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By T C. Westerfield, G, M J. Mankosa

An innovative separator known as the HydroFloat cell has been developed specifically for the upgrading of coarse particles that are difficult to recover using conventional flotation cells. The novel characteristic of this separator is the formation of a hindered teeter-bed of fluidised solids into which small air bubbles are injected. The air bubbles selectively attach to hydrophobic particles and form particle/bubble agglomerates that segregate atop the teeter-bed due to their lower apparent specific gravity. The low-density agglomerates are eventually carried into the product overflow launder by the rising current of teeter water. Hydrophilic particles remain in the teeter-bed and are discharged to underflow as a high solids content tailing. Benefits of this hybrid flotation-density separator include enhanced bubble-particle contacting, increased particle residence time, and very low air demand. Test data indicate that significant improvements in the recovery of coarse particles can be achieved using this innovative technology. This article describes the theoretical basis for the development of the HydroFloat cell and provides an overview of recent pilot-scale tests conducted for the phosphate industry.

Jan 1, 2005

During 1995 a catastrophic accident took place at the No 2 Vaal Reefs shaft in South Africa, when a locomotive fell onto a cage, causing the death of 104 people. The subsequent Commission of Enquiry found that the safety detaching hook had opened when hit by parts of the falling locomotive, detaching the cage from the rope and allowing the cage to drop 400 m down the shaft. It was believed that had the hook not detached, the rope would have been sufficiently elastic not to have failed, implying that many fatalities may have been avoided. In addition, the risk of accidental opening of hooks due to impact with smaller falling objects in shafts became a concern. This paper deals with a comprehensive statistical investigation that was performed to quantify this risk, establish acceptable levels of such risks and to derive criteria for the resistance of detachment hooks against accidental opening caused by impacts. The investigation involved a survey, dynamic finite element analyses and Monte Carlo simulations.

Jan 1, 2005

By Y Peng, D Wannas

In the fine particle flotation technologies being developed today the fine hydrophilic (gangue) particles are usually well dispersed. These highly dispersed fine particles can be recovered into the flotation froth product by mechanical entrainment. Flocculation of hydrophilic particles caused by polymer depressants could potentially reduce the mechanical entrainment of these particles. This paper reports testwork completed on fine particles of several solids, iron oxide, hydroxylapatite, galena and sphalerite, as well as on a relatively coarse quartz sample (-75+38 ¦m). Dodecylamine was used as a collector for the quartz, and several dispersants and polymer depressants, including sodium silicate, sodium metaphosphate, zinc sulfate, potassium dichromate, corn starch, corn dextrin and carboxymethyl celluloses (with molecular weights of both 700 000 and 80 000) were used as flotation modifiers. The major part of the testwork involved flotation tests in a 200 ml flotation column. Both water and solid recoveries were recorded. The degree of flocculation and dispersion was determined by settling tests in 250 ml graduated cylinders. It was observed that flocculation of the fine hydrophilic particles significantly reduced their mechanical entrainment, while dispersion severely aggravated it. Thus, in the flotation separation of artificial mixtures of the -75+38 ¦m quartz and fine iron oxide or hydroxylapatite, polymer depressants that caused flocculation were found to perform better than the ones that did not cause flocculation.

Jan 1, 2005

Folklore suggests that oxidation is detrimental to sulfide mineral flotation, and in many instances is the reason given for values reporting in the tailing. However, while a considerable body of work examining galena oxidation is available in the literature there are very few studies that investigate the consequences of galena oxidation on its subsequent flotation in base metal sulfide ores. This work clearly demonstrates that pyrite forms a galvanic couple with galena, due to the large difference in their rest potentials, and results in accelerated oxidation of galena, particularly as the pyrite content of the ore is increased. The most obvious effect of the galvanic oxidation of galena by pyrite is the release into the system of galena oxidation products, providing an ample supply of lead ions available to activate gangue minerals, most notably of which in lead/zinc ores is sphalerite. The inadvertent activation of sphalerite by lead ions inevitably leads to the recovery of liberated sphalerite into the lead concentrate, and as a consequence a reduction in the lead concentrate grade. That is, a loss of selectivity for galena against sphalerite. If galena oxidation is excessive not only is there a considerable loss in lead concentrate grade, but also a marked decreased in lead recovery as the flotation rates of the gangue minerals increase, until they rival that of galena.

Jan 1, 2005

By Emre Biringen

"Results from a small-scale laboratory experimental program show the changes in the vertical stiffness and strength of a soft clayey soil adjacent to the shaft of an inserted pile (i.e. expansion of a cylindrical cavity). The experimental program provides a realistic axi-symmetric physical model of an element of a cylindrical pile and the surrounding soil. The study interprets the improvement and assesses its magnitude in vertical stress-strain-strength properties of a normally consolidated soft cohesive soil in response to preloading impact in the radial direction. The results verify that insertion of a cylindrical pile causes densification of surrounding soil in a radial direction due to change in stress state around the pile, and thus consolidating and stiffening of the soil.The test results indicate that most improvement in modulus and strength takes place within a distance of 4 times the radius of a pile, though significant improvement is realized to a distance of 8-10 times the radius, beyond where there is negligible effect. Settlement characteristics of the surrounding soil in a zone of 12 times the pile radius improve significantly after the formation of a cylindrical cavity. The miniature vane shear strength tests show a 1.5 times increase in a zone of 4 times the pile radius compared to the strength at 10 pile radii. The results also imply that the spacing of cylindrical piles should not be more than 4 to 10 times pile radius, so that the surrounding soil matrix may improve the vertical bearing capacity under any foundation or embankment loading.INTRODUCTIONThe engineering community is familiar with different techniques to improve the bearing capacity and settlement characteristics of weak cohesive and organic soils. Some of the in situ techniques to improve the properties of soft ground (e.g. soft clays) prior to placement of foundations are vertical preloading, deep cemenUlime mixing, stone columns, and grouting (Henn 1996; Moseley 1993). In addition to these methods, researchers have recently showed interest in achieving soft ground improvement by means of applying radial compression method for which different names exist including expanding pile (Kelleher et al. 2001 ), Preload™ Pier (Biringen and Edil 2003), and sand compaction pile (Lee et al. 2004). Handy (2001) has described how preloading can also be achieved by imposition of radial loading in soft ground with an expected improvement in stiffness. The idea behind the latter method is densification and consolidation of soft soil in the radial direction by controlled displacement for which the process can be viewed as a cavity expansion problem (Vesic 1972)."

Jan 1, 2005

By Monica Prezzi

"Auger cast-in-place (ACIP} piles and drilled displacement piles are being increasingly used as foundation elements for structures, particularly in projects requiring accelerated construction or involving the rehabilitation of foundations of existing, overstressed structures. Auger cast-in-place piles (also referred to as continuous-flight-auger piles) are widely used to construct the foundations of all types of structures. There are many different types of drilled displacement piles, with the installation methods varying according to the equipment used. Depending on the specific rotary piling technology used, responses ranging from those associated with non-displacement to those associated with full-displacement piles are obtained. Conventional pile design methods do not account for how the various construction techniques involved in auger piling change the soil state around the pile during installation and, hence, cannot accurately estimate the pile resistance in a consistent way. Research on this subject, identifying the different variables that must be accounted for in design and linking these variables to installation methods, is lacking. This paper describes the different piling methods available for auger cast-in-place and drilled displacement piles, the equipment used to install them and the quality control processes typically used. It also reviews some of the design methods currently used.IntroductionDeep foundations are extensively used in geotechnical engineering practice. The wide spectrum of piling methods results in a variety of pile types. Each type behaves differently, depending on the installation or construction methods. On one end of the spectrum are non-displacement piles, the classicql examples of which are bored piles or drilled · shafts. These piles are constructed by removing a cylinder of soil from the ground and replacing it with concrete and reinforcement. On the other end are full-displacement piles, such as closed-ended pipe piles or precast reinforced concrete piles, which are typically driven into the ground. Driven piles preload the materials below the toe of the pile and displace the soil surrounding the pile shaft laterally during the installation process. Therefore, displacement piles are, in general, more likely to have a stiffer response than non-displacement piles. This is true particularly in the case of sandy soils where displacement causes densification."

Jan 1, 2005

By C. -S. Xie, J. -H. Kong

The microstructure and mechanical properties of X80 hot-rolled thick steel strips with a thickness of 17.5mm produced in Wuhan Iron & Steel Company (WISCO) are introduced in the paper. The steel strips as fabricated through proper thermomechanical processing (TMP)/ on-line accelerated cooling (OLAC) processing have shown high strength and toughness, low brittle transition temperature, good weldability, and high Shear Area (SA) percentage in Drop Weight Tear Test (DWTT). The microstructure of the steel strips is characterized with mainly acicular ferrite, and fine dispersed Martensitc-Austenite (M-A) phases. It is determined that the mechanical properties are improved due to the presence of the fine M-A phases and precipitates, which could be formed by reducing the finish rolling and coiling temperatures.

Jan 1, 2005

By P. -Q. Wu

A modified electrochemical noise (EN) technique has been applied to monitor corrosion wear of TiN-coated ASP23 steel and TiN-coated AISI 316 stainless steel sliding against corundum in 0.5 M H2SO4. Experimental results show that the EN technique can sensitively detect potential and current variations during a corrosion-wear process. Corrosion-wear mechanisms of TiN coatings depend on their substrate properties. If the substrate is passive, such as AISI 316 stainless steel, the potential and current variations reflect the properties of the coating. Depassivation and repassivation alternately take place on the tribo-activated wear area during the steady-state phase. If the substrate is active, such as ASP23 tool steel, the electrochemical noise is dominated by dissolution of the substrate at the pinholes and the hydrogen evolution all over the exposed surface.

Jan 1, 2005

By R. Baker

A novel electrochemical half-cell and corresponding working electrode were designed to evaluate the electro-catalytic activities of catalysts in an environment close to that of an operating proton exchange or polymer electrolyte fuel cell (PEMFC). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques were employed using the novel cell to characterize various methanol electro-oxidation parameters that contribute to the overall reaction on a fuel cell anode. The effect of temperature on methanol oxidation kinetics was examined in the potential range of 0.31 to 0.65V (vs. NHE). The data was collected in the temperature range of 20 to 80°C. Based on the experimental analysis and literature data, an equivalent circuit model (ECM) for methanol oxidation was proposed and was used to fit the EIS experimental data. The experimental data and ECM electrochemical data was used to extract electrochemical kinetic parameters for methanol oxidation such as the exchange current density, Tafel slope, and energy of activation for the reaction. Kinetic data, especially at different temperatures, is very limited in the literature.

Jan 1, 2005

Proper water and thermal management is essential for obtaining high performance of Proton Exchange Membrane Fuel Cells (PEMFCs). A steady, two-dimensional water and thermal management model was developed, aiming at considering pressure drop, open circuit voltage variation with stack temperature, water vapor effects on membrane conductivity, which made the model physically more reasonable and more suitable for various operating conditions. The model could predict the distributions of a series of important parameters along the flow channel, and thus the effects of various operating and design parameters on the fuel cell performance could be investigated easily by numerical trial-and-error method. The modeling results compared well with the available experimental results from the literatures. The results also showed that the humidification is crucial for the performance of PEMFCs. The model could be a very useful engineering tool for the optimization of PEMFCs.

Jan 1, 2005

By J S. Laskowski

Froth flotation process requires the use of frothers. These important flotation agents are commonly characterised as either æselectiveÆ or æpowerfulÆ and are chosen following general guidelines and verification by laboratory and/or pilot plant tests. Fundamental properties of the flotation frothers have been extensively studied over the last few years. These studies have led to the development of standardised procedures to characterise frothers in terms of their ability to reduce bubble size and to increase foam stability. In this research project, the performance of five frothers in flotation of coal is evaluated and related to the fundamental properties of these agents. Since the recovery of water in the concentrate is closely related to the non-selective transport of solid particles by entrainment, the tested frothers are also assessed in terms of their ability to promote the transport of water towards the froth collection zone, both in absence and in presence of solids.

Jan 1, 2005

By K. Freytag

The extraction of lignite in open-cast mines has a severe impact on the landscape. Proper landscaping after the shut-down of the mines has always been the statutory responsibility of the mine operator. The large area of the land used for open-cast lignite mining requires special regional planning procedures well in advance of the permitting procedure stipulated in the mining law. The lignite plan determines, among other things, the objectives of land reclamation. These objectives will then be outlined in more detail in the mine operation plans and implemented accordingly. Apart from the actual mining laws and regulations, a large number of environmental laws also determine the process of land reclamation. The success achieved in the field of land reclamation in all mining regions during the recent decades has shown that the lignite mining industry creates new landscapes that do not leave any scars in the countryside and merge very well with it.

Jan 1, 2005

By Junya Tokita

In Japan, packaged explosives have traditionally been used as the most common explosive for tunneling. Recently, some blasting systems such as ANFO with a kettle loader and emulsion explosives with a pump loader have been trialed in order to improve safety and efficiency of the charging process. There are issues with these systems relative to the Japanese market. ANFO dissolves in water easily, and generates ammonia gas when it contacts with concrete. Emulsion explosives need costly pump ing unit s, and there is a need to control residuals in the pump unit. Additionally, there are obstacles by Japanese law to site mixing of emulsion explosives.

Jan 1, 2005

By Michael Gauna, William J. Gray, Joseph C. Zelanko

Mechanized mining in the underground coal industry has continued to evolve since the introduction of the remote control mining machine. Remote control continuous mining machines without an onboard operator’s compartment are now the norm in the industry. Extended cuts in excess of 30 ft (9.1 m) are commonplace. Unfortunately, machine operator positioning has become an often unrecognized safety concern, particularly when remote control continuous mining machines excavate a turn (turn a crosscut). From January 2001 through July 2004, remote control continuous mining machine operators or helpers have been involved in ten roof fall fatalities and eight machinery crushing fatalities. The machinery crushing incidents occurred when machines were being repositioned or moved to another place. Of the ten roof fall fatalities, three occurred while a crosscut was being turned and a fourth fatality occurred while mining was being conducted adjacent to the crosscut. The operating time associated with turning crosscuts is a relatively small part of the mining cycle. In recent years, however, a disproportionate number of fatal incidents appear to have been associated with this activity. Procedures for reducing the incidence of operator fatalities while turning crosscuts are discussed. These techniques include: minimizing the number of turn cuts, limiting turn cut depth, establishing no work zones and using visual warning devices to designate them, installing more roof/rib support in the vicinity of the turn cut, using notch cuts prior to initiating a full turn cut, and positioning the remote control miner operator in nontraditional locations.

Jan 1, 2005

By Z. Xie

Gas diffusion electrodes (GDEs) for high temperature polymer electrolyte fuel cells (PEFCs) have been prepared using ZrP-modified Nafion ionomer. The performances of these GDEs as cathodes and anodes were evaluated and compared with conventional Nafion ionomer GDEs using Nafion 112 as the PEM under elevated temperature and reduced relative humidity. ZrP-modified Nafion ionomer was incorporated into the catalyst layer to enhance water retention and/or increase the protonic conductivity. The fabrication of ZrP-GDEs was implemented by the ion exchange of Nafion solution with zirconyl chloride, followed by the impregnation of GDEs in H3PO4 solution. The composite electrolytes in the catalyst layer possessed a ZrP content of 20% by weight. GDEs were characterized by TGA, SEM, XRD, and CV. Scanning electron microscopy (SEM) indicated evenly distributed elemental Zr and P within the catalyst layer. Cyclic voltammetry shows a reduced electrochemically-active surface area when the ZrP is incorporated into GDEs. Polarization and impedance analyses indicate the cathode with ZrP-modified Nafion ionomer did not show an enhanced or decreased performance, compared with conventional Nafion ionomer GDEs under elevated temperature and decreased humidity. However, when GDEs with ZrP¬Nafion ionomer were used as the anode, an improved performance was observed. Preliminary experiments show that the anode is more sensitive to dehydration than the cathode under elevated temperature and/or low humidity. Improving the anode water retention capability will help to reduce losses at the anode. However, the incorporation of hygroscopic agents in the cathode catalyst layer is not essential because it is self-humidified by electrochemically-produced water even under elevated operating temperature and lower humidity.

Jan 1, 2005

By V Malysiak, N J. Shackleton

In the flotation of platinum group minerals pyroxene is a major gangue mineral. This study shows using zeta potential and ToF-SIMS analyses that when pyroxene is exposed to copper, nickel and/or calcium ions in solution at alkaline pHs a surface reaction occurs between the hydroxy species, in the case of copper and nickel, or divalent calcium ions and the pyroxene surface which influences the floatability of the pyroxene. Following exposure to copper and nickel ions at pH 9 addition of SIBX resulted in the pyroxene floating readily. It is also shown, in the case of copper, that the activating effect of the adsorbed copper hydroxy species can be reduced by the addition of complexing amines prior to SIBX. Proposals are made to explain these observations.

Jan 1, 2005

This paper examines the latest advances in mine drive and motor systems. In the last decade, the drive technology employed for large mine winders has migrated from the traditional dc technology to ac motors with cyclo convertor drives. Recent advances in pulse width modulation (PWM) drives have resulted in these being applied to large winder drives. While having many advantages for the winder system, the PWM drive must be carefully designed to ensure long-term reliable operation. When combined with induction motor technology, the PWM drive presents the ideal solution for winder drives. This paper examines the factors in choosing a suitable PWM drive for a winder installation. Factors under consideration include: winder duty cycle, drive rating restrictions, choice of power semiconductor device, cooling, and low speed operation.The cage induction motor is the motor of choice for large winder drives and has a number of advantages over the synchronous motor. The induction motor is ideally suited to integrated winder applications where the motor is built inside the friction drum, as installed at WMCÆs Olympic Dam site. The challenges of integrating the induction motor into the friction drum will be detailed, including: assembly, ventilation, air gap adjustment, and position sensors.

Jan 1, 2005

By Andrukaitis. E.

The increasing use of electronic equipment by the Canadian Forces has increased the importance of electric power. A power source that is packed with energy and yet light, small and durable is the common request of military users. However, this needs to be achieved while also addressing the requirements of safety, reliability and low temperature performance. The potential use of fuel cells in a military environment has become a possibility in several areas in the 21st century. Some examples of power source requirements and the materials related R&D required to give better, higher energy power systems in the future will be discussed.

Jan 1, 2005

By Z. Zhang

Aluminum boron carbide particulate reinforced composites have found new applications in nuclear industry due to their special capability to capture neutrons, Recently, Alcan successfully developed a liquid metal mixing process to fabricate Al¬B4C metal matrix composite instead of powder metallurgical technology. In the process, titanium is added into the composites to control interactions between boron carbide particulates and aluminum matrix, To understand the effects of titanium on the composites, the solidification microstructure of Al-16%B4C without or with titanium was examined by optical and electron microscopes. The results show that titanium can improve the uniformity of the particulate distribution within aluminum matrix if the titanium content in the composites is more than 0,5%, Furthermore, it is found that the layer with rich titanium on the surface of the particulates can limit the formation of AlB2 type compounds, which may greatly deteriorate the fluidity of the composites, In addition, it is also found that the amount of the reaction products in the composites increases with the increase of holding time. However, the rate of the increase is mitigated by the increase of the content of titanium in the composites. Besides, a procedure was proposed and implemented for the evaluation of uniformity of particulate distribution within aluminum matrix.

Jan 1, 2005

Two characteristics of the modern mining industry are that there is a skill shortage and that young professional people rise rapidly into highly responsible supervisory positions. With this responsibility comes the burden of identifying and managing health and safety risks. Without the benefit of a comprehensive health and safety training program, these young professionals may be putting both themselves and those under their supervision at risk. The Moura Mine explosions and the asbestos health disaster should not be just artifacts of history, but highly valued lessons that impress the need for comprehensive health and safety risk management strategies on young professionals. From the perspective of the former secretary of the Committee to implement the findings of the Moura (Disaster) Inquiry and as the former coordinator of the Coal Workers Health Scheme, key issues in occupational health and safety management systems are explored.

Jan 1, 2005