, until the high OPEC oil cartel charges had to be borne. Now, in common with all oil-deficit areas, the Philippines and South Korea are seeking lower cost sources of energy. Both countries have coal deposits. In the case of the Philippines, the reserves are in scattered, relatively small deposits. Most of the coal deposits are faulted, folded and, in general present formidable production problems for limited reserves. Nonetheless production has been on the order of about 70,000 to 150,000 tons per year in the last 30 years. Prior productions (1920-1941) varied between 9,000 Co 150,000 tons per year. (13)

Jan 1, 1978

By J. J. Brummer

The possibility of diamonds occurring in Canada was first raised by W. H. Hobbs in 1899, who concluded: "that the apex of the fan of diamond distribution probably lies somewhere in the strip of the territory bordering James Bay on the east." This was based on the occurrence of diamonds in surficial sediments at various locations south of the Great Lakes. There are two recorded discoveries of drift diamonds in Ontario: (a) the Peterborough Diamond, 33 carats in size, poorly documented and found sometime before 1920;and (b) the Jarvi Diamond, 0.255 carat, found during 1971 in Sheraton Township near Timmins . Both discoveries were in surficial sediments and their source(s) have not been located. During 1960, Selco Exploration Company Ltd. started a heavy-mineral sample program of river gravels in the James Bay Lowlands of Ontario. This was continued by Canadian Rock Company Ltd. (1962-1963) and the Ontario Division of Mines (1973). The surveys discovered the presence of kimberlite minerals in gravel samples from streams draining the Moose River Basin. A total of 53 pyrope grains, four magnesian ilmenites and one grain of chrome diopside were identified from 32 sample locations. A study of the distribution of these minerals suggested the kimberlite source rocks to be located along the north margin or within the Kapuskasing gravity "high" in the area immediately south of James Bay. The Jarvi Diamond, found on an esker east of Timmins, could well have originated from this area. During 1965, an esker was sampled by the Geological Survey of Canada, and the results attracted attention to the area south of Lake Abitibi. At 9 out of 34 sites sampled along the Munro esker, Lee recorded the presence of pyrope garnets and very minor chrome diopside.

Jan 1, 1978

By Paul E. Scheerer

Synthetically produced magnesium hydroxide serves as the precursor for much of the magnesium oxide produced in the world today. Magnesium oxide, in a variety of physical and chemically reactive forms, is a very important commodity. It is used as the main component in refractories employed in steelmaking furnaces and in many base metal refining furnaces. In the chemical industry, it serves as a raw material in the production of epsom salts, rayon acetate, oxychloride and oxysulfate cements and magnesium sulfonates. It is a minor component in fertilizers and animal feeds. It serves as the starting material for producing fused magnesia, used as an electrical insulator in electric heating elements. It is employed in the magnesium sulfite process for pulp digestion in the paper industry. Additional uses are in SO2 scrubbers, as a neutralizing agent in the tanning industry and as a component in rubber compounding. Magnesium oxide is produced not only from synthetically produced magnesium hydroxide. It is produced from natural magnesites, natural brucites, and natural and synthetic hydro-magnesites. Synthetic magnesium hydroxide, as a starting material provides more control of the chemical purity and chemical reactivity of resulting magnesium oxide products because of the uniform nature, chemical and physical, of the hydroxide that can be produced. Synthetic magnesium hydroxide is produced by precipitation of Mg (OH)2 from magnesium chloride bearing seawater or natural brines through the use of a base such as Ca(OH)2 or NaOH.

Jan 1, 1978

By Young C. Kim, William C. Cassun

A proper economic analysis of pit slope design must reflect the trade-off between the benefits and the increased risk of slope failure inherent in steeper slope angles. This paper describes the results of a case study in which a newly developed probabilistic economic analysis procedure was applied to the selection of a pit slope design at a large porphyry copper mine in the southwestern U.S. The paper also demonstrates the availability of the required data such as the probability of failure schedule and cost of failure models, under "real-life" conditions.

Jan 1, 1978

By W. D. Grimsley, R. P. King, J. B. See

Samples (15 to 20 g) of pre-calcined Mamatwan manganese ore or pure Mn 304 smaller than 48 mesh were reacted at temperatures in the range 1000 to 1300°C with samples of spectrographically pure graphite smaller than 325 mesh. Samples (1 g) of ore or pure Mn02 smaller than 48 mesh were reacted at temperatures of 1000 and 1200°C with pure graphite fines in argon, with graphite in carbon, .'1onoxide, and with carbon monoxide alone. In each case, the loss of mass as a function of time was recorded with a hermobalance. The rate and degree of reduction were found to increase with additions of carbon and with increasing temperature up to 1300oC, when they reached their maximum. The shape of the reduction curves, together with the results obtained from examination of the products of reaction by microscopy and X-ray diffraction, were used as the basis for a postulated reduction mechanism. Some details are given of an initial kinetic model that was used to verify the proposed mechanism. It was found that the reduction of Mamatwan ore by graphite at temperatures in the range 1000 to 1300°C occurs in two stages: (i) an initial stage during which the higher oxides of manganese are rapidly reduced to MnO with concurrent formation of CaMn2O4 and (ii) a longer stage during which CaMn2O4 and MnO are reduced to carbides by carbon dissolved in the ferromanganese phase.

Jan 1, 1978